CN105176715B - A kind of Detergent power - Google Patents
A kind of Detergent power Download PDFInfo
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- CN105176715B CN105176715B CN201510574081.0A CN201510574081A CN105176715B CN 105176715 B CN105176715 B CN 105176715B CN 201510574081 A CN201510574081 A CN 201510574081A CN 105176715 B CN105176715 B CN 105176715B
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Abstract
A kind of Detergent power, it is related to cleaning agent and preparation method thereof.The invention solves traditional the problem of adding alkali to cause beer bottle brightness difference and clean effect difference merely.Detergent power is prepared by anion surfactant, nonionic surfactant, antisludging agent, defoamer, sodium tripolyphosphate, sodium gluconate, sodium metasilicate, solid base and distilled water.Preparation method：First, weigh；2nd, dissolve, that is, obtain Detergent power.The present invention is used for a kind of Detergent power and preparation method thereof.
Description
Technical field
The present invention relates to cleaning agent and preparation method thereof.
Background technology
According to statistics, there are more than 850 families in national Beer Brewage producer now, produces about 8,000,000 tons of beer, current nearly all beer per year
Brewery uses returnable bottle, and dirt is serious, and Beer bottle washing is one of critical process of beer production, beer bottle
Cleaning performance directly affects the outward appearance of beer bottle and the inherent quality of beer.Therefore, it is necessary to by cleaning and sterilizing to reach clear
Clean, bright, sterile purpose.Traditional Beer bottle washing using liquid caustic soda, solid caustic soda or soda ash etc., concentration of lye reach 4% with
On, but clean bottle rate is not high, and it is especially helpless to the difficult wash bottle of weight dirt with dirts such as colloid, grease, protein, wine dirts, and
Obscured in the presence of bottle appearance after laundering, washing is costly, transport, storage, using dangerous, perishable human body skin, easily makes equipment knot
Incrustation scale, it is big to test bottle operation labor intensity, the problems such as polluting environment.Therefore, being studied by lot of experiments, one successfully have developed
Kind is efficient, still, safe, can suppress the novel beer mildew bottle bottle cleaning agent of equipment scale generation.
The content of the invention
The invention solves traditional the problem of adding alkali to cause beer bottle brightness difference and clean effect difference merely, and provide
A kind of Detergent power and preparation method thereof.
A kind of Detergent power of the present invention, Detergent power is in parts by weight by 1 part~10 parts anionic surfaces
Activating agent, 1 part~10 portions nonionic surfactants, 15 parts~30 parts antisludging agents, 0.5 part~2 parts defoamers, 35 parts~50 parts
Sodium tripolyphosphate, 10 parts~25 parts sodium gluconates, 1 part~10 parts sodium metasilicates, 1 part~2 parts solid bases and 450 parts~550
Part distilled water is prepared；
Described anion surfactant is Brij 35 sodium sulphate, ammonium lauryl sulfate, ten
Sodium dialkyl sulfate, neopelex, SAS, fatty alcohol sodium isethionate, N- lauroyl musculamine acid
Sodium, coconut acyl methyl taurine sodium, N- lauroyls sodium hydrogen α-aminoglutarate, amide groups APEO magnesium sulfate, laruyl alcohol polyoxy second
Alkene ether carboxylic acid sodium, 1-isobutyl-3,5-dimethylhexylphosphoric acid, 1-isobutyl-3,5-dimethylhexylphosphoric acid sylvite, 1-isobutyl-3,5-dimethylhexylphosphoric acid ester triethanolamine, α-alkenyl
Sodium sulfonate or paratoluenesulfonic acid sodium salt；
Described nonionic surfactant is fatty monoethanol amide, fatty acid distribution of coconut oil diglycollic amide, fat
Fat acid polyoxyethylene ester, Dodecyl Glucoside, alkylolamides, higher aliphatic acid diglycollic amide, aliphatic amine polyoxyethylene ether,
Carboxyl synthol APEO, APES or AEO；
Described antisludging agent is amino trimethyl phosphoric acid, carboxyl ethylidene diphosphonic acid, ethylene diamine tetra methylene phosphonic acid sodium, second two
The methylenephosphonic acid of amine four, the sodium of carboxyl ethylidene diphosphonic acid four, amino trimethyl tetrasodium phosphate, benzotriazole sodium, methylbenzene a pair of horses going side by side three
Nitrogen azoles, poly (sodium aspartate), sodium tripolyphosphate, calgon or polyacrylate；
Described defoamer is higher alcohols, benzyl carbinol oleate, Laurate alcohol ester phenylacetate, polyoxyethylene, poly dimethyl silicon
Oxygen alkane, polyoxypropylene, polypropylene glycerol aether, polyoxy propyl alcohol amidogen ether, high-carbon alcohol fatty acid ester polymer, polyoxypropylene Ji Wusi
Alcohol ether or silicone emulsion.
A kind of preparation method of Detergent power of the present invention, is to prepare according to the following steps：
First, weigh：1 part~10 portions anion surfactants are weighed in parts by weight, 1 part~10 parts non-ionic surfaces are lived
Property agent, 15 parts~30 parts antisludging agents, 0.5 part~2 parts defoamers, 35 parts~50 parts sodium tripolyphosphates, 10 parts~25 parts glucose
Sour sodium, 1 part~10 parts sodium metasilicates, 1 part~2 parts solid bases and 450 parts~550 parts distilled water；
2nd, dissolve：First under the conditions of temperature is 75 DEG C~85 DEG C and magnetic agitation, into 450 parts~550 parts distilled water
1 part~2 parts solid bases are added, is completely dissolved to solid base, obtains alkali lye, be then 75 DEG C~85 DEG C and magnetic agitation in temperature
Under the conditions of, 0.5 part~2 parts defoamers, 35 parts~50 parts sodium tripolyphosphates, 10 parts~25 parts glucose are sequentially added into alkali lye
Sour sodium, 1 part~10 parts sodium metasilicates, 1 part~10 portions anion surfactants, 1 part~10 portions nonionic surfactants and
15 parts~30 parts antisludging agents, mixed dissolution, that is, obtain Detergent power；
Described anion surfactant is Brij 35 sodium sulphate, ammonium lauryl sulfate, ten
Sodium dialkyl sulfate, neopelex, SAS, fatty alcohol sodium isethionate, N- lauroyl musculamine acid
Sodium, coconut acyl methyl taurine sodium, N- lauroyls sodium hydrogen α-aminoglutarate, amide groups APEO magnesium sulfate, laruyl alcohol polyoxy second
Alkene ether carboxylic acid sodium, 1-isobutyl-3,5-dimethylhexylphosphoric acid, 1-isobutyl-3,5-dimethylhexylphosphoric acid sylvite, 1-isobutyl-3,5-dimethylhexylphosphoric acid ester triethanolamine, α-alkenyl
Sodium sulfonate or paratoluenesulfonic acid sodium salt；
Described nonionic surfactant is fatty monoethanol amide, fatty acid distribution of coconut oil diglycollic amide, fat
Fat acid polyoxyethylene ester, Dodecyl Glucoside, alkylolamides, higher aliphatic acid diglycollic amide, aliphatic amine polyoxyethylene ether,
Carboxyl synthol APEO, APES or AEO；
Described antisludging agent is amino trimethyl phosphoric acid, carboxyl ethylidene diphosphonic acid, ethylene diamine tetra methylene phosphonic acid sodium, second two
The methylenephosphonic acid of amine four, the sodium of carboxyl ethylidene diphosphonic acid four, amino trimethyl tetrasodium phosphate, benzotriazole sodium, methylbenzene a pair of horses going side by side three
Nitrogen azoles, poly (sodium aspartate), sodium tripolyphosphate, calgon or polyacrylate；
Described defoamer is higher alcohols, benzyl carbinol oleate, Laurate alcohol ester phenylacetate, polyoxyethylene, poly dimethyl silicon
Oxygen alkane, polyoxypropylene, polypropylene glycerol aether, polyoxy propyl alcohol amidogen ether, high-carbon alcohol fatty acid ester polymer, polyoxypropylene Ji Wusi
Alcohol ether or silicone emulsion.
The beneficial effects of the invention are as follows：Detergent power produced by the present invention has strong detergency, and wash bottle effect is good, nothing
Bubble, it is safe the advantages of, clean bottle rate is up to more than 99%.Detergent power prepared by the present invention, scale removal, except mildew effect it is good；
Still, nontoxic, production and application is simple, safety.The inventive method preparation technology is simple, and cost is low, after old bottle is scrubbed, outer sightseeing
It is clean bright, while there is good economic benefit and social benefit.
Brief description of the drawings
Fig. 1 is Detergent power made from embodiment one for the figure before Beer bottle washing；
Fig. 2 is Detergent power made from embodiment one for the figure after Beer bottle washing.
Specific embodiment
Specific embodiment one：Present embodiment be a kind of Detergent power in parts by weight by 1 part~10 parts the moon from
Sub- surfactant, 1 part~10 portions nonionic surfactants, 15 parts~30 parts antisludging agents, 0.5 part~2 parts defoamers, 35 parts
~50 parts of sodium tripolyphosphates, 10 parts~25 parts sodium gluconates, 1 part~10 parts sodium metasilicates, 1 part~2 parts solid bases and 450 parts
~550 parts of distilled water are prepared；
Described anion surfactant is Brij 35 sodium sulphate, ammonium lauryl sulfate, ten
Sodium dialkyl sulfate, neopelex, SAS, fatty alcohol sodium isethionate, N- lauroyl musculamine acid
Sodium, coconut acyl methyl taurine sodium, N- lauroyls sodium hydrogen α-aminoglutarate, amide groups APEO magnesium sulfate, laruyl alcohol polyoxy second
Alkene ether carboxylic acid sodium, 1-isobutyl-3,5-dimethylhexylphosphoric acid, 1-isobutyl-3,5-dimethylhexylphosphoric acid sylvite, 1-isobutyl-3,5-dimethylhexylphosphoric acid ester triethanolamine, α-alkenyl
Sodium sulfonate or paratoluenesulfonic acid sodium salt；
Described nonionic surfactant is fatty monoethanol amide, fatty acid distribution of coconut oil diglycollic amide, fat
Fat acid polyoxyethylene ester, Dodecyl Glucoside, alkylolamides, higher aliphatic acid diglycollic amide, aliphatic amine polyoxyethylene ether,
Carboxyl synthol APEO, APES or AEO；
Described antisludging agent is amino trimethyl phosphoric acid, carboxyl ethylidene diphosphonic acid, ethylene diamine tetra methylene phosphonic acid sodium, second two
The methylenephosphonic acid of amine four, the sodium of carboxyl ethylidene diphosphonic acid four, amino trimethyl tetrasodium phosphate, benzotriazole sodium, methylbenzene a pair of horses going side by side three
Nitrogen azoles, poly (sodium aspartate), sodium tripolyphosphate, calgon or polyacrylate；
Described defoamer is higher alcohols, benzyl carbinol oleate, Laurate alcohol ester phenylacetate, polyoxyethylene, poly dimethyl silicon
Oxygen alkane, polyoxypropylene, polypropylene glycerol aether, polyoxy propyl alcohol amidogen ether, high-carbon alcohol fatty acid ester polymer, polyoxypropylene Ji Wusi
Alcohol ether or silicone emulsion.
The beneficial effect of present embodiment is：Detergent power made from present embodiment has strong detergency, wash bottle
Effect is good, still, it is safe the advantages of, clean bottle rate is up to more than 99%.Detergent power prepared by present embodiment, scale removal,
Except mildew effect is good；Still, nontoxic, production and application is simple, safety.Present embodiment method preparation technology is simple, and cost is low, old
After bottle is scrubbed, smooth appearance is bright, while has good economic benefit and social benefit.
Principle：For Retrieve beer bottle because source is different, its dirt composition is considerably complicated, mainly has:Extraneous dust, dirt, oil
The present invention such as fat, carbohydrate, protein, wine dirt, colloid fouling, mildew, old label paper and adhesive are former using similar compatibility
Reason.Whiteness is calcium, the dirt of magnesium ion composition in beer bottle, adds this antisludging agent of poly (sodium aspartate), because chelant is made
With causing scaling cations (such as ca2+, Mg2+Deng) chelate stable with chelating agent effect generation, so as to prevent its with into dirty cloudy
Ion (such as CO3 2-, SO4 2-Deng) contact so that into dirt probability be greatly reduced, due to peptizaiton prevent into dirt it is interparticle
Contact with each other and condense, so as to prevent the growth of dirt.The full name of bleeding agent is AEO, belongs to non-ionic surface
Activating agent, bleeding agent have been as its name suggests osmosises, and with fixed hydrophilic lipophilic group, are determined in the surface energy of solution
To arrangement, and the material that can be remarkably decreased surface tension.
Embodiment two：The difference of present embodiment and embodiment one is：Described solid base is
NaOH.It is other identical with embodiment one.
Embodiment three：The difference of present embodiment and one of embodiment one or two is：By weight
Number is by 3 parts~6 portions anion surfactants, 3 parts~6 portions nonionic surfactants, 20 parts~30 parts antisludging agents, 1 part~2
Part defoamer, 40 parts~50 parts sodium tripolyphosphates, 10 parts~20 parts sodium gluconates, 3 parts~6 parts sodium metasilicates, 1.5 parts~2
Part solid base and 450 parts~500 parts distilled water are prepared.It is other identical with embodiment one or two.
Embodiment four：A kind of preparation method of Detergent power described in present embodiment, specifically according to
What following steps were carried out：
First, weigh：1 part~10 portions anion surfactants are weighed in parts by weight, 1 part~10 parts non-ionic surfaces are lived
Property agent, 15 parts~30 parts antisludging agents, 0.5 part~2 parts defoamers, 35 parts~50 parts sodium tripolyphosphates, 10 parts~25 parts glucose
Sour sodium, 1 part~10 parts sodium metasilicates, 1 part~2 parts solid bases and 450 parts~550 parts distilled water；
2nd, dissolve：First under the conditions of temperature is 75 DEG C~85 DEG C and magnetic agitation, into 450 parts~550 parts distilled water
1 part~2 parts solid bases are added, is completely dissolved to solid base, obtains alkali lye, be then 75 DEG C~85 DEG C and magnetic agitation in temperature
Under the conditions of, 0.5 part~2 parts defoamers, 35 parts~50 parts sodium tripolyphosphates, 10 parts~25 parts glucose are sequentially added into alkali lye
Sour sodium, 1 part~10 parts sodium metasilicates, 1 part~10 portions anion surfactants, 1 part~10 portions nonionic surfactants and
15 parts~30 parts antisludging agents, mixed dissolution, that is, obtain Detergent power；
Described anion surfactant is Brij 35 sodium sulphate, ammonium lauryl sulfate, ten
Sodium dialkyl sulfate, neopelex, SAS, fatty alcohol sodium isethionate, N- lauroyl musculamine acid
Sodium, coconut acyl methyl taurine sodium, N- lauroyls sodium hydrogen α-aminoglutarate, amide groups APEO magnesium sulfate, laruyl alcohol polyoxy second
Alkene ether carboxylic acid sodium, 1-isobutyl-3,5-dimethylhexylphosphoric acid, 1-isobutyl-3,5-dimethylhexylphosphoric acid sylvite, 1-isobutyl-3,5-dimethylhexylphosphoric acid ester triethanolamine, α-alkenyl
Sodium sulfonate or paratoluenesulfonic acid sodium salt；
Described nonionic surfactant is fatty monoethanol amide, fatty acid distribution of coconut oil diglycollic amide, fat
Fat acid polyoxyethylene ester, Dodecyl Glucoside, alkylolamides, higher aliphatic acid diglycollic amide, aliphatic amine polyoxyethylene ether,
Carboxyl synthol APEO, APES or AEO；
Described antisludging agent is amino trimethyl phosphoric acid, carboxyl ethylidene diphosphonic acid, ethylene diamine tetra methylene phosphonic acid sodium, second two
The methylenephosphonic acid of amine four, the sodium of carboxyl ethylidene diphosphonic acid four, amino trimethyl tetrasodium phosphate, benzotriazole sodium, methylbenzene a pair of horses going side by side three
Nitrogen azoles, poly (sodium aspartate), sodium tripolyphosphate, calgon or polyacrylate；
Described defoamer is higher alcohols, benzyl carbinol oleate, Laurate alcohol ester phenylacetate, polyoxyethylene, poly dimethyl silicon
Oxygen alkane, polyoxypropylene, polypropylene glycerol aether, polyoxy propyl alcohol amidogen ether, high-carbon alcohol fatty acid ester polymer, polyoxypropylene Ji Wusi
Alcohol ether or silicone emulsion.
The beneficial effect of present embodiment is：Detergent power made from present embodiment has strong detergency, wash bottle
Effect is good, still, it is safe the advantages of, clean bottle rate is up to more than 99%.Detergent power prepared by present embodiment, scale removal,
Except mildew effect is good；Still, nontoxic, production and application is simple, safety.Present embodiment method preparation technology is simple, and cost is low, old
After bottle is scrubbed, smooth appearance is bright, while has good economic benefit and social benefit.
Embodiment five：Present embodiment is with the difference of embodiment four：Solid described in step 1
Alkali is NaOH.It is other identical with embodiment four.
Embodiment six：Present embodiment is with one of embodiment four or five difference：Pressed in step 1
Parts by weight weigh 3 parts~6 portions anion surfactants, 3 parts~6 portions nonionic surfactants, 20 parts~30 parts scale inhibitions
Agent, 1 part~2 parts defoamers, 40 parts~50 parts sodium tripolyphosphates, 10 parts~20 parts sodium gluconates, 3 parts~6 parts sodium metasilicates,
1.5 parts~2 parts solid bases and 450 parts~500 parts distilled water.It is other identical with embodiment four or five.
Using following verification experimental verifications effect of the present invention：
Embodiment one：
Detergent power in parts by weight by 10 portions of anion surfactants, 8 portions of nonionic surfactants, 20 parts
Antisludging agent, 2 parts of defoamers, 35 parts of sodium tripolyphosphates, 20 parts of sodium gluconates, 8 parts of sodium metasilicates, 1.8 parts of solid bases and 500 parts
Distilled water is prepared；
10 portions of described anion surfactants are 5 parts of neopelexes and 5 parts of paratoluenesulfonic acid sodium salts；
8 portions of described nonionic surfactants are 5 parts of AEOs and 3 parts of Dodecyl Glucosides；
Described antisludging agent is poly (sodium aspartate)；
Described defoamer is Laurate alcohol ester phenylacetate.
Described solid base is NaOH.
A kind of above-mentioned Detergent power is to prepare according to the following steps：
First, weigh：10 portions of anion surfactants, 8 portions of nonionic surfactants, 20 parts of resistances are weighed in parts by weight
Dirty agent, 2 parts of defoamers, 35 parts of sodium tripolyphosphates, 20 parts of sodium gluconates, 8 parts of sodium metasilicates, 1.8 parts of solid bases and 500 parts of steamings
Distilled water；
2nd, dissolve：First under the conditions of temperature is 80 DEG C and magnetic agitation, 1.8 parts of solids are added into 500 parts of distilled water
Alkali, it is completely dissolved to solid base, obtains alkali lye, then under the conditions of temperature is 80 DEG C and magnetic agitation, is added successively into alkali lye
Enter 20 parts of antisludging agents, 2 parts of defoamers, 35 parts of sodium tripolyphosphates, 20 parts of sodium gluconates and 8 parts of sodium metasilicates, 10 parts of anion
Surfactant and 8 portions of nonionic surfactants, mixed dissolution, that is, obtain Detergent power；
10 portions of described anion surfactants are 5 parts of neopelexes and 5 parts of paratoluenesulfonic acid sodium salts；
8 portions of described nonionic surfactants are 5 parts of AEOs and 3 parts of Dodecyl Glucosides；
Described antisludging agent is poly (sodium aspartate)；
Described defoamer is Laurate alcohol ester phenylacetate.
Described solid base is NaOH.
Fig. 1 is Detergent power made from embodiment one for the figure before Beer bottle washing；It is clear as seen from the figure
Beer bottle before washing has a large amount of mildews and a dirt, and beer bottle is very dirty.Fig. 2 be Detergent power made from embodiment one for
Figure after Beer bottle washing.The beer bottle outward appearance cleaned as seen from the figure with cleaning agent is bright, for mildew and dirt
Cleaning performance is very good.
| Beer bottle sequence number | 1 | 2 | 3 | 4 | 5 | 6 |
| Clean rate | 99.19% | 99.01% | 99.89% | 99.11% | 99.32% | 99.05% |
Claims (1)
1. a kind of Detergent power, it is characterised in that Detergent power is in parts by weight by 10 parts of anion surface actives
Agent, 8 portions of nonionic surfactants, 20 parts of antisludging agents, 2 parts of defoamers, 35 parts of sodium tripolyphosphates, 20 parts of sodium gluconates, 8 parts
Sodium metasilicate, 1.8 parts of solid bases and 500 parts of distilled water are prepared；
10 portions of described anion surfactants are 5 parts of neopelexes and 5 parts of paratoluenesulfonic acid sodium salts；
8 portions of described nonionic surfactants are 5 parts of AEOs and 3 parts of Dodecyl Glucosides；
Described antisludging agent is poly (sodium aspartate)；
Described defoamer is Laurate alcohol ester phenylacetate；
Described solid base is NaOH；
A kind of described Detergent power is to prepare according to the following steps：
First, weigh：10 portions of anion surfactants, 8 portions of nonionic surfactants, 20 parts of scale inhibitions are weighed in parts by weight
Agent, 2 parts of defoamers, 35 parts of sodium tripolyphosphates, 20 parts of sodium gluconates, 8 parts of sodium metasilicates, 1.8 parts of solid bases and 500 parts of distillations
Water；
2nd, dissolve：First under the conditions of temperature is 80 DEG C and magnetic agitation, 1.8 parts of solid bases are added into 500 parts of distilled water,
It is completely dissolved to solid base, obtains alkali lye, then under the conditions of temperature is 80 DEG C and magnetic agitation, 20 is sequentially added into alkali lye
Part antisludging agent, 2 parts of defoamers, 35 parts of sodium tripolyphosphates, 20 parts of sodium gluconates, 8 parts of sodium metasilicates, 10 parts of anionic surfaces are lived
Property agent and 8 portions of nonionic surfactants, mixed dissolution, that is, obtain Detergent power.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510574081.0A CN105176715B (en) | 2015-09-10 | 2015-09-10 | A kind of Detergent power |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510574081.0A CN105176715B (en) | 2015-09-10 | 2015-09-10 | A kind of Detergent power |
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| CN105176715A CN105176715A (en) | 2015-12-23 |
| CN105176715B true CN105176715B (en) | 2018-01-23 |
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|---|---|---|---|---|
| CN106085606A (en) * | 2016-06-25 | 2016-11-09 | 李莹 | Detergent |
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| CN107904027A (en) * | 2017-11-21 | 2018-04-13 | 常州市蓝勖化工有限公司 | A kind of Detergent power |
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| CN109735854A (en) * | 2019-01-28 | 2019-05-10 | 安徽唯楚新材料有限公司 | A kind of environment-friendlyaluminium aluminium board cleaning agent and its cleaning method |
| CN110240977B (en) * | 2019-06-28 | 2020-11-10 | 天津市博仁易洁物业服务有限公司 | Multifunctional cleaning agent and preparation method thereof |
| CN112480929A (en) * | 2020-10-23 | 2021-03-12 | 伯恩光学(惠州)有限公司 | Glass thinning agent |
| CN112745989A (en) * | 2020-12-30 | 2021-05-04 | 王晓立 | Quick-acting beer bottle label-removing cleaning additive |
| CN117210285B (en) * | 2023-09-12 | 2024-04-09 | 沁襄新材料(广州)有限公司 | Oil-removing antibacterial cleaning agent and preparation method thereof |
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| CN1073478A (en) * | 1991-12-11 | 1993-06-23 | 化学工业部上海化工研究院 | Prescription of composite detergent |
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| CN105176715A (en) | 2015-12-23 |
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