CN105384237B - A kind of autotrophic denitrification integrated apparatus for handling high ammonia-nitrogen wastewater and startup method - Google Patents

A kind of autotrophic denitrification integrated apparatus for handling high ammonia-nitrogen wastewater and startup method Download PDF

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CN105384237B
CN105384237B CN201510837241.6A CN201510837241A CN105384237B CN 105384237 B CN105384237 B CN 105384237B CN 201510837241 A CN201510837241 A CN 201510837241A CN 105384237 B CN105384237 B CN 105384237B
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line detector
nitrogen
plc
sludge
ammonia
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CN105384237A (en
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韩晓宇
张树军
常江
甘萍
甘一萍
阜崴
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Beijing Drainage Group Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
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Abstract

A kind of autotrophic denitrification integrated apparatus for handling high ammonia-nitrogen wastewater and startup method, are aerated, and be up equipped with the gas skirt in upside down funnel shape using the husky head of aeration.Device promotes sludge in gas skirt to flow up in aeration, meanwhile, covering outer sludge can be automatically into cover, and formation is circulated, and can reach more preferable mass transfer effect.Device is by being inoculated with a small amount of granule sludge, in the case where being accumulated without nitrous, gradually steps up aeration quantity, cultivates the granule sludge of more bigger more high load capacities.By 37d, ammonia nitrogen loading reaches 0.47Kg/ (m3.d), the average ammonia nitrogen loading of inoculation particle is reached.The present invention is applied to middle and high concentration ammonia-nitrogen sewage denitrogenation processing, simple in construction, and automaticity is high, and denitrification effect is good, and operating cost is low, the startup available for the autotrophic denitrification integration of culture processing high ammonia-nitrogen wastewater.

Description

A kind of autotrophic denitrification integrated apparatus for handling high ammonia-nitrogen wastewater and startup method
Technical field
The present invention relates to Water and Waste Water Engineering and field of environment engineering, more particularly, to it is a kind of handle high ammonia-nitrogen wastewater from Support denitrification integrated device and start method.
Background technology
Nitrate pollution is one of major reason that current body eutrophication phenomenon takes place frequently, at the same be also sewage disposal with again The crucial crux of raw reuse, how the nitrogen pollutant removed in sewage of economical and efficient turns into domestic and international experts and scholars and phase The study hotspot of government department is closed, what China promulgated for 2002《Urban wastewater treatment firm pollutant emission standard》(GB18918- 2002) require that all pollutant discharging unit's effluent qualities are less than 5mg/L for ammonia nitrogen in, total nitrogen is less than 15mg/L." 12 " its people warp In Ji and social development planning outline, the target of total amount of ammonia emission reduction 10% is clearly proposed.According to newly-increased the binding indicator, such as What realizes that the target of ammonia nitrogen emission reduction also needs to explore in practice.
It is nitration denitrification technique to apply most sewage water denitrification techniques at present, and the technique first passes through nitrifier by sewage Ammonium oxidation into nitrate nitrogen, then by denitrifying bacterium using organic matter by nitrate-nitrogen reduction be nitrogen.Traditional sewage water denitrification Complex operation, operating cost are high and produce a large amount of denitrification sludge, and for problem above, researcher have developed many Plant new denitrification process, such as short-cut nitrification and denitrification technique, synchronous nitration and denitrification technique, denitrifying phosphorus removal technique, anaerobism ammonia Oxidation technology etc., wherein anaerobic ammonia oxidation process are most economical efficient sewage water denitrification technique generally acknowledged at present, and its core is logical Cross anaerobic ammonia oxidizing bacteria using nitrite be electron acceptor by ammonia nitrogen direct oxidation as nitrogen, substantially reduce the anti-nitre of tradition nitrification The reaction process of chemical industry skill, anaerobic ammonia oxidation process has obvious advantage compared with traditional denitrification process:Anaerobic ammonia oxidizing bacteria Using nitrite as electron acceptor, organic carbon source is not needed in denitrification process;Nitrifying process only need to be by 1/2 ammonium oxidation to Asia Nitrate, about saves aeration energy consumption 50%;Anaerobic ammonia oxidizing bacteria is chemoautotrophic bacteria, and sludge yield is only to pass in denitrification process 10% or so of system nitration denitrification sludge yield, greatlys save follow-up sludge treatment expense;In addition, Anammox technology is also There is denitrifying load high, reduce greenhouse gas emission etc. a little.Anammox technology is applied in high ammonia-nitrogen wastewater processing, can be compared with Operating cost is significantly saved, significant economic benefit is produced.Anaerobic ammonia oxidation process can be reduced compared with traditional handicraft simultaneously The discharge of greenhouse gases nitrous oxide, environmental benefit is obvious.
Anaerobic ammonia oxidation process possesses many technical advantages, has been always domestic and international expert since the eighties in last century Study hotspot, but how by Anammox Technique Popularizing application always world-famous puzzle, anaerobic ammonia oxidizing bacteria grows from generation to generation Time is very long, is 11 days or so, and anaerobic ammonia oxidation process initial start stage sludge loss is serious, anaerobic ammonoxidation bacterium concentrating Culture is abnormal difficult, and the First Anammox engineering startup time is 3 years in the world, and the startup cycle of overlength limits the skill The Rapid Popularization application of art, in order to shorten the startup time of anaerobic ammonia oxidation process, need to improve reactor to anaerobic ammonia oxidizing bacteria Withholding ability, anaerobic ammonia oxidizing bacteria is obtained fast enriching, newest result of study shows to form particle in reactor dirty Mud or add Novel biofilm carrier can strengthened anaerobic ammoxidation bacterium withholding ability, but at present this technology still suffer from certain technology Problem, including:1. anaerobic ammonia oxidizing bacteria gas deliverability is stronger, therefore causes granule sludge not free settling, is easily lost in water outlet;② The simple biomembrane process anaerobic ammonia oxidizing bacteria biofilm time is longer, and microbial biomass is relatively low, and reactor for treatment ability is difficult to improve, And biomembrane is easy to fall off, storage and new construction inoculation are difficult.
To sum up, current Anammox Technique Popularizing application needs to include the problem of solution:How to be enriched with reactor The anaerobic ammonia oxidizing bacteria of high concentration;The potential loss risk of anaerobic ammonia oxidizing bacteria in reactor how is reduced, the steady of processing system is improved It is qualitative;How Anammox engineering inoculation difficulty, the reproducibility of enhancement engineering are reduced.Accordingly, it would be desirable to develop a kind of new Utilization Anammox technical finesse high ammonia-nitrogen wastewater device.
The content of the invention
It is an object of the present invention to provide it is a kind of efficiently, compact conformation, simple structure, automaticity it is higher, just In the autotrophic denitrification integrated apparatus and its startup method of the processing high ammonia-nitrogen wastewater of operation.Especially, whole denitrification reaction Complete, be aerated by using the husky head of aeration in a reaction unit, and be up equipped with gas skirt, by aeration Promoting in gas skirt sludge to flow up, cover outer sludge can be automatically into cover, and formation is circulated, the more preferable biography of acquisition Matter effect, further improves the utilization ratio of oxygen.
According to one embodiment of present invention, a kind of autotrophic denitrification integrated apparatus for handling high ammonia-nitrogen wastewater, whole dress Main body is put for sbr reactor device, agitator, aerator, thermometer be installed in device, and provided with pH value on-line detector, Dissolved oxygen on-line detector, nitrite nitrogen on-line detector, ammonia nitrogen on-line detector;Device be connected with inlet channel, drainage pipeline, Spoil disposal pipeline, air duct, overflow pipe, sampling pipe;Gas skirt is fixed on sbr reactor by the support of 3 composition annulars On the inwall of device;Electrically operated valve and intake pump are provided with the inlet channel;Electrically operated valve is motorized adjustment butterfly valve or rhombus Valve, and equipped with PLC, intake pump is provided with frequency-variable controller, and provided with PLC;The air duct is provided with gas Flowmeter body, electrically operated valve, and connect air blower;Gas flow is calculated as online gas flowmeter, and air blower is equipped with frequency conversion control Device processed, and provided with PLC;Thermometer, agitator, pH value on-line detector, dissolved oxygen in the reaction tank are examined online Instrument, nitrite nitrogen on-line detector, ammonia nitrogen on-line detector is surveyed to be connected with PLC progress signal.
According to one embodiment of present invention, aerator is made up of the husky head of 4 aerations of annular, and in aerator Top is equipped with gas skirt;The gas skirt is fixed on the inwall of sbr reactor device by the support of 3 composition annulars, in inversion Funnel-form.
According to one embodiment of present invention, bottom of device is connected by ring flange.
According to one embodiment of present invention, device is fixed on apparatus platform.
It is another object of the present invention to the autotrophic denitrification one for proposing the processing high ammonia-nitrogen wastewater described in a kind of basis Disguise the startup method put, starting step is:
Inoculation:The sludge of the sbr reactor device inoculation is granule sludge;Wherein, the accounting of granule sludge is 5%;
Water inlet:Influent quality is high ammonia nitrogen, the waste water of low ratio of carbon to ammonium, and flooding time is 30min, and inflow temperature control exists 20-30℃;
Reaction:After the completion of water inlet, agitator, aerator and thermometer can be automatically opened up by PLC;The air hose Road is provided with gas flowmeter, electrically operated valve, and connects air blower;Gas flow is calculated as online gas flowmeter, and air blower is equal Provided with frequency-variable controller, and provided with PLC;During running, pH value on-line detector, dissolved oxygen on-line detector, Asia Nitrate nitrogen on-line detector and ammonia nitrogen on-line detector carry out signal with PLC and are connected, in the accumulation without nitrite nitrogen Aeration quantity is suitably heightened down, ammonia nitrogen loading is improved, and the reaction time is 23h, and reaction temperature is controlled at 28-32 DEG C;
Precipitation:After reaction terminates, PLC can close agitator, aerator and thermometer automatically;
Draining:After precipitation terminates, PLC can automatically open up drainage pipeline and carry out draining;If sludge is excessive, can be manual Open spoil disposal pipeline and carry out spoil disposal;
It is idle:Standby time is preset value, after draining terminates, i.e., into fill phase.
According to one embodiment of present invention, standby time described in the start-up course is 0.
Beneficial effects of the present invention are mainly manifested in the following aspects:
1st, whole denitrification reaction is completed in a reaction unit, whole device compact conformation, simple structure, automation journey Degree is higher, be easy to operation.
2nd, the device is aerated using the husky head of aeration, and is up equipped with gas skirt.Device promotes gas collection in aeration Sludge is flowed up in cover, meanwhile, covering outer sludge can be automatically into cover, and formation is circulated, and can reach more preferable mass transfer effect Really, the utilization ratio of oxygen is further improved so that the aeration energy consumption of whole device is further reduced.At whole Anammox The startup time of reason system greatly shortens;
3rd, the device is inoculated with the returned sludge of sewage treatment plant of Gaobeidian City and the granule sludge of pilot scale, and granule sludge is higher Biomass concentration further increases anaerobic ammonia oxidizing bacteria total amount, can obtain higher nitric efficiency;And using in suspended sludge The short distance nitration effect of ammonia oxidation bacteria, completes nitrosation process;Whole device is fully by the advantage of suspended sludge and granule sludge Organically combine, by rational structure of reactor, realize the quick startup and stable operation of device.
Brief description of the drawings
Fig. 1 is a kind of schematic diagram for the autotrophic denitrification integrated apparatus for handling high ammonia-nitrogen wastewater in the present invention;
Fig. 2 is the 1-1 profiles in Fig. 1;
In figure:1- apparatus platforms;2- inlet channels;3- drainage pipelines;4- sampling pipes;5- overflow pipes;6- discharge pipelines Road;7- ring flanges;8- gas skirts;9- gas collection cover stents;10- aerators;11- air inlet pipe;12- thermometers;13- agitators;14- Sbr reactor device;15- motor-driven valves;16- intake pumps;17- flowmeters;18- air blowers;19-pH values on-line detector, 20- dissolved oxygens On-line detector, 21- nitrite nitrogens on-line detector, 22- ammonia nitrogen on-line detectors
Embodiment
The additional aspect and advantage of the present invention will be set forth in part in the description, and will partly become from the following description Obtain substantially, or recognize that embodiments of the invention are described in detail following with schema by the practice of the present invention.
The present invention is further illustrated below in conjunction with the accompanying drawings, but the present invention is not limited to following examples.
Embodiment 1
Referring to accompanying drawing 1, main body of the invention is a cylindrical sbr reactor device 14, always high 1400mm, radius 150mm, always Volume 100L, dischargeable capacity 90L.Agitator 13, aerator 10, thermometer 12 are installed in described device, and existed provided with pH value Line detector 19, dissolved oxygen on-line detector 20, nitrite nitrogen on-line detector 21, ammonia nitrogen on-line detector 22;Device is connected with Inlet channel 2, drainage pipeline 3, spoil disposal pipeline 6, air duct 11, overflow pipe 5, sampling pipe 4.The gas skirt 8 passes through 3 The support 9 of individual composition annular is fixed on the inwall of sbr reactor device 14.The He of electrically operated valve 15 is provided with the inlet channel 2 Intake pump 16.Electrically operated valve 15 is motorized adjustment butterfly valve or diamond valve, and equipped with PLC, intake pump 16 has VFC Device, and provided with PLC.The air duct 11 is provided with gas flowmeter 17, electrically operated valve 15, and connects air blower 18.Gas flowmeter 17 is online gas flowmeter, and air blower 18 is equipped with frequency-variable controller, and provided with PLC.It is described Thermometer 12, agitator 13, pH value on-line detector 19, dissolved oxygen on-line detector 20, nitrite nitrogen in reaction tank is online Detector 21, ammonia nitrogen on-line detector 22 carry out signal with PLC and are connected.Described device is simple in construction, automates journey Degree is high, and denitrification effect is good, and operating cost is low.Described device bottom is connected by ring flange 7, is easy to aeration tube 11 and aerator 10 Cleaning and replacing.Described device is fixed on apparatus platform 1, is easy to the carrying of sbr reactor device 14.
Present apparatus startup optimization in such a way:
Inoculation:The sludge that the sbr reactor device 14 is inoculated with is the returned sludge of sewage treatment plant of Gaobeidian City and of pilot scale Grain sludge.Wherein, it is preferred that the accounting of granule sludge is 5%, granule sludge is only accounted on a small quantity.
Water inlet:Influent quality is that municipal sewage plant's digested sludge is dehydrated high ammonia nitrogen, the waste water of low ratio of carbon to ammonium such as liquid, compared with Goodly, flooding time is 30min, and inflow temperature is controlled at 20-30 DEG C.Electrically operated valve 15 and water inlet are provided with inlet channel 2 Pump 16.Electrically operated valve 15 is motorized adjustment butterfly valve or diamond valve, and equipped with PLC, intake pump 16 has frequency-variable controller, and Provided with PLC.
Reaction:After the completion of water inlet, agitator 13, aerator 10 and thermometer 12 can be automatically opened up by PLC.It is described Air duct 11 is provided with gas flowmeter 17, electrically operated valve 15, and connects air blower 18.Gas flowmeter 17 is online gas Flowmeter, air blower 18 is equipped with frequency-variable controller, and provided with PLC.During running, pH value on-line detector 19, Dissolved oxygen on-line detector 20, nitrite nitrogen on-line detector 21 and ammonia nitrogen on-line detector 22 are believed with PLC Number connection, it is appropriate under the accumulation without nitrite nitrogen to heighten aeration quantity, ammonia nitrogen loading is improved, it is preferred that the reaction time is 23h, Reaction temperature is controlled at 28-32 DEG C.
Precipitation:After reaction terminates, PLC can close agitator 13, aerator 10 and thermometer 12 automatically.
Draining:After precipitation terminates, PLC can automatically open up drainage pipeline 3 and carry out draining.If sludge is too many, can hand Dynamic spoil disposal pipeline 6 of opening carries out appropriate spoil disposal.
It is idle:Standby time can voluntarily adjust.In the influence run for conditions such as reduction temperature to reaction, the start-up course Standby time is 0.After draining terminates, i.e., into fill phase.
The device is in a manner described after startup optimization, and by 37d, ammonia nitrogen loading reaches 0.47Kg/ (m3.d), reaches inoculation The average ammonia nitrogen loading of particle.The present invention can be used for the startup of the autotrophic denitrification integration of culture processing high ammonia-nitrogen wastewater.
Embodiments of the invention detailed above, the example of the embodiment is shown in the drawings, wherein from beginning to end Same or similar label represents same or similar element or the element with same or like function.Below with reference to attached The embodiment of figure description is exemplary, is only used for explaining the present invention, and is not considered as limiting the invention.
In the description of the invention, it is necessary to illustrate, unless otherwise clearly defined and limited, term " installation ", " phase Even ", " connection " should be interpreted broadly, for example, it may be being fixedly connected, be integrally connected or be detachably connected;Can be with It is mechanical connection or electrical connection or the connection of two element internals;Can be joined directly together, middle matchmaker can also be passed through Jie is indirectly connected to, for the ordinary skill in the art, can understand that the specific of above-mentioned term contains as the case may be Justice.
Although an embodiment of the present invention has been shown and described, it will be understood by those skilled in the art that:Not In the case of departing from the principle and objective of the present invention a variety of change, modification, replacement and modification can be carried out to these embodiments, this The scope of invention is limited by claim and its equivalent.

Claims (1)

1. a kind of startup method for the autotrophic denitrification integrated apparatus for handling high ammonia-nitrogen wastewater, whole device main body is a SBR Agitator (13), aerator (10), thermometer (12) are installed in reactor (14), device, and provided with pH value on-line detector (19), dissolved oxygen on-line detector (20), nitrite nitrogen on-line detector (21), ammonia nitrogen on-line detector (22);Device is connected with Inlet channel (2), drainage pipeline (3), spoil disposal pipeline (6), air duct (11), overflow pipe (5), sampling pipe (4);
It is characterized in that:Gas skirt (8) is fixed on the inwall of sbr reactor device (14) by the support (9) of 3 composition annulars; Electrically operated valve (15) and intake pump (16) are provided with the inlet channel (2);Electrically operated valve (15) be motorized adjustment butterfly valve or Diamond valve, and equipped with PLC, intake pump (16) is provided with frequency-variable controller, and provided with PLC;The air duct (11) gas flowmeter (17), electrically operated valve (15) are provided with, and connects air blower (18);Gas flowmeter (17) is online gas Flowmeter body, air blower (18) is equipped with frequency-variable controller, and provided with PLC;Thermometer (12) in the reaction tank, Agitator (13), pH value on-line detector (19), dissolved oxygen on-line detector (20), nitrite nitrogen on-line detector (21), ammonia Nitrogen on-line detector (22) carries out signal with PLC and is connected;
Aerator (10) is made up of the husky head of 4 aerations of annular, and is equipped with gas skirt (8) in the top of aerator (10); The gas skirt (8) is fixed on the inwall of sbr reactor device (14) by the support (9) of 3 composition annulars, in upside down funnel Shape;
Bottom of device is connected by ring flange (7);
Device is fixed on apparatus platform (1);
The starting step of the startup method of the autotrophic denitrification integrated apparatus of above-mentioned processing high ammonia-nitrogen wastewater is:
Inoculation:The sludge of sbr reactor device (14) inoculation is granule sludge;Wherein, the accounting of granule sludge is 5%;
Water inlet:Influent quality is high ammonia nitrogen, the waste water of low ratio of carbon to ammonium, and flooding time is 30min, and inflow temperature is controlled in 20-30 ℃;
Reaction:After the completion of water inlet, agitator (13), aerator (10) and thermometer (12) can be automatically opened up by PLC; During operation, pH value on-line detector (19), dissolved oxygen on-line detector (20), nitrite nitrogen on-line detector (21) and ammonia nitrogen On-line detector (22) carries out signal with PLC and is connected, and suitably heightens aeration quantity under the accumulation without nitrite nitrogen, carries High ammonia nitrogen loading, the reaction time is 23h, and reaction temperature is controlled at 28-32 DEG C;
Precipitation:After reaction terminates, PLC can close agitator (13), aerator (10) and thermometer (12) automatically;
Draining:After precipitation terminates, PLC can automatically open up drainage pipeline (3) and carry out draining;If sludge is excessive, beat manually The mud pipeline (6) that begins to rehearse carries out spoil disposal;
It is idle:Standby time is preset value, after draining terminates, i.e., into fill phase;
Standby time described in the start-up course is 0.
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CN105800776B (en) * 2016-04-14 2019-05-21 湖南大学 One kind reducing N in sewage disposal process2The FNA effluent technique of O discharge
CN106186308B (en) * 2016-08-31 2022-07-12 北京城市排水集团有限责任公司 Integrated anaerobic ammonia oxidation granular sludge denitrification device and control method thereof
CN107265639B (en) * 2017-07-01 2020-04-28 清华大学 Integrated split-phase combined wastewater denitrification device and wastewater denitrification method

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