CN205973971U - Integration anaerobic ammonium oxidation granular sludge denitrification device - Google Patents

Integration anaerobic ammonium oxidation granular sludge denitrification device Download PDF

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CN205973971U
CN205973971U CN201621024978.2U CN201621024978U CN205973971U CN 205973971 U CN205973971 U CN 205973971U CN 201621024978 U CN201621024978 U CN 201621024978U CN 205973971 U CN205973971 U CN 205973971U
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ammonium oxidation
granular sludge
anaerobic ammonium
reactor
oxidation granular
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韩晓宇
张树军
阜崴
孟春霖
彭永臻
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Beijing Drainage Group Co Ltd
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Beijing Drainage Group Co Ltd
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Abstract

The utility model relates to an integration anaerobic ammonium oxidation granular sludge denitrification device, including high -ammonia nitrogen waste water water tank and integration anaerobic ammonium oxidation granular sludge reactor, integration anaerobic ammonium oxidation granular sludge reactor is provided with agitator and on -line monitoring subassembly, the on -line monitoring subassembly is including the level gauge, pH on -line monitoring appearance, DO on -line monitoring appearance and the ORP on -line monitoring appearance that link to each other with the communication of PLC controller respectively, the bottom of the pool of integration anaerobic ammonium oxidation granular sludge reactor still is provided with aeration equipment. Does it restrain through low DO in the controlled reaction ware and FA and realizes sludge digestion liquid short -cut nitrification through the integrated biomembrane biofilm reactor's that the inoculation operational effect is stable mixed mud and anaerobic ammonium oxidation anaerobic reactor's granular sludge anaerobic ammonium oxidation through pH, ORP in the controlled reaction ware, realizes anaerobic ammonium oxidation granular sludge formation and multiplication simultaneously to improve the device and nitrify the load, reduce area, the ability of the anti low -temperature impact of reinforcing system.

Description

Integral anaerobic ammonium oxidation granular sludge nitrogen rejection facility
Technical field
This utility model is related to technical field of biological sewage treatment, more particularly, to a kind of anaerobism ammonia processing high ammonia-nitrogen wastewater Oxidation autotrophic denitrification device and its control method, this device and control method are applied to high ammonia-nitrogen wastewater denitrogenation processing.
Background technology
In recent years China's body eutrophication phenomenon takes place frequently, and inland river water pollution is serious, and wherein nitrate pollution is to lead to One of principal element of body eutrophication, therefore, up-to-date ten, water of appearance《Water prevention and cure of pollution plan》In be distinctly claimed " select There are the pollutant such as the total nitrogen of prominent impact on quality of water environment, basin, the constraint of regional pollution thing prediction emission are included in research Property index system.According to newly-increased the binding indicator, how high-efficiency and economic realizes the target of ammonia nitrogen reduction of discharging also needs to visit in practice Rope.
The most sewage water denitrification technique of application is nitration denitrification technique at present, and this technique first passes through nitrifier by sewage Ammonium oxidation become nitrate nitrogen, then using Organic substance, nitrate-nitrogen reduction is nitrogen by denitrifying bacterium.Traditional sewage water denitrification Complex operation, operating cost are high and produce a large amount of denitrification mud, and for problem above, research worker have developed many Plant new denitrification process, such as short-cut nitrification and denitrification technique, synchronous nitration and denitrification technique, denitrifying phosphorus removal technique, anaerobism ammonia Oxidation technology etc., wherein anaerobic ammonia oxidation process are the most economical efficient sewage water denitrification technique generally acknowledged at present, and its core is logical Cross anaerobic ammonia oxidizing bacteria with nitrite for electron acceptor by ammonia nitrogen direct oxidation as nitrogen, substantially reduce tradition nitrify anti-nitre The reaction process of metallization processes, anaerobic ammonia oxidation process has obvious advantage compared with traditional denitrification process:Anaerobic ammonia oxidizing bacteria With nitrite as electron acceptor, in denitrification process, do not need organic carbon source;Nitrifying process only need to be by 1/2 ammonium oxidation to Asia Nitrate, about saves aeration energy consumption 50%;Anaerobic ammonia oxidizing bacteria is chemoautotrophic bacteria, and in denitrification process, sludge yield is only and passes The 10% about of system nitration denitrification sludge yield, greatlys save follow-up sludge treatment expense;In addition, Anammox technology is also There is the advantages of denitrifying load height, minimizing greenhouse gas emission.Anammox technology is applied in high ammonia-nitrogen wastewater process, can be relatively Significantly save operating cost, produce significant economic benefit.Anaerobic ammonia oxidation process can reduce compared with traditional handicraft simultaneously The discharge of greenhouse gases nitrous oxide, environmental benefit is obvious.
It is sensitive, easily that the subject matter that at present Anammox technology application faces has strain to be difficult enrichment, environmental condition It is suppressed, be therefore typically employed in form granule sludge in reactor or add Novel biofilm carrier and carry out reinforced anaerobic ammonia Oxidation bacteria hold ability of staying, but the simple biomembrane process anaerobic ammonia oxidizing bacteria biofilm time is longer, and microbial biomass is relatively low, reaction Device disposal ability is difficult to improve, and biomembrane is easy to fall off, is difficult storage and new construction inoculation.Although pure granule sludge technique is relatively Biomembrane process has more advantages, but because granule sludge culture is more difficult, reaction condition requirement is harsher, accordingly, it would be desirable to Develop a kind of new integral anaerobic ammonium oxidation granular sludge nitrogen rejection facility, under the conditions of effective reaction controlling, realize granule The formation of mud and multiplication.
Utility model content
The purpose of this utility model is exactly to solve above-mentioned technical problem it is proposed that a kind of integral anaerobic ammoxidation Grain sludge denitrification device, it passes through to inoculate the stable mixing sludge of integral biological membrane biomembrane reactor of operational effect and detest The granule sludge of anaerobic ammonium oxidation anaerobic reactor, realizes sludge-digestion liquid short distance by controlling the low DO and FA suppression in reactor Nitration-anaerobic ammoxidation, that is, the rate of rise realizing AOB is more than the rate of rise of NOB, so that NOB is constantly fallen so that being by elutriation In system, ANAMMOX replaces NOB becomes dominant microflora, passes through to control pH value, ORP value and water discharge time in reactor simultaneously, realizes Anaerobic ammonium oxidation granular sludge is formed and multiplication, thus improving device nitrification load, reduces floor space, strengthening system low-temperature resistance The ability of impact.
In order to achieve the above object, this utility model adopts the following technical scheme that realization:
Integral anaerobic ammonium oxidation granular sludge nitrogen rejection facility, this device includes high ammonia-nitrogen wastewater water tank and integral anaerobic Ammonium oxidation granular sludge reactor;Wherein, high ammonia-nitrogen wastewater water tank passes through intake pump and integral anaerobic ammonium oxidation granular sludge The inlet valve of reactor is connected;In integral anaerobic ammonium oxidation granular sludge reactor, the mixing sludge of inoculation comes from one Change biofilm reactor and Anammox anaerobic reactor;It is provided with integral anaerobic ammonium oxidation granular sludge reactor and stir Mix device and on-line monitoring assembly;On-line monitoring assembly includes liquidometer, the pH on-line monitoring being connected respectively with PLC communication Instrument, DO on-line computing model and ORP on-line computing model;The at the bottom of pond of integral anaerobic ammonium oxidation granular sludge reactor is additionally provided with exposure Device of air, this aerator includes punching aeration tube and the air compressor being connected with punching aeration tube by connecting tube, connects Gas control valve is additionally provided with pipe;Drain valve is additionally provided with described integral anaerobic ammonium oxidation granular sludge reactor and takes Sample pipe;Described gas control valve and drain valve are all communicated to connect with PLC.
As the optimization further of such scheme, high ammonia-nitrogen wastewater water tank is provided with overflow pipe and blow-down pipe, overflow pipe It is arranged on the case top of high ammonia-nitrogen wastewater water, blow-down pipe is arranged on the bottom of high ammonia-nitrogen wastewater water tank;Be also associated with blow-down pipe with The atmospheric valve of PLC communication connection;It is additionally provided with heating rod in the casing of high ammonia-nitrogen wastewater water tank.
As the optimization further of such scheme, described connecting tube is additionally provided with the gas with PLC communication connection Flowmeter body;In integral anaerobic ammonium oxidation granular sludge reactor, the top of described aerator is additionally provided with water conservancy diversion dress Put;The at the bottom of pond of described integral anaerobic ammonium oxidation granular sludge reactor is additionally provided with emptying pipe;
As the optimization further of such scheme, described guiding device is horn-like deflector;In high ammonia-nitrogen wastewater water tank Casing in be additionally provided with and control, with heating rod, the temperature control meter that is connected, be provided with wastewater temperature in high ammonia-nitrogen wastewater water tank and sense Device, temperature control meter controls communication connection with wastewater temperature sensor, and temperature control meter is also communicated to connect with PLC.
Operation process principle of the present utility model:By in high ammonia-nitrogen wastewater injecting reactor, during water inlet sewage with Mud in reactor is fully contacted, and after water inlet end, opens air compressor and blasts air into reactor, be in reactor Mixing sludge provide biochemical reaction needed for oxygen, turn on agitator strengthen mixed effect, under aerobic conditions, granule sludge Organic substance in sewage is converted into carbon dioxide and water, the ammonium oxidation in sewage is nitrite nitrogen by ammonia oxidation bacteria simultaneously, DO, pH and ORP in reactor is controlled by PLC, under micro-oxygen conditions, anaerobic ammonia oxidizing bacteria using nitrite nitrogen is Electron acceptor, ammonium oxidation is nitrogen, produces a small amount of nitrate nitrogen simultaneously, when ammonia nitrogen concentration is reduced to below 1.0mg/L, stop Only air compressor and agitator, reaction terminates, and enters precipitate phase, after the completion of precipitation arranges upper clear supernate as final outflow water Go out, complete this circulation.
With the prior art phase such as traditional high-ammonia-nitrogen sewage handling process and conventional Anammox denitrification treatment process This utility model has the advantage that ratio:
1) whole denitrification reaction completes in a reaction unit, whole device compact conformation, simple structure, automatization's journey Degree is higher, be easy to operation.
2) make full use of the ecosystem characterization of ammonia oxidation bacteria and anaerobic ammonia oxidizing bacteria, create the micro- oxygen environment being suitable for its growth, By envirment factor stimulation, forming outer layer is ammonia oxidation bacteria, and the internal granule sludge for anaerobic ammonia oxidizing bacteria is prevented effectively from The inhibitory action to anaerobic ammonia oxidizing bacteria for the too high dissolved oxygen, sets up good Tiny ecosystem.
3) cultivate anaerobic ammonium oxidation granular thing mud in single-reactor, it is to avoid traditional anaerobic ammonia oxidation process mud Be easy to run off, anaerobic ammonia oxidizing bacteria biology the low defect of total amount.
4) the more traditional denitrification process of integral anaerobic ammonia oxidation process can save about 50% aeration energy consumption, and granule sludge Technique is not subject to dissolved oxygen limit value, reactor sludge concentration high, makes whole device have higher denitrifying load, saves and takes up an area and build It is set as this.
Brief description
Fig. 1 is this utility model integral anaerobic ammonium oxidation granular sludge nitrogen rejection facility structural scheme of mechanism.
In figure 1 is high ammonia-nitrogen wastewater water tank;2 integrated anaerobic ammonium oxidation granular sludge reactors;3 is overflow pipe;4 are Heating rod;5 is emptying valve;6 is blow-down pipe;7 is intake pump;8 is drain valve;9 is stirring paddle;10 is guiding device;11 are Probe tube;12 is emptying pipe;13 is punching aeration tube;14 is tolerance effusion meter;15 is gas control valve;16 is air compression Machine;17 is liquidometer;18 is pH on-line computing model;19 is DO on-line computing model;20 is ORP on-line computing model;21 is water intaking valve Door;22 is PLC.
Specific embodiment
With reference to the accompanying drawings and examples this utility model is described further:As shown in figure 1, integral anaerobic ammonia oxygen Change granule sludge nitrogen rejection facility and be provided with the high ammonia-nitrogen wastewater water tank 1 of open-like shape, integral anaerobic ammonium oxidation granular sludge reactor 2;
A kind of integral anaerobic ammonium oxidation granular sludge nitrogen rejection facility, this device includes high ammonia-nitrogen wastewater water tank 1 and one Change anaerobic ammonium oxidation granular sludge reactor 2;Wherein, high ammonia-nitrogen wastewater water tank passes through intake pump 7 and integral anaerobic ammoxidation The inlet valve 21 of granular sludge reactor is connected;The mixing sludge of inoculation in integral anaerobic ammonium oxidation granular sludge reactor Come from combined biofilm reactor and Anammox anaerobic reactor;Integral anaerobic ammonium oxidation granular sludge reactor Inside it is provided with agitator 9 and on-line monitoring assembly;On-line monitoring assembly includes the liquid level being connected respectively with PLC 22 communication Meter 17, pH on-line computing model 18, DO on-line computing model 19 and ORP on-line computing model 20;Integral anaerobic ammonium oxidation granular sludge The at the bottom of pond of reactor is additionally provided with aerator, and this aerator includes punching aeration tube 13 and passes through to be connected with punching aeration tube The air compressor 16 that pipe is connected, connecting tube is additionally provided with gas control valve 15;Described integral anaerobic ammonium oxidation granular is dirty Drain valve 8 and probe tube 11 are additionally provided with mud reactor;Described gas control valve and drain valve all with PLC communication link Connect.Overflow pipe 3 and blow-down pipe 6 are provided with high ammonia-nitrogen wastewater water tank, overflow pipe is arranged on the case top of high ammonia-nitrogen wastewater water, emptying Pipe is arranged on the bottom of high ammonia-nitrogen wastewater water tank;Atmospheric valve 5 with PLC communication connection is also associated with blow-down pipe;? It is additionally provided with heating rod 4 in the casing of high ammonia-nitrogen wastewater water tank.It is additionally provided with described connecting tube and PLC communication connection Gas flowmeter 14;In integral anaerobic ammonium oxidation granular sludge reactor, the top of described aerator is additionally provided with Guiding device 10;The at the bottom of pond of described integral anaerobic ammonium oxidation granular sludge reactor is additionally provided with emptying pipe 12;Described water conservancy diversion Device is horn-like deflector;The casing of high ammonia-nitrogen wastewater water tank is additionally provided with and controls, with heating rod, the temperature control meter being connected, It is provided with wastewater temperature sensor, temperature control meter controls communication connection, temperature control with wastewater temperature sensor in high ammonia-nitrogen wastewater water tank Meter is also communicated to connect with PLC.
The above-mentioned description to embodiment is to be understood that for ease of those skilled in the art and apply this reality With new.Person skilled in the art obviously easily can make various modifications to these embodiments, and here is said Bright General Principle is applied in other embodiment without through performing creative labour.Therefore, this utility model is not limited to this In embodiment, those skilled in the art according to announcement of the present utility model, without departing from changing that this utility model category is made Entering and change all should be within protection domain of the present utility model.

Claims (4)

1. a kind of integral anaerobic ammonium oxidation granular sludge nitrogen rejection facility it is characterised in that:This device includes high ammonia-nitrogen wastewater water Case (1) and integral anaerobic ammonium oxidation granular sludge reactor (2);Wherein, high ammonia-nitrogen wastewater water tank passes through intake pump (7) and The inlet valve (21) of body anaerobic ammonium oxidation granular sludge reactor is connected;Integral anaerobic ammonium oxidation granular sludge reactor The mixing sludge of middle inoculation comes from combined biofilm reactor and Anammox anaerobic reactor;Integral anaerobic ammonia oxygen Change in granular sludge reactor and be provided with agitator (9) and on-line monitoring assembly;On-line monitoring assembly include respectively with PLC control Liquidometer (17), pH on-line computing model (18), DO on-line computing model (19) and ORP on-line computing model that device (22) communication is connected (20);The at the bottom of pond of integral anaerobic ammonium oxidation granular sludge reactor is additionally provided with aerator, and this aerator includes punching Aeration tube (13) and the air compressor (16) being connected by connecting tube with punching aeration tube, connecting tube are additionally provided with gas and adjust Section valve (15);Drain valve (8) and probe tube (11) are additionally provided with described integral anaerobic ammonium oxidation granular sludge reactor;Institute State gas control valve and drain valve is all communicated to connect with PLC.
2. a kind of integral anaerobic ammonium oxidation granular sludge nitrogen rejection facility according to claim 1 it is characterised in that:High ammonia Overflow pipe (3) and blow-down pipe (6) are provided with nitrogen waste water water tank, overflow pipe is arranged on the case top of high ammonia-nitrogen wastewater water, blow-down pipe It is arranged on the bottom of high ammonia-nitrogen wastewater water tank;Atmospheric valve (5) with PLC communication connection is also associated with blow-down pipe;? It is additionally provided with heating rod (4) in the casing of high ammonia-nitrogen wastewater water tank.
3. a kind of integral anaerobic ammonium oxidation granular sludge nitrogen rejection facility according to claim 1 and 2 it is characterised in that: Gas flowmeter (14) with PLC communication connection is additionally provided with described connecting tube;In integral anaerobic ammoxidation In grain sewage sludge reactor, the top of described aerator is additionally provided with guiding device (10);Described integral anaerobic ammoxidation The at the bottom of pond of grain sewage sludge reactor is additionally provided with emptying pipe (12).
4. a kind of integral anaerobic ammonium oxidation granular sludge nitrogen rejection facility according to claim 3 it is characterised in that:Described Guiding device is horn-like deflector;The casing of high ammonia-nitrogen wastewater water tank is additionally provided with and controls, with heating rod, the temperature control being connected Meter, is provided with wastewater temperature sensor in high ammonia-nitrogen wastewater water tank, temperature control meter and wastewater temperature sensor control communication connection, temperature Control meter is also communicated to connect with PLC.
CN201621024978.2U 2016-08-31 2016-08-31 Integration anaerobic ammonium oxidation granular sludge denitrification device Active CN205973971U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106186308A (en) * 2016-08-31 2016-12-07 北京城市排水集团有限责任公司 Integral anaerobic ammonium oxidation granular sludge nitrogen rejection facility and control method thereof
CN108178302A (en) * 2018-01-05 2018-06-19 北京工业大学 Quickly started based on azanol and the integrated apparatus and method of stably maintaining shortcut nitrification/Anammox
CN109319929A (en) * 2018-12-14 2019-02-12 湖南军信环保股份有限公司 A kind of novel integrated Anammox reaction system

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106186308A (en) * 2016-08-31 2016-12-07 北京城市排水集团有限责任公司 Integral anaerobic ammonium oxidation granular sludge nitrogen rejection facility and control method thereof
CN106186308B (en) * 2016-08-31 2022-07-12 北京城市排水集团有限责任公司 Integrated anaerobic ammonia oxidation granular sludge denitrification device and control method thereof
CN108178302A (en) * 2018-01-05 2018-06-19 北京工业大学 Quickly started based on azanol and the integrated apparatus and method of stably maintaining shortcut nitrification/Anammox
CN108178302B (en) * 2018-01-05 2021-02-05 北京工业大学 Device and method for integrating rapid start and stable maintenance of shortcut nitrification/anaerobic ammonia oxidation based on hydroxylamine
CN109319929A (en) * 2018-12-14 2019-02-12 湖南军信环保股份有限公司 A kind of novel integrated Anammox reaction system

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