CN105213205A - A kind of have the microcapsule shining rear reparation effect and the sunscreen cream containing this microcapsule - Google Patents
A kind of have the microcapsule shining rear reparation effect and the sunscreen cream containing this microcapsule Download PDFInfo
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- CN105213205A CN105213205A CN201510735751.2A CN201510735751A CN105213205A CN 105213205 A CN105213205 A CN 105213205A CN 201510735751 A CN201510735751 A CN 201510735751A CN 105213205 A CN105213205 A CN 105213205A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/11—Encapsulated compositions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/447—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof containing sulfur
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/602—Glycosides, e.g. rutin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/67—Vitamins
- A61K8/678—Tocopherol, i.e. vitamin E
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
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Abstract
The present invention disclose a kind of have shine after repair effect microcapsule and containing the sunscreen cream of this microcapsule, described microcapsule capsule wall material comprises maltodextrin, arabic gum and hydroxyethyl-cellulose; Core materials comprises Oleum Cocois, Oleum Hippophae, Jojoba wax, squalane, vitamin E, Radix Hamamelidis Mollis ethanol extract, Herba Portulacae ethanol extract, peoniflorin, green tea ethanol extract, Cys and span; Described sunscreen cream comprises composition: above-mentioned have the microcapsule, Oleum Cocois, lanoline, ethanol, zinc oxide, titanium dioxide, OctMet, PAROSOL 1789,2-cyano group-3,3-diphenyl 2-Propenoic acid-2-ethylhexyl ester, vitamin E, deionized water, xanthan gum and the span 20 that shine rear reparation effect.The present invention gets up to be added in sunscreen cream by repairing composition embedding after solarization by microcapsule technology, makes sunscreen cream play sun-proof and repair double effects after shining, and effectively avoids both to coexist and the bad interactive competition phenomenon that causes.
Description
Technical field
The invention belongs to sun-proof technical field, be specifically related to a kind of have shine after repair effect microcapsule and containing the sunscreen cream of this microcapsule.
Background technology
UVA and UVB in sunlight can penetrate skin corium, and make skin produce sunburn, peel, tanned etc. shines rear phenomenon, and then makes skin old and feeble in advance, causes some irremediable injuries, if for a long time by the impact of UVA and UVB, also likely cause skin carcinoma to skin.
In order to prevent skin by tanned and sunburn, the sunscreen cream product that with the addition of sun-prevention component arises at the historic moment.Even if but use sunscreen cream to carry out how tight protection, also the injury that ultraviolet brings can not very be isolated, repairing after shining is reclamation activities important after long-time Exposure to Sunlight, but carry out repairing in short time only after solarization and just can play useful effect, if Exposure to Sunlight is repaired after a whole day again, good repairing effect will do not reached.
Current sunscreen cream effect is comparatively single, only has sun-proof function, and not having sunscreen cream that is sun-proof and reparation double effects after shining concurrently commercially has sale, has certain gaps in market.But, existing sun-prevention component and rear the reparation between composition of solarization have certain reciprocal effect relation, namely when both coexist in a kind of product, certain negative function may be had, the sun-proof function of sunscreen cream is weakened, and make the system of sunscreen cream become unstable, be not easy evenly to be coated on skin.
Summary of the invention
For prior art above shortcomings, technical problem to be solved by this invention is: how to provide a kind of and have the microcapsule shining rear reparation effect and the sunscreen cream containing this microcapsule, in order to weaken sun-prevention component and to repair the bad reciprocal action relation between composition after shining, make the sunscreen cream containing solarization rear reparation effect microcapsule obtained have concurrently sun-proof and repair double effects after shining, and the problem of system instability can not be produced.
In order to solve the problems of the technologies described above, the present invention adopts following technical scheme: a kind of have the microcapsule shining rear reparation effect, and be a kind of microcapsule of nucleocapsid structure, cyst material comprises maltodextrin, arabic gum and hydroxyethyl-cellulose; Core materials comprises Oleum Cocois, Oleum Hippophae, Jojoba wax, squalane, vitamin E, Radix Hamamelidis Mollis ethanol extract, Herba Portulacae ethanol extract, peoniflorin, green tea ethanol extract, Cys and span.
Containing the above-mentioned sunscreen cream with the microcapsule shining rear reparation effect; comprise the composition of following weight portion: 10 ~ 20 parts above-mentioned have shine after repair the microcapsule of effect, Oleum Cocois 30 ~ 40 parts, 15 ~ 20 parts of lanolines, 15 ~ 20 parts of ethanol, 3 ~ 6 parts of zinc oxide, 2 ~ 5 parts of titanium dioxide, 5 ~ 10 parts of OctMets, 4 ~ 7 parts of PAROSOL 1789s, 5 ~ 8 parts of 2-cyano group-3,3-diphenyl 2-Propenoic acid-2-ethylhexyl esters, 10 ~ 12 parts of vitamin Es, 20 ~ 30 parts of deionized waters, 8 ~ 12 parts of xanthan gum and 3 ~ 5 parts of span 20s.
Compared to existing technology, the present invention has following beneficial effect:
1, the present invention adopts natural plant extracts to repair composition as after solarization, and found when employing 4 parts of vitamin Es, 3 parts of Radix Hamamelidis Mollis ethanol extract, 3 parts of Herba Portulacae ethanol extract, 4 parts of peoniflorins, 5 parts of green tea ethanol extract and 2 parts of Cys composite usages by research, the best of efficacy exertion is repaired after shining, effectively can alleviate the rubescent hot phenomenon that after shining, skin occurs, farthest to releive skin, the generation of the phenomenon that prevents from tanning severely.
2, the present invention will repair composition embedding by microcapsule technology after natural solarization, and the microcapsule after embedding is added in sunscreen cream, make the sunscreen cream obtained in use can play double effects that is sun-proof and that repair after shining simultaneously, just can the skin after solarization be repaired in the short time after solarization; And the sunscreen cream adopting this technology obtained, effectively prevent sun-prevention component and after shining, repair composition and coexist and the bad interactive competition phenomenon that causes, make this sunscreen cream effectively can ensure sun-proof function before use and after shining, repair effect to disappear or to decline, there is excellent performance.
3, the present invention have shine after to repair the microcapsule embedded property of effect good, the embedding rate of microcapsule is up to 97.12%, make can not be subject to the impact that in external environment, light, heat, oxygen etc. are too much in this microcapsule storage process, effectively ensure that the activity of active substance is not destroyed, the effect extending product keeps the phase.
4, microcapsule product shape of the present invention is regular, cyst wall has uniform thickness, and has uniform intensity, can retain the perfect shape of microcapsule and not be destroyed, the problem that capsule-core is revealed can not be caused, can not be damaged during effectively ensureing product stock, transport, shelf life.
5, sunscreen cream stable system of the present invention, the problem such as there will not be water separating of oil, not easy to apply, has stable character.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail, in the present embodiment if no special instructions, raw materials used be commercially available.
Described Radix Hamamelidis Mollis ethanol extract, Herba Portulacae ethanol extract and green tea ethanol extract are after the ethanol water of employing 70% carries out alcohol extraction to Radix Hamamelidis Mollis, Herba Portulacae and green tea respectively, successively the extract that obtains of decompression recycling ethanol, lyophilization.
There is in following embodiment the microcapsule repairing effect after shining and adopt preparation with the following method:
(1) take maltodextrin and arabic gum, add deionized water, heating for dissolving at 75 ~ 85 DEG C, is mixed with mixed solution A; Wherein, the volume of the deionized water added is 25 ~ 36 times of maltodextrin and arabic gum gross mass;
(2) add hydroxyethyl-cellulose in the mixed solution A prepared to step (1), after stirring, at 75 ~ 85 DEG C, supersound process 1 ~ 4min, obtains capsule wall solution B; Wherein, hyperacoustic power is 400 ~ 550W;
(3) Oleum Cocois, Oleum Hippophae, Jojoba wax, squalane, vitamin E, Radix Hamamelidis Mollis ethanol extract, Herba Portulacae ethanol extract, peoniflorin, green tea ethanol extract and Cys is taken, under the water bath condition of 60 ~ 80 DEG C after supersound process 5 ~ 10min, with high speed dispersor dispersion 3 ~ 6min, obtain mixture C; Wherein the rotating speed of dispersion machine is 2000 ~ 2500r/min;
(4) in mixture C, add span, use homogenizer homogenizing 5 ~ 15min, obtain emulsifying homogeneous liquid D; Wherein homogenization pressure is 55 ~ 60MPa;
(5) by after capsule wall solution B and emulsifying homogeneous liquid D mix homogeneously, after first using high speed dispersor dispersion 2 ~ 5min, then carry out homogenizing 2 ~ 7min, obtain mixed liquor E; Wherein, the rotating speed of high speed dispersor is 1500 ~ 2000r/min, and homogenization pressure is 40 ~ 50MPa;
(6) spraying dry is carried out to mixed liquor E, there is described in obtaining the microcapsule repairing effect after shining; Wherein, controlling inlet temperature is 175 ~ 178 DEG C, and leaving air temp is 85 ~ 92 DEG C, feed rate 4.00 ~ 4.45mL/min.
The following sunscreen cream with this microcapsule is adopted and is prepared with the following method:
1) take Oleum Cocois, lanoline, span 20 and vitamin E, agitating heating 5 ~ 10min at 70 ~ 75 DEG C, obtains A phase; Wherein, the rotating speed of stirring is 250 ~ 350r/min;
2) get ethanol, zinc oxide, titanium dioxide, OctMet, PAROSOL 1789 and 2-cyano group-3,3-diphenyl 2-Propenoic acid-2-ethylhexyl ester, supersound process 5 ~ 15min under room temperature, obtains B phase; Wherein, ultrasonic power is 250 ~ 400W;
3) remove ionized water and xanthan gum, in 60 ~ 80 DEG C of stirred in water bath heating 10 ~ 15min, obtain C phase; Wherein, speed of agitator is 250 ~ 300r/min;
4) under 50 ~ 60 DEG C of water bath condition, B is added in A phase and obtains mixed phase D, stir process 20 ~ 30min is carried out to mixed phase D; Wherein, speed of agitator is 350 ~ 450r/min;
5) be added to by C in the mixed phase D after step 4) process, stir 5 ~ 7min at 50 ~ 60 DEG C after, homogenizing 10 ~ 20min, obtains Emulsion Phase E; Wherein, speed of agitator is 300 ~ 400r/min, and homogenization pressure is 45 ~ 55MPa;
6) getting the microcapsule repairing effect after above-mentioned obtained having is shone adds in homogeneous phase E, stirs 4 ~ 6min, obtains homogeneous phase F; Wherein, speed of agitator is 120 ~ 180r/min;
7) by homogeneous phase F through 18 ~ 20h ageing, obtain described containing have shine after repair the sunscreen cream of the microcapsule of effect.
Embodiment 1:
Have the microcapsule repairing effect after shining, be a kind of microcapsule of nucleocapsid structure, the parts by weight of cyst material are: 20 parts of maltodextrins, 15 parts of arabic gums and 10 parts of hydroxyethyl-celluloses; The parts by weight of core materials are: 20 portions of Oleum Cocois, 5 parts of Oleum Hippophaes, 5 parts of Jojoba waxes, 3 parts of squalanes, 3 parts of vitamin Es, 2 parts of Radix Hamamelidis Mollis ethanol extract, 2 parts of Herba Portulacae ethanol extract, 1 part of peoniflorin, 2 parts of green tea ethanol extract, 1 part of Cys and 1 part of sorbester p17.
Containing the above-mentioned sunscreen cream with the microcapsule shining rear reparation effect; comprise the composition of following weight portion: 10 parts above-mentioned have shine after repair the microcapsule of effect, 30 portions of Oleum Cocois, 15 parts of lanolines, 15 parts of ethanol, 3 parts of zinc oxide, 2 parts of titanium dioxide, 5 parts of OctMets, 4 parts of PAROSOL 1789s, 5 parts of 2-cyano group-3,3-diphenyl 2-Propenoic acid-2-ethylhexyl esters, 10 parts of vitamin Es, 20 parts of deionized waters, 8 parts of xanthan gum and 3 parts of span 20s.
Embodiment 2:
Have the microcapsule repairing effect after shining, be a kind of microcapsule of nucleocapsid structure, the parts by weight of cyst material are: 30 parts of maltodextrins, 25 parts of arabic gums and 15 parts of hydroxyethyl-celluloses; The parts by weight of core materials are: 25 portions of Oleum Cocois, 15 parts of Oleum Hippophaes, 10 parts of Jojoba waxes, 5 parts of squalanes, 5 parts of vitamin Es, 4 parts of Radix Hamamelidis Mollis ethanol extract, 4 parts of Herba Portulacae ethanol extract, 5 parts of peoniflorins, 6 parts of green tea ethanol extract, 3 parts of Cys and 3 parts of sorbester p17s.
Containing the above-mentioned sunscreen cream with the microcapsule shining rear reparation effect; comprise the composition of following weight portion: 20 parts above-mentioned have shine after repair the microcapsule of effect, 40 portions of Oleum Cocois, 20 parts of lanolines, 20 parts of ethanol, 6 parts of zinc oxide, 5 parts of titanium dioxide, 10 parts of OctMets, 7 parts of PAROSOL 1789s, 8 parts of 2-cyano group-3,3-diphenyl 2-Propenoic acid-2-ethylhexyl esters, 12 parts of vitamin Es, 30 parts of deionized waters, 12 parts of xanthan gum and 5 parts of span 20s.
Embodiment 3:
Have the microcapsule repairing effect after shining, be a kind of microcapsule of nucleocapsid structure, the parts by weight of cyst material are: 25 parts of maltodextrins, 20 parts of arabic gums and 13 parts of hydroxyethyl-celluloses; The parts by weight of core materials are: 23 portions of Oleum Cocois, 10 parts of Oleum Hippophaes, 8 parts of Jojoba waxes, 4 parts of squalanes, 4 parts of vitamin Es, 3 parts of Radix Hamamelidis Mollis ethanol extract, 3 parts of Herba Portulacae ethanol extract, 4 parts of peoniflorins, 5 parts of green tea ethanol extract, 2 parts of Cys and 2 parts of sorbester p17s.
Containing the above-mentioned sunscreen cream with the microcapsule shining rear reparation effect; comprise the composition of following weight portion: 15 parts above-mentioned have shine after repair the microcapsule of effect, 35 portions of Oleum Cocois, 18 parts of lanolines, 18 parts of ethanol, 5 parts of zinc oxide, 4 parts of titanium dioxide, 8 parts of OctMets, 6 parts of PAROSOL 1789s, 6 parts of 2-cyano group-3,3-diphenyl 2-Propenoic acid-2-ethylhexyl esters, 11 parts of vitamin Es, 26 parts of deionized waters, 10 parts of xanthan gum and 4 parts of span 20s.
The embedding rate repairing the microcapsule of effect after shining above-mentioned obtained having is investigated, the microcapsule embedded rate that the microcapsule embedded rate that the microcapsule embedded rate that result display embodiment 1 obtains is 95.76%, embodiment 2 is obtained is 96.38%, embodiment 3 is obtained is 97.12%, has good embedding effect.
The present invention will repair composition embedding by microcapsule technology after natural solarization, and the microcapsule after embedding is added in sunscreen cream, make the sunscreen cream obtained in use can play double effects that is sun-proof and that repair after shining simultaneously, just can the skin after solarization be repaired in the short time after solarization; And the sunscreen cream adopting this technology obtained, effectively prevent sun-prevention component and after shining, repair composition and coexist and the bad interactive competition phenomenon that causes, make this sunscreen cream effectively can ensure sun-proof function before use and after shining, repair effect to disappear or to decline, there is excellent performance.
What finally illustrate is, above embodiment is only in order to illustrate technical scheme of the present invention and unrestricted, although applicant's reference preferred embodiment is to invention has been detailed description, those of ordinary skill in the art is to be understood that, technical scheme of the present invention is modified or equivalent replacement, and do not depart from the aim of technical solution of the present invention and scope, all should be encompassed in the middle of right of the present invention.
Claims (6)
1. have the microcapsule repairing effect after shining, be a kind of microcapsule of nucleocapsid structure, it is characterized in that, cyst material comprises maltodextrin, arabic gum and hydroxyethyl-cellulose; Core materials comprises Oleum Cocois, Oleum Hippophae, Jojoba wax, squalane, vitamin E, Radix Hamamelidis Mollis ethanol extract, Herba Portulacae ethanol extract, peoniflorin, green tea ethanol extract, Cys and span.
2. have the microcapsule repairing effect after shining according to claim 1, it is characterized in that, described surfactant is sorbester p17.
3. have the microcapsule repairing effect after shining according to claim 2, it is characterized in that, the parts by weight of described cyst material are: 20 ~ 30 parts of maltodextrins, 15 ~ 25 parts of arabic gums and 10 ~ 15 parts of hydroxyethyl-celluloses; The parts by weight of described core materials are: 20 ~ 25 portions of Oleum Cocois, 5 ~ 15 parts of Oleum Hippophaes, 5 ~ 10 parts of Jojoba waxes, 3 ~ 5 parts of squalanes, 3 ~ 5 parts of vitamin Es, 2 ~ 4 parts of Radix Hamamelidis Mollis ethanol extract, 2 ~ 4 parts of Herba Portulacae ethanol extract, 1 ~ 5 part of peoniflorin, 2 ~ 6 parts of green tea ethanol extract, 1 ~ 3 part of Cys and 1 ~ 3 part of sorbester p17.
4. have the microcapsule repairing effect after shining according to claim 3, it is characterized in that, the parts by weight of described cyst material are: 25 parts of maltodextrins, 20 parts of arabic gums and 13 parts of hydroxyethyl-celluloses; The parts by weight of described core materials are: 23 portions of Oleum Cocois, 10 parts of Oleum Hippophaes, 8 parts of Jojoba waxes, 4 parts of squalanes, 4 parts of vitamin Es, 3 parts of Radix Hamamelidis Mollis ethanol extract, 3 parts of Herba Portulacae ethanol extract, 4 parts of peoniflorins, 5 parts of green tea ethanol extract, 2 parts of Cys and 2 parts of sorbester p17s.
5. there is described in arbitrary containing claim 1 ~ 4 sunscreen cream of microcapsule repairing effect after shining, it is characterized in that, comprise the composition of following weight portion: there is described in 10 ~ 20 parts of claim 1 ~ 4 are arbitrary the microcapsule repairing effect after shining, 30 ~ 40 portions of Oleum Cocois, 15 ~ 20 parts of lanolines, 15 ~ 20 parts of ethanol, 3 ~ 6 parts of zinc oxide, 2 ~ 5 parts of titanium dioxide, 5 ~ 10 parts of OctMets, 4 ~ 7 parts of PAROSOL 1789s, 5 ~ 8 parts of 2-cyano group-3, 3-diphenyl 2-Propenoic acid-2-ethylhexyl ester, 10 ~ 12 parts of vitamin Es, 20 ~ 30 parts of deionized waters, 8 ~ 12 parts of xanthan gum and 3 ~ 5 parts of span 20s.
6. sunscreen cream according to claim 5; it is characterized in that; comprise the composition of following weight portion: there are described in 15 parts of claim 1 ~ 4 are arbitrary the microcapsule repairing effect after shining, 35 portions of Oleum Cocois, 18 parts of lanolines, 18 parts of ethanol, 5 parts of zinc oxide, 4 parts of titanium dioxide, 8 parts of OctMets, 6 parts of PAROSOL 1789s, 6 parts of 2-cyano group-3,3-diphenyl 2-Propenoic acid-2-ethylhexyl esters, 11 parts of vitamin Es, 26 parts of deionized waters, 10 parts of xanthan gum and 4 parts of span 20s.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510735751.2A CN105213205B (en) | 2015-11-03 | 2015-11-03 | It is a kind of that there is the microcapsules of after-sun and the suncream containing the microcapsules |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510735751.2A CN105213205B (en) | 2015-11-03 | 2015-11-03 | It is a kind of that there is the microcapsules of after-sun and the suncream containing the microcapsules |
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| CN105213205A true CN105213205A (en) | 2016-01-06 |
| CN105213205B CN105213205B (en) | 2018-04-13 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107519025A (en) * | 2017-08-23 | 2017-12-29 | 中山大学惠州研究院 | A kind of hydrophobic sun-proof microcapsules and preparation method thereof |
| CN113197799A (en) * | 2020-04-21 | 2021-08-03 | 百欧生命标准有限公司 | Cosmetic composition for improving skin condition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1287877A (en) * | 1999-07-27 | 2001-03-21 | 株式会社资生堂 | Micro-capsule and its prepn. method |
| JP2015054841A (en) * | 2013-09-12 | 2015-03-23 | 株式会社成和化成 | Oil-in-water type emulsion cosmetic |
| CN104434548A (en) * | 2014-12-16 | 2015-03-25 | 重庆小丸科贸有限公司 | Hydrogel microcapsule with sunscreen effect |
-
2015
- 2015-11-03 CN CN201510735751.2A patent/CN105213205B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1287877A (en) * | 1999-07-27 | 2001-03-21 | 株式会社资生堂 | Micro-capsule and its prepn. method |
| JP2015054841A (en) * | 2013-09-12 | 2015-03-23 | 株式会社成和化成 | Oil-in-water type emulsion cosmetic |
| CN104434548A (en) * | 2014-12-16 | 2015-03-25 | 重庆小丸科贸有限公司 | Hydrogel microcapsule with sunscreen effect |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107519025A (en) * | 2017-08-23 | 2017-12-29 | 中山大学惠州研究院 | A kind of hydrophobic sun-proof microcapsules and preparation method thereof |
| CN113197799A (en) * | 2020-04-21 | 2021-08-03 | 百欧生命标准有限公司 | Cosmetic composition for improving skin condition |
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| CN105213205B (en) | 2018-04-13 |
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