CN105347832A - Helical carbon fiber composite ceramic for water activation as well as preparation method and application thereof - Google Patents
Helical carbon fiber composite ceramic for water activation as well as preparation method and application thereof Download PDFInfo
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- CN105347832A CN105347832A CN201510882454.0A CN201510882454A CN105347832A CN 105347832 A CN105347832 A CN 105347832A CN 201510882454 A CN201510882454 A CN 201510882454A CN 105347832 A CN105347832 A CN 105347832A
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Abstract
The invention discloses helical carbon fiber composite ceramic for water activation. The helical carbon fiber composite ceramic comprises a ceramic phase and helical carbon fibers, wherein the helical carbon fibers are distributed and loaded on the ceramic phase. By using the helical carbon fibers, the harmful substance fluctuation can be changed to be fluctuation matched with human bodies. To be specific, sub-micron helical carbon fibers and the ceramic raw material are compounded and then subjected to oxygen insulation sintering, so as to obtain the composite ceramic. The composite ceramic can change the fluctuation harmful to the human bodies and generated by multiple chemical substances, element chlorine, harmful bacteria and the like into fluctuation beneficial to bodies, and enables water molecules to be subjected to declension vibration activation, so that water molecules are changed into smaller molecular clusters and the blood flow volume of human brains is increased obviously; in addition, through the special fluctuation, the effect of inhibiting bacterium reproduction is realized. On the basis of a fluctuation effect, all needed is to add a small amount of the helical carbon fiber composite ceramic, and thus the water quality can be changed instantly. In a water activation treatment process, pollutants are not adsorbed, and chemical changes do not occur, so that later cleaning and maintenance are not required and the helical carbon fiber composite ceramic disclosed by the invention can be used for a long time.
Description
Technical field
The invention belongs to water treatment field, be specifically related to the coiled carbon fibers composite ceramics and preparation method thereof for activated water and application
Background technology
Drink water to healthy effect very greatly, except because drinking-water the inside is containing impurity, (mud, sterilization chlorine bleaching agent, be harmful to medicine, chemical substance, heavy metal class, bacterium class etc.) influence factor beyond, the activity (energy of water molecules) of water molecules self is also very important.The low quality of former water, carrying out filtration refining being also difficult to removes the harmful medicine of trace and chemical substance, completely so be not suitable for directly being used as tap water.
Research shows, puts aside huge information data inside human brain, and these information datas can judge to people it is useful or harmful by material.Whether tap water is applicable to comprising human body to utilize this super memory function and insight just can judge.If brain judges it is harmful when drinking ArsenazoⅢ, cerebral blood flow (CBF) reduces, to stop objectionable impurities to flow in brain.If brain is judged as benefit materials, then cerebral blood flow (CBF) just increases, nutrient supply brain, waste is discharged, plays a part to improve immunizing power.These all substances in the world, and immaterial, all with certain natural frequency vibration.There is the vibration useful to human body; Also have harmful vibration, when suitable with the distinctive fluctuation of human body, brain just judges it is harmful and start refusal, and cerebral blood flow (CBF) just declines.The particularly pharmaceutical chemicals of synthetic and unwanted bacteria class, their fluctuation has very large distortion and stress, and the fluctuation of human body is unsuitable, so brain instructs refusal they, thus cerebral blood flow (CBF) declines.
We investigate the impact of city tap-water on cerebral blood flow (CBF), and result shows that most of metropolitan tap water all has remarkably influenced to cerebral blood flow (CBF), is all not suitable for directly drinking.The mineral water of area, mountain area rich in mineral substances just can improve cerebral blood flow (CBF); Picture aspartame artificial sweeteners element, the beverage such as man-made additive or Coca-Cola, then can reduce cerebral blood flow (CBF); On the contrary, rice, bean curd, vinegar, the daily breads such as beer just can increase cerebral blood flow (CBF).Same material is also more refining, more makes cerebral blood flow (CBF) reduce, and mineral salt and rock salt can make cerebral blood flow (CBF) improve.Cerebral blood flow (CBF) improves with regard to illustrating useful to health, is instead then harmful to.
Summary of the invention
The present invention is by studying coiled carbon fibers to the impact of HUMAN HEALTH, and its using method, based on the principle that material fluctuation changes, works out a kind of coiled carbon fibers composite ceramics for activated water and preparation method thereof and the application in water treatment.
Technical scheme of the present invention is achieved in that
For the coiled carbon fibers composite ceramics of activated water, comprise ceramic phase and coiled carbon fibers, described coiled carbon fibers distribution is carried and is attached to ceramic phase.
Preferably, described coiled carbon fibers is randomly dispersed in ceramic phase.
Preferably, described ceramic phase is the ceramic of solid fraction form.Ceramic phase can be any solid shape, also can be made into the form such as artwork ornaments, practical ceramic tile, even can directly combine in the water receptacle of ceramic form, and its Main Function is the carrier as carrying coiled carbon fibers.
Preferably, the mass ratio of described coiled carbon fibers for being greater than 0wt%, and is less than or equal to 80%.
Preferred further, the mass ratio of described coiled carbon fibers is 0.01wt%-80wt%.
Preferably, the diameter of described coiled carbon fibers is 10nm-100um.
First the making method of the above-mentioned coiled carbon fibers composite ceramics for activated water, comprise the steps:, get quantitative ceramic raw material, spiral talked fiber in mass ratio for the content of 0.01wt% ~ 80wt% adds as in ceramic raw material, mix for subsequent use; Secondly, ceramic molding is adopted by mixing material to be made into the ceramic germule of solid fraction form; Finally after germule seasoning, sinter ceramic in an inert atmosphere.
Preferably, in above-mentioned making method, described ceramic molding is that roll shaping, kapillary drips any one forming method in form sediment shaping, dry-pressing formed, hydrostatic profile, roll-forming.
Preferably, in above-mentioned making method, wherein sintering temperature is 1000-1200 DEG C.
Coiled carbon fibers composite ceramics of the present invention can life-time service, for the coiled carbon fibers composite ceramics of activated water in the application of drinking water treatment, coiled carbon fibers composite ceramics can be added in water receptacle, or in the pipeline that water flows through, install coiled carbon fibers composite ceramics, also can be prepared into coiled carbon fibers composite ceramics container splendid attire water.
Coiled carbon fibers composite ceramics, in the application of aquaculture water treatment, is loaded on tank and crosses in water pipe by the described coiled carbon fibers composite ceramics for activated water.
Water treatment principle of the present invention is: coiled carbon fibers composite ceramics can by the many chemical substances in water, such as chlorion, and the harmful fluctuation that the material such as unwanted bacteria occurs converts the fluctuation useful to human body to, and make the sensitization that water molecules generation declension vibrates, the molecular clustering making water molecules become less, significantly improves cerebral blood flow; Also there is additionally by its special fluctuation the effect of anti-bacteria breeding.
The present invention also tool has the following advantages:
1, spiral is talked fiber to be combined with ceramic phase, the advantages such as formation coiled carbon fibers composite ceramics has Stability Analysis of Structures, is convenient to preserve, easy to use.
2, water can activate by coiled carbon fibers composite ceramics, and activation-sensitization that water molecules generation declension is vibrated, makes the molecular clustering that water molecules becomes less.
3, water treatment method of the present invention is physical treatment,, there is not chemical reaction in coiled carbon fibers composite ceramics not adsorb harmful components in water treatment procedure, in water, chemical form change also can not occur in long-term placement, therefore, it is possible to life-time service, effect can not decay.
4, because be present fluctuation effect, so CMC ceramic bead is not dirty, effect does not also reduce, and life-time service does not need to change, clean, convenient especially.
5, suppress the unwanted bacteria breeding in water, kill bacteria, improves the activity of water, improves organism in water survival condition, and the water surrounding being specially adapted to culturing pool is improved.
Embodiment
Be clearly and completely described to the technical scheme in the embodiment of the present invention below, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
The present invention is used for the coiled carbon fibers composite ceramics of activated water, comprise ceramic phase 1 and some coiled carbon fibers 3 (abbreviation: CMC), described coiled carbon fibers 3 distributes to carry and is attached to ceramic phase, concrete, described coiled carbon fibers 3 can be randomly dispersed in ceramic phase, it is that certain rule or random pattern are distributed in ceramic phase that coiled carbon fibers 3 also can be assembled, or overlays on ceramic phase outside surface.Described ceramic phase is the ceramic of solid fraction form.Ceramic phase can be any solid shape, as square, irregularly shaped, also can be made into the form such as artwork ornaments, practical ceramic tile, even can directly combine in the water receptacle of ceramic form, its Main Function be as carrying coiled carbon fibers carrier.Described ceramic phase preferably adopts ceramic bead structure, has the advantages such as attractive in appearance, easy-to-use, applied widely.
In the present invention, the mass ratio of described coiled carbon fibers for being greater than 0wt%, and is less than or equal to 80%.Described coiled carbon fibers micron order coiled carbon fibers.As long as the amount that the content of coiled carbon fibers is very small in theory can reach good effect, and after being combined with ceramic phase, for being attached in ceramic phase on it is tangible, according to the water yield of required process and the completed state of the narrow body of pottery, its mass ratio can between 0.01wt% ~ 80wt%.
Contriver is found by test, coiled carbon fibers composite ceramics to the treatment effect of water clearly, cerebral blood flow (CBF) can improve fast, and the cerebral blood flow (CBF) that the present invention mentions can adopt ultrasonic blood flow detection instrument to test, and the ultrasonic measuring method of twocouese blood flow can be adopted to measure.
The making method of the above-mentioned coiled carbon fibers composite ceramics for activated water, comprises the steps:
First, get quantitative ceramic raw material, spiral is talked fiber in mass ratio for the content of 0.01wt% ~ 80wt% is added in ceramic raw material, mix for subsequent use; Secondly, ceramic molding is adopted by mixing material to be made into the ceramic germule of solid fraction form; Finally after germule seasoning, sinter ceramic in an inert atmosphere, wherein sintering temperature is 1000-1200 DEG C.Described ceramic molding is that roll shaping, kapillary drips any one forming method in form sediment shaping, dry-pressing formed, hydrostatic profile, roll-forming.
The present invention is made the multiple difform ceramic composites such as ceramic bead, ceramic particle and ceramic cylinder by different ceramic raw materials, coiled carbon fibers adding proportion, and is carried out the experiment of water activation treatment, specific as follows:
The preparation of embodiment one, coiled carbon fibers composite ceramic beads: the floor tile powder getting 0.5wt% coiled carbon fibers and 99.5wt%, first floor tile powder is carried out 40 spraying dry, then coiled carbon fibers and the agravic method of floor tile powder are mixed, adopt rolling method to add water and be rolled onto complex body, diameter reaches the ball of 3-5 millimeter, sort out drying with sieve, then put into oxygen-free atmosphere stove and make coiled carbon fibers composite ceramic beads with 1180 DEG C of high temperature sinterings.
In an experiment, by cerebral blood flow (CBF) be 1.8L/min 10 liters of tap water in add coiled carbon fibers composite ceramic beads, go out the cerebral blood flow (CBF) fast lifting of saliva to 7L/min.
The preparation of embodiment two, coiled carbon fibers composite ceramic particle: first-selection gets 37wt% red soil and granite powder 63wt%; then 100wt% water is added; after mud by 0.5wt% more than ball milling to 10000-hole sieve; add 0.2wt% coiled carbon fibers to be again uniformly mixed; this mixing mud pressure filter is dehydrated into mud cake; mud cake drying, tablets press are ground into the particle of 2-4 mm in size, then are formed by oxygen-free atmosphere stove 1050 DEG C of sintering.
In an experiment, get coiled carbon fibers composite ceramic particle some, put into internal diameter 17mm, in the cylinder of length 450mm, cerebral blood flow (CBF) is the flow rate of tap water with 50L/min of 1.8L/min, and the cerebral blood flow (CBF) going out saliva rises to 6L/min.
Embodiment three, the cylindrical preparation of coiled carbon fibers composite ceramics: after getting the mud of 2wt% more than 23wt% red soil, smolmitza 17wt%, granite powder 60wt%, additional 100wt% water, ball milling to 10000-hole sieve, add 1wt%CMC to be uniformly mixed, this mixing mud pressure filter is dehydrated into mud cake, the mud bar of diameter 5 millimeters is extruded with soil kneader, be cut into the mud section of 5 millimeters long, mud section drying oxygen-free atmosphere stove 1000 DEG C of sintering form.
In an experiment, in the container of 200 liters, add the water of cerebral blood flow (CBF) 0.6L/min, add the ceramic cylinder talking fiber containing spiral inside, after stirring, measure its cerebral blood flow (CBF) 6L/min.
The application of above-mentioned coiled carbon fibers composite ceramics is specially: in the application of drinking water treatment, can add coiled carbon fibers composite ceramics in water receptacle, or installs coiled carbon fibers composite ceramics in the pipeline flow through at water.Coiled carbon fibers composite ceramics is by continuative improvement water quality.
In addition, coiled carbon fibers composite ceramics of the present invention is also applicable to being applied in aquaculture water treatment very much, in the application of aquaculture water treatment, coiled carbon fibers composite ceramics is loaded on tank and crosses in water pipe.
The present invention can be used for the water activation treatment of any occasion, is not limited to above-mentioned application example, and just comparatively common, the effective use occasion of above-mentioned example, coiled carbon fibers composite ceramics only need contact with water, must have activated water, improve the effect of water quality.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (10)
1. for the coiled carbon fibers composite ceramics of activated water, it is characterized in that, comprise ceramic phase and coiled carbon fibers, described coiled carbon fibers distribution is carried and is attached to ceramic phase.
2., as claimed in claim 1 for the coiled carbon fibers composite ceramics of activated water, it is characterized in that, described coiled carbon fibers is randomly dispersed in ceramic phase.
3., as claimed in claim 1 for the coiled carbon fibers composite ceramics of activated water, it is characterized in that, described ceramic phase is the ceramic of solid fraction form.
4. the coiled carbon fibers composite ceramics for activated water according to any one of claim 1-3, is characterized in that, the mass ratio of described coiled carbon fibers for being greater than 0wt%, and is less than or equal to 80%.
5., as claimed in claim 4 for the coiled carbon fibers composite ceramics of activated water, it is characterized in that, the mass ratio of described coiled carbon fibers is 0.01wt%-80wt%.
6. the coiled carbon fibers composite ceramics for activated water according to any one of claim 1-3 or 5, is characterized in that, the diameter of described coiled carbon fibers is 10nm-100um.
7. the making method of the coiled carbon fibers composite ceramics for activated water according to any one of claim 1-6, it is characterized in that, comprise the steps: first, get quantitative ceramic raw material, spiral is talked fiber in mass ratio for the content of 0.01wt% ~ 80wt% adds as in ceramic raw material, mix for subsequent use; Secondly, ceramic molding is adopted by mixing material to be made into the ceramic germule of solid fraction form; Finally after germule seasoning, sinter ceramic in an inert atmosphere.
8. as claimed in claim 7 for the making method of the coiled carbon fibers composite ceramics of activated water, it is characterized in that, described ceramic molding is that roll shaping, kapillary drips any one forming method in form sediment shaping, dry-pressing formed, hydrostatic profile, roll-forming.
9., as claimed in claim 7 for the making method of the coiled carbon fibers composite ceramics of activated water, it is characterized in that, wherein sintering temperature is 1000-1200 DEG C.
10. the coiled carbon fibers composite ceramics for activated water according to any one of claim 1-6 is in the application of drinking water treatment, it is characterized in that, in water receptacle, add coiled carbon fibers composite ceramics, or install coiled carbon fibers composite ceramics in the pipeline flow through at water.
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CN106830927A (en) * | 2017-01-26 | 2017-06-13 | 广东东方锆业科技股份有限公司 | The method that a kind of shaping of drop shallow lake prepares zirconia ceramics microballon |
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CN1336248A (en) * | 2000-08-01 | 2002-02-20 | 李裕成 | Making-process of active sintered microfiltering film |
JP2007330198A (en) * | 2006-06-16 | 2007-12-27 | Bridgestone Flowtech Corp | Structure for improving water quality |
CN103933661A (en) * | 2014-04-09 | 2014-07-23 | 杨少明 | Health caring annexing agent and application of health caring annexing agent |
CN205241540U (en) * | 2015-12-03 | 2016-05-18 | 泉州凯佳新材料研究院有限公司 | A spiral carbon fiber composite ceramic for activated water |
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Patent Citations (4)
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CN1336248A (en) * | 2000-08-01 | 2002-02-20 | 李裕成 | Making-process of active sintered microfiltering film |
JP2007330198A (en) * | 2006-06-16 | 2007-12-27 | Bridgestone Flowtech Corp | Structure for improving water quality |
CN103933661A (en) * | 2014-04-09 | 2014-07-23 | 杨少明 | Health caring annexing agent and application of health caring annexing agent |
CN205241540U (en) * | 2015-12-03 | 2016-05-18 | 泉州凯佳新材料研究院有限公司 | A spiral carbon fiber composite ceramic for activated water |
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CN106830927A (en) * | 2017-01-26 | 2017-06-13 | 广东东方锆业科技股份有限公司 | The method that a kind of shaping of drop shallow lake prepares zirconia ceramics microballon |
CN106830927B (en) * | 2017-01-26 | 2019-10-18 | 广东东方锆业科技股份有限公司 | A method of drop shallow lake molding prepares zirconia ceramics microballon |
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