CN105289507A - Ammonia-gas purifying agent - Google Patents

Ammonia-gas purifying agent Download PDF

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Publication number
CN105289507A
CN105289507A CN201510787025.5A CN201510787025A CN105289507A CN 105289507 A CN105289507 A CN 105289507A CN 201510787025 A CN201510787025 A CN 201510787025A CN 105289507 A CN105289507 A CN 105289507A
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CN
China
Prior art keywords
parts
ammonia
synergist
decontamination agent
bactericide
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Pending
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CN201510787025.5A
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Chinese (zh)
Inventor
王晶
肖延安
杨彦清
赵敏洁
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Wuxi Imprint Nano Technology Co Ltd
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Wuxi Imprint Nano Technology Co Ltd
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Priority to CN201510787025.5A priority Critical patent/CN105289507A/en
Publication of CN105289507A publication Critical patent/CN105289507A/en
Pending legal-status Critical Current

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  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

A disclosed ammonia-gas purifying agent is prepared from the following raw materials in parts by weight: 5-12 parts of aluminium oxide, 12-25 parts of diatomite, 5-12 parts of quartz stone, 10-15 parts of polymeric ferric sulfate, 12-32 parts of calcium hypochlorite, 12-20 parts of alumina silicate, 5-12 parts of a bactericide, 12-20 parts of a synergist, 20-30 parts of an activator, 4-12 parts of a polymeric flocculant, and 20-50 parts of deionized water. The ammonia-gas purifying agent is wide in raw material source, low in price, good in stability and long in service life, is capable of effectively removing ammonia gas and other harmful gases in indoor air, and is capable of killing bacteria in air and purifying air.

Description

A kind of ammonia decontamination agent
Technical field
The present invention relates to a kind of ammonia decontamination agent.
Background technology
At present, ammonia is mainly for the manufacture of nitric acid, explosive, synthetic fibers, and in a large number for antidiuresis element, ammonium fertilizer, also can be used as cold-producing medium.In addition ammonia is as a kind of common concrete antifreezer, is a kind of common indoor air pollutants.Ammonia is a kind of colourless gas, irritant foul smell, and lta is very easily water-soluble, easily liquefies.Liquid ammonia will corrode some plastic products, rubber and coating.Heat, naked light, be difficult to light and danger is lower.
Ammonia has toxicity, can occur after sucking a large amount of ammonia in a short time shedding tears, pharyngalgia, hoarseness, cough, phlegm can be with the trace of blood, uncomfortable in chest, expiratory dyspnea, can with dizziness, headache, Nausea and vomiting, weak etc., can occur that cyanosis, eye conjunctiva and congestion of throat and oedema, respiratory rate are fast, pulmonary rale etc.Can be there is pulmonary edema, adult respiratory distress syndrome (ARDS) in severe patient, edema of the larynx spasm or tunica mucosa bronchiorum necrosis come off to cause and suffocate, also can complicated with pneumothorax, mediastinal emphesema.Sucking high concentration can be dead rapidly.
The purification techniques of current room air mainly contains the technology such as photocatalytic degradation, absorption, plasma technology, ozone treatment, anion process.Wherein, photocatalysis needs enough strong ultraviolet light, and catalytic efficiency is low, and ammonia is difficult to oxidation and oxidation can produce the larger pollutant of the toxicity such as nitrogen oxide, and photocatalysis method is inapplicable; It is inapplicable in room that ozone technology easily produces larger air pollution, and be oxidized by ammonia equally, can produce toxic pollutant; Anion technology can only make room air sense organ becomes pure and fresh, does not have the effect of decontamination of chemical pollutant.In addition the method for washing can be adopted to absorb ammonia, but operating equipment is unprecedented very large, and easily causes corrosive secondary pollution.Show with the application experience of the developed country such as America and Europe decades: adsorption and purification technology is the most important in the purification techniques that pollutes of ammonia and effective method the most.
The adsorption and purification technology of current ammonia is substantially all utilize charcoal absorption.And ammonia is small-molecule substance, the non-constant of adsorption capacity of boiling point very low activity charcoal.Therefore, the cleanser developing the higher indoor ammonia pollution of a kind of efficiency is very necessary.
Summary of the invention
The defect that the present invention seeks to exist for prior art provides a kind of ammonia decontamination agent.
The present invention for achieving the above object, adopts following technical scheme: a kind of ammonia decontamination agent, and it is made up of the raw material of following parts by weight: alundum (Al2O3) 5-12 part, diatomite 12-25 part, quartz 5-12 part, bodied ferric sulfate 10-15 part, calcium hypochlorite 12-32 part, alumina silicate 12-20 part, bactericide 5-12 part, synergist 12-20 part, activator 20-30 part, high polymer coagulant 4-12 part, and deionized water 20-50 part.
Further, it is made up of the raw material of following parts by weight: alundum (Al2O3) 5 parts, 12 parts, diatomite, quartz 5 parts, bodied ferric sulfate 10 parts, calcium hypochlorite 12 parts, alumina silicate 12 parts, 5 parts, bactericide, synergist 12 parts, activator 20 parts, high polymer coagulant 4 parts, and deionized water 20 parts.
Further, it is made up of the raw material of following parts by weight: alundum (Al2O3) 8 parts, 18 parts, diatomite, quartz 8 parts, bodied ferric sulfate 11 parts, calcium hypochlorite 24 parts, alumina silicate 17 parts, 7 parts, bactericide, synergist 17 parts, activator 25 parts, high polymer coagulant 8 parts, and deionized water 36 parts.
Further, it is made up of the raw material of following parts by weight: alundum (Al2O3) 12 parts, 25 parts, diatomite, quartz 12 parts, bodied ferric sulfate 15 parts, calcium hypochlorite 32 parts, alumina silicate 20 parts, 12 parts, bactericide, synergist 20 parts, activator 30 parts, high polymer coagulant 12 parts, and deionized water 50 parts.
Further, described activator is the butyl acetate solution of 10-20% by mass fraction, and mass fraction is the cyclohexanone solution of 5-10%, and mass fraction is the banana oil solution of 5-15%, and mass fraction is that the acetone soln of 10-30% mixes.
Further, described bactericide is any one in kresoxim-methyl, Fluoxastrobin, fluoxastrobin, Prochloraz, fluorine bacterium azoles and fludioxonil.
Further, described synergist is YZ901 synergist.
Further, described high polymer coagulant is mixed by the sodium hydroxide solution of mass fraction to be the titanium sulfate solution of 20-30% and mass fraction be 10-15%; Wherein, the mass ratio of described titanium sulfate solution and sodium hydroxide solution is 2:1.
Beneficial effect of the present invention: the raw material sources of ammonia decontamination agent of the present invention are extensive, cheap, good stability, and the life-span is long, effectively can remove the pernicious gases such as the ammonia in room air, and bacterium in air can be killed, purify air.
Detailed description of the invention
The present invention relates to a kind of ammonia decontamination agent, it is made up of the raw material of following parts by weight: alundum (Al2O3) 5-12 part, diatomite 12-25 part, quartz 5-12 part, bodied ferric sulfate 10-15 part, calcium hypochlorite 12-32 part, alumina silicate 12-20 part, bactericide 5-12 part, synergist 12-20 part, activator 20-30 part, high polymer coagulant 4-12 part, and deionized water 20-50 part.
In further scheme, described activator is the butyl acetate solution of 10-20% by mass fraction, and mass fraction is the cyclohexanone solution of 5-10%, and mass fraction is the banana oil solution of 5-15%, and mass fraction is that the acetone soln of 10-30% mixes.
In further scheme, described bactericide is any one in kresoxim-methyl, Fluoxastrobin, fluoxastrobin, Prochloraz, fluorine bacterium azoles and fludioxonil.
In further scheme, described synergist is YZ901 synergist.
In further scheme, described high polymer coagulant is mixed by the sodium hydroxide solution of mass fraction to be the titanium sulfate solution of 20-30% and mass fraction be 10-15%; Wherein, the mass ratio of described titanium sulfate solution and sodium hydroxide solution is 2:1.
Example 1, the preparation method of above-mentioned ammonia decontamination agent is as follows:
1), according to weight fraction meter, take: alundum (Al2O3) 5 parts, 12 parts, diatomite, quartz 5 parts, bodied ferric sulfate 10 parts, calcium hypochlorite 12 parts, alumina silicate 12 parts, puts into ultrasonic grinder successively and carries out ultramicro grinding, obtain particulate base after sieve;
2) particulate base, by step 1 obtained puts into blending tank successively, fully mixes, and incorporation time is 0.5 hour, and mixing temperature is 40 degree; And then in blending tank, add 5 parts, bactericide successively, synergist 12 parts, activator 20 parts and high polymer coagulant 4 parts, and carry out stirring reaction, reaction temperature is 50 degree, and the reaction time is 1 hour, finally add deionized water 20 parts, precipitate and isolate supernatant and obtain required ammonia decontamination agent.
Use above-mentioned ammonia decontamination agent 0.2L, by spray pattern, be sprayed at the indoor of 100 square meters, make cleanser slow releasing in living environment, close after 1 hour; Detected by professional checkout equipment, ammonia removal rate reaches 70%, and effectively can remove other harmful bacterias in room air.
Example 2, the preparation method of above-mentioned ammonia decontamination agent is as follows:
1), according to weight fraction meter, take: alundum (Al2O3) 8 parts, 18 parts, diatomite, quartz 8 parts, bodied ferric sulfate 11 parts, calcium hypochlorite 24 parts, alumina silicate 17 parts, puts into ultrasonic grinder successively and carries out ultramicro grinding, obtain particulate base after sieve;
2) particulate base, by step 1 obtained puts into blending tank successively, fully mixes, and incorporation time is 1 hour, and mixing temperature is 50 degree; And then in blending tank, add 7 parts, bactericide successively, synergist 17 parts, activator 25 parts, high polymer coagulant 8 parts, and carry out stirring reaction, reaction temperature is 55 degree, reaction time is 1.5 hours, finally adds deionized water 36 parts, precipitates and isolates supernatant and obtains required ammonia decontamination agent.
Use above-mentioned ammonia decontamination agent 0.2L, by spray pattern, be sprayed at the indoor of 100 square meters, make cleanser slow releasing in living environment, close after 1 hour; Detected by professional checkout equipment, ammonia removal rate reaches 80%, and effectively can remove other harmful bacterias in room air.
Example 3, the preparation method of above-mentioned ammonia decontamination agent is as follows:
1), according to weight fraction meter, take: alundum (Al2O3) 12 parts, 25 parts, diatomite, quartz 12 parts, bodied ferric sulfate 15 parts, calcium hypochlorite 32 parts, alumina silicate 20 parts, puts into ultrasonic grinder successively and carries out ultramicro grinding, obtain particulate base after sieve;
2) particulate base, by step 1 obtained puts into blending tank successively, fully mixes, and incorporation time is 1.5 hours, and mixing temperature is 60 degree; And then in blending tank, add 12 parts, bactericide successively, synergist 20 parts, activator 30 parts, high polymer coagulant 50 parts, and carry out stirring reaction, reaction temperature is 60 degree, reaction time is 2 hours, finally adds deionized water 36 parts, precipitates and isolates supernatant and obtains required ammonia decontamination agent.
Use above-mentioned ammonia decontamination agent 0.2L, by spray pattern, be sprayed at the indoor of 100 square meters, make cleanser slow releasing in living environment, close after 1 hour; Detected by professional checkout equipment, ammonia removal rate reaches 90%, and effectively can remove other harmful bacterias in room air.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.

Claims (8)

1. an ammonia decontamination agent, is characterized in that, it is made up of the raw material of following parts by weight: alundum (Al2O3) 5-12 part, diatomite 12-25 part, quartz 5-12 part, bodied ferric sulfate 10-15 part, calcium hypochlorite 12-32 part, alumina silicate 12-20 part, bactericide 5-12 part, synergist 12-20 part, activator 20-30 part, high polymer coagulant 4-12 part, and deionized water 20-50 part.
2. a kind of ammonia decontamination agent as claimed in claim 1, it is characterized in that, it is made up of the raw material of following parts by weight: alundum (Al2O3) 5 parts, 12 parts, diatomite, quartz 5 parts, bodied ferric sulfate 10 parts, calcium hypochlorite 12 parts, alumina silicate 12 parts, 5 parts, bactericide, synergist 12 parts, activator 20 parts, high polymer coagulant 4 parts, and deionized water 20 parts.
3. a kind of ammonia decontamination agent as claimed in claim 1, it is characterized in that, it is made up of the raw material of following parts by weight: alundum (Al2O3) 8 parts, 18 parts, diatomite, quartz 8 parts, bodied ferric sulfate 11 parts, calcium hypochlorite 24 parts, alumina silicate 17 parts, 7 parts, bactericide, synergist 17 parts, activator 25 parts, high polymer coagulant 8 parts, and deionized water 36 parts.
4. a kind of ammonia decontamination agent as claimed in claim 1, it is characterized in that, it is made up of the raw material of following parts by weight: alundum (Al2O3) 12 parts, 25 parts, diatomite, quartz 12 parts, bodied ferric sulfate 15 parts, calcium hypochlorite 32 parts, alumina silicate 20 parts, 12 parts, bactericide, synergist 20 parts, activator 30 parts, high polymer coagulant 12 parts, and deionized water 50 parts.
5. a kind of ammonia decontamination agent as described in any one of Claims 1-4, it is characterized in that, described activator is the butyl acetate solution of 10-20% by mass fraction, mass fraction is the cyclohexanone solution of 5-10%, mass fraction is the banana oil solution of 5-15%, and mass fraction is that the acetone soln of 10-30% mixes.
6. a kind of ammonia decontamination agent as described in any one of Claims 1-4, is characterized in that, described bactericide is any one in kresoxim-methyl, Fluoxastrobin, fluoxastrobin, Prochloraz, fluorine bacterium azoles and fludioxonil.
7. a kind of ammonia decontamination agent as described in any one of Claims 1-4, is characterized in that, described synergist is YZ901 synergist.
8. a kind of ammonia decontamination agent as described in any one of Claims 1-4, is characterized in that, described high polymer coagulant is mixed by the sodium hydroxide solution of mass fraction to be the titanium sulfate solution of 20-30% and mass fraction be 10-15%; Wherein, the mass ratio of described titanium sulfate solution and sodium hydroxide solution is 2:1.
CN201510787025.5A 2015-11-16 2015-11-16 Ammonia-gas purifying agent Pending CN105289507A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106566703A (en) * 2016-11-15 2017-04-19 安徽理工大学 Detergent for emulsive explosives, preparation method for detergent and application of detergent
CN108212132A (en) * 2017-12-04 2018-06-29 佛山杰致信息科技有限公司 A kind of preparation method of chlorine purification agent

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101284693A (en) * 2008-05-26 2008-10-15 董超平 Natural organic polymer composite flocculant, method for preparing the same and applications
CN103537255A (en) * 2013-07-28 2014-01-29 王泽辉 Nanometer oxide ceramic purification and adsorption material with decomposition and bactericidal performance
KR20140138250A (en) * 2012-03-30 2014-12-03 제이엑스 닛코닛세키에너지주식회사 Method for producing lubricant base oil

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101284693A (en) * 2008-05-26 2008-10-15 董超平 Natural organic polymer composite flocculant, method for preparing the same and applications
KR20140138250A (en) * 2012-03-30 2014-12-03 제이엑스 닛코닛세키에너지주식회사 Method for producing lubricant base oil
CN103537255A (en) * 2013-07-28 2014-01-29 王泽辉 Nanometer oxide ceramic purification and adsorption material with decomposition and bactericidal performance

Non-Patent Citations (2)

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JOCHEN LAMBAUER等著: "《纳米技术与能源》", 30 September 2014, 北京:机械工业出版社 *
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106566703A (en) * 2016-11-15 2017-04-19 安徽理工大学 Detergent for emulsive explosives, preparation method for detergent and application of detergent
CN106566703B (en) * 2016-11-15 2019-02-19 安徽理工大学 A kind of emulsion cleaning agent, preparation method and application
CN108212132A (en) * 2017-12-04 2018-06-29 佛山杰致信息科技有限公司 A kind of preparation method of chlorine purification agent

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