CN105175995A - 一种覆铜板用环氧树脂组合物及其应用 - Google Patents

一种覆铜板用环氧树脂组合物及其应用 Download PDF

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CN105175995A
CN105175995A CN201510483488.2A CN201510483488A CN105175995A CN 105175995 A CN105175995 A CN 105175995A CN 201510483488 A CN201510483488 A CN 201510483488A CN 105175995 A CN105175995 A CN 105175995A
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epoxy resin
phosphorus
resol
weight parts
composition
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CN201510483488.2A
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CN105175995B (zh
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徐莹
方克洪
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Shengyi Technology Co Ltd
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Shengyi Technology Co Ltd
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Priority to CN201510483488.2A priority Critical patent/CN105175995B/zh
Priority to US15/743,930 priority patent/US20180201761A1/en
Priority to PCT/CN2015/096517 priority patent/WO2017020462A1/zh
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    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
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Abstract

本发明涉及一种覆铜板用环氧树脂组合物及其应用，该环氧树脂组合物可用于预浸料及覆铜箔层压板的制备。本发明通过采用溴化双酚A和含磷酚醛分别作为溴和磷元素来源，并调节所述环氧树脂组合物中两者的比例，使溴含量控制在5-12％，磷含量控制在0.2-1.5％，其阻燃性可达UL94？V-0级；利用该环氧树脂组合物制作的预浸料和层压板不仅降低了卤素含量，改善了耐热性，而且使基材的耐压性有所改善，具有低吸潮性、良好的粘结性、反应性以及加工性，并可满足相比漏电起痕指数(CTI)>600V，大大降低了生产成本。

Description

一种覆铜板用环氧树脂组合物及其应用
技术领域
本发明涉及层压板技术领域，具体涉及一种环氧树脂组合物，尤其涉及一种覆铜板用环氧树脂组合物及用其制作的预浸料，层压板与印刷电路板。
背景技术
随着欧盟指令WEEE(WasteElectricalandElectronicEquipment)和RoHS(RestrictionofHazardousSubstances)的正式实施，全球电子业进入了无铅焊接时代。由于无铅焊接温度的提高，对印制电路覆铜板的耐热性和热稳定性提出了更高的要求。受欧盟颁发的“绿色”法规的影响，溴元素作为阻燃元素是否应该用在高分子领域又被推到了争议的风口浪尖上。虽然四溴双酚A作为阻燃剂还未发现其对环境有什么较大的负面影响，但是对于将其列为禁用物质的呼声越来越高。因此未来阻燃对于溴元素的依赖程度势必会逐渐降低。寻找一种耐热性好吸湿率低且对溴依存度较小的覆铜板技术就更加迫在眉睫。
传统FR4大都采用溴阻燃。溴元素阻燃效率高，并且如四溴双酚A这一类的阻燃物质成本低廉且容易推广。但如果仅靠溴阻燃，在普通FR4中总溴含量一般要到达15％(溴元素占板材中有机固形物的质量比)以上才能达到UL94V-0级。较高的溴含量不仅有悖于环境友好，同时由于C-Br键容易断裂，也导致材料本身的耐热性严重下降；而且高溴含量的有机物不利于在高温高压潮湿且容易受污染的环境下工作，因为溴元素会加速线路板两电路之间的材料漏电失效，因而降低溴含量可以使材料适应高压高湿等恶劣环境，如中国专利CN101654004A、CN102382420A公开的内容中，从环氧树脂及填料出发，采用降低树脂体系中溴含量到10-15％或者经特殊改性的环氧树脂，并添加大量的氢氧化铝等无机填料使材料能适应恶劣环境。但是由于氢氧化铝用量过大，会产生耐热性下降的问题，这是因为氢氧化铝的热分解温度低，从200℃便开始脱水，而PCB焊接的温度在245-260℃，使得最终制成的板材在高温下容易出现分层起泡，从而影响产品的可靠性。
使用磷元素阻燃也能达到阻燃的目的，因为磷阻燃体系不含溴元素，因此耐热性方面要比溴阻燃体系好很多。但是磷元素容易吸潮，单纯靠磷元素阻燃的板材吸湿率较高，不利于板材的电性能的稳定性；且目前磷系阻燃剂价格普遍较高，成本压力较大，因此虽然对于无卤化的呼声很高，但由于成本原因要放弃溴阻燃目前也不太可能。中国专利CN102093670A公开了一种用含9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物(DOPO)结构的含磷酚醛实现阻燃的方法，虽然DOPO吸水率要比磷酸酯低，但由于其用量较大，磷含量也在2％以上，因此吸湿率也没有得到较好的改善。
目前的覆铜板配方大都采用溴阻燃或者磷阻燃，溴阻燃体系溴含量较高，通常要到15％以上才能达到阻燃，但是较高的溴含量导致耐热性较差，相对漏电起痕指数(CTI)也难以达到600V。采用磷阻燃由于磷含量太高又会有吸湿率增大的弊端。
CN101892027和CN101808466虽披露了溴与磷共用，但二者由于使用了大量丁腈橡胶，相对于环氧树脂，丙烯腈结构吸水率更高，复合基材的耐电压性下降，此外丁腈橡胶中的丙烯腈结构会加速溴的分解，对含溴体系的CTI性能不利。
因此，寻找一种具有低吸潮性、高相对漏电起痕指数(CTI)值，并具有良好的耐热性、粘结性、反应性以及加工性的环氧树脂组合物是目前亟待解决的问题。
发明内容
本发明的目的在于提供一种环氧树脂组合物，特别是一种覆铜板用环氧树脂组合物及用其制作的预浸料，层压板与印刷电路板。
为达到此发明目的，本发明采用以下技术方案：
第一方面，本发明提供了一种环氧树脂组合物，以有机固形物重量份计，包括如下组分：
(A)环氧树脂：50-100重量份；
(B)含磷酚醛：2-30重量份；
(C)溴化双酚A：1-40重量份；
(D)其他固化剂：10-60重量份；
(E)固化促进剂：0.05-1.0重量份；
其中，所述的环氧树脂组合物中，溴含量占所述组合物中有机固形物重量之和的5～12％；磷含量占所述组合物中有机固形物重量之和的0.2～1.5％。
由于现有的覆铜板制作中，单独采用含溴环氧树脂阻燃材料时，其溴含量通常要到15％以上才能达到阻燃，但是较高的溴含量会导致其耐热性变差，CTI值也难以达到600V；而单独采用含磷阻燃剂进行阻燃时，通常也要在较高磷含量下才能实现UL94V-0级，然而由于磷含量太高又会有吸湿率增大的弊端。本发明在阻燃元素的引入方式上，采用同时添加含磷酚醛和溴化双酚A的方式，并调节二者用量，使溴含量在5％-12％，磷含量在0.2％-1.5％，不仅使阻燃性达到UL94V-0级，而且与单纯采用含溴环氧树脂阻燃材料阻燃的覆铜板相比，具有更高的耐热性，且能达到较高CTI值(CTI>600V)，与单独采用含磷阻燃剂阻燃的覆铜板相比，吸湿率较低，耐浸焊时间较长。
本发明所述的环氧树脂组合物中，溴元素和磷元素优选来自含磷酚醛和溴化双酚A。
现有的覆铜板材料大都分开采用溴阻燃体系，或者磷阻燃体系。用量最大的溴阻燃覆铜板多是使用溴化环氧树脂作为溴源，一般的这类覆铜板都需要很高的溴含量才能实现阻燃的目的，但是这类板材由于溴含量较高，材料本身的CTI性能受到严重限制，含溴体系要实现高耐热高CTI性非常困难；无卤覆铜板磷元素引入方式较大，主流方向是使用含磷环氧或含磷酚醛，但是这类板材磷含量较高，磷易吸水，因此吸水率比溴阻燃体系高出很多。
本发明通过采用溴化双酚A作为溴元素来源，与提供磷元素的含磷酚醛进行组合使用，两者可形成交联互穿网络，从而更好的发挥协同作用，其只需较低含量的溴和磷元素即可实现基材的阻燃性达到UL94V-0级，而且，可进一步使基材的吸水率变小、高CTI，且粘结性、加工性和工艺操作性好，减小了阻燃对溴元素的依赖，从而更加环保。
本发明中，所述的环氧树脂为50-100重量份，例如可以是50重量份、55重量份、60重量份、65重量份、70重量份、75重量份、80重量份、85重量份、90重量份、95重量份、100重量份。
本发明中，所述的含磷酚醛为2-30重量份，例如可以是2重量份、5重量份、8重量份、10重量份、12重量份、15重量份、18重量份、20重量份、22重量份、25重量份、28重量份、30重量份。
本发明中，所述的溴化双酚A为1-40重量份，例如可以是1重量份、2重量份、5重量份、8重量份、10重量份、12重量份、15重量份、18重量份、20重量份、22重量份、25重量份、28重量份、30重量份、32重量份、35重量份、38重量份、40重量份。
本发明中，所述的其它固化剂为10-60重量份，例如可以是10重量份、12重量份、15重量份、18重量份、20重量份、22重量份、25重量份、28重量份、30重量份、32重量份、35重量份、38重量份、40重量份、42重量份、45重量份、48重量份、50重量份、52重量份、55重量份、58重量份、60重量份。
本发明中，所述的固化促进剂为0.05-1.0重量份，例如可以是0.05重量份、0.08重量份、0.1重量份、0.2重量份、0.3重量份、0.4重量份、0.5重量份、0.6重量份、0.7重量份、0.8重量份、0.9重量份、1.0重量份。
本发明中，所述的环氧树脂组合物中，溴含量占所述组合物中有机固形物重量之和的5-12％，例如可以是5％、5.5％、6％、6.5％、7％、7.5％、8％、8.5％、9％、9.5％、10％、10.5％、11％、11.5％、12％，优选为5-10％，进一步优选为5-8％。
本发明中，所述的环氧树脂组合物中，磷含量占所述组合物中有机固形物重量之和的0.2-1.5％，例如可以是0.2％、0.3％、0.4％、0.5％、0.6％、0.7％、0.8％、0.9％、1.0％、1.1％、1.2％、1.3％、1.4％、1.5％，优选为0.5-1.5％，进一步优选为0.8-1.5％。
本发明中，所述的含磷酚醛为含磷有菲型化合物，优选为二氢-9-氧-10-磷杂菲对应的酚醛树脂。
优选地，所述的含磷酚醛为如下酚醛树脂中的至少一种：
DOPO-HPM；DOPO-TRIOL；
DOPO-PN；OD-PN；
Ar-DOPO-N；CHPQ-PA；
本发明中，所述的溴化双酚A具有如下化学结构式：
其中，R1-R4中至少有一个为Br原子，当R1-R4不是Br原子时则为H原子，例如可以是R1为Br原子，R1-R3为H原子，或者R1和R2为Br原子，R3-R4为H原子等等。
本发明中，所述的环氧树脂为双酚A型环氧树脂、邻甲酚型酚醛环氧树脂、双酚A型酚醛环氧树脂、苯酚型环氧树脂、双环戊二烯型环氧树脂、MDI环氧树脂、双酚F型环氧树脂、双酚S型环氧树脂、双酚F型环氧树脂、四官能环氧树脂、萘型环氧树脂或联苯型环氧树脂中的任意一种或至少两种的混合。
本发明中，所述的其他固化剂为酚醛树脂、芳香二胺类固化剂、双氰胺、脂肪族胺、酸酐、活性聚酯或氰酸酯中的任意一种或至少两种的混合。
优选地，所述的酚醛树脂为苯酚型酚醛树脂、双酚A型酚醛树脂、邻甲酚酚醛树脂、三酚酚醛树脂、萘型酚醛树脂、联苯型酚醛树脂或双环戊二烯酚醛树脂中的任意一种或至少两种的混合。
优选地，所述的芳香二胺类固化剂具有如下化学结构式：
其中，X为-CH2-、-O-或R1、R3与R4为H、-CH3或-C2H5，R2为H、-CH3或-C2H5。
本发明中，所述的固化促进剂为咪唑类固化促进剂、有机膦固化促进剂或三级胺固化促进剂中的任意一种或至少两种的混合。
优选地，所述的咪唑类固化促进剂为2-甲基咪唑、2-甲基-4-乙基咪唑、2-十一烷基咪唑、2-苯基咪唑或1-氰乙基-2-乙基-4-甲基咪唑中的任意一种或至少两种的混合。
优选地，所述的有机膦固化促进剂为三丁基膦和/或三苯基膦。
优选地，所述的三级胺固化促进剂为苄基二甲基胺。
本发明中，固化促进剂的添加量不宜过量，添加量太大时反应会很快，不利于工艺操作与材料的储存。
本发明中，所述的环氧树脂组合物还含有填料，优选为无机填料。
优选地，所述的填料为勃姆石、氢氧化铝、硫酸钡、氟化钙、氢氧化镁、二氧化硅、玻璃粉、高岭土、滑石粉、云母粉、氧化铝、氧化锌、氧化镁、氮化硼、氮化铝或碳酸钙中的任意一种或至少两种的混合。
优选地，所述填料的平均粒径为0.3-20μm。
优选地，按所述环氧树脂组合物中各组分的有机固形物之和为100重量份计，所述填料的含量为1-200重量份，例如可以是1重量份、5重量份、10重量份、20重量份、30重量份、50重量份、60重量份、80重量份、100重量份、120重量份、140重量份、150重量份、180重量份、200重量份，优选为50-100重量份。
本发明通过添加氢氧化铝、硫酸钡或勃姆石等填料可进一步提高基板的相比漏电起痕指数(CTI)，使基板的相比漏电起痕指数(CTI)达到600V以上。
为使所述的无机填料在环氧树脂中分散均匀以及提升树脂与填料之间的结合力，所述的环氧树脂组合物还可以适当添加助剂，使用的助剂为氨基硅烷偶联剂或环氧基硅烷偶联剂，这类偶联剂无重金属存在，对人体健康无不良影响，使用量为无机填料的0.5-2％重量份。
优选地，所述的环氧树脂组合物还含有溶剂，优选为有机溶剂。
优选地，所述的溶剂为N,N’-二甲基甲酰胺、乙二醇***、丙二醇甲醚、丙酮、丁酮、甲醇、乙醇、苯或甲苯中的任意一种或至少两种的混合。
本发明的环氧树脂组合物，可以使用溶剂调节粘度，通过采用上述溶剂，能够调节所述环氧树脂组合物中固体组分含量达到40-80％。
第二方面，本发明还提供了一种使用如本发明第一方面所述的环氧树脂组合物制作的预浸料，其包括基体材料；和通过浸渍干燥后附着在其上的环氧树脂组合物。
优选地，所述的基体材料为无纺或有纺玻璃纤维布。
第三方面，本发明还提供了一种层压板，其包含如本发明第二方面所述的预浸料。
第四方面，本发明提供了一种印刷电路板，其包含如本发明第三方面所述的层压板。
与现有技术相比，本发明具有以下有益效果：
(1)本发明所述的环氧树脂组合物通过采用溴化双酚A和含磷酚醛分别作为溴和磷元素来源，并结合特定的磷溴比例，在有效控制成本的同时，不仅使阻燃性可达UL94V-0级，还改善了材料的相比漏电起痕指数(CTI)，能达到CTI>600V。
(2)本发明所述的环氧树脂组合物，与纯溴阻燃体系相比具有更好的耐热性，与纯磷阻燃体系相比具有更低的吸湿率，即解决了纯溴阻燃耐热性差和纯磷阻燃吸湿率高的问题，综合性能优异。
(3)使用本发明的环氧树脂组合物制作的预浸料和覆铜箔层压板，具有高玻璃化转变温度、高耐热性、高剥离强度、高相比漏电起痕指数(CTI)以及良好的加工性，适合于无铅焊接。
(4)本发明可以进一步减小阻燃对溴元素的依赖性，从而更加环保。
具体实施方式
下面通过具体实施方式来进一步说明本发明的技术方案，但并不局限于此。
本领域技术人员应该明了，所述实施例仅仅是帮助理解本发明，不应视为对本发明的具体限制。
实施例覆铜箔层压板的制备方法
将环氧树脂、含磷酚醛、溴化双酚A、其他固化剂、填料及固化促进剂，配合有机溶剂，利用搅拌分散设备，对其进行均匀混合，将所述的环氧树脂组合物预浸在无纺或有纺玻璃纤维布上，并在上胶机中(120-180℃)进行干燥，制成半固化状态的印制电路板用半固化片。
将上述半固化片数张叠合，叠层的单侧或双侧再叠合上铜箔，然后放置到120-200℃层压机上，热压固型，制成用于印制电路板加工的覆铜箔层压板；所述铜箔还可以采用铝箔、银箔或不锈钢箔进行替换。
针对上述实施例制成的覆铜箔层压板，测试其玻璃化转变温度、相比漏电起痕指数(CTI)、阻燃性、耐浸焊时间、PCT吸水率、5％热失重和钻孔加工性等性能，如下述实施例1-4与比较例1-7进一步给予说明与描述。
实施例1-4与比较例1-5的环氧树脂组合物中所用的各组分及其含量(按重量份计)如表1所示，表1中的环氧树脂组合物是按固体含量100％计算的；各组分代号及其对应的组分名称如下所示：
(A)环氧树脂：
(A1)MDI环氧树脂：97103，环氧当量为290g/eq，美国DOW化学公司生产；
(A2)四官能环氧树脂：1031，环氧当量210g/eq，美国Momentive化学公司生产；
(B)固化剂：
(B1)线性酚醛树脂：2812，美国Momentive化学公司生产；
(B2)芳香二胺：4,4-DDS，台湾寅生生产；
(C1)四溴双酚A：TBBPA，美国雅宝化学生产；
(D1)含磷酚醛：92741，DOW化学生产；
(E)填料：
(E1)勃姆石：蚌埠鑫源石英材料有限公司；
(E2)氢氧化铝：雅宝化学公司；
(E3)硫酸钡：贵州红星公司；
(F)固化促进剂：2-E-4MI，日本四国化成生产；
(G)有机溶剂：丁酮，陶氏化学有限公司。
采用以下方法对实施例1-4和比较例1-7制备的覆铜箔层压板进行测试，各性能参数的测试方法如下：
(A)玻璃化转变温度(Tg)
根据差示扫描量热法(DSC)，按照IPC-TM-6502.4.25所规定的DSC方法进行测定。
(B)相对漏电起痕指数(CTI)
按照GB/T4207-84所规定的方法进行测试。
(C)耐浸焊时间
将尺寸100×100mm的双面带铜箔板材浸在加热到288℃的焊锡槽中，计算其从浸入到出现板材分层爆板的时间。
(D)PCT吸水率
预先干燥样品称重后再放入高压锅中蒸煮4小时，看质量变化率。
(E)5％热失重
以5℃/min升温速率，在氮气氛下升温到500℃，记录样品质量损失5％时的温度。
(F)钻孔加工性
将厚度为1.6mm的板两块叠加在一起，用0.3mm钻头进行钻孔，钻速110krpm，落速33mm/s，连续钻5000孔，每1000孔时，观察钻头的刃尖磨损情况，由磨损的大小确定钻孔加工性好坏。
(G)阻燃性
按照UL94所规定的方法进行测试。
(H)击穿电压
按IPC标准方法进行测试。
对实施例1-4和比较例1-7制备的覆铜箔层压板进行测试的结果如表2所示。
表1
比较例6和比较例7的制备方法及材料厂商如下：
比较例6：合成橡胶(商品牌号Nipol1072CGX，美国ZEON公司生产)23重量份，溴化环氧(商品牌号DER530A80，DOW公司生产)25重量份，高溴环氧(商品牌号EPICLON153-60M，大日本油墨生产)21重量份，联苯环氧(NC3000H，日本化药生产)25重量份，2E4MI(日本四国化成生产)0.2重量份，芳香二胺4,4-DDS(台湾寅生生产)10.1重量份，苯氧基磷腈(SPB-100，磷含量13.4％，美国雅宝生产)20重量份，氢氧化铝(美国雅宝生产)15重量份，勃姆石(蚌埠鑫源石英材料有限公司)31重量份，硫酸钡(贵州红星公司)8重量份，溶剂MEK调节固含量至66％。
计算：溴含量为12.0％，磷含量为0.2％，填料比例及配比与实施例1相同。
比较例7：丁腈橡胶改性环氧(SC-024，SHIN-A生产)33重量份，溴化环氧树脂(DEBR530A80，陶氏化学公司生产)67重量份，双氰胺3份，2-甲基咪唑0.02份，四溴双酚A6重量份，含磷酚醛(LC950，SHIN-A生产)31重量份，氢氧化铝(美国雅宝生产)17重量份，勃姆石(蚌埠鑫源石英材料有限公司)34重量份，硫酸钡(贵州红星公司)9重量份，溶剂MEK调节固含量至66％。
计算：溴含量为12％，磷含量为0.2％，填料比例及配比与实施例1相同。
表2
从表1-表2可以看出以下几点：
(1)从实施例1-4可以看出，实施例1-4的环氧树脂组合物，其阻燃性均可达到UL94V-0级，并且耐浸焊时间均大于600s，钻孔加工性良好。
(2)从实施例1-4可以看出，实施例1-3的环氧树脂组合物其相对漏电起痕指数(CTI)均可达到600V，而实施例4的环氧树脂组合物其相对漏电起痕指数(CTI)只有200V，说明采用在环氧树脂组合物中加入适量的填料，可使基板获得高CTI。
(3)与比较例3相比，实施例1-4的PCT吸水率优于比较例3，由于比较例3中只采用了含磷酚醛，其磷含量高达2.5％，使得其吸潮性上升，而实施例1-4同时采用含磷酚醛和溴化双酚A，其在磷含量只有0.2％-1.5％的情况下便可实现低吸潮性，说明采用含磷酚醛和溴化双酚A复配技术后，基板可获得低吸水性。
(4)与比较例2相比，实施例2-4采用磷溴协同阻燃只需要10％以下的溴元素就能达到阻燃UL94V-0级，而比较例2只引入了溴元素阻燃，虽然溴含量达到9.5％，但仍然达不到阻燃UL94V-0级。
(5)与比较例1相比，实施例1-4由于采用磷溴协同阻燃路线，在同样达到阻燃UL94V-0级的情况下只需要12％以下的溴元素，因此实施例1-4相比于比较例1具有更高的化学耐热性，即5％热失重温度要比比较例1高出9℃以上，耐浸焊时间也更长。
(6)比较例4和比较例5分别为溴含量和磷含量不在发明范围的情况，可以看出当溴含量为4.3％，磷含量为0.2％时，虽然CTI和耐热性都很好，但阻燃达不到UL94V-0级；当溴含量为12％，磷含量为0.1％时，材料的CTI虽然达到600V，但阻燃仍然达不到UL94V-0级。
(7)比较例6和比较例7分别为专利CN101808466A和CN101892027A所发明的树脂组合物在和本发明相同溴含量及磷含量以及同样的填料体系下，两篇专利都未能达到CTI600V，且吸水率明显高于本发明，相比而言本发明耐压能力更为优异。
综上所述，本发明所述的环氧树脂组合物，相比于纯溴阻燃体系耐热性有很大提高，并且加入勃姆石等填料后CTI在600V以上；相比于纯磷阻燃体系吸水率更低，钻孔加工性好，阻燃性好。本发明使用上述环氧树脂组合物制作的半固化片与覆铜板，其优异的CTI特性，使得其能明显改善PCB在恶劣环境下的适应能力；同时相对高的耐热性，耐浸焊时间长，能适合于无铅焊接的需要。并且该发明可以进一步减小阻燃对溴元素的依赖性，从而更加环保。
申请人声明，本发明通过上述实施例来说明本发明的工艺方法，但本发明并不局限于上述工艺步骤，即不意味着本发明必须依赖上述工艺步骤才能实施。所属技术领域的技术人员应该明了，对本发明的任何改进，对本发明所选用原料的等效替换及辅助成分的添加、具体方式的选择等，均落在本发明的保护范围和公开范围之内。

Claims (10)

1.一种环氧树脂组合物，其特征在于，以有机固形物重量份计，包括如下组分：
(A)环氧树脂：50-100重量份；
(B)含磷酚醛：2-30重量份；
(C)溴化双酚A：1-40重量份；
(D)其他固化剂：10-60重量份；
(E)固化促进剂：0.05-1.0重量份；
其中，所述的环氧树脂组合物中，溴含量占所述组合物中有机固形物重量之和的5-12％；磷含量占所述组合物中有机固形物重量之和的0.2-1.5％。
2.如权利要求1所述的环氧树脂组合物，其特征在于，所述的环氧树脂组合物中，溴含量占所述组合物中有机固形物重量之和的5-10％，优选为5-8％；磷含量占所述组合物中有机固形物重量之和的0.5-1.5％，优选为0.8-1.5％。
3.如权利要求1或2所述的环氧树脂组合物，其特征在于，所述的含磷酚醛为含磷有菲型化合物，优选为二氢-9-氧-10-磷杂菲对应的酚醛树脂；
优选地，所述的含磷酚醛为如下酚醛树脂中的至少一种：
4.如权利要求1-3任一项所述的环氧树脂组合物，其特征在于，所述的溴化双酚A具有如下化学结构式：
其中，R1-R4中至少有一个为Br原子。
5.如权利要求1-4任一项所述的环氧树脂组合物，其特征在于，所述的环氧树脂为双酚A型环氧树脂、邻甲酚型酚醛环氧树脂、双酚A型酚醛环氧树脂、苯酚型环氧树脂、双环戊二烯型环氧树脂、MDI环氧树脂、双酚F型环氧树脂、双酚S型环氧树脂、双酚F型环氧树脂、四官能环氧树脂、萘型环氧树脂或联苯型环氧树脂中的任意一种或至少两种的混合。
6.如权利要求1-5任一项所述的环氧树脂组合物，其特征在于，所述的其他固化剂为酚醛树脂、芳香二胺类固化剂、双氰胺、脂肪族胺、酸酐、活性聚酯或氰酸酯中的任意一种或至少两种的混合；
优选地，所述的酚醛树脂为苯酚型酚醛树脂、双酚A型酚醛树脂、邻甲酚酚醛树脂、三酚酚醛树脂、萘型酚醛树脂、联苯型酚醛树脂或双环戊二烯酚醛树脂中的任意一种或至少两种的混合；
优选地，所述的芳香二胺类固化剂具有如下化学结构式：
其中，X为-CH2-、-O-或R1、R3与R4为H、-CH3或-C2H5，R2为H、-CH3或-C2H5；
优选地，所述的固化促进剂为咪唑类固化促进剂、有机膦固化促进剂或三级胺固化促进剂中的任意一种或至少两种的混合；
优选地，所述的咪唑类固化促进剂为2-甲基咪唑、2-甲基-4-乙基咪唑、2-十一烷基咪唑、2-苯基咪唑或1-氰乙基-2-乙基-4-甲基咪唑中的任意一种或至少两种的混合；
优选地，所述的有机膦固化促进剂为三丁基膦和/或三苯基膦；
优选地，所述的三级胺固化促进剂为苄基二甲基胺。
7.如权利要求1-6任一项所述的环氧树脂组合物，其特征在于，所述的环氧树脂组合物还含有填料，优选为无机填料；
优选地，所述的填料为勃姆石、氢氧化铝、硫酸钡、氟化钙、氢氧化镁、二氧化硅、玻璃粉、高岭土、滑石粉、云母粉、氧化铝、氧化锌、氧化镁、氮化硼、氮化铝或碳酸钙中的任意一种或至少两种的混合；
优选地，所述填料的平均粒径为0.3-20μm；
优选地，按所述环氧树脂组合物中各组分的有机固形物之和为100重量份计，所述填料的含量为1-200重量份，优选为50-100重量份；
优选地，所述的环氧树脂组合物还含有溶剂，优选为有机溶剂；
优选地，所述的溶剂为N,N’-二甲基甲酰胺、乙二醇***、丙二醇甲醚、丙酮、丁酮、甲醇、乙醇、苯或甲苯中的任意一种或至少两种的混合。
8.一种使用如权利要求1-7任一项所述的环氧树脂组合物制作的预浸料，其特征在于，其包括基体材料；和通过浸渍干燥后附着在其上的环氧树脂组合物；
优选地，所述的基体材料为无纺或有纺玻璃纤维布。
9.一种层压板，其特征在于，其包含如权利要求8所述的预浸料。
10.一种印刷电路板，其特征在于，其包含如权利要求9所述的层压板。
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CN110330689A (zh) * 2018-03-27 2019-10-15 台光电子材料股份有限公司 含磷阻燃剂、其制备方法、含有该含磷阻燃剂的树脂组合物及其制品
CN110872430A (zh) * 2019-11-29 2020-03-10 陕西生益科技有限公司 一种高cti的树脂组合物、预浸料、层压板和覆金属箔层压板
CN111534056A (zh) * 2020-04-15 2020-08-14 浙江华正新材料股份有限公司 一种树脂组合物、预浸料及其层压板
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CN110330689A (zh) * 2018-03-27 2019-10-15 台光电子材料股份有限公司 含磷阻燃剂、其制备方法、含有该含磷阻燃剂的树脂组合物及其制品
CN110330689B (zh) * 2018-03-27 2021-06-29 台光电子材料股份有限公司 含磷阻燃剂、其制备方法、含有该含磷阻燃剂的树脂组合物及其制品
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