CN105220268A - A kind of POLYAMIDE YARNS with high efficiency flame retardance - Google Patents
A kind of POLYAMIDE YARNS with high efficiency flame retardance Download PDFInfo
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- CN105220268A CN105220268A CN201510585602.2A CN201510585602A CN105220268A CN 105220268 A CN105220268 A CN 105220268A CN 201510585602 A CN201510585602 A CN 201510585602A CN 105220268 A CN105220268 A CN 105220268A
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Abstract
A kind of POLYAMIDE YARNS with high efficiency flame retardance, relate to POLYAMIDE YARNS textile manufacturing techniques field, have following component to be prepared from: PA6 section, carbon fiber, aluminium hydroxide, silicone powder, nano silicon, alkali-free glass fibre, red unicorn master batch, zinc oxide, silica gel sulfuration, agent titanium dioxide, flame retardant, described flame retardant is prepared from by following component: coupling agent, anti-oxidant auxiliary agent, lubricant, red unicorn master batch.The present invention effectively can improve the anti-flammability of POLYAMIDE YARNS, improve the burning-point of POLYAMIDE YARNS, the anti-wear performance of POLYAMIDE YARNS can also be improved while ensureing anti-flammability, be convenient for people to use and effectively raise security performance, the anti-wear performance of POLYAMIDE YARNS can also be increased simultaneously, improve wilfulness and increase the service life.
Description
Technical field:
The present invention relates to POLYAMIDE YARNS textile manufacturing techniques field, be specifically related to a kind of POLYAMIDE YARNS with high efficiency flame retardance.
Background technology:
POLYAMIDE YARNS is a kind of weaving face fabric, has the polytypes such as monofilament, strand, special yarn, compared to the glossiness of silk broadcloth, POLYAMIDE YARNS fabric sheen is poor, as the sensation having coated one deck wax, rub back and forth with hand simultaneously, can feel friction sense between fabric.
In daily life, this fabric be mainly used at present make sportswear, scarf etc., still by people have an optimistic view of, in medical, be mainly used in making bandage, POLYAMIDE YARNS product is mainly for the production of trimming cloth.The advantage of POLYAMIDE YARNS is more well-pressed, and not balling-up is wrinkle resistant, convenient for cleaning.Because therefore some specific uses of POLYAMIDE YARNS require high to the fire resistance of POLYAMIDE YARNS, especially some medical products are applied in even on clothes, excellent fire retardancy is needed to guarantee the result of use of product, but domestic market seldom can produce of fine quality and that fire resistance is good POLYAMIDE YARNS in the manufacturing of POLYAMIDE YARNS, but along with the requirement of continuous expansion people to fire resistance in market is increasing, the effect of the quality of current POLYAMIDE YARNS and product itself can not meet the demand in market, therefore this patent provides a kind of POLYAMIDE YARNS with high efficiency flame retardance, he effectively can improve the anti-flammability of POLYAMIDE YARNS, improve the burning-point of POLYAMIDE YARNS, the anti-wear performance of POLYAMIDE YARNS can also be improved while ensureing anti-flammability.
Summary of the invention:
Technical problem to be solved by this invention is to provide a kind of POLYAMIDE YARNS with high efficiency flame retardance, and this product effectively can improve the anti-flammability of POLYAMIDE YARNS, improves the burning-point of POLYAMIDE YARNS, can also improve the anti-wear performance of POLYAMIDE YARNS while ensureing anti-flammability.
There is a POLYAMIDE YARNS for high efficiency flame retardance, have following component to be prepared from:
PA6 section 70-75 weight portion
Carbon fiber 20-30 weight portion
Aluminium hydroxide 30-35 weight portion
Silicone powder 5-10 weight portion
Nano silicon 5-10 weight portion
Alkali-free glass fibre 8-10 weight portion
Red unicorn master batch 5-10 weight portion
Zinc oxide 1-3 weight portion
Silica gel sulfuration 2-7 weight portion
Agent titanium dioxide 0.5-1.5 weight portion
Flame retardant 1-3 weight portion
Described flame retardant is prepared from by following component:
Coupling agent 10 weight portion
Anti-oxidant auxiliary agent 10 weight portion
Lubricant 10 weight portion
Red unicorn master batch 10 weight portion;
Have a POLYAMIDE YARNS for high efficiency flame retardance, the optimum proportioning of each component materials is:
PA6 cuts into slices 73 weight portions
Carbon fiber 25 weight portion
Aluminium hydroxide 32 weight portion
Silicone powder 8 weight portion
Nano silicon 8 weight portion
Alkali-free glass fibre 9 weight portion
Red unicorn master batch 8 weight portion
Zinc oxide 2 weight portion
Silica gel sulfuration 5 weight portion
Agent titanium dioxide 1 weight portion
Flame retardant 2 weight portion
Described flame retardant is prepared from by following component:
Coupling agent 10 weight portion
Anti-oxidant auxiliary agent 10 weight portion
Lubricant 10 weight portion
Red unicorn master batch 10 weight portion;
Above-mentioned a kind of POLYAMIDE YARNS with high efficiency flame retardance, its preparation method comprises the following steps:
(1) prepare flame retardant, by coupling agent 10 weight portion, anti-oxidant auxiliary agent 10 weight portion, lubricant 10 weight portion, red unicorn master batch 10 weight portion, join in high-speed mixer together and mix;
(2) raw material: PA6 section 70-75 weight portion, carbon fiber 20-30 weight portion, aluminium hydroxide 30-35 weight portion, silicone powder 5-10 weight portion, nano silicon 5-10 weight portion, alkali-free glass fibre 8-10 weight portion, red unicorn master batch 5-10 weight portion, flame retardant 1-3 weight portion is prepared according to following proportioning
(3) above-mentioned raw materials is carried out separately according to this drying process, use drying oven during process, temperature is arranged on 80-85 degree Celsius, continues 10 minutes;
(4) zinc oxide 1-3 weight portion, silica gel sulfuration 2-7 weight portion, agent titanium dioxide 0.5-1.5 weight portion are joined according to this in masticator and carry out, for subsequent use after kneading 20-30 minute;
(5) spin fluid is prepared: utilize master batch to annotate pump and accurately add above each raw material, then mixed melting;
(6) spinning: above-mentioned spin fluid is quantitatively pressed into filament spinning component through measuring pump, is sprayed by spinnerets, forms tow in spinning window;
(7) aft-loaded airfoil: the fiber made is carried out successively draw-teisting, sizing, balance, dyeing grades and test package operation finally makes a kind of POLYAMIDE YARNS with high efficiency flame retardance.
The product that the present invention obtains not only possesses the good feature of fire resistance and also has good anti-wear performance, in the formula of whole invention, utilize coupling agent, anti-oxidant auxiliary agent, lubricant 1, red unicorn master batch combination is prepared into flame retardant, utilize and add the performance that flame retardant can be whole raw material and product increase fire resistance in the feed, and also add a large amount of red phosphor masterbatch in the feed, the compositions such as aluminium hydroxide these can better play fire resistance under the adjustment of flame retardant, zinc oxide in addition, silica gel sulfuration, agent titanium dioxide add the anti-wear performance that can increase POLYAMIDE YARNS, the finished product of the POLYAMIDE YARNS that whole like this processing step can be just in the process made has the raising of high degree in fire-retardant and wear-resisting.
Beneficial effect of the present invention is the anti-flammability that effectively can improve POLYAMIDE YARNS, improve the burning-point of POLYAMIDE YARNS, the anti-wear performance of POLYAMIDE YARNS can also be improved while ensureing anti-flammability, be convenient for people to use and effectively raise security performance, the anti-wear performance of POLYAMIDE YARNS can also be increased simultaneously, improve wilfulness and increase the service life.
Detailed description of the invention:
The technological means realized to make the present invention, creation characteristic, reaching object and effect is easy to understand, below in conjunction with concrete example, setting forth the present invention further.
Embodiment 1:
There is a POLYAMIDE YARNS for high efficiency flame retardance, have following component to be prepared from:
PA6 cuts into slices 73 weight portions
Carbon fiber 25 weight portion
Aluminium hydroxide 32 weight portion
Silicone powder 8 weight portion
Nano silicon 8 weight portion
Alkali-free glass fibre 9 weight portion
Red unicorn master batch 8 weight portion
Zinc oxide 2 weight portion
Silica gel sulfuration 5 weight portion
Agent titanium dioxide 1 weight portion
Flame retardant 2 weight portion
Described flame retardant is prepared from by following component:
Coupling agent 10 weight portion
Anti-oxidant auxiliary agent 10 weight portion
Lubricant 10 weight portion
Red unicorn master batch 10 weight portion;
Above-mentioned a kind of POLYAMIDE YARNS with high efficiency flame retardance, its preparation method comprises the following steps:
(1) prepare flame retardant, by coupling agent 10 weight portion, anti-oxidant auxiliary agent 10 weight portion, lubricant 10 weight portion, red unicorn master batch 10 weight portion, join in high-speed mixer together and mix;
(2) prepare raw material: PA6 according to following proportioning to cut into slices 73 weight portions, carbon fiber 25 weight portion, aluminium hydroxide 32 weight portion, silicone powder 8 weight portion, nano silicon 8 weight portion, alkali-free glass fibre 9 weight portion, red unicorn master batch 8 weight portion, flame retardant 2 weight portion
(3) above-mentioned raw materials is carried out separately according to this drying process, use drying oven during process, temperature is arranged on 80-85 degree Celsius, continues 10 minutes;
(4) zinc oxide 2 weight portion, silica gel sulfuration 5 weight portion, agent titanium dioxide 1 weight portion are joined according to this in masticator and carried out, kneading is for subsequent use after 25 minutes;
(5) spin fluid is prepared: utilize master batch to annotate pump and accurately add above each raw material, then mixed melting;
(6) spinning: above-mentioned spin fluid is quantitatively pressed into filament spinning component through measuring pump, is sprayed by spinnerets, forms tow in spinning window;
(7) aft-loaded airfoil: the fiber made is carried out successively draw-teisting, sizing, balance, dyeing grades and test package operation finally makes a kind of POLYAMIDE YARNS with high efficiency flame retardance.
Embodiment 2:
There is a POLYAMIDE YARNS for high efficiency flame retardance, have following component to be prepared from:
PA6 cuts into slices 70 weight portions
Carbon fiber 20 weight portion
Aluminium hydroxide 30 weight portion
Silicone powder 5 weight portion
Nano silicon 5 weight portion
Alkali-free glass fibre 8 weight portion
Red unicorn master batch 5 weight portion
Zinc oxide 1 weight portion
Silica gel sulfuration 2 weight portion
Agent titanium dioxide 0.5 weight portion
Flame retardant 1 weight portion
Described flame retardant is prepared from by following component:
Coupling agent 10 weight portion
Anti-oxidant auxiliary agent 10 weight portion
Lubricant 10 weight portion
Red unicorn master batch 10 weight portion;
Above-mentioned a kind of POLYAMIDE YARNS with high efficiency flame retardance, its preparation method comprises the following steps:
(1) prepare flame retardant, by coupling agent 10 weight portion, anti-oxidant auxiliary agent 10 weight portion, lubricant 10 weight portion, red unicorn master batch 10 weight portion, join in high-speed mixer together and mix;
(2) prepare raw material: PA6 according to following proportioning to cut into slices 70 weight portions, carbon fiber 20 weight portion, aluminium hydroxide 30 weight portion, silicone powder 5 weight portion, nano silicon 5 weight portion, alkali-free glass fibre 8 weight portion, red unicorn master batch 5 weight portion, flame retardant 1 weight portion
(3) above-mentioned raw materials is carried out separately according to this drying process, use drying oven during process, temperature is arranged on 80-85 degree Celsius, continues 10 minutes;
(4) zinc oxide 1 weight portion, silica gel sulfuration 2 weight portion, agent titanium dioxide 0.5 weight portion are joined according to this in masticator and carried out, kneading is for subsequent use after 20 minutes;
(5) spin fluid is prepared: utilize master batch to annotate pump and accurately add above each raw material, then mixed melting;
(6) spinning: above-mentioned spin fluid is quantitatively pressed into filament spinning component through measuring pump, is sprayed by spinnerets, forms tow in spinning window;
(7) aft-loaded airfoil: the fiber made is carried out successively draw-teisting, sizing, balance, dyeing grades and test package operation finally makes a kind of POLYAMIDE YARNS with high efficiency flame retardance.
Embodiment 3
There is a POLYAMIDE YARNS for high efficiency flame retardance, have following component to be prepared from:
PA6 cuts into slices 75 weight portions
Carbon fiber 30 weight portion
Aluminium hydroxide 35 weight portion
Silicone powder 10 weight portion
Nano silicon 10 weight portion
Alkali-free glass fibre 10 weight portion
Red unicorn master batch 10 weight portion
Zinc oxide 3 weight portion
Silica gel sulfuration 7 weight portion
Agent titanium dioxide 1.5 weight portion
Flame retardant 3 weight portion
Described flame retardant is prepared from by following component:
Coupling agent 10 weight portion
Anti-oxidant auxiliary agent 10 weight portion
Lubricant 10 weight portion
Red unicorn master batch 10 weight portion;
Above-mentioned a kind of POLYAMIDE YARNS with high efficiency flame retardance, its preparation method comprises the following steps:
(1) prepare flame retardant, by coupling agent 10 weight portion, anti-oxidant auxiliary agent 10 weight portion, lubricant 10 weight portion, red unicorn master batch 10 weight portion, join in high-speed mixer together and mix;
(2) prepare raw material: PA6 according to following proportioning to cut into slices 75 weight portions, carbon fiber 30 weight portion, aluminium hydroxide 35 weight portion, silicone powder 10 weight portion, nano silicon 10 weight portion, alkali-free glass fibre 10 weight portion, red unicorn master batch 10 weight portion, flame retardant 1 weight portion
(3) above-mentioned raw materials is carried out separately according to this drying process, use drying oven during process, temperature is arranged on 80-85 degree Celsius, continues 10 minutes;
(4) zinc oxide 3 weight portion, silica gel sulfuration 7 weight portion, agent titanium dioxide 1.5 weight portion are joined according to this in masticator and carried out, kneading is for subsequent use after 30 minutes;
(5) spin fluid is prepared: utilize master batch to annotate pump and accurately add above each raw material, then mixed melting;
(6) spinning: above-mentioned spin fluid is quantitatively pressed into filament spinning component through measuring pump, is sprayed by spinnerets, forms tow in spinning window;
(7) aft-loaded airfoil: the fiber made is carried out successively draw-teisting, sizing, balance, dyeing grades and test package operation finally makes a kind of POLYAMIDE YARNS with high efficiency flame retardance.
More than show and describe general principle of the present invention and principal character and advantage of the present invention.The technical staff of the industry should understand; the present invention is not restricted to the described embodiments; what describe in above-described embodiment and description just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.Application claims protection domain is defined by appending claims and equivalent thereof.
Claims (2)
1. one kind has the POLYAMIDE YARNS of high efficiency flame retardance, it is characterized in that: have following component to be prepared from: PA6 section 70-75 weight portion, carbon fiber 20-30 weight portion, aluminium hydroxide 30-35 weight portion, silicone powder 5-10 weight portion, nano silicon 5-10 weight portion, alkali-free glass fibre 8-10 weight portion, red unicorn master batch 5-10 weight portion, zinc oxide 1-3 weight portion, silica gel sulfuration 2-7 weight portion, agent titanium dioxide 0.5-1.5 weight portion, flame retardant 1-3 weight portion, described flame retardant is prepared from by following component: coupling agent 10 weight portion, anti-oxidant auxiliary agent 10 weight portion, lubricant 10 weight portion, red unicorn master batch 10 weight portion,
Described a kind of POLYAMIDE YARNS with high efficiency flame retardance, the optimum proportioning of each component materials is, and: PA6 cuts into slices 73 weight portions, carbon fiber 25 weight portion, aluminium hydroxide 32 weight portion, silicone powder 8 weight portion, nano silicon 8 weight portion, alkali-free glass fibre 9 weight portion, red unicorn master batch 8 weight portion, zinc oxide 2 weight portion, silica gel sulfuration 5 weight portion, agent titanium dioxide 1 weight portion, flame retardant 2 weight portion, described flame retardant is prepared from by following component: coupling agent 10 weight portion, anti-oxidant auxiliary agent 10 weight portion, lubricant 10 weight portion, red unicorn master batch 10 weight portion.
2. there is a preparation method for the POLYAMIDE YARNS of high efficiency flame retardance, it is characterized in that: comprise the following steps:
(1) prepare flame retardant, by coupling agent 10 weight portion, anti-oxidant auxiliary agent 10 weight portion, lubricant 10 weight portion, red unicorn master batch 10 weight portion, join in high-speed mixer together and mix;
(2) raw material: PA6 section 70-75 weight portion, carbon fiber 20-30 weight portion, aluminium hydroxide 30-35 weight portion, silicone powder 5-10 weight portion, nano silicon 5-10 weight portion, alkali-free glass fibre 8-10 weight portion, red unicorn master batch 5-10 weight portion, flame retardant 1-3 weight portion is prepared according to following proportioning
(3) above-mentioned raw materials is carried out separately according to this drying process, use drying oven during process, temperature is arranged on 80-85 degree Celsius, continues 10 minutes;
(4) zinc oxide 1-3 weight portion, silica gel sulfuration 2-7 weight portion, agent titanium dioxide 0.5-1.5 weight portion are joined according to this in masticator and carry out, for subsequent use after kneading 20-30 minute;
(5) spin fluid is prepared: utilize master batch to annotate pump and accurately add above each raw material, then mixed melting;
(6) spinning: above-mentioned spin fluid is quantitatively pressed into filament spinning component through measuring pump, is sprayed by spinnerets, forms tow in spinning window;
(7) aft-loaded airfoil: the fiber made is carried out successively draw-teisting, sizing, balance, dyeing grades and test package operation finally makes a kind of POLYAMIDE YARNS with high efficiency flame retardance.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510585602.2A CN105220268A (en) | 2015-09-15 | 2015-09-15 | A kind of POLYAMIDE YARNS with high efficiency flame retardance |
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| CN201510585602.2A CN105220268A (en) | 2015-09-15 | 2015-09-15 | A kind of POLYAMIDE YARNS with high efficiency flame retardance |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109898172A (en) * | 2019-02-27 | 2019-06-18 | 圣华盾防护科技股份有限公司 | A kind of high strength fibre and life line |
| CN110983484A (en) * | 2019-12-06 | 2020-04-10 | 浙江升丽纺织有限公司 | High-wear-resistance flame-retardant fabric and preparation method thereof |
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| US20110288210A1 (en) * | 2010-05-21 | 2011-11-24 | Pinnavaia Thomas J | Mesoporous Silicate Fire Retardant Compositions |
| CN102492295A (en) * | 2011-11-29 | 2012-06-13 | 南京鸿瑞塑料制品有限公司 | Preparation method of ultrafine low precipitation red phosphorus inflaming retarding glass fiber reinforced nylon |
| CN104294392A (en) * | 2014-10-15 | 2015-01-21 | 东华大学 | MCA flame-resistant polyamide 6 fibers and preparation method thereof |
| CN104328526A (en) * | 2014-11-13 | 2015-02-04 | 南通市苏中纺织有限公司 | Preparation method of wear-resisting and antistatic high-performance enhanced nylon yarns |
| CN104746168A (en) * | 2015-04-09 | 2015-07-01 | 泰索新材料科技（杭州）有限公司 | Flame-retardant polyamide 66 fiber and preparation method thereof |
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2015
- 2015-09-15 CN CN201510585602.2A patent/CN105220268A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US20110288210A1 (en) * | 2010-05-21 | 2011-11-24 | Pinnavaia Thomas J | Mesoporous Silicate Fire Retardant Compositions |
| CN102492295A (en) * | 2011-11-29 | 2012-06-13 | 南京鸿瑞塑料制品有限公司 | Preparation method of ultrafine low precipitation red phosphorus inflaming retarding glass fiber reinforced nylon |
| CN104294392A (en) * | 2014-10-15 | 2015-01-21 | 东华大学 | MCA flame-resistant polyamide 6 fibers and preparation method thereof |
| CN104328526A (en) * | 2014-11-13 | 2015-02-04 | 南通市苏中纺织有限公司 | Preparation method of wear-resisting and antistatic high-performance enhanced nylon yarns |
| CN104746168A (en) * | 2015-04-09 | 2015-07-01 | 泰索新材料科技（杭州）有限公司 | Flame-retardant polyamide 66 fiber and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109898172A (en) * | 2019-02-27 | 2019-06-18 | 圣华盾防护科技股份有限公司 | A kind of high strength fibre and life line |
| CN110983484A (en) * | 2019-12-06 | 2020-04-10 | 浙江升丽纺织有限公司 | High-wear-resistance flame-retardant fabric and preparation method thereof |
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Application publication date: 20160106 |