CN105314670A - 碳酸四氨基合铜的制备方法及其应用 - Google Patents
碳酸四氨基合铜的制备方法及其应用 Download PDFInfo
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- CN105314670A CN105314670A CN201410365004.XA CN201410365004A CN105314670A CN 105314670 A CN105314670 A CN 105314670A CN 201410365004 A CN201410365004 A CN 201410365004A CN 105314670 A CN105314670 A CN 105314670A
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- CN
- China
- Prior art keywords
- molecular sieve
- copper
- preparation
- cha type
- ammonia
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010949 copper Substances 0.000 title claims abstract description 37
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 33
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 claims abstract description 28
- 239000002808 molecular sieve Substances 0.000 claims description 66
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 66
- 229910002796 Si–Al Inorganic materials 0.000 claims description 33
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 22
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 13
- 229910052698 phosphorus Inorganic materials 0.000 claims description 13
- 239000011574 phosphorus Substances 0.000 claims description 13
- 239000007787 solid Substances 0.000 claims description 13
- 238000009423 ventilation Methods 0.000 claims description 12
- 229910021529 ammonia Inorganic materials 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 10
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 6
- 238000009826 distribution Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 239000000969 carrier Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 238000007654 immersion Methods 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 abstract description 11
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 229910001431 copper ion Inorganic materials 0.000 abstract 1
- 238000000746 purification Methods 0.000 abstract 1
- 239000002253 acid Substances 0.000 description 31
- 238000001354 calcination Methods 0.000 description 11
- 239000000243 solution Substances 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 8
- 239000000428 dust Substances 0.000 description 8
- 150000003863 ammonium salts Chemical class 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- 239000000084 colloidal system Substances 0.000 description 4
- 230000000536 complexating effect Effects 0.000 description 4
- 238000009413 insulation Methods 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical group OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- ZICQBHNGXDOVJF-UHFFFAOYSA-N diamantane Chemical compound C1C2C3CC(C4)CC2C2C4C3CC1C2 ZICQBHNGXDOVJF-UHFFFAOYSA-N 0.000 description 2
- 238000003618 dip coating Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- CYPPCCJJKNISFK-UHFFFAOYSA-J kaolinite Chemical compound [OH-].[OH-].[OH-].[OH-].[Al+3].[Al+3].[O-][Si](=O)O[Si]([O-])=O CYPPCCJJKNISFK-UHFFFAOYSA-J 0.000 description 2
- 229910052622 kaolinite Inorganic materials 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- -1 wherein Chemical class 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000010710 diesel engine oil Substances 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
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- Catalysts (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201410365004.XA CN105314670B (zh) | 2014-07-29 | 2014-07-29 | 碳酸四氨基合铜溶液的制备方法 |
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CN201410365004.XA CN105314670B (zh) | 2014-07-29 | 2014-07-29 | 碳酸四氨基合铜溶液的制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN105314670A true CN105314670A (zh) | 2016-02-10 |
CN105314670B CN105314670B (zh) | 2017-09-26 |
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CN201410365004.XA Active CN105314670B (zh) | 2014-07-29 | 2014-07-29 | 碳酸四氨基合铜溶液的制备方法 |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SU1248956A1 (ru) * | 1984-01-02 | 1986-08-07 | Предприятие П/Я А-3481 | Способ получени аммиаката меди |
CN1172074A (zh) * | 1997-08-15 | 1998-02-04 | 张礼英 | 铜包钢氨浸法制氧化铜或硫酸铜 |
CN1362285A (zh) * | 2001-12-20 | 2002-08-07 | 南化集团研究院 | 低汽气比无铬高变催化剂及其制法 |
CN101668589A (zh) * | 2007-02-27 | 2010-03-10 | 巴斯福催化剂公司 | 铜cha沸石催化剂 |
-
2014
- 2014-07-29 CN CN201410365004.XA patent/CN105314670B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SU1248956A1 (ru) * | 1984-01-02 | 1986-08-07 | Предприятие П/Я А-3481 | Способ получени аммиаката меди |
CN1172074A (zh) * | 1997-08-15 | 1998-02-04 | 张礼英 | 铜包钢氨浸法制氧化铜或硫酸铜 |
CN1362285A (zh) * | 2001-12-20 | 2002-08-07 | 南化集团研究院 | 低汽气比无铬高变催化剂及其制法 |
CN101668589A (zh) * | 2007-02-27 | 2010-03-10 | 巴斯福催化剂公司 | 铜cha沸石催化剂 |
Non-Patent Citations (1)
Title |
---|
黄光辉: "孔雀石的化学合成", 《中学化学教学参考》 * |
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Publication number | Publication date |
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CN105314670B (zh) | 2017-09-26 |
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Effective date of registration: 20180504 Address after: 210032 15, B block, Zhong Dan yuan, No. 3-1, new Kumho Road, Nanjing hi tech Development Zone, Jiangsu. Patentee after: Nanjing Kai Li environmental protection materials Co.,Ltd. Address before: 100085 5-1-601, Haidian District, Beijing. Patentee before: Sun Hong |
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Denomination of invention: Preparation method of tetraamino copper carbonate solution Effective date of registration: 20220825 Granted publication date: 20170926 Pledgee: Luzhou Bank Co.,Ltd. Luxian Sub branch Pledgor: Nanjing Kai Li environmental protection materials Co.,Ltd. Registration number: Y2022510000248 |
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Date of cancellation: 20230726 Granted publication date: 20170926 Pledgee: Luzhou Bank Co.,Ltd. Luxian Sub branch Pledgor: Nanjing Kai Li environmental protection materials Co.,Ltd. Registration number: Y2022510000248 |
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Denomination of invention: Preparation Method of Copper Tetraamino Carbonate Solution Effective date of registration: 20230731 Granted publication date: 20170926 Pledgee: Luzhou Bank Co.,Ltd. Luxian Sub branch Pledgor: Nanjing Kai Li environmental protection materials Co.,Ltd. Registration number: Y2023510000187 |