CN105383197B - A kind of printing process of quartz - Google Patents

A kind of printing process of quartz Download PDF

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Publication number
CN105383197B
CN105383197B CN201510653596.XA CN201510653596A CN105383197B CN 105383197 B CN105383197 B CN 105383197B CN 201510653596 A CN201510653596 A CN 201510653596A CN 105383197 B CN105383197 B CN 105383197B
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Prior art keywords
bottom plate
ink
quartz
plank
printing
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CN105383197A (en
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黎雄杰
温国雄
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Guangdong Legend New Materials Co.,Ltd.
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FOSHAN BLUE SEA QUARTZ STONE Co Ltd
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Publication of CN105383197A publication Critical patent/CN105383197A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/0041Digital printing on surfaces other than ordinary paper
    • B41M5/007Digital printing on surfaces other than ordinary paper on glass, ceramic, tiles, concrete, stones, etc.
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • B41M7/009After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using thermal means, e.g. infrared radiation, heat

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  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Thermal Sciences (AREA)
  • Toxicology (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Printing Methods (AREA)
  • Finishing Walls (AREA)

Abstract

The invention discloses a kind of printing processes of quartz, include the following steps:Select bottom plate:Bottom plate pattern is selected according to the gloss, particle diameter and form and aspect of simulation objectives plank;Heat bottom plate:Ground is placed in infrared heating continuous tunnel furnace and is heated to 90 DEG C, to remove the moisture in bottom plate gap;Colored drawing prints:Ink is printed on bottom plate by digital coloured drawing printing machine;Heating in vacuum is permeated:The bottom plate for being printed with ink is placed in vacuum heater, is vacuumized, and is heated to 200 DEG C, vacuum infiltration to 0.5-0.8mm, the plank painted;Surface hardening treatment:With nano-milled material on the plank of colouring polishing grinding, be sealed, cure process.Using the present invention, ink adhesive force can be improved, the fidelity of product is high, and hardness is high, anti-pressure and abrasion-proof.

Description

A kind of printing process of quartz
Technical field
The present invention relates to field of stone processing more particularly to a kind of printing processes of quartz.
Background technology
Quartz is a kind of physical property and the sufficiently stable mineral resources of chemical property, is had rich in color, fine and close Non-porous, the advantages that hardness is high, nontoxic radiationless, it is usually used in public building and house decoration.It is various to product however as market Change demand is growing, and need to be further improved to the pattern and color processing technology of quartz.Marble is colorful, and tone is more Sample, none is identical for decorative pattern, is the building and ornament materials of top grade, but marble is expensive, ordinary consumer is difficult to lower Price obtains multifarious selection.For this purpose, the prior art starts to try to produce the lithotome or artificial stone of Scagliola Material.
Chinese patent CN1631679A discloses a kind of method for printing of enameling in lithotome, includes the following steps:The One, plane polishing processing is carried out to the surface of plate shaped building stone;Second, make at bottoming in the stone surface pigment for completing polishing Reason;Original rough sketch is transferred on the surface of plate shaped building stone by third using screen printing method.It is at low cost although simple for process Honest and clean, technological requirement is low, but case hardness is inadequate, pattern, assortment list one, and not abundant enough, printing precision is poor, artificial stone effect Difference.
Chinese patent CN102765287B discloses a kind of water transfer preparation process applied to artificial stone, is shifted and is printed using water Pattern on water transfer film is imprinted in artificial stone by brush technology, ink is adsorbed by the priming paint on artificial stone, although such side Stone material colour image made from method is changeable, but color is unnatural, cannot sanding and polishing repeatedly, cleaning is difficult, poor adhesive force, at Product rate is low.
Invention content
Technical problem to be solved by the present invention lies in provide a kind of printing process of quartz, ink attachment can be improved The fidelity of power, product is high, and hardness is high, anti-pressure and abrasion-proof.
In order to solve the above technical problem, the present invention provides a kind of printing processes of quartz, include the following steps:
Select bottom plate:Bottom plate pattern is selected according to the gloss, particle diameter and form and aspect of simulation objectives plank;
Heat bottom plate:Ground is placed in infrared heating continuous tunnel furnace and is heated to 90 DEG C, to remove the moisture in bottom plate gap;
Colored drawing prints:Ink is printed on bottom plate by digital coloured drawing printing machine;
Heating in vacuum is permeated:The bottom plate for being printed with ink is placed in vacuum heater, is vacuumized, and is heated to 200 DEG C, vacuum infiltration to 0.5-0.8mm, the plank painted;
Surface hardening treatment:With nano-milled material on the plank of colouring polishing grinding, be sealed, cure process.
As the improvement of said program, infrared heating continuous tunnel furnace is divided to two sections of temperature controls, the first temperature control segment temperature to control in 55-65 In DEG C, the second temperature control segment temperature controls in 85-95 DEG C, transmission speed 0.8-1.2m/min.
As the improvement of said program, the colored drawing print steps are further comprising the steps of:
Pattern is printed on referral material by digital coloured drawing printing machine;
Referral material printing surface is attached on the bottom plate of heating again, ink is made to be attached on bottom plate.
As the improvement of said program, referral material is customization paper, and front is paper material, and the back side is seal coating.
As the improvement of said program, the ink includes that following raw material is made:Inorganic pigment, low viscosity resin, esters Solvent and auxiliary agent.
As the improvement of said program, nano-milled material is mainly made of crystal, lotion, auxiliary agent, and the crystal is main Ingredient is silica.
As the improvement of said program, a diameter of 40-80nm of the crystal.
Implement the embodiment of the present invention, has the advantages that:
Printing process of the present invention carries out heating removing by infrared heating continuous tunnel furnace to the quartz bottom plate before printing Ink moisture, and being permeated after printing by heating in vacuum, make quartz bottom plate micropore and crackle and the ink of gasification it Between form pressure difference, ink can enter the inside of bottom plate easily along micropore and crackle, and ink adhesive force is very strong, and product can Polishing grinding is non-discolouring repeatedly.And the printing precision of product is high, and pattern is abundant, and fidelity is high, solves the surface of the prior art Hardness is inadequate, and pattern, assortment list one, printing precision is poor, and artificial stone effect is poor, poor adhesive force, the low equal technical barriers of yield rate.
Description of the drawings
Fig. 1 is a kind of flow chart of the printing process of quartz of the present invention.
Specific implementation mode
To make the object, technical solutions and advantages of the present invention clearer, the present invention is made into one below in conjunction with attached drawing Step ground detailed description.
As shown in Figure 1, a kind of printing process of quartz of the present invention, includes the following steps:
S100 selects bottom plate:Bottom plate pattern is selected according to the gloss, particle diameter and form and aspect of simulation objectives plank.
Such as abundant stone material of jade, marble decorative pattern pattern, it is suitable to need to select when being emulated using quartz Bottom plate is to reach the gloss, particle diameter and form and aspect of simulation objectives plank.
For example, it is desired to when the plank of the high jade stone pattern reason of quartz, the quartz bottom plate gloss accordingly selected is bloom 90 Degree, range estimation are pure white without granule crystal, form and aspect.
For another example, when quartz height being needed to imitate the plank of hole jade line, the quartz bottom plate gloss that accordingly selects is 50 degree, particle Crystal diameter is 0.3MM or so, form and aspect are light color.
Thus fundamentally close to the gloss of target plate, particle diameter and form and aspect, to improve the emulation journey of quartz Degree.
S101 heats bottom plate:Ground is placed in infrared heating continuous tunnel furnace and is heated to 90 DEG C, to remove the water in bottom plate gap Point.
Quartz hardness is high, and compactness is good, if but amplifying observation can find the surface of plank there are fine and closely woven micropore and Crackle, quartzite slate are stored by long-term, and the moisture in air can gradually penetrate into these micropores and crackle, and be not easy again It releases.And ink used in the present invention is oily ink, it is immiscible with water therefore aqueous in such as micropore and crackle of quartz Point, then ink is difficult to infiltrate into micropore and crackle in printing process, adheres to so as to cause the ink on quartzite slate surface Force difference is not easy to produce qualified products.
Quartzite slate will not be deformed in 200 DEG C of temperature below, and heat conduction, the heat dissipation of plank can provide longer constant temperature slowly Time, this is we provided the heatable condition of plank.The present invention is discharged by way of heating as possible before printing as a result, The moisture being mixed in micropore and crackle.Existing quartz printing technology such as silk-screen printing, water trans-printing, heat transfer print The characteristics of brush, numerial code spray drawing, pad pasting spray painting etc. are due to technique is all not required to heating, drying processing to remove quartzite slate micropore With the moisture in crackle, and the present invention is conducive to the infiltration of ink by increasing heating stepses.
Preferably, the present invention carries out the heating to bottom plate using infrared heating continuous tunnel furnace.Infrared dehydration is to utilize Electromagnetic radiation heat pass principle, conduct heat in direct mode and achieve the purpose that heat drying object, have penetration power, can inside and outside simultaneously Heating.It can be also easily removed so even being moisture a small amount of in quartzite slate fine and closely woven micropore and crackle.
More preferably, infrared heating continuous tunnel furnace is divided to two sections of temperature controls, the first temperature control segment temperature to control in 55-65 DEG C, the second control Temperature section temperature controls in 85-95 DEG C, transmission speed 0.8-1.2m/min.Specifically, the tunnel of infrared heating continuous tunnel furnace is total Long 10m, wherein the first temperature control segment length 3m, the second temperature control segment length 7m.When heating, quartz bottom plate is from the first temperature control segment compared with low temperature It is sent to the second temperature control segment of high temperature, by the heating, drying of about 10min, can remove the moisture of 80-95% in bottom plate.
S102, colored drawing printing:Ink is printed on bottom plate by digital coloured drawing printing machine.
Digital coloured drawing machine breaches digital printing technical bottleneck, realize truly one rise print, need not plate-making, Full color image is once completed.The printing effect of extremely low printing cost and high quality is more convenient than conventional printing system economy, seldom System investments, biometrics mode of operation and limited space hold, make system have bigger market prospects.It is to tradition The preferably supplement of printing, is the regeneration product of conventional presses.Generally applicable printing different materials such as quartz, hilllock stone, wood-based plate Material, calcium silicate board, density board or plastic plate.
In existing quartzite slate, some quartz particles are smaller, and it is containing large-sized stone also to have considerable part Diamond stone particle, when colored drawing prints, ink is difficult to form point-to-point attachment on big quartz particle, to occur poly- ink or The situation of ink is dissipated, the pattern fidelity and aesthetic feeling of obtained product are severely impacted.
The characteristics of for quartzite slate, for the smaller quartzite slate of particle, S102 steps of the present invention can lead to It crosses digital coloured drawing printing machine and ink is directly printed on backplate surface according to patterns, you can complete print steps.
For the quartzite slate that particle is larger, colored drawing print steps of the present invention are further comprising the steps of:
Pattern is printed on referral material by digital coloured drawing printing machine;
Referral material printing surface is attached on the bottom plate of heating again, ink is made to be attached on bottom plate.
It should be noted that the referral material is a kind of specific customization paper, front(Printing surface)It is paper material, the back side It is seal coating, 280 DEG C of referral material requirements heatproof.
S103, heating in vacuum infiltration:The bottom plate for being printed with ink is placed in vacuum heater, is vacuumized, and is heated To 200 DEG C, vacuum infiltration to 0.5-0.8mm, the plank painted.
The backplate surface printed by digital coloured drawing spreads one layer of ink, but since quartz compactness is strong, micropore is fine and closely woven, Ink is difficult to be attached on quartz, therefore the present invention is to solve this technical problem, by the bottom after S102 steps It is placed on progress heating in vacuum infiltration in vacuum heater.
It should be noted that the characteristics of ink of the present invention is ink when ink droplet quantity is 8-15PL, ink is in 8- It parches within 15 seconds, the condensing temperature of the ink is 156 DEG C, and gasification temperature is 160 DEG C, and condensing temperature differs only by 4 with gasification temperature ℃.I.e. ink rapidly can switch to gaseous state from solid-state, and gaseous ink has high permeability, can successfully infiltrate into micropore and In crackle.
Wherein, the ink includes that following raw material is made:Inorganic pigment, low viscosity resin, esters solvent and auxiliary agent.
According to the liquefaction of ink and gasification temperature, need to be heated to 200 DEG C in S103 steps, it is ensured that ink gasifies and infiltrates into In quartz micropore.
After S101 infrared heatings, moisture in quartz micropore and crackle by other gases by except being filled.Bottom plate is put Enter vacuum heater to be heated again, gas can be discharged in micropore and crackle at this time, form negative-pressure vacuum state, and is adhered to Gasification can occur at 160 DEG C and form positive pressure for the ink of backplate surface, to the shape between micropore and crackle and the ink of gasification At pressure difference, ink can enter the inside of bottom plate along micropore and crackle, when ink bleed is to apart from backplate surface 0.5-0.8mm When can stop.
By heating in vacuum infiltration technology, the point-to-point infiltration of ink can be attached on plank, product figure obtained Case is naturally true to nature, and printing precision is high, and ink adhesive force is very strong, product can repeatedly polishing grinding it is non-discolouring.
S104, Surface hardening treatment:With nano-milled material on the plank of colouring polishing grinding, be sealed, harden Processing.
It should be noted that nano-milled material of the present invention is mainly made of crystal, lotion, auxiliary agent, the auxiliary agent Can be suspending agent, antifoaming agent, levelling agent, dispersant etc..The crystal main component is silica, crystal diameter 40- 80nm.And about 1000 nanometers of the length of quartz crackle, about 300 nanometers of width, about 500 nanometers of the diameter of micropore pass through nanometer In the surface polishing grinding of quartz bottom plate, nano-milled material crystals can easily enter in crackle and micropore grinding-material, right Crackle and micropore are closed, to realize that product is not easy to fade by inlc seal in crackle and micropore.
It is further illustrated below by way of specific embodiment:
Embodiment 1
Simulation objectives:Jade stone pattern manages plank
Select bottom plate:It without granule crystal, form and aspect is pure white the bottom of as that quartz bottom plate gloss, which is 90 degree of bloom, range estimation, Plate.
Heat bottom plate:Ground is placed in infrared heating continuous tunnel furnace and is heated to 90 DEG C, to remove the moisture in bottom plate gap;It is red External heat continuous tunnel furnace is divided to two sections of temperature controls, the first temperature control segment temperature to control in 57 DEG C, and the second temperature control segment temperature controls in 88 DEG C, Transmission speed is 0.8m/min.
Colored drawing prints:Ink is printed on bottom plate by digital coloured drawing printing machine.
Heating in vacuum is permeated:The bottom plate for being printed with ink is placed in vacuum heater, is vacuumized, and is heated to 200 DEG C, vacuum infiltration to 0.5mm, the plank painted;
Surface hardening treatment:With nano-milled material on the plank of colouring polishing grinding, be sealed, cure process, Finally obtain the plank managed with jade stone pattern.
Embodiment 2
Simulation objectives:Jade stone pattern manages plank
Select bottom plate:It without granule crystal, form and aspect is pure white the bottom of as that quartz bottom plate gloss, which is 90 degree of bloom, range estimation, Plate.
Heat bottom plate:Ground is placed in infrared heating continuous tunnel furnace and is heated to 90 DEG C, to remove the moisture in bottom plate gap;It is red External heat continuous tunnel furnace is divided to two sections of temperature controls, the first temperature control segment temperature to control in 60 DEG C, and the second temperature control segment temperature controls in 90 DEG C, Transmission speed is 1m/min.
Colored drawing prints:Ink is printed on bottom plate by digital coloured drawing printing machine.
Heating in vacuum is permeated:The bottom plate for being printed with ink is placed in vacuum heater, is vacuumized, and is heated to 200 DEG C, vacuum infiltration to 0.7mm, the plank painted;
Surface hardening treatment:With nano-milled material on the plank of colouring polishing grinding, be sealed, cure process, Finally obtain the plank managed with jade stone pattern.
Embodiment 3
Simulation objectives:Jade stone pattern manages plank
Select bottom plate:It without granule crystal, form and aspect is pure white the bottom of as that quartz bottom plate gloss, which is 90 degree of bloom, range estimation, Plate.
Heat bottom plate:Ground is placed in infrared heating continuous tunnel furnace and is heated to 90 DEG C, to remove the moisture in bottom plate gap;It is red External heat continuous tunnel furnace is divided to two sections of temperature controls, the first temperature control segment temperature to control in 62 DEG C, and the second temperature control segment temperature controls in 92 DEG C, Transmission speed is 1.2m/min.
Colored drawing prints:Ink is printed on bottom plate by digital coloured drawing printing machine.
Heating in vacuum is permeated:The bottom plate for being printed with ink is placed in vacuum heater, is vacuumized, and is heated to 200 DEG C, vacuum infiltration to 0.8mm, the plank painted;
Surface hardening treatment:With nano-milled material on the plank of colouring polishing grinding, be sealed, cure process, Finally obtain the plank managed with jade stone pattern.
Embodiment 4
Simulation objectives:Imitative hole jade card material
Select bottom plate:Quartz bottom plate gloss is 50 degree, a diameter of 0.3MM of granule crystal or so, form and aspect are light color.
Heat bottom plate:Ground is placed in infrared heating continuous tunnel furnace and is heated to 90 DEG C, to remove the moisture in bottom plate gap;It is red External heat continuous tunnel furnace is divided to two sections of temperature controls, the first temperature control segment temperature to control in 62 DEG C, and the second temperature control segment temperature controls in 92 DEG C, Transmission speed is 1.2m/min.
Colored drawing prints:Ink is printed on bottom plate by digital coloured drawing printing machine.
Heating in vacuum is permeated:The bottom plate for being printed with ink is placed in vacuum heater, is vacuumized, and is heated to 200 DEG C, vacuum infiltration to 0.8mm, the plank painted;
Surface hardening treatment:With nano-milled material on the plank of colouring polishing grinding, be sealed, cure process, Finally obtain the plank with imitative hole jade line.
Embodiment 5
Simulation objectives:Imitative hole jade card material
Select bottom plate:Quartz bottom plate gloss is 50 degree, a diameter of 0.3MM of granule crystal or so, form and aspect are light color.
Heat bottom plate:Ground is placed in infrared heating continuous tunnel furnace and is heated to 90 DEG C, to remove the moisture in bottom plate gap;It is red External heat continuous tunnel furnace is divided to two sections of temperature controls, the first temperature control segment temperature to control in 60 DEG C, and the second temperature control segment temperature controls in 90 DEG C, Transmission speed is 1m/min.
Colored drawing prints:Ink is printed on bottom plate by digital coloured drawing printing machine.
Heating in vacuum is permeated:The bottom plate for being printed with ink is placed in vacuum heater, is vacuumized, and is heated to 200 DEG C, vacuum infiltration to 0.7mm, the plank painted;
Surface hardening treatment:With nano-milled material on the plank of colouring polishing grinding, be sealed, cure process, Finally obtain the plank with imitative hole jade line.
In order to further printing process more of the present invention and the properties of product difference obtained by existing method, if The following experiment of meter:
One, experimental subjects
Reference example 1:Using stone material made from silk-screen printing as disclosed in patent CN1631679A;
Reference example 2:Using stone material made from water trans-printing technology as disclosed in CN102765287B;
Above-described embodiment 1-5.
Two, experiment content
1, adhesive force is tested
Each experimental subjects takes 5 laboratory samples, and white cotton gauze is bound in the bottom of the fixture of 1.5KGF, dips in 75% True alcohol, then again with white cotton gauze on the pattern of printing round-trip 30 back and forth, whether taken off according to product printed patterns It falls, notch broken string, situations such as ink adhesion is bad judge the quality of adhesive force.
2, case hardness is tested
It is tested using Mohs' hardness test method.
3, wearability test
According to《Natural ornamental stone test method (the 8th part):System structure is mounted with unifonn static pressure differential detection stone material Strength Testing Methods (GB/T 9966.8-2008)》National standard test method is tested.
Three, experimental result
Experimental result is as shown in table 1
1 laboratory sample performance comparison table of table
By above-mentioned experiment it is found that relative to reference example 1 and 2, emulation board made from the printing process through the invention Material, not only pattern is abundant, and color is naturally, fidelity is high, and the color fastness of product is high, and ink adhesive force is good, and hardness is high, resistance to compression It is wear-resisting, ornament materials is can be used as suitable for table top, desktop, metope, ground.
Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than is protected to the present invention The limitation of range is protected, although being explained in detail to the present invention with reference to preferred embodiment, those skilled in the art should Understand, technical scheme of the present invention can be modified or replaced equivalently, without departing from the essence of technical solution of the present invention And range.

Claims (6)

1. a kind of printing process of quartz, which is characterized in that include the following steps:
Select bottom plate:Bottom plate pattern is selected according to the gloss, particle diameter and form and aspect of simulation objectives plank;
Heat bottom plate:Ground is placed in infrared heating continuous tunnel furnace and is heated to 90 DEG C, to remove the moisture in bottom plate gap;
Colored drawing prints:Ink is printed on bottom plate by digital coloured drawing printing machine;
Heating in vacuum is permeated:The bottom plate for being printed with ink is placed in vacuum heater, is vacuumized, and is heated to 200 DEG C, very Sky infiltrates into 0.5-0.8mm, the plank painted;
Surface hardening treatment:With nano-milled material on the plank of colouring polishing grinding, be sealed, cure process;
Infrared heating continuous tunnel furnace is divided to two sections of temperature controls, the first temperature control segment temperature to control in 55-65 DEG C, the control of the second temperature control segment temperature In 85-95 DEG C, transmission speed 0.8-1.2m/min.
2. the printing process of quartz as described in claim 1, which is characterized in that the colored drawing print steps further include following step Suddenly:
Pattern is printed on referral material by digital coloured drawing printing machine;
Referral material printing surface is attached on the bottom plate of heating again, ink is made to be attached on bottom plate.
3. the printing process of quartz as claimed in claim 2, which is characterized in that referral material is customization paper, and front is papery Material, the back side are seal coating.
4. the printing process of quartz as described in claim 1, which is characterized in that the ink includes that following raw material is made:Nothing Machine pigment, low viscosity resin, esters solvent and auxiliary agent.
5. the printing process of quartz as described in claim 1, which is characterized in that nano-milled material mainly by crystal, lotion, Auxiliary agent forms, and the crystal main component is silica.
6. the printing process of quartz as claimed in claim 5, which is characterized in that a diameter of 40-80nm of the crystal.
CN201510653596.XA 2015-10-12 2015-10-12 A kind of printing process of quartz Active CN105383197B (en)

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IT202100003353A1 (en) * 2021-02-15 2022-08-15 Siti B & T Group Spa PROCESS AND PLANT FOR THE PRODUCTION OF SLABS IN MINERAL GRITS BOUND WITH RESINS

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CN107160882B (en) * 2017-04-27 2019-01-18 佛山市美之居装饰材料有限公司 A kind of true stone exterior wall board production technology

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CN86104010A (en) * 1986-06-16 1987-12-30 烟台大学 Colouring of natural marble and products thereof
CN1175560A (en) * 1997-05-08 1998-03-11 林建伟 Method for coloring marble and granite
CN1460601A (en) * 2003-05-14 2003-12-10 薛华林 Natural marble colour etched picture and its making method
CN1631679A (en) * 2004-12-27 2005-06-29 陈嘉星 Multicolor printing method on natural stone
CN1647943A (en) * 2004-01-30 2005-08-03 摄影人数位影像制作股份有限公司 Processing method for digital ink jet printing
CN1803463A (en) * 2006-01-11 2006-07-19 王天晓 Method for forming digital image at brick surface
CN103753996A (en) * 2014-02-10 2014-04-30 吕联景 Method for forming surface patterns of artificial marble

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IT1289117B1 (en) * 1996-06-28 1998-09-25 Gabriele Valente PROCEDURE FOR THE DECORATION OF STONE MATERIALS AND / OR WALLS AS WELL AS THE MACHINE FOR THE IMPLEMENTATION OF THIS PROCEDURE.
US7270407B2 (en) * 2001-06-29 2007-09-18 Hewlett-Packard Development Company, L.P. Methods for digitally printing on ceramics

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Publication number Priority date Publication date Assignee Title
CN86104010A (en) * 1986-06-16 1987-12-30 烟台大学 Colouring of natural marble and products thereof
CN1175560A (en) * 1997-05-08 1998-03-11 林建伟 Method for coloring marble and granite
CN1460601A (en) * 2003-05-14 2003-12-10 薛华林 Natural marble colour etched picture and its making method
CN1647943A (en) * 2004-01-30 2005-08-03 摄影人数位影像制作股份有限公司 Processing method for digital ink jet printing
CN1631679A (en) * 2004-12-27 2005-06-29 陈嘉星 Multicolor printing method on natural stone
CN1803463A (en) * 2006-01-11 2006-07-19 王天晓 Method for forming digital image at brick surface
CN103753996A (en) * 2014-02-10 2014-04-30 吕联景 Method for forming surface patterns of artificial marble

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT202100003353A1 (en) * 2021-02-15 2022-08-15 Siti B & T Group Spa PROCESS AND PLANT FOR THE PRODUCTION OF SLABS IN MINERAL GRITS BOUND WITH RESINS
WO2022172242A1 (en) * 2021-02-15 2022-08-18 Siti - B&T Group S.P.A. Process and system for the manufacturing of slabs made of resin-bonded mineral grits

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