CN105293483B - A kind of method that original position prepares transient metal doped porous graphene - Google Patents
A kind of method that original position prepares transient metal doped porous graphene Download PDFInfo
- Publication number
- CN105293483B CN105293483B CN201510900841.2A CN201510900841A CN105293483B CN 105293483 B CN105293483 B CN 105293483B CN 201510900841 A CN201510900841 A CN 201510900841A CN 105293483 B CN105293483 B CN 105293483B
- Authority
- CN
- China
- Prior art keywords
- transition metal
- graphene
- chitosan
- doped porous
- porous graphene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Abstract
The present invention relates to a kind of method that original position prepares transient metal doped porous graphene.Specific steps include：The preparation of chitosan/transition metal particles complex：The salting liquid of transition metal is well mixed with chitosan aqueous solution, glacial acetic acid solution is added dropwise, is sufficiently stirred for being formed colloid, freeze-dried formation chitosan foam, the salt of the transition metal and the mass ratio of chitosan are 1:5‑50；Chitosan foam is placed in non-oxidizing atmosphere and calcined, the mixture of transition metal/graphene is made under the catalysis of transition metal；By the mixture and K of transition metal/graphene2HPO4Solid phase is blended, and is placed in non-oxidizing atmosphere and calcines after ball milling；Pickling removes which part transition metal and impurity, and vacuum drying is produced.Catalytic conversion and corrasion of the present invention by transition metal, using chitosan as raw material, remove transition metal particles with reference to pickling, prepare transient metal doped porous graphene, suitable for large-scale promotion.
Description
Technical field
The present invention relates to porous carbon materials and field of nanometer material technology, specifically a kind of original position prepares transient metal doped many
The method of hole graphene.
Background technology
Graphene is the two-dimentional allotrope of carbon.From 2004, Geim etc. [1] was successfully separated out graphene using adhesive tape
Since, graphene rapidly becomes the study hotspot in the whole world.Graphene integrates numerous good characteristics, such as high carrier migration
Rate, good translucency, high heat conductance, high mechanical properties and high electrochemical stability etc..Wherein, most peculiar part is stone
The electric property that the unique electronic structure of black alkene is shown, electron-trajectory transport such as at room temperature, unusual quantum hall effect
With quantum tunneling effect etc..Carbon atom in graphene is with SP2Hybridized orbit and adjacent carbon atom formation σ keys, remaining P electricity
Sub-track then constitutes pi bond, therefore electron cloud is symmetric in carbon atom plane both sides.This bonding mode is similar with phenyl ring,
So graphene can regard the condensed-nuclei aromatics being made up of a large amount of phenyl ring as.Although CNT and fullerene also have SP2Hydridization
Structure, but the angle between the carbon atom of bonding is less than 120 °, 120 ° of intrinsic angle differences with graphene, this is just determined
Graphene carbon atom it is active relatively low.The existing method for preparing graphene is mainly oxidation-reduction method, micromechanics stripping method, liquid
Phase stripping method, epitaxial growth method, chemical vapour deposition technique and arc process etc..These methods exist that cost is higher and yield compared with
Low the problem of, such as in oxidation-reduction method, graphene is easily reunited in the liquid phase, reduces the quality of graphene.
Recently, porous graphene material receives extensive research, and due to the pore structure of porous graphene in itself, it has
Higher specific surface area and the passage for storing and transporting beneficial to electrons/ions, gas and liquid.Such as Ruoff [2] uses KOH
Activation process graphene oxide, prepares the super capacitor material of higher energy density and specific capacitance.[3] such as wooden scholar's spring are used
Acid treatment graphene oxide, obtains porous graphene, and the carrier of the noble metal catalyst as Proton Exchange Membrane Fuel Cells,
Drastically increase the mass transfer ability of Catalytic Layer.Graphene is as a kind of new carbon material, and introducing will pole after loose structure
The earth improves some shortcomings that graphene is present, and particularly the porous graphene after heterogeneous nonmetal doping can be extensive
It is applied to energy storage and conversion art, such as fuel cell and lithium ion battery [4,5].
The technology of preparing of the catforming of current graphene is more ripe, chemical vapour deposition technique [6] be based on
The catalytic action of metal (such as Ni-based, copper-based) is crossed, solid-state or gaseous carbon source are converted into graphene at a certain temperature
Method.For the catalysis corrasion of transition metal, Chinese patent literature CN102849734A then discloses " a kind of with transition
The method that metal or transistion metal compound prepare porous graphene for activator ", this method utilizes transition metal and its chemical combination
Thing catalysis etching graphene sheet layer, loose structure is obtained with this.But this method is that, using graphene as raw material, cost is higher, no
It is suitable for large-scale promotion.And for the report of transient metal doped graphene, such as Dai [7] is by cobalt acetate and graphene oxide
Mixing, is made the graphene of cobaltosic oxide doping after hydro-thermal reaction, and the composite material exhibits go out excellent oxygen reduction activity.
But do not possess loose structure with this obtained graphene, and the cobaltosic oxide of load easily comes off from graphenic surface.
Therefore, herein by the catalytic conversion and corrasion of transition metal and its compound, by the chitosan after carbonization
Graphene is partially converted into, then pickling removes part metals particle, obtains the porous graphene material of transition metal original position doping
Material.
[1]Novoselov K S,Geim A K,Morozov S V,et al.Electric field effect in
atomically thin carbon films[J].science,2004,306(5696):666-669.
[2]Zhu Y,Murali S,Stoller M D,et al.Carbon-based supercapacitors
produced by activation of graphene[J].Science,2011,332(6037):1537-1541.
[3]Cheng K,He D,Peng T,et al.Porous graphene supported Pt catalysts
for proton exchange membrane fuel cells[J].Electrochimica Acta,2014,132:356-
363.
[4]Xiao J,Mei D,Li X,et al.Hierarchically porous graphene as a
lithium–air battery electrode[J].Nano letters,2011,11(11):5071-5078.
[5]Han S,Wu D,Li S,et al.Porous graphene materials for advanced
electrochemical energy storage and conversion devices[J].Advanced Materials,
2014,26(6):849-864.
[6]Reina A,Jia X,Ho J,et al.Large area,few-layer graphene films on
arbitrary substrates by chemical vapor deposition[J].Nano letters,2008,9(1):
30-35.
[7]Liang Y,Li Y,Wang H,et al.Co3O4nanocrystals on graphene as a
synergistic catalyst for oxygen reduction reaction[J].Nature materials,2011,
10(10):780-786.
The content of the invention
The technical problems to be solved by the invention are for transient metal doped porous graphene porous stone in the prior art
There is provided a kind of method that original position prepares transient metal doped porous graphene for deficiency present in black alkene preparation.
In order to solve the above technical problems, the technical solution adopted by the present invention is：
A kind of method that original position prepares transient metal doped porous graphene, specific steps include：
(1) preparation of chitosan/transition metal particles complex：The salting liquid of transition metal and chitosan aqueous solution are mixed
Close uniform, glacial acetic acid solution is added dropwise, is sufficiently stirred for forming colloid, freeze-dried formation chitosan foam, the transition metal
Salt and chitosan mass ratio be 1:5-50；
(2) by chitosan foam be placed in non-oxidizing atmosphere calcine, under the catalysis of transition metal be made transition metal/
The mixture of graphene；
(3) by the mixture and K of transition metal/graphene2HPO4Solid phase is blended, and non-oxidizing gas are placed in after ball milling
Calcined in atmosphere；
(4) pickling removes which part transition metal and impurity, and transient metal doped porous graphite can be made in vacuum drying
Alkene.
In such scheme, the transition metal described in step (1) is in platinum, palladium, iron, cobalt, nickel, copper, gold, silver, zinc, chromium
One or more.
In such scheme, the chitosan aqueous solution concentration described in step (1) is 20mg/mL~50mg/mL.
In such scheme, the concentration of salt solution of the transition metal described in step (1) is 0.5mg/mL~10mg/mL.
In such scheme, the glacial acetic acid solution consumption described in step (1) is the 0.5%~3% of mixed liquor volume.
In such scheme, the mixing time described in step (1) is 1~12h.
In such scheme, non-oxidizing atmosphere described in step (2), (4) be one kind in argon gas, nitrogen, hydrogen or
It is several.
In such scheme, the calcining heat described in step (2) is 700~1200 DEG C, and soaking time is 1~5h, heating speed
Rate is 3~10 DEG C/min.
In such scheme, carbon material mixture and K described in step (3)2HPO4Mass ratio be 1~4:4~1, during ball milling
Between be 4-6h.
In such scheme, the calcining heat described in step (3) is 700~1100 DEG C, and heating rate is 3~8 DEG C/min, is protected
The warm time is 1~5h.
In such scheme, in step (4), one kind in sulfuric acid, hydrochloric acid, acetic acid, nitric acid, chloroazotic acid of described acid or
It is several.
In such scheme, in step (4), the concentration of pickling is 1~6mol/L.
In such scheme, in step (4), the temperature of vacuum drying treatment is 40~80 DEG C, and drying time is 1~24h.
Transition metal salt and chitosan are mixed after gel by the present invention, and metal ion will effectively be adsorbed in chitosan
In skeleton, dewater treatment is made using the method for lyophilized auxiliary, and in calcining carbonization in reacting furnace, obtain transistion metal compound with
The mixture of carbon, in the process, metallic can play a part of catalyst and etching agent, and carbon material is catalytically conveted into stone
Black alkene.Then K is utilized2HPO4At high temperature carbon material is carried out activation process to open carbon-coating, promote acid solution to penetrate into carbon-coating
In, part metals particle is removed, so that transient metal doped porous graphene is made.
The invention has the advantages that：Catalytic conversion and corrasion of the present invention by transition metal, using chitosan as raw material,
Chitosan nitrogenous characteristic in itself is taken full advantage of, transition metal particles is removed with reference to pickling, common carbon source can be converted into
Metal-doped porous graphene is crossed, it is suitable for large-scale promotion.And this technique is relatively simple, the cycle is short and cost is relatively low, prepares
Porous graphene pore structure enrich, pore-size distribution is wide, and hole density is big, passes through and changes the addition of transition metal salt and can adjust hole
Density；It is with low cost not using graphene oxide or graphene as raw material, it can be mass-produced.It may be used on fuel cell
In catalyst, lithium ion battery negative material and ultracapacitor, with extensive prospect.
Brief description of the drawings
Fig. 1 is the transmission electron microscope picture of transient metal doped porous graphene.
Wherein:(a), (b) is the porous graphene region without transition metal；(c) it is porous graphene cladding transition gold
The region of category.
Fig. 2 is the Raman spectrogram of transient metal doped porous graphene.
Wherein：(a) it is the Raman spectrogram for the mixture for calcining obtained transition metal/graphene for the first time, (b) is warp
Pickling removes the Raman spectrogram of transition metal.
Fig. 3 is the XRD spectrum of transient metal doped porous graphene.
Embodiment
Content for a better understanding of the present invention, is further illustrated below with reference to instantiation.But should refer to
Go out, implementation of the invention is not limited to following several embodiments.
Embodiment 1
1g chitosans are scattered in 30ml deionized waters, 10mL acetic acid cobalt liquors are added, solution concentration is 10mg/mL,
Ultrasonic 30min, then stirring 5h formation chitosan colloids under 2.5% glacial acetic acid solution, normal temperature are slowly added dropwise.Chitosan colloid is turned
Move in freeze drier, chitosan foam is made after dehydration completely.Then chitosan foam is placed in vacuum tube furnace,
Protective atmosphere is high-purity argon gas, and heating rate is 3 DEG C/min, and is incubated 2h at 800 DEG C, obtains transition metal/graphene
Mixture.By transition metal/graphene mixture and K2HPO4By 1：3 mass ratio solid phase mixing, and in planetary ball mill
Middle grinding 4h, transfers in vacuum tube furnace and calcines, protective atmosphere is high-purity argon gas, is risen to by 5 DEG C/min heating rate
900 DEG C, it is incubated 2h.Hydrochloric acid solution pickling of the reaction product through 6mol/L after calcining, and filtering and washing is to neutrality, it is true at 60 DEG C
Sky is dried, and transition metal cobaltosic oxide doping porous graphene is made.As shown in Fig. 1 (a), the region is transmission electron microscope observing
Under porous graphene low power image, with abundant porous network structure.After amplified, it is observed that obvious ring
Shape graphene lattice fringe, and the removal that middle hole is due to transition metal is caused, such as shown in Fig. 1 (b).And in Fig. 1
(c) in, clearly cobaltosic oxide metal lattice striped is occurred in that, surrounding is then the graphene layer of cladding.Fig. 2 Raman spectrums
Show, in 2700cm in the Raman spectrogram of the mixture of transition metal/graphene after calcining for the first time-1There is graphite in place
The 2D peaks of alkene, I (D)/I (G) value is 1.13, shows just to have obtained I (D)/I after graphene, pickling by first time calcining
(G) value rises to 1.53, and this is due to the removal of cobaltosic oxide and causes the formation of a large amount of hole defects.Fig. 3 is then four oxidations
The XRD spectrum of three cobalt doped porous graphenes, wherein, 2 θ=21.8 ° are (002) peak of graphene, when 2 θ are 32 °, 37 °, 45 °
(220) of cobaltosic oxide, (311), (400) peak are corresponded to respectively.
Embodiment 2
1g chitosans are scattered in 50ml deionized waters, 8mL iron nitrate solutions are added, solution concentration is 5mg/mL, surpassed
Sound 30min, then stirring 12h formation chitosan colloids under 0.9% glacial acetic acid solution, normal temperature are slowly added dropwise.Chitosan colloid is turned
Move in freeze drier, chitosan foam is made after dehydration completely.Then chitosan foam is placed in vacuum tube furnace,
Protective atmosphere is high pure nitrogen, and heating rate is 5 DEG C/min, and is incubated 2h at 700 DEG C, obtains transition metal/graphene
Mixture.By transition metal/graphene mixture and K2HPO4By 1：4 mass ratio solid phase mixing, and in planetary ball mill
Middle grinding 4h, transfers in vacuum tube furnace and calcines, protective atmosphere is high pure nitrogen, is risen to by 3 DEG C/min heating rate
800 DEG C, it is incubated 1h.Sulfuric acid solution pickling of the reaction product through 1mol/L after calcining, and filtering and washing is to neutrality, it is true at 40 DEG C
Sky is dried, and transient metal doped porous graphene is made.
Embodiment 3
1g chitosans are scattered in 20ml deionized waters, 40mL acetic acid zinc solutions are added, solution concentration is 0.5mg/mL,
Ultrasonic 30min, then stirring 8h formation chitosan colloids under 3% glacial acetic acid solution, normal temperature are slowly added dropwise.Chitosan colloid is shifted
Into freeze drier, chitosan foam is made after dehydration completely.Then chitosan foam is placed in vacuum tube furnace, protected
Shield atmosphere is high-purity argon gas, and heating rate is 4 DEG C/min, and is incubated 1h at 1000 DEG C, obtains the mixed of transition metal/graphene
Compound.By transition metal/graphene mixture and K2HPO4By 1：2 mass ratio solid phase mixing, and in planetary ball mill
Grinding 5h, transfers in vacuum tube furnace and calcines, protective atmosphere is high-purity argon gas, and 700 are risen to by 8 DEG C/min heating rate
DEG C, it is incubated 3h.Acetum pickling of the reaction product through 2mol/L after calcining, and filtering and washing is to neutrality, vacuum at 70 DEG C
Dry, transient metal doped porous graphene is made.
Embodiment 4
1g chitosans are scattered in 40ml deionized waters, the ammino platinum solution of 4mL dinitrosos two is added, solution concentration is
8mg/mL, ultrasonic 30min, then stirring 4h formation chitosan colloids under 0.5% glacial acetic acid solution, normal temperature are slowly added dropwise.Shell is gathered
Carbohydrate gum body is transferred in freeze drier, and chitosan foam is made after dehydration completely.Then chitosan foam is placed in vacuum
In tube furnace, protective atmosphere is hydrogen, and heating rate is 6 DEG C/min, and is incubated 4h at 900 DEG C, obtains transition metal/graphite
The mixture of alkene.By transition metal/graphene mixture and K2HPO4By 1：1 mass ratio solid phase mixing, and in planetary ball
Grinding 5h in grinding machine, transfers in vacuum tube furnace and calcines, protective atmosphere is hydrogen, is risen to by 5 DEG C/min heating rate
1000 DEG C, it is incubated 2h.Wang aqueous solution pickling of the reaction product through 3mol/L after calcining, and filtering and washing is to neutrality, at 50 DEG C
Vacuum drying, is made transient metal doped porous graphene.
Embodiment 5
1g chitosans are scattered in 30ml deionized waters, 5mL dichlorodiamine palladium solution are added, solution concentration is 10mg/
ML, ultrasonic 30min, then stirring 6h formation chitosan colloids under 2% glacial acetic acid solution, normal temperature are slowly added dropwise.By chitosan colloid
It is transferred in freeze drier, chitosan foam is made after dehydration completely.Then chitosan foam is placed in vacuum tube furnace
In, protective atmosphere is hydrogen, and heating rate is 5 DEG C/min, and is incubated 5h at 800 DEG C, obtains the mixed of transition metal/graphene
Compound.By transition metal/graphene mixture and K2HPO4By 2：1 mass ratio solid phase mixing, and in planetary ball mill
Grinding 4h, transfers in vacuum tube furnace and calcines, protective atmosphere is hydrogen, and 900 DEG C are risen to by 6 DEG C/min heating rate,
It is incubated 4h.Wang aqueous solution pickling of the reaction product through 3mol/L after calcining, and filtering and washing is to neutrality, vacuum is done at 60 DEG C
It is dry, transient metal doped porous graphene is made.
Embodiment 6
1g chitosans are scattered in 40ml deionized waters, 20mL nickel acetate solutions are added, solution concentration is 5mg/mL, surpassed
Sound 30min, then stirring 8h formation chitosan colloids under 2.8% glacial acetic acid solution, normal temperature are slowly added dropwise.Chitosan colloid is shifted
Into freeze drier, chitosan foam is made after dehydration completely.Then chitosan foam is placed in vacuum tube furnace, protected
Shield atmosphere is high pure nitrogen, and heating rate is 10 DEG C/min, and is incubated 1h at 1100 DEG C, obtains transition metal/graphene
Mixture.By transition metal/graphene mixture and K2HPO4By 3：1 mass ratio solid phase mixing, and in planetary ball mill
Middle grinding 6h, transfers in vacuum tube furnace and calcines, protective atmosphere is high pure nitrogen, is risen to by 4 DEG C/min heating rate
1000 DEG C, it is incubated 2h.Hydrochloric acid solution pickling of the reaction product through 4mol/L after calcining, and filtering and washing is to neutrality, at 40 DEG C
Vacuum drying, is made transient metal doped porous graphene.
Embodiment 7
1g chitosans are scattered in 30ml deionized waters, 10mL silver nitrate solutiones are added, solution concentration is 5mg/mL, surpassed
Sound 30min, then stirring 1h formation chitosan colloids under 1.5% glacial acetic acid solution, normal temperature are slowly added dropwise.Chitosan colloid is shifted
Into freeze drier, chitosan foam is made after dehydration completely.Then chitosan foam is placed in vacuum tube furnace, protected
Shield atmosphere is high-purity argon gas, and heating rate is 8 DEG C/min, and is incubated 1h at 1200 DEG C, obtains the mixed of transition metal/graphene
Compound.By transition metal/graphene mixture and K2HPO4By 1：1 mass ratio solid phase mixing, and in planetary ball mill
Grinding 4h, transfers in vacuum tube furnace and calcines, protective atmosphere is high-purity argon gas, and 800 are risen to by 6 DEG C/min heating rate
DEG C, it is incubated 5h.Salpeter solution pickling of the reaction product through 6mol/L after calcining, and filtering and washing is to neutrality, vacuum at 40 DEG C
Dry, transient metal doped porous graphene is made.
Embodiment 8
1g chitosans are scattered in 40ml deionized waters, 10mL copper-baths are added, solution concentration is 20mg/mL,
Ultrasonic 30min, then stirring 10h formation chitosan colloids under 1.25% glacial acetic acid solution, normal temperature are slowly added dropwise.By chitosan colloid
It is transferred in freeze drier, chitosan foam is made after dehydration completely.Then chitosan foam is placed in vacuum tube furnace
In, protective atmosphere is hydrogen, and heating rate is 4 DEG C/min, and is incubated 2h at 1000 DEG C, obtains transition metal/graphene
Mixture.By transition metal/graphene mixture and K2HPO4By 1：4 mass ratio solid phase mixing, and in planetary ball mill
Middle grinding 6h, transfers in vacuum tube furnace and calcines, protective atmosphere is hydrogen, and 1100 are risen to by 5 DEG C/min heating rate
DEG C, it is incubated 2h.Salpeter solution pickling of the reaction product through 2mol/L after calcining, and filtering and washing is to neutrality, vacuum at 40 DEG C
Dry, transient metal doped porous graphene is made.
Embodiment 9
1g chitosans are scattered in 20ml deionized waters, 5mL chlorauric acid solutions are added, solution concentration is 4mg/mL, surpassed
Sound 30min, then stirring 8h formation chitosan colloids under 2% glacial acetic acid solution, normal temperature are slowly added dropwise.Chitosan colloid is transferred to
In freeze drier, chitosan foam is made after dehydration completely.Then chitosan foam is placed in vacuum tube furnace, protected
Atmosphere is high-purity argon gas, and heating rate is 8 DEG C/min, and is incubated 3h at 800 DEG C, obtains the mixing of transition metal/graphene
Thing.By transition metal/graphene mixture and K2HPO4By 1：2 mass ratio solid phase mixing, and the powder in planetary ball mill
5h is ground, transfers in vacuum tube furnace and calcines, protective atmosphere is high-purity argon gas, and 800 are risen to by 5 DEG C/min heating rate
DEG C, it is incubated 3h.Wang aqueous solution pickling of the reaction product through 3mol/L after calcining, and filtering and washing is to neutrality, vacuum at 40 DEG C
Dry, transient metal doped porous graphene is made.
Embodiment 10
1g chitosans are scattered in 30ml deionized waters, 10mL acetic acid chromium solutions are added, solution concentration is 20mg/mL,
Ultrasonic 30min, then stirring 5h formation chitosan colloids under 3% glacial acetic acid solution, normal temperature are slowly added dropwise.Chitosan colloid is shifted
Into freeze drier, chitosan foam is made after dehydration completely.Then chitosan foam is placed in vacuum tube furnace, protected
Shield atmosphere is high pure nitrogen, and heating rate is 4 DEG C/min, and is incubated 3h at 1100 DEG C, obtains the mixed of transition metal/graphene
Compound.By transition metal/graphene mixture and K2HPO4By 4：1 mass ratio solid phase mixing, and in planetary ball mill
Grinding 5h, transfers in vacuum tube furnace and calcines, protective atmosphere is high pure nitrogen, and 900 are risen to by 3 DEG C/min heating rate
DEG C, it is incubated 1h.Salpeter solution pickling of the reaction product through 1mol/L after calcining, and filtering and washing is to neutrality, vacuum at 80 DEG C
Dry, transient metal doped porous graphene is made.
The characterizing method of reference implementation example 1, has carried out transmission electron microscope etc. to the embodiment 2-10 materials prepared and has characterized, as a result
Show that embodiment 2-10 has prepared transient metal doped porous graphene.
Claims (9)
1. a kind of method that original position prepares transient metal doped porous graphene, it is characterised in that：Specific steps include：
（1）The preparation of chitosan/transition metal particles complex：The salting liquid of transition metal is mixed with chitosan aqueous solution
It is even, glacial acetic acid solution is added dropwise, is sufficiently stirred for forming colloid, freeze-dried formation chitosan foam, the salt of the transition metal
Mass ratio with chitosan is 1:5-50；Step（1）Described transition metal be selected from platinum, palladium, iron, cobalt, nickel, copper, gold, silver, zinc,
One or more in chromium；
（2）Chitosan foam is placed in 700 ~ 1200 DEG C of calcinings in non-oxidizing atmosphere, was made under the catalysis of transition metal
Cross the mixture of Metal/grapheme；
（3）By the mixture and K of transition metal/graphene2HPO4Solid phase is blended, and is placed in after ball milling in non-oxidizing atmosphere
Calcining；
（4）Pickling removes which part transition metal and impurity, and transient metal doped porous graphene can be made in vacuum drying.
2. the method that original position according to claim 1 prepares transient metal doped porous graphene, it is characterised in that：Step
（1）Described chitosan aqueous solution concentration is 20mg/mL ~ 50mg/mL；Step（1）The concentration of salt solution of described transition metal
For 0.5mg/mL ~ 10mg/mL.
3. the method that original position according to claim 1 prepares transient metal doped porous graphene, it is characterised in that：Step
（1）Described glacial acetic acid solution consumption is the 0.5% ~ 3% of mixed liquor volume；Step（1）Described mixing time is 1 ~ 12h.
4. the method that original position according to claim 1 prepares transient metal doped porous graphene, it is characterised in that：Step
（2）、（3）Described non-oxidizing atmosphere is the one or several kinds in argon gas, nitrogen, hydrogen.
5. the method that original position according to claim 1 prepares transient metal doped porous graphene, it is characterised in that：Step
（2）Calcining soaking time used is 1 ~ 5h, and heating rate is 3 ~ 10 DEG C/min.
6. the method that original position according to claim 1 prepares transient metal doped porous graphene, it is characterised in that：Step
（3）Described transition metal/graphene and K2HPO4Mass ratio be 1~4:4~1, Ball-milling Time is 4-6h.
7. the method that original position according to claim 1 prepares transient metal doped porous graphene, it is characterised in that：Step
（3）Described calcining heat is 700 ~ 1100 DEG C, and heating rate is 3 ~ 8 DEG C/min, and soaking time is 1 ~ 5h.
8. the method that original position according to claim 1 prepares transient metal doped porous graphene, it is characterised in that：Step
（4）In, the described sour one or several kinds in sulfuric acid, hydrochloric acid, acetic acid, nitric acid, chloroazotic acid.
9. the method that original position according to claim 1 prepares transient metal doped porous graphene, it is characterised in that：Step
（4）In, the concentration of spent pickling acid is 1 ~ 6mol/L；The temperature of vacuum drying treatment is 40 ~ 80 DEG C, and drying time is 1 ~ 24h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510900841.2A CN105293483B (en) | 2015-12-08 | 2015-12-08 | A kind of method that original position prepares transient metal doped porous graphene |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510900841.2A CN105293483B (en) | 2015-12-08 | 2015-12-08 | A kind of method that original position prepares transient metal doped porous graphene |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105293483A CN105293483A (en) | 2016-02-03 |
| CN105293483B true CN105293483B (en) | 2017-07-11 |
Family
ID=55191430
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510900841.2A Expired - Fee Related CN105293483B (en) | 2015-12-08 | 2015-12-08 | A kind of method that original position prepares transient metal doped porous graphene |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105293483B (en) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI648423B (en) * | 2016-03-08 | 2019-01-21 | 財團法人工業技術研究院 | Metal-doped graphene and growth method of the same |
| CN105923629B (en) * | 2016-04-26 | 2018-08-17 | 哈尔滨工程大学 | The method that dipping recrystallization carbonization biomass prepares the compound Heteroatom doping porous carbon materials of transition metal |
| CN106356537B (en) * | 2016-11-18 | 2019-05-28 | 中南大学 | A kind of preparation method of N doping porous carbon foam material and its application in metal-air battery |
| KR20200028408A (en) | 2017-07-10 | 2020-03-16 | 존 알렉산더 노엘 | Phase change material and its production method |
| CN108011110A (en) * | 2017-11-23 | 2018-05-08 | 华南理工大学 | A kind of transition metal of high-specific surface area-nitrogen co-doped carbon oxygen reduction catalyst and preparation method and application |
| CN108470916B (en) * | 2018-02-07 | 2020-09-01 | 深圳大学 | Fuel cell oxygen reduction catalyst taking three-dimensional porous carbon material as raw material and preparation method thereof |
| CN109592673B (en) * | 2018-11-07 | 2022-01-28 | 江苏城乡建设职业学院 | Preparation method of graphene oxide supported silver-palladium composite material |
| CN110067003B (en) * | 2019-04-22 | 2020-05-05 | 北京航空航天大学 | Metal monoatomic doped graphene material and preparation method and application thereof |
| CN110201702A (en) * | 2019-06-14 | 2019-09-06 | 北京大学深圳研究生院 | Carbon carries the nitrogenous compound oxygen reduction catalyst preparation method of monoatomic metal and gained catalyst |
| CN110240143A (en) * | 2019-07-15 | 2019-09-17 | 浙江工业大学 | It is a kind of for the N doping carbon aerogel material of supercapacitor, preparation method and application |
| CN110400935A (en) * | 2019-07-30 | 2019-11-01 | 南京汉尔斯生物科技有限公司 | A kind of preparation method and fuel cell electrode of fuel cell nano-electrode material |
| CN110327964A (en) * | 2019-08-02 | 2019-10-15 | 浙江师范大学 | A kind of vanadium catalyst and preparation method thereof for thioether selective oxidation |
| CN111732102B (en) * | 2019-12-04 | 2021-06-15 | 中国科学院上海硅酸盐研究所 | Method for preparing porous carbon material by ruthenium particle assisted etching in strong alkaline environment |
| CN113772619B (en) * | 2020-06-10 | 2023-07-11 | 宝山钢铁股份有限公司 | Microporous channel membrane and preparation method thereof |
| CN113101926B (en) * | 2021-03-18 | 2023-03-31 | 杭州电子科技大学 | Preparation method of metal composite graphene oxygen reduction reaction electrocatalyst material |
| CN113120878A (en) * | 2021-04-19 | 2021-07-16 | 北京化工大学 | Preparation method of N, B co-doped carbon-based supercapacitor electrode material |
| CN114408903A (en) * | 2022-01-12 | 2022-04-29 | 华南理工大学 | Method for preparing in-plane porous few-layer graphene material at low temperature in environment-friendly manner |
| CN114572973A (en) * | 2022-05-03 | 2022-06-03 | 营口理工学院 | Method for preparing graphene composite aerogel by intercalation-in-situ polymerization synergistic method |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102515151A (en) * | 2011-12-22 | 2012-06-27 | 哈尔滨工程大学 | Porous graphene with stratified columnar support structure and its preparation method |
| CN104003374A (en) * | 2014-05-04 | 2014-08-27 | 昆明理工大学 | Preparation method of graphene-based nanocomposite material having three-dimensional porous structure |
| CN104925796B (en) * | 2015-06-24 | 2017-03-15 | 上海大学 | A kind of preparation method of porous class grapheme material |
-
2015
- 2015-12-08 CN CN201510900841.2A patent/CN105293483B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN105293483A (en) | 2016-02-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105293483B (en) | A kind of method that original position prepares transient metal doped porous graphene | |
| Yuan et al. | A review of transition metal chalcogenide/graphene nanocomposites for energy storage and conversion | |
| Zhang et al. | Fe, Co, N-functionalized carbon nanotubes in situ grown on 3D porous N-doped carbon foams as a noble metal-free catalyst for oxygen reduction | |
| Deng et al. | Coupling hollow Fe3O4 nanoparticles with oxygen vacancy on mesoporous carbon as a high-efficiency ORR electrocatalyst for Zn-air battery | |
| Jiang et al. | Nitrogen and fluorine dual-doped mesoporous graphene: a high-performance metal-free ORR electrocatalyst with a super-low HO 2− yield | |
| Christy et al. | Cobaltite oxide nanosheets anchored graphene nanocomposite as an efficient oxygen reduction reaction (ORR) catalyst for the application of lithium-air batteries | |
| Jiang et al. | 3D porous cellular NiCoO2/graphene network as a durable bifunctional electrocatalyst for oxygen evolution and reduction reactions | |
| WO2012083511A1 (en) | Preparation method and use of manganese dioxide nano-rod | |
| CN106981671A (en) | A kind of three-dimensional porous nitrogen-doped graphene and its preparation method and application | |
| Dong et al. | Molybdenum-doped mesoporous carbon/graphene composites as efficient electrocatalysts for the oxygen reduction reaction | |
| Lu et al. | Transformation of carbon-encapsulated metallic Co into ultrafine Co/CoO nanoparticles exposed on N-doped graphitic carbon for high-performance rechargeable zinc-air battery | |
| CN104140097A (en) | Phosphor doped grapheme and preparing method thereof | |
| CN103022445A (en) | Preparation method for negative electrode material of power lithium ion battery | |
| Chen et al. | N-doped 3D porous carbon catalyst derived from biowaste Triarrhena sacchariflora panicle for oxygen reduction reaction | |
| Chen et al. | 1D bamboo-like N-doped carbon nanotubes with encapsulated iron-based nanoparticles as an advanced Zn-air battery cathode electrocatalyst | |
| CN104108709A (en) | Porous graphene and preparation method thereof | |
| Jiao et al. | Non-precious transition metal single-atom catalysts for the oxygen reduction reaction: progress and prospects | |
| Du et al. | Design of Fe, N co-doped multi-walled carbon nanotubes for efficient oxygen reduction | |
| Zan et al. | Ultrathin two-dimensional phosphorus and nitrogen Co-doped carbon nanosheet as efficient oxygen reduction electrocatalyst | |
| Wang et al. | A facile strategy to fabricate nitrogen-doped graphene aerogel-supported Fe 3 N nanoparticles as efficient electrocatalysts for the oxygen reduction reaction | |
| Jamesh et al. | ORR/OER activity and zinc-air battery performance of various kinds of graphene-based air catalysts | |
| Xin et al. | Coupling Mo2C@ C core-shell nanocrystals on 3D graphene hybrid aerogel for high-performance lithium ion battery | |
| Yang et al. | Electronic structure modulation of bifunctional oxygen catalysts for rechargeable Zn–air batteries | |
| Luo et al. | In situ integration of Co5. 47N and Co0. 72Fe0. 28 alloy nanoparticles into intertwined carbon network for efficient oxygen reduction | |
| Yang et al. | Chlorella-derived porous heteroatom-doped carbons as robust catalysts for oxygen reduction reaction in direct glucose alkaline fuel cell |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20170711 Termination date: 20181208 |