CN105084468B - Manufacture hydrogen rich water alloy ceramic and its preparation method and application - Google Patents
Manufacture hydrogen rich water alloy ceramic and its preparation method and application Download PDFInfo
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- CN105084468B CN105084468B CN201510456288.8A CN201510456288A CN105084468B CN 105084468 B CN105084468 B CN 105084468B CN 201510456288 A CN201510456288 A CN 201510456288A CN 105084468 B CN105084468 B CN 105084468B
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Abstract
The invention belongs to environmental friendly material technical field, and in particular to one kind manufacture hydrogen rich water alloy ceramic and its preparation method and application.The alloy ceramic is made up of the raw material of following percetage by weight：3 30 parts of 30 85 parts of substrate component, 20 60 parts of hydrogen-rich component, 2 25 parts of antibacterial components and binding agent；Wherein, substrate component is made up of tourmaline, water member stone, silica, calcium oxide and zeolite；Hydrogen-rich component is made up of metal magnesium powder, magnesia powder and KDF alloy powders；Antibacterial components are made up of zinc oxide, titanium oxide and cerium oxide；Binding agent is the one or more in high-purity distilled water, carboxy-propyl cellulose or bentonite.The alloy ceramic has manufacture week-base water, negative potential water and hydrogen rich water three zones, is also acted on antibacterial and activated water.Present invention simultaneously provides its preparation method and application, technique is simple, is easily achieved, and is applied in the products such as water purifier, purifying kettle and cup.
Description
Technical field
The invention belongs to environmental friendly material technical field, and in particular to one kind manufacture hydrogen rich water alloy ceramic and its system
Preparation Method and application.
Background technology
Medical research shows many diseases, the freedom that including aging to be all due to cylinder accumulation cannot remove in time
Caused by base.Free radical is that human body cell produces a kind of chemicals that are very active, having very strong oxidation in metabolic process
Matter, also it is active oxygen.Free radical attack life macromolecule can cause tissue cell insult, be the basic original for causing body aging
Cause, and the important cause of the malignant disease such as induced tumor.Excessive active oxygen radical can produce destruction, cause human body
The damage of normal cell and tissue, so as to cause a variety of diseases, such as heart disease, senile dementia, Parkinson's and tumour.This
Outside, the solar irradiation in external environment, air pollution, flue dust, agricultural chemicals etc. can all promote human body to produce more active oxygen radicals,
Cause nucleic acid mutation, this is mankind aging and ill root.
And the water of hydrogen has the effect of removing biological interior free yl.Hydrogen is inherently a kind of optimal anti-oxidant
Agent because hydrogen molecule is very fine, into it is internal can rapid osmotic to whole body, and penetration cell film, take away among be difficult to eliminate
Pernicious active oxygen, its synthetic water is excreted, the running without influenceing other benign activity oxygen and body function.It is most heavy
What is wanted is that destroyed and oxidized cell can be restored." hydrogen " in water has most strong reducing power, and we often eat big
Partial Antioxidation agent, such as vitamin, are not easy to through cell membrane, and pointedly only pernicious active oxygen can not be eliminated, more
In addition a large amount of vitamins are eaten, also it is difficult to storage in vivo and absorbs.The experimental analysis done according to Japanese Ohta Shigeo professor, hydrogen
The oxidation resistance and cell restorability of gas are most severe so far.
Hydrogen rich water, as the term suggests being exactly the water rich in hydrogen, Japanese is " Shui Sushui ".Rich in hydrionic water element water
(Hydrogen Water), as hydrogen reduction water, it is different from common water, by its reducing power, internal superfluous work can be removed
Property oxygen (oxygen radical).Hydrogen rich water is not only clean, has hydrogen to have energy, is all that small molecule running water group is presented, can also purify blood, make
Unobstructed blood, vigorous, prevention of various diseases is metabolized, promotes health.In July, 2007, Japanese medical university scholar exist《It is natural
Medical science》Report, the hydrogen of animal breath 2% can effectively remove free radical.
Currently manufactured hydrogen rich water technology mainly has following three kinds：First, direct current electrolysis water prepares hydrogen, caused hydrogen
Being partially soluble in water turns into hydrogen rich water；Hydrogeneous hydrogen rich water is prepared into second, hydrogen is directly filled with water；Third, natural ceramics
Material light electrolysis prepares hydrogen, and caused hydrogen is soluble in water into hydrogen rich water.Three of the above method respectively has advantage and disadvantage, wherein direct current
Electric electrolytic hydrogen production Technical comparing is ripe, but manufacturing cost is high, the shortcomings of being also easy to produce ozone peculiar smell, causes the product marketing ratio
It is slower.Such as patent 201510126957.5, a kind of portable hydrogen-rich cup；Patent 201410679373.6, a kind of hydrogen rich water
Rod；Patent 201280061730.1, water element water making device.The method introduced in these patents, it is higher manufacturing cost to be present, and
Ozone is also easy to produce while hydrogen rich water is manufactured, causes peculiar smell in water larger, lacks trace element and alkalescent, in the short time just
The shortcomings of being reduced to light water.But high concentration of hydrogen water can be prepared in water electrolysis hydrogen production technology, treatment water is suitable as, but make
Health care is carried out for daily drunk hydrogen rich water, is unfavorable for health on the contrary.
Hydrogen is filled with to the hydrogen rich water prepared in water, the problems such as difficult storage and hydrogen volatilization be present, there is certain limitation,
It is only used for being prepared into packed or filling hydrogen water sale.For example, patent CN201410166247.0, a kind of preparation of hydrogen rich water
Technique, hydrogen-rich water polo is made in composite mixture heating, is fitted into closed retort, the pure water being passed through after degassing,
Hydrogen rich water is made in stirring, filtered filling to be made.Hydrogen molecule content is 20 times of common alkaline ionized water in manufactured water.But
This method can only carry out filling storage, it is impossible to prepare hydrogen water whenever and wherever possible, and carry inconvenience.
Natural ceramic material light electrolysis hydrogen manufacturing, typically using the Material claddings such as Tourmaline (tourmaline), metal magnesium powder or straight
Connect and hydrogen water is prepared using the ripple metal light electrolysis living such as magnesium granules, magnesium rod, but poor in timeliness be present in above material, and hydrogen manufacturing content is low,
Alkalescence is uncontrollable, and easy the shortcomings of separating out sediment, has a strong impact on the mouthfeel of water.Meanwhile the ripple metal living such as magnesium granules and magnesium rod
Easily aoxidize under air ambient, no longer worked substantially after oxidation, and the excessive magnesium ion of easy dissolution in water, cause
Magnesium ion is exceeded in water.Existing market situation is seen, above product quality is uneven, and functional effect is undesirable.Through inquiry, go back
Do not find directly to carry out document or patent document of hydrogen manufacturing etc. using magnesium granules or magnesium rod, have patent can manufacture negative potential water and
Alkaline small water.Such as patent CN201510008767.3, a kind of antibacterial negative potential ball and preparation method and application；Patent
CN201010618600.6, composite antibacterial far infrared medical stone porous ceramic ball and preparation method；Patent 200910199142.4,
A kind of composition that can produce negative potential and preparation method and application.
How natural minerals ceramic material is applied, produce and be advantageous to the hydrogen rich water of health and turn into the prior art urgently
The problem of to be solved.
The content of the invention
In view of the shortcomings of the prior art, it is an object of the invention to provide one kind to manufacture hydrogen rich water alloy ceramic, has
Week-base water, negative potential water and hydrogen rich water three zones are manufactured, are also acted on antibacterial and activated water；Present invention simultaneously provides its system
Preparation Method and methods for using them.
Manufacture hydrogen rich water alloy ceramic of the present invention, is made up of the raw material of following parts by weight：Substrate component
30-85 parts, hydrogen-rich component 20-60 parts, antibacterial components 2-25 parts and binding agent 3-30 parts；
Wherein,
Substrate component is made up of tourmaline, water member stone, silica, calcium oxide and zeolite；
Hydrogen-rich component is made up of metal magnesium powder, magnesia powder and KDF alloy powders；
Antibacterial components are made up of zinc oxide, titanium oxide and cerium oxide；
Binding agent is the one or more in high-purity distilled water, carboxy-propyl cellulose or bentonite.
Wherein：
Substrate component is made up of the raw material of following percetage by weight：
Tourmaline 20-45%, water member stone 10-30%, silica 20-45%, calcium oxide 10-35% and zeolite 10-30%.
Hydrogen-rich component is made up of the raw material of following percetage by weight：
Metal magnesium powder 20-60%, magnesia powder 20-60% and KDF alloy powder 10-50%.Described metal magnesium powder, oxygen
The particle diameter for changing magnesium powder and KDF alloy powders is 30-100 μm.
Antibacterial components are made up of the raw material of following percetage by weight：
Zinc oxide 20-50%, titanium oxide 20-50% and cerium oxide 5-30%.
Binding agent is preferably to be made up of the raw material of following percetage by weight：
High-purity distilled water 30-65%, carboxy-propyl cellulose 10-30% and bentonite 20-50%.
The preparation method of described manufacture hydrogen rich water alloy ceramic, comprises the following steps：
(1) pre-process：
By tourmaline, water member stone, silica, calcium oxide and zeolite mixed grinding 6-10h, to 500 μm of diameter of particle ＜, obtain
Substrate component；
By zinc oxide, titanium oxide, cerium oxide mixed grinding 6-10h, to 50 μm of diameter of particle ＜, antibacterial components are obtained；
Metal magnesium powder, magnesia powder and KDF alloy powders are mixed, obtain hydrogen-rich component；
High-purity distilled water, carboxy-propyl cellulose and bentonite are mixed, obtain binding agent；
(2) batch mixing：Substrate component, hydrogen-rich component and antibacterial components are added into batch mixer by charge ratio, mix 1-5 hours；
(3) it is molded：The material for the mixing that step (2) is prepared is added to nodulizer or stamping machine shaping, is molded
Journey constantly sprays binding agent；
(4) bakee, screen：Material is bakeed, screened after the shaping that step (3) is prepared, and produces described system
Get rich hydrogen water alloy ceramic.
Wherein：Stoving temperature is 150-480 DEG C, and the baking time is 0.5-2h.
Described manufacture hydrogen rich water alloy ceramic is shaped as granular pattern, wafer type, column type, diamond type, cast or the heart
Type.
The application of described manufacture hydrogen rich water alloy ceramic, is applied in water purifier, purifying kettle, cup product, also
It can be used in deodorization decontamination, aquaculture, flower planting, health care and beauty industry.
In preparation method of the present invention, substrate component, hydrogen-rich component and antibacterial components separate batch mixing, avoid each component material
Between because caused by particle diameter is inconsistent it is less economical and merge it is insufficient the shortcomings of.Because substrate component is mainly with natural crystal
The grinding of powder body material batch mixing is made, it is desirable to which particle diameter is less than 500 microns, mainly considers that the particle size range has preferable feature
And economy.Hydrogen-rich component is made up of materials such as metal magnesium powder, magnesia powders, and because magnesium metal is inflammable, conventional grinding has one
Fixed danger, directly take the commercially available magnesium powder of buying, magnesia powder and KDF alloy powders to carry out batch mixing compound, can avoid and base
Situations such as other materials batch mixing is uneven in material component occurs.Each material requirements diameter of particle of antibacterial components is the smaller the better, so
Antibacterial components raw material mixed grinding to particle diameter is less than 50 microns, its more preferable anti-microbial property of competence exertion.So according to each material
Performance and economy consider, by the grinding of separated batch mixing reach required particle diameter, and it is compound then to carry out component, can play
The function of each material, there is preferable economy again.
Antibacterial component requirements batch mixing grinding particle diameter is less than 50 microns in the present invention, is because of zinc oxide, titanium oxide in component
To reach sub-micron or nanoscale with cerium oxide could preferably give play to antibiotic effect.
Substrate component of the present invention requires that batch mixing grinding particle diameter is less than 500 microns, is that the performance based on each composition in component is steady
Qualitative and economy considers.
Substrate component of the present invention with the addition of zeolite group mineral material, and mainly zeolite has natural microcellular structure, compares surface
Product is very big.Zeolite mixed with tourmaline, water member stone, silica and calcium oxide fully after, then with hydrogen-rich component and antibacterial components
Batch mixing, manufactured alloy ceramic has more microcellular structure after low-temperature bake.It is distributed in the micropore framework of the material
Numerous micron order and nano level duct and micropore, the contact area of each function raw material and water is increased, so as to strengthen
Alloy ceramic of the present invention carries out the efficiency of light electrolysis to water.The specific surface area of alloy ceramic is more much than like product
50-100 times.
Substrate component addition tourmaline and water member stone mineral material of the present invention, made using activated water of the material in water
The remote red line energy wave discharged with, its own self poling characteristic can shake big water clusters into small water clusters, from
And realize the effect of activated water.Activated water has preferable penetration and dissolving power, to promoting body metabolism, strengthens body
Immunity plays preferable effect.
Hydrogen-rich component of the present invention adds KDF alloy powders, and KDF alloys are Copper-zinc alloy materials, have purified water and micro- electricity
Solve water function.Technology and product all comparative maturities of KDF alloys.After KDF alloys mix with magnesium metal and magnesia, each metal from
Son has higher potential difference in water, can form numerous galvanic effect, each metal ion can cooperate with when being contacted with water
Synergy, numerous light electrolysis contact is produced, so as to increase the dynamics to water light electrolysis, enhance the function of manufacture hydrogen molecule.
In antibacterial components material of the present invention, rare-earth oxidation cerium material is added, is mainly made using the natural antibacterial of cerium oxide
With also cerium oxide can activate the titanium oxide and zinc oxide material in alloy ceramic, can significantly improve zinc ion
Anti-microbial property, it is excited to produce the quantity of hydroxyl radical free radical with water, so as to realize the purpose of enhancing anti-microbial property.Antibacterial of the present invention
Component material does not use conventional silver metal material, mainly considers that addition silver ion cost is too high, also silver ion easily aoxidizes
Discoloration, does not have antibacterial action not only, separates out silver ion excess in water on the contrary, is unfavorable for health.
The present invention uses baked and cured technology, rather than uses low-firing technology, and each component material can be allowed fully to merge,
Microcellular structure, increase and the contact area of water are prepared into, strengthens light electrolysis efficiency, while can be sustained and separate out trace element etc..
The present invention needs to develop into variously-shaped product according to application, wide with application, good in economic efficiency etc. excellent
Point.
Binding agent is constantly sprayed in forming process of the present invention, alloy ceramic can be allowed to form stratiform in forming process
Light electrolysis functional response layer, the specific surface area for increasing material simultaneously, improve the persistence of micro-electrolysis reaction, add the product longevity
Life.
The hydrogen rich water alloy ceramic that the present invention is prepared has following technical indicator：
Specific surface area：＞ 0.5 × 104cm2/g；
Density：1.35~1.4g/cm3；
Bulk density：1.15~1.22kg/cm3。
Detection：Detected through Shandong Center for Disease Control ＆ Prevention, according to《Drinking Water transmission ＆ distribution wetting system and protective materials
Hygienic safety evaluation specification》(2001), the method for inspection uses《Drinking Water inspection specification》(2001), by spherical alloy ceramics
Material 24 ± 1h of soak time, 25 ± 5 DEG C of soaking temperature.As a result show：Color, turbidity, smelly and taste, naked eyes visible, pH,
The indexs such as total dissolved solid, oxygen demand, arsenic, cadmium, lead, mercury, chloroform, volatile phenol meet standard criterion requirement.
Municipal tap water ORP value is 354mV, in mass ratio：1 part of ceramal and 10 parts of water ratios, add the manufacture
After hydrogen rich water alloy ceramic immersion 5min, reduction >=-150mV；Distilled water ORP value is 10mV, in mass ratio：1 part of alloy
Ceramics and 10 parts of water ratios, after adding the manufacture hydrogen rich water alloy ceramic immersion 5min, reduction >=-150mV.
The pH of municipal tap water is 7.0, in mass ratio：1 part of ceramal and 10 parts of water ratios, add the manufacture hydrogen-rich
After water alloy ceramic immersion 5min, pH=8.2-8.8；The pH of distilled water is 5.5, in mass ratio：1 part of ceramal and 10
Part water ratio, after adding the manufacture hydrogen rich water alloy ceramic immersion 5min, pH=7.8-8.0.
The TDS values of municipal tap water are 170, in mass ratio：1 part of ceramal and 10 parts of water ratios, add the manufacture
After hydrogen rich water alloy ceramic immersion 5min, TDS=260；The TDS values of distilled water are 30, in mass ratio：1 part of alloy pottery
Porcelain and 10 parts of water ratios, after adding the manufacture hydrogen rich water alloy ceramic immersion 5min, TDS=150.
In summary, beneficial effects of the present invention are as follows：
(1) present invention manufacture hydrogen rich water alloy ceramic, there is manufacture three big work(of hydrogen rich water, week-base water and negative potential water
Can, also acted on antibacterial and activated water.After tested, in mass ratio：1 part of ceramal and 10 parts of water ratios, the hydrogen-rich of manufacture
The content of hydrogen molecule, can reach 300-800ppb in water；PH value is between 8-9.5；Oxidation-reduction potential ORP value be -150 to -
300mV；Half-peak breadth through NMR test water oxygen 17 is distributed in 65-85 hertz；Zinc, magnesium, calcium, metasilicic acid in hydrogen rich water
It is abundant Deng trace element.So the water collection hydrogen-rich of alloy ceramic of the present invention manufacture, weak base, negative potential, subset and micro-
Secondary element is in one.
(2) the alloy ceramic shape has spherical, piece shape, column type etc., needs to prepare according to application variously-shaped.
It may be used in the products such as water purifier, purifying kettle and cup, manufacture the healthy water of hydrogen-rich, added value of product can be lifted, improve body
Body health.It can be additionally used in the industries such as deodorization decontamination, aquaculture, flower planting and health and beauty.
(3) it is of the invention to be had the following advantages that compared with existing hydrogen rich water technology of preparing：Compared with direct current electrolysis water, close
Golden ceramic material has that cost is low, using simple, be avoided that and produce the peculiar smell such as ozone, the hydrogen rich water produced is alkalescent, micro-
Secondary element enriches；Compared with hydrogen is filled with water process for making hydrogen, alloy ceramic process for making hydrogen has storage easy, avoids manufacturing
Hydrogen water function is single, can manufacture and integrate the advantages such as hydrogen-rich, negative potential water, small molecule, alkalescence and antibacterial；With metal magnesium material
Process for making hydrogen is compared, and alloy ceramic has the advantages that not aoxidize, is not likely to produce sediment, rich in trace element.
(4) preparation method of the present invention, have be easy to industrialized production, good in economic efficiency, practical ranges are wide
The advantages that.
(5) preparation method of the present invention, stratiform functional layer and microcellular structure can be formed, adds the ratio surface of material
Area, enhance light electrolysis hydrogen production efficiency.
Brief description of the drawings
Fig. 1 is the manufacture hydrogen rich water alloy ceramic appearance assumption diagram that the embodiment of the present invention 1 is prepared；
Fig. 2 is the manufacture hydrogen rich water alloy ceramic appearance assumption diagram that the embodiment of the present invention 2 is prepared；
Fig. 3 is the manufacture hydrogen rich water alloy ceramic appearance assumption diagram that the embodiment of the present invention 4 is prepared；
Fig. 4 is the manufacture hydrogen rich water alloy ceramic appearance assumption diagram that the embodiment of the present invention 5 is prepared.
Embodiment
With reference to embodiment, the present invention will be further described.
All raw materials used in embodiment are purchased in market unless otherwise specified.
Embodiment 1
Described manufacture hydrogen rich water alloy ceramic, is made up of the raw material of following parts by weight：
16 parts of 57 parts of substrate component, 40 parts of hydrogen-rich component, 13 parts of antibacterial components and binding agent；
The substrate component is made up of the raw material of following percetage by weight：
Tourmaline 32%, water member stone 20%, silica 28%, calcium oxide 10% and zeolite 10%.
The hydrogen-rich component is made up of the raw material of following percetage by weight：
Metal magnesium powder 30%, magnesia powder 20% and KDF alloy powders 50%.
The antibacterial components are made up of the raw material of following percetage by weight：
Zinc oxide 20%, titanium oxide 50% and cerium oxide 30%.
The binding agent is made up of the raw material of following percetage by weight：
High-purity distilled water 30%, carboxy-propyl cellulose 30% and bentonite 40%.
The preparation method：
(1) pre-process：
By tourmaline, water member stone, silica, calcium oxide and zeolite mixed grinding 6h, to 500 μm of diameter of particle ＜, base is obtained
Material component；
By zinc oxide, titanium oxide, cerium oxide mixed grinding 8h, to 50 μm of diameter of particle ＜, antibacterial components are obtained；
Metal magnesium powder, magnesia powder and KDF alloy powders are mixed, obtain hydrogen-rich component；
High-purity distilled water, carboxy-propyl cellulose and bentonite are mixed, obtain binding agent；
(2) batch mixing：Substrate component, hydrogen-rich component and antibacterial components are added into batch mixer by charge ratio, mixed 1 hour；
(3) it is molded：The material for the mixing that step (2) is prepared is added to nodulizer shaping, and forming process is constantly sprayed
Spill binding agent；
(4) bakee, screen：Material is bakeed, screened after the shaping that step (3) is prepared, and produces described system
Get rich hydrogen water alloy ceramic.
Wherein, stoving temperature is 150 DEG C, and the baking time is 2h.
Described manufacture hydrogen rich water alloy ceramic is shaped as granular pattern.
Embodiment 2
Described manufacture hydrogen rich water alloy ceramic, is made up of the raw material of following parts by weight：
12 parts of 60 parts of substrate component, 50 parts of hydrogen-rich component, 20 parts of antibacterial components and binding agent；
The substrate component is made up of the raw material of following percetage by weight：
Tourmaline 25%, water member stone 10%, silica 20%, calcium oxide 20% and zeolite 25%.
The hydrogen-rich component is made up of the raw material of following percetage by weight：
Metal magnesium powder 40%, magnesia powder 20% and KDF alloy powders 40%.
The antibacterial components are made up of the raw material of following percetage by weight：
Zinc oxide 30%, titanium oxide 50% and cerium oxide 20%.
The binding agent is made up of the raw material of following percetage by weight：
High-purity distilled water 40%, carboxy-propyl cellulose 10% and bentonite 50%.
The preparation method：
(1) pre-process：
By tourmaline, water member stone, silica, calcium oxide and zeolite mixed grinding 7h, to 500 μm of diameter of particle ＜, base is obtained
Material component；
By zinc oxide, titanium oxide, cerium oxide mixed grinding 6h, to 50 μm of diameter of particle ＜, antibacterial components are obtained；
Metal magnesium powder, magnesia powder and KDF alloy powders are mixed, obtain hydrogen-rich component；
High-purity distilled water, carboxy-propyl cellulose and bentonite are mixed, obtain binding agent；
(2) batch mixing：Substrate component, hydrogen-rich component and antibacterial components are added into batch mixer by charge ratio, mixed 2 hours；
(3) it is molded：The material for the mixing that step (2) is prepared is added to nodulizer shaping, and forming process is constantly sprayed
Spill binding agent；
(4) bakee, screen：Material is bakeed, screened after the shaping that step (3) is prepared, and produces described system
Get rich hydrogen water alloy ceramic.
Wherein, stoving temperature is 200 DEG C, and the baking time is 1.5h.
Described manufacture hydrogen rich water alloy ceramic is shaped as granular pattern.
Embodiment 3
Described manufacture hydrogen rich water alloy ceramic, is made up of the raw material of following parts by weight：
20 parts of 40 parts of substrate component, 30 parts of hydrogen-rich component, 15 parts of antibacterial components and binding agent；
The substrate component is made up of the raw material of following percetage by weight：
Tourmaline 20%, water member stone 15%, silica 35%, calcium oxide 15% and zeolite 15%.
The hydrogen-rich component is made up of the raw material of following percetage by weight：
Metal magnesium powder 50%, magnesia powder 30% and KDF alloy powders 20%.
The antibacterial components are made up of the raw material of following percetage by weight：
Zinc oxide 40%, titanium oxide 40% and cerium oxide 20%.
The binding agent is made up of the raw material of following percetage by weight：
High-purity distilled water 50%, carboxy-propyl cellulose 30% and bentonite 20%.
The preparation method：
(1) pre-process：
By tourmaline, water member stone, silica, calcium oxide and zeolite mixed grinding 8h, to 500 μm of diameter of particle ＜, base is obtained
Material component；
By zinc oxide, titanium oxide, cerium oxide mixed grinding 7h, to 50 μm of diameter of particle ＜, antibacterial components are obtained；
Metal magnesium powder, magnesia powder and KDF alloy powders are mixed, obtain hydrogen-rich component；
High-purity distilled water, carboxy-propyl cellulose and bentonite are mixed, obtain binding agent；
(2) batch mixing：Substrate component, hydrogen-rich component and antibacterial components are added into batch mixer by charge ratio, mixed 3 hours；
(3) it is molded：The material for the mixing that step (2) is prepared is added to nodulizer shaping, and forming process is constantly sprayed
Spill binding agent；
(4) bakee, screen：Material is bakeed, screened after the shaping that step (3) is prepared, and produces described system
Get rich hydrogen water alloy ceramic.
Wherein, stoving temperature is 300 DEG C, and the baking time is 1.5h.
Described manufacture hydrogen rich water alloy ceramic is shaped as granular pattern.
Embodiment 4
Described manufacture hydrogen rich water alloy ceramic, is made up of the raw material of following parts by weight：
25 parts of 85 parts of substrate component, 60 parts of hydrogen-rich component, 25 parts of antibacterial components and binding agent；
The substrate component is made up of the raw material of following percetage by weight：
Tourmaline 40%, water member stone 11%, silica 25%, calcium oxide 12% and zeolite 12%.
The hydrogen-rich component is made up of the raw material of following percetage by weight：
Metal magnesium powder 60%, magnesia powder 30% and KDF alloy powders 10%.
The antibacterial components are made up of the raw material of following percetage by weight：
Zinc oxide 50%, titanium oxide 40% and cerium oxide 10%.
The binding agent is made up of the raw material of following percetage by weight：
High-purity distilled water 60%, carboxy-propyl cellulose 10% and bentonite 30%.
The preparation method：
(1) pre-process：
By tourmaline, water member stone, silica, calcium oxide and zeolite mixed grinding 9h, to 500 μm of diameter of particle ＜, base is obtained
Material component；
By zinc oxide, titanium oxide, cerium oxide mixed grinding 10h, to 50 μm of diameter of particle ＜, antibacterial components are obtained；
Metal magnesium powder, magnesia powder and KDF alloy powders are mixed, obtain hydrogen-rich component；
High-purity distilled water, carboxy-propyl cellulose and bentonite are mixed, obtain binding agent；
(2) batch mixing：Substrate component, hydrogen-rich component and antibacterial components are added into batch mixer by charge ratio, mixed 4 hours；
(3) it is molded：The material for the mixing that step (2) is prepared is added to stamping machine shaping, and forming process is constantly sprayed
Spill binding agent；
(4) bakee, screen：Material is bakeed, screened after the shaping that step (3) is prepared, and produces described system
Get rich hydrogen water alloy ceramic.
Wherein, stoving temperature is 400 DEG C, and the baking time is 1h.
Described manufacture hydrogen rich water alloy ceramic is shaped as wafer type.
Embodiment 5
Described manufacture hydrogen rich water alloy ceramic, is made up of the raw material of following parts by weight：
20 parts of 30 parts of substrate component, 50 parts of hydrogen-rich component, 10 parts of antibacterial components and binding agent；
The substrate component is made up of the raw material of following percetage by weight：
Tourmaline 23%, water member stone 14%, silica 22%, calcium oxide 11% and zeolite 30%.
The hydrogen-rich component is made up of the raw material of following percetage by weight：
Metal magnesium powder 30%, magnesia powder 40% and KDF alloy powders 30%.
The antibacterial components are made up of the raw material of following percetage by weight：
Zinc oxide 50%, titanium oxide 20% and cerium oxide 30%.
The binding agent is made up of the raw material of following percetage by weight：
High-purity distilled water 40%, carboxy-propyl cellulose 50% and bentonite 10%.
The preparation method：
(1) pre-process：
By tourmaline, water member stone, silica, calcium oxide and zeolite mixed grinding 10h, to 500 μm of diameter of particle ＜, base is obtained
Material component；
By zinc oxide, titanium oxide, cerium oxide mixed grinding 9h, to 50 μm of diameter of particle ＜, antibacterial components are obtained；
Metal magnesium powder, magnesia powder and KDF alloy powders are mixed, obtain hydrogen-rich component；
High-purity distilled water, carboxy-propyl cellulose and bentonite are mixed, obtain binding agent；
(2) batch mixing：Substrate component, hydrogen-rich component and antibacterial components are added into batch mixer by charge ratio, mixed 5 hours；
(3) it is molded：The material for the mixing that step (2) is prepared is added to stamping machine shaping, and forming process is constantly sprayed
Spill binding agent；
(4) bakee, screen：Material is bakeed, screened after the shaping that step (3) is prepared, and produces described system
Get rich hydrogen water alloy ceramic.
Wherein, stoving temperature is 480 DEG C, and the baking time is 0.5h.
Described manufacture hydrogen rich water alloy ceramic is shaped as wafer type.
Embodiment 6
Described manufacture hydrogen rich water alloy ceramic, is made up of the raw material of following parts by weight：
30 parts of 70 parts of substrate component, 25 parts of hydrogen-rich component, 5 parts of antibacterial components and binding agent；
The substrate component is made up of the raw material of following percetage by weight：
Tourmaline 20%, water member stone 10%, silica 25%, calcium oxide 35% and zeolite 10%.
The hydrogen-rich component is made up of the raw material of following percetage by weight：
Metal magnesium powder 20%, magnesia powder 60% and KDF alloy powders 20%.
The antibacterial components are made up of the raw material of following percetage by weight：
Zinc oxide 40%, titanium oxide 30% and cerium oxide 30%.
The binding agent is made up of the raw material of following percetage by weight：
High-purity distilled water 30%, carboxy-propyl cellulose 40% and bentonite 30%.
The preparation method：
(1) pre-process：
By tourmaline, water member stone, silica, calcium oxide and zeolite mixed grinding 8h, to 500 μm of diameter of particle ＜, base is obtained
Material component；
By zinc oxide, titanium oxide, cerium oxide mixed grinding 8h, to 50 μm of diameter of particle ＜, antibacterial components are obtained；
Metal magnesium powder, magnesia powder and KDF alloy powders are mixed, obtain hydrogen-rich component；
High-purity distilled water, carboxy-propyl cellulose and bentonite are mixed, obtain binding agent；
(2) batch mixing：Substrate component, hydrogen-rich component and antibacterial components are added into batch mixer by charge ratio, mixed 4 hours；
(3) it is molded：The material for the mixing that step (2) is prepared is added to stamping machine shaping, and forming process is constantly sprayed
Spill binding agent；
(4) bakee, screen：Material is bakeed, screened after the shaping that step (3) is prepared, and produces described system
Get rich hydrogen water alloy ceramic.
Wherein, stoving temperature is 300 DEG C, and the baking time is 1h.
Described manufacture hydrogen rich water alloy ceramic is shaped as diamond type.
Embodiment 7
Described manufacture hydrogen rich water alloy ceramic, is made up of the raw material of following parts by weight：
12 parts of 60 parts of substrate component, 50 parts of hydrogen-rich component, 20 parts of antibacterial components and binding agent；
The substrate component is made up of the raw material of following percetage by weight：
Tourmaline 23%, water member stone 14%, silica 22%, calcium oxide 11% and zeolite 30%.
The hydrogen-rich component is made up of the raw material of following percetage by weight：
Metal magnesium powder 20%, magnesia powder 60% and KDF alloy powders 20%.
The antibacterial components are made up of the raw material of following percetage by weight：
Zinc oxide 40%, titanium oxide 40% and cerium oxide 20%.
The binding agent is carboxy-propyl cellulose.
The preparation method：
(1) pre-process：
By tourmaline, water member stone, silica, calcium oxide and zeolite mixed grinding 8h, to 500 μm of diameter of particle ＜, base is obtained
Material component；
By zinc oxide, titanium oxide, cerium oxide mixed grinding 7h, to 50 μm of diameter of particle ＜, antibacterial components are obtained；
Metal magnesium powder, magnesia powder and KDF alloy powders are mixed, obtain hydrogen-rich component；
(2) batch mixing：Substrate component, hydrogen-rich component and antibacterial components are added into batch mixer by charge ratio, mixed 3 hours；
(3) it is molded：The material for the mixing that step (2) is prepared is added to nodulizer shaping, and forming process is constantly sprayed
Spill binding agent；
(4) bakee, screen：Material is bakeed, screened after the shaping that step (3) is prepared, and produces described system
Get rich hydrogen water alloy ceramic.
Wherein, stoving temperature is 250 DEG C, and the baking time is 2h.
Described manufacture hydrogen rich water alloy ceramic is shaped as granular pattern.
The manufacture hydrogen rich water alloy ceramic that embodiment 3 is prepared is rinsed well with deionized water.By 50 grams of conjunctions
Golden ceramsite material is put into beaker, pours into 200mL pure water, tests the hydrogen of 5 minutes, 10 minutes, 60 minutes and 720 minutes respectively
Content, pH value, TDS values and ORP value, test result are shown in Table 1.
Hydrogen content detection uses U.S. Honeywell Honeywell XP-H2 hydrogen detectors；PH detections are using high accuracy
PH acid-base value test pen acidometer p-II of band temperature-compensating；Using conductive solid particles TDS testers, (South Korea is public for TDS detections
Department's production)；ORP detections are using Shenzhen production MT-8050 type pen type ORP (oxidation-reduction potential).
The test result added in the pure water of table 1 after the manufacture hydrogen rich water alloy ceramic that embodiment 3 is prepared
| 5 minutes | 10 minutes | 60 minutes | 720 minutes | |
| Hydrogen content (ppb) | 560 | 650 | 850 | 1050 |
| PH value | 8.3 | 8.5 | 8.8 | 9.2 |
| TDS values (ppm) | 163 | 173 | 182 | 214 |
| ORP value (mV) | -87 | -123 | -155 | -255 |
The manufacture hydrogen rich water alloy ceramic that embodiment 1-7 is prepared is used to manufacture hydrogen rich water in cup, and it is right
The hydrogen rich water of generation carries out a series of tests.
(1) hydrogen rich water and the pH value of pure water are tested
Pure water and each one glass of hydrogen rich water, with precise chemical reagents paper respectively put in a cup shake (or instill pH value try
Agent).Result of the test：Chemical reagent paper color in pure water is yellow, pH value 5.5；Chemical reagent paper in hydrogen rich water is
Blue (as small-micelle water) pH value is 8.2-9.5.
(2) comparison of running water and hydrogen-rich bubble green tea, milk powder, bean powder is tested
Being made tea with running water has bitter taste and bleaching powder taste, steeps bean powder indissoluble solution, and making milk powder indissoluble also has fishy smell.Use hydrogen-rich
Bubble tea significantly reduces or without bitter taste, tea flavour fragrance；Bean powder, milk powder are just washed open quickly, and pleasant aroma.
(3) test hydrogen rich water and soak small tomato
Hydrogen rich water and each one glass of running water or pure water, several small tomato immersion 5-10 minutes are respectively put into, soak hydrogen-rich
Minute bubbles have been overworked on the tomato of water, it is harder with hand touch texture, it is more fragrant to taste taste；Soak running water or pure water small kind
Eggplant does not have any change.
(4) the laughable experiment of hydrogen rich water
Hydrogen rich water is poured into glass (1/10), instills 2-3 drop pH reagents, display blueness, it is in weak base to illustrate hydrogen rich water
Property (the interior environment for representing healthy body)；A little cola is poured into glass, the color table that reddens shows that cola for acidity, illustrates to drink cola
Vivo environment is highly acid afterwards.By hydrogen rich water injection equipped with laughable glass, color is changed into blueness, represent hydrogen rich water can in
With the acidity of cola.
(5) experiment of hydrogen rich water and glucose
By glucose implantation glass cup (1/5), instill 2-3 drop pH reagents, become it is red represent glucose for highly acid (with
This represents that diabetes patient is acidic constitution).By glass of the hydrogen rich water injection equipped with glucose, color is changed into blueness, represents rich
Hydrogen water can neutralize the acidity of glucose.
(6) hydrogen-rich water soluble oil is tested
Required article：Transparent water cup 5-6, one bottle of pH reagents, pH value contrast table one are opened, one bottle of edible oil, chopsticks a pair of.
Two cups are taken to be separately added into the oil (1/3 glass) of equivalent, then one glass of access hydrogen rich water, one glass of access running water,
Stirred respectively with chopsticks, untill the cup of hydrogen rich water does not see water.Pour into fat unnecessary in oily representative's body in cup
Fat and oily substance, the micel of hydrogen rich water is small, and activity is strong, and solvability is strong, can dissolve emulsified fat, and running water belongs to
Macromolecular mass water, does not decompose emulsification.
(7) hydrogen-rich hydrolysis tea experiment
Required article：Transparent water cup 5-6, one bottle of pH reagents, pH value contrast table one are opened, (Iron Guanyin, can not be too for tealeaves
Dry, coarse tealeaves effect is best) bag.Two cups are taken to be respectively put into the tealeaves of equivalent, one glass of access hydrogen rich water, one glass connects
Enter running water, it can be found that when the color of hydrogen rich water has dark brown, running water or colourless.The water clusters of hydrogen rich water are small, decompose,
Penetrating power is strong, it is easy to the composition in tea bubbled out to come, and the water clusters of running water are big, penetration is poor, so tea does not have
Become color.
(8) tincture of iodine reduction experiment
Required article：Transparent water cup 5-6, one bottle of pH reagents, pH value contrast table one are opened, one bottle of the tincture of iodine, rice, chopsticks one
It is double.Take a small amount of rice to be respectively put into two cups, add a small amount of running water (covering rice), then add 3-4 drops
The tincture of iodine, stir, at this moment water and rice all blackening；Then, one glass of addition hydrogen rich water, the running water of one glass of addition equivalent, this
When：The cup water for adding hydrogen rich water has become clear, meter Bian Bai, and water base of the cup for adding running water does not change.
(9) conductive experiment
Required article：Transparent big cup 5-6 is individual, one bottle of pH reagents, pH value contrast table one are opened, one bottle of pure water, band plug
Electric wire (2 meters or so) one end connect socket and bulb, from centre by a wherein strand disconnect.Two cups are taken to be separately added into
The hydrogen rich water and pure water of amount, the electric wire that first will be switched off are connected, plugged in, and bulb is light, and it is good to illustrate bulb；Again will
The line connected is opened, and is put into pure water, bulb does not work, and illustrates that pure water is free of mineral matter and trace element；Place into hydrogen-rich
The bright horse back of lamp is light in water, illustrates mineral matter of the hydrogen rich water containing abundant ion like.
Claims (5)
1. one kind manufacture hydrogen rich water alloy ceramic, it is characterised in that：It is made up of the raw material of following parts by weight：Substrate component
30-85 parts, hydrogen-rich component 20-60 parts, antibacterial components 2-25 parts and binding agent 3-30 parts；
Wherein,
Substrate component is made up of tourmaline, water member stone, silica, calcium oxide and zeolite；
Hydrogen-rich component is made up of metal magnesium powder, magnesia powder and KDF alloy powders；
Antibacterial components are made up of zinc oxide, titanium oxide and cerium oxide；
Binding agent is the one or more in high-purity distilled water, carboxy-propyl cellulose or bentonite；
Hydrogen-rich component is made up of the raw material of following percetage by weight：
Metal magnesium powder 20-60%, magnesia powder 20-60% and KDF alloy powder 10-50%；
The particle diameter of metal magnesium powder, magnesia powder and KDF alloy powders is 30-100 μm；
Antibacterial components are made up of the raw material of following percetage by weight：
Zinc oxide 20-50%, titanium oxide 20-50% and cerium oxide 5-30%；
Described manufacture hydrogen rich water alloy ceramic is prepared with the following method：
（1）Pretreatment：
By tourmaline, water member stone, silica, calcium oxide and zeolite mixed grinding 6-10h, to 500 μm of diameter of particle ＜, base material is obtained
Component；
By zinc oxide, titanium oxide, cerium oxide mixed grinding 6-10h, to 50 μm of diameter of particle ＜, antibacterial components are obtained；
Metal magnesium powder, magnesia powder and KDF alloy powders are mixed, obtain hydrogen-rich component；
High-purity distilled water, carboxy-propyl cellulose and bentonite are mixed, obtain binding agent；
（2）Batch mixing：Substrate component, hydrogen-rich component and antibacterial components are added into batch mixer by charge ratio, mix 1-5 hours；
（3）Shaping：By step（2）The material for the mixing being prepared is added to nodulizer or stamping machine shaping, and forming process is not
Disconnected sprinkling binding agent；
（4）Bakee, screening：By step（3）Material is bakeed, screened after the shaping being prepared, and it is rich to produce described manufacture
Hydrogen water alloy ceramic；
Stoving temperature is 200-480 DEG C, and the baking time is 0.5-2h.
2. manufacture hydrogen rich water alloy ceramic according to claim 1, it is characterised in that：Substrate component is by following weight
The raw material of percentage is made：
Tourmaline 20-45%, water member stone 10-30%, silica 20-45%, calcium oxide 10-35% and zeolite 10-30%.
3. manufacture hydrogen rich water alloy ceramic according to claim 1, it is characterised in that：Binding agent is by following weight hundred
The raw material of fraction is made：
High-purity distilled water 30-65%, carboxy-propyl cellulose 10-30% and bentonite 20-50%.
4. manufacture hydrogen rich water alloy ceramic according to claim 1, it is characterised in that：Described manufacture hydrogen-rich hydration
Golden ceramic material is shaped as granular pattern, wafer type, column type, diamond type, cast or cardioid.
A kind of 5. application of the manufacture hydrogen rich water alloy ceramic described in claim 1, it is characterised in that：It is applied to water purification
In device, purifying kettle, cup and humidifier product, additionally it is possible to for deodorization decontamination, aquaculture, flower planting, health care and beauty
In industry.
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| CN101417830A (en) * | 2008-09-04 | 2009-04-29 | 张金松 | Filter material for micro electrolysis and preparation method thereof |
| CN101817614B (en) * | 2010-05-14 | 2012-05-02 | 水经(上海)生物科技有限公司 | Micro-polluted drinking water treatment method and equipment |
| CN104072106B (en) * | 2014-07-15 | 2015-08-19 | 任新年 | A kind of water unit feldspar ball and preparation method thereof |
| CN104609527A (en) * | 2015-01-08 | 2015-05-13 | 厦门建霖工业有限公司 | Antibacterial negative potential ball as well as preparation method and application thereof |
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