CN105175835A - High-performance fire-retardant computer cable - Google Patents
High-performance fire-retardant computer cable Download PDFInfo
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- CN105175835A CN105175835A CN201510607795.7A CN201510607795A CN105175835A CN 105175835 A CN105175835 A CN 105175835A CN 201510607795 A CN201510607795 A CN 201510607795A CN 105175835 A CN105175835 A CN 105175835A
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Abstract
The invention discloses a high-performance fire-retardant computer cable. The cable comprises a cable core, the cable core comprises three insulating wires, each insulating wire comprises a conductor and an insulating layer wrapping the conductor, the cable core is sequentially wrapped by a shielding layer and a sheath layer, and the sheath layer is made of a modified polyvinyl chloride material. The modified polyvinyl chloride material is prepared from, by weight, polyvinyl chloride, first chloroprene rubber, butyl rubber, second chloroprene rubber, silicon rubber, sulfur, vulcanizer HTDM, vulcanization accelerator CZ, vulcanization accelerator TMTD, antiager A, antiager D, antiager 4010NA, tricresyl phosphate, trioctyl phosphate, dioctyl sebacate, coumarone resin, sepiolite, halloysite, zinc oxide, modified hollow microspheres, RF-90 resin, hexakis (methoxymethyl) melamine resin and zirconium oxide. The high-performance fire-retardant computer cable is excellent in fire-retardant and mechanical performance.
Description
Technical field
The present invention relates to field of cable technology, particularly relate to a kind of high-performance refractory computer cable.
Background technology
High-performance refractory computer cable is the cable being applicable to the connection such as voltage rating 300/500V and the following cybernation higher to anti-electromagnetic disturbance requirement, instrument detection, be widely used in the fields such as automatic equipment, the automatic control circuit in some emphasis fire-fighting regions needs a large amount of fire resistant flame retardant high-performance refractory computer cables, but fire-resistant, the mechanical property of existing high-performance refractory computer cable can not meet growing demand, larger hidden danger is formed to line facility and personal security.
Summary of the invention
Based on the technical problem that background technology exists, the present invention proposes a kind of high-performance refractory computer cable, its excellent fire retarding performance, excellent in mechanical performance.,
A kind of high-performance refractory computer cable that the present invention proposes, comprise cable core, cable core comprises three insulated conductors, and insulated conductor comprises conductor and is coated on the insulation layer outside conductor, at cable core outer coated screen layer and restrictive coating successively, wherein restrictive coating adopts modified polyvinyl chloride material to make.
Preferably, the raw material of modified polyvinyl chloride material comprises by weight: polyvinyl chloride 20-40 part, chloroprene rubber 20-30 part, isoprene-isobutylene rubber 18-26 part, chloroprene rubber 5-15 part, silicon rubber 15-30 part, sulphur 0.5-1.8 part, vulcanizing agent HTDM0.5-1.4 part, accelerator CZ 1-2 part, vulcanization accelerator TMTD 0.2-0.8 part, antioxidant A 1.5-3 part, antioxidant D 1-3 part, antioxidant 4010NA 0.5-1.8 part, Tritolyl Phosphate 1-3 part, trioctyl phosphate 1-3 part, dioctyl sebacate 1-1.8 part, coumarone indene resin 0.5-1.4 part, sepiolite 20-30 part, halloysite 5-15 part, zinc oxide 1-2 part, modification tiny balloon 30-40 part, RF-90 resin 0.5-2.5 part, hexamethoxymethyl melamine resin 1-3 part, zirconium white 0.5-2.5 part.
Preferably, in the preparation process of modification tiny balloon: hollow glass micro-ball is sent in hydrochloric acid, reflux, washing, drying obtains pre-treatment material; By beta-cyclodextrin, MALEIC ANHYDRIDE, pre-treatment abrasive lapping evenly, send in reactor and heat, stir; dinethylformamide, triethylamine, kaolin, the stirring of 3-glycydoxy Trimethoxy silane is added under nitrogen protection; cleaning, dry, obtain modification tiny balloon.
Preferably, in the preparation process of modification tiny balloon: sent in 100-120 part hydrochloric acid by 60-80 part hollow glass micro-ball by weight, the concentration of hydrochloric acid is 0.8-1.5mol/L, reflux 1-3h, washing, and drying obtains pre-treatment material; By weight that 20-30 part beta-cyclodextrin, 30-50 part MALEIC ANHYDRIDE, 70-100 part pre-treatment abrasive lapping is even; be heated to 95-98 DEG C in feeding reactor stir; churning time is 15-30min; 70-80 part dinethylformamide, 2-5 part triethylamine, 30-40 part kaolin, 0.5-2.5 part 3-glycydoxy Trimethoxy silane stirring at normal temperature 20-30h is added under nitrogen protection; ultrasonic cleaning; drying, obtains modification tiny balloon.
Preferably, the weight ratio of sulphur, vulcanizing agent HTDM, accelerator CZ and vulcanization accelerator TMTD is 1.2-1.5:0.6-1:1.3-1.5:0.3-0.5.
Preferably, the weight ratio of sepiolite, halloysite and modification tiny balloon is 24-26:10-13:34-36.
Preferably, the weight ratio of polyvinyl chloride, chloroprene rubber, isoprene-isobutylene rubber, chloroprene rubber and silicon rubber is 30-34:22-25:20-24:8-13:20-24.
Preferably, the raw material of modified polyvinyl chloride material comprises by weight: polyvinyl chloride 30-34 part, chloroprene rubber 22-25 part, isoprene-isobutylene rubber 20-24 part, chloroprene rubber 8-13 part, silicon rubber 20-24 part, sulphur 1.2-1.5 part, vulcanizing agent HTDM0.6-1 part, accelerator CZ 1.3-1.5 part, vulcanization accelerator TMTD 0.3-0.5 part, antioxidant A 1.8-2.3 part, antioxidant D 2-2.6 part, antioxidant 4010NA 1-1.3 part, Tritolyl Phosphate 1.5-2.2 part, trioctyl phosphate 2-2.6 part, dioctyl sebacate 1.2-1.4 part, coumarone indene resin 0.8-1 part, sepiolite 24-26 part, halloysite 10-13 part, zinc oxide 1.3-1.6 part, modification tiny balloon 34-36 part, RF-90 resin 1-1.8 part, hexamethoxymethyl melamine resin 1.4-1.9 part, zirconium white 1-1.6 part.
In the present invention, above-mentioned modified polyvinyl chloride material adopts preparation technology's preparation of ordinary rubber, and namely starting material prepare → plasticate → mixing → shaping → sulfuration → rest and reorganization → inspection.
In the present invention, with polyvinyl chloride, chloroprene rubber, isoprene-isobutylene rubber, chloroprene rubber and silicon rubber for base material, Tritolyl Phosphate, trioctyl phosphate, dioctyl sebacate and coumarone indene resin mating reaction, good processability, thermal stability is excellent, and fire performance is fabulous, and sulphur, vulcanizing agent HTDM are as vulcanizing agent, coordinate interpolation accelerator CZ and vulcanization accelerator TMTD to help sulfuration, goods rubber has well fire-resistant and mechanical property; Add sepiolite, halloysite, zinc oxide and modification tiny balloon synergy, not only cheap, and goods can be applicable to the occasion comparatively harsh to fire resistant requirements, and halogen-free environmental; Wherein in modification tiny balloon, using empty glass microsphere as matrix, there is active substance on its surface firmly chemical bonds, the adsorbent of matrix and matrix surface is all containing cavity, inside and outside double-layer cavity structure makes product size controlled, overall crosslinking structure is good, and organic fabulous with the bonding force of inorganic material with other, the fire-resistant and mechanical property of goods strengthens further.
Accompanying drawing explanation
Fig. 1 is the structural representation of a kind of high-performance refractory computer cable that the present invention proposes.
Embodiment
As shown in Figure 1, Fig. 1 is the structural representation of a kind of high-performance refractory computer cable that the present invention proposes.
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
With reference to Fig. 1, a kind of high-performance refractory computer cable, comprises cable core, cable core comprises three insulated conductors, insulated conductor comprises conductor 1 and is coated on the insulation layer 2 outside conductor 1, and at cable core outer coated screen layer 3 and restrictive coating 4 successively, wherein restrictive coating 4 adopts modified polyvinyl chloride material to make.
The raw material of modified polyvinyl chloride material comprises by weight: polyvinyl chloride 20 parts, chloroprene rubber 30 parts, isoprene-isobutylene rubber 18 parts, chloroprene rubber 15 parts, 15 parts, silicon rubber, 1.8 parts, sulphur, vulcanizing agent HTDM0.5 part, accelerator CZ 2 parts, vulcanization accelerator TMTD 0.2 part, antioxidant A 3 parts, antioxidant D 1 part, antioxidant 4010NA 1.8 parts, Tritolyl Phosphate 1 part, trioctyl phosphate 3 parts, dioctyl sebacate 1 part, coumarone indene resin 1.4 parts, sepiolite 20 parts, halloysite 15 parts, 1 part, zinc oxide, modification tiny balloon 40 parts, RF-90 resin 0.5 part, hexamethoxymethyl melamine resin 3 parts, zirconium white 0.5 part.
Embodiment 2
With reference to Fig. 1, a kind of high-performance refractory computer cable, comprises cable core, cable core comprises three insulated conductors, insulated conductor comprises conductor 1 and is coated on the insulation layer 2 outside conductor 1, and at cable core outer coated screen layer 3 and restrictive coating 4 successively, wherein restrictive coating 4 adopts modified polyvinyl chloride material to make.
The raw material of modified polyvinyl chloride material comprises by weight: polyvinyl chloride 40 parts, chloroprene rubber 20 parts, isoprene-isobutylene rubber 26 parts, chloroprene rubber 5 parts, 30 parts, silicon rubber, 0.5 part, sulphur, vulcanizing agent HTDM1.4 part, accelerator CZ 1 part, vulcanization accelerator TMTD 0.8 part, antioxidant A 1.5 parts, antioxidant D 3 parts, antioxidant 4010NA 0.5 part, Tritolyl Phosphate 3 parts, trioctyl phosphate 1 part, dioctyl sebacate 1.8 parts, coumarone indene resin 0.5 part, sepiolite 30 parts, halloysite 5 parts, 2 parts, zinc oxide, modification tiny balloon 30 parts, RF-90 resin 2.5 parts, hexamethoxymethyl melamine resin 1 part, zirconium white 2.5 parts.
Embodiment 3
With reference to Fig. 1, a kind of high-performance refractory computer cable, comprises cable core, cable core comprises three insulated conductors, insulated conductor comprises conductor 1 and is coated on the insulation layer 2 outside conductor 1, and at cable core outer coated screen layer 3 and restrictive coating 4 successively, wherein restrictive coating 4 adopts modified polyvinyl chloride material to make.
The raw material of modified polyvinyl chloride material comprises by weight: polyvinyl chloride 30 parts, chloroprene rubber 25 parts, isoprene-isobutylene rubber 20 parts, chloroprene rubber 13 parts, 20 parts, silicon rubber, 1.5 parts, sulphur, vulcanizing agent HTDM0.6 part, accelerator CZ 1.5 parts, vulcanization accelerator TMTD 0.3 part, antioxidant A 2.3 parts, antioxidant D 2 parts, antioxidant 4010NA 1.3 parts, Tritolyl Phosphate 1.5 parts, trioctyl phosphate 2.6 parts, dioctyl sebacate 1.2 parts, coumarone indene resin 1 part, sepiolite 24 parts, halloysite 13 parts, 1.3 parts, zinc oxide, modification tiny balloon 36 parts, RF-90 resin 1 part, hexamethoxymethyl melamine resin 1.9 parts, zirconium white 1 part.
In the preparation process of modification tiny balloon: send in 100 parts of hydrochloric acid by 80 parts of hollow glass micro-balls by weight, the concentration of hydrochloric acid is 1.5mol/L, reflux 1h, washing, and drying obtains pre-treatment material; By weight that 30 parts of beta-cyclodextrins, 30 parts of MALEIC ANHYDRIDE, 100 parts of pre-treatment abrasive lappings are even; be heated to 95 DEG C in feeding reactor stir; churning time is 30min; 70 parts of dinethylformamides, 5 parts of triethylamines, 30 parts of kaolin, 2.5 parts of 3-glycydoxy Trimethoxy silane stirring at normal temperature 20h are added under nitrogen protection; ultrasonic cleaning; drying, obtains modification tiny balloon.
Embodiment 4
With reference to Fig. 1, a kind of high-performance refractory computer cable, comprises cable core, cable core comprises three insulated conductors, insulated conductor comprises conductor 1 and is coated on the insulation layer 2 outside conductor 1, and at cable core outer coated screen layer 3 and restrictive coating 4 successively, wherein restrictive coating 4 adopts modified polyvinyl chloride material to make.
The raw material of modified polyvinyl chloride material comprises by weight: polyvinyl chloride 34 parts, chloroprene rubber 22 parts, isoprene-isobutylene rubber 24 parts, chloroprene rubber 8 parts, 24 parts, silicon rubber, 1.2 parts, sulphur, vulcanizing agent HTDM1 part, accelerator CZ 1.3 parts, vulcanization accelerator TMTD 0.5 part, antioxidant A 1.8 parts, antioxidant D 2.6 parts, antioxidant 4010NA 1 part, Tritolyl Phosphate 2.2 parts, trioctyl phosphate 2 parts, dioctyl sebacate 1.4 parts, coumarone indene resin 0.8 part, sepiolite 26 parts, halloysite 10 parts, 1.6 parts, zinc oxide, modification tiny balloon 34 parts, RF-90 resin 1.8 parts, hexamethoxymethyl melamine resin 1.4 parts, zirconium white 1.6 parts.
In the preparation process of modification tiny balloon: send in 120 parts of hydrochloric acid by 60 parts of hollow glass micro-balls by weight, the concentration of hydrochloric acid is 0.8mol/L, reflux 3h, washing, and drying obtains pre-treatment material; By weight that 20 parts of beta-cyclodextrins, 50 parts of MALEIC ANHYDRIDE, 70 parts of pre-treatment abrasive lappings are even; be heated to 98 DEG C in feeding reactor stir; churning time is 15min; 80 parts of dinethylformamides, 2 parts of triethylamines, 40 parts of kaolin, 0.5 part of 3-glycydoxy Trimethoxy silane stirring at normal temperature 30h are added under nitrogen protection; ultrasonic cleaning; drying, obtains modification tiny balloon.
Embodiment 5
With reference to Fig. 1, a kind of high-performance refractory computer cable, comprises cable core, cable core comprises three insulated conductors, insulated conductor comprises conductor 1 and is coated on the insulation layer 2 outside conductor 1, and at cable core outer coated screen layer 3 and restrictive coating 4 successively, wherein restrictive coating 4 adopts modified polyvinyl chloride material to make.
The raw material of modified polyvinyl chloride material comprises by weight: polyvinyl chloride 31 parts, chloroprene rubber 24 parts, isoprene-isobutylene rubber 22 parts, chloroprene rubber 11 parts, 22 parts, silicon rubber, 1.4 parts, sulphur, vulcanizing agent HTDM0.8 part, accelerator CZ 1.45 parts, vulcanization accelerator TMTD 0.45 part, antioxidant A 2.2 parts, antioxidant D 2.4 parts, antioxidant 4010NA 1.25 parts, Tritolyl Phosphate 1.6 parts, trioctyl phosphate 2.4 parts, dioctyl sebacate 1.35 parts, coumarone indene resin 0.95 part, sepiolite 25 parts, halloysite 12 parts, 1.45 parts, zinc oxide, modification tiny balloon 35 parts, RF-90 resin 1.5 parts, hexamethoxymethyl melamine resin 1.6 parts, zirconium white 1.3 parts.
In the preparation process of modification tiny balloon: send in 115 parts of hydrochloric acid by 75 parts of hollow glass micro-balls by weight, the concentration of hydrochloric acid is 1.3mol/L, reflux 1.5h, washing, and drying obtains pre-treatment material; By weight that 24 parts of beta-cyclodextrins, 46 parts of MALEIC ANHYDRIDE, 85 parts of pre-treatment abrasive lappings are even; be heated to 96 DEG C in feeding reactor stir; churning time is 24min; 76 parts of dinethylformamides, 3.5 parts of triethylamines, 36 parts of kaolin, 2.3 parts of 3-glycydoxy Trimethoxy silane stirring at normal temperature 26h are added under nitrogen protection; ultrasonic cleaning; drying, obtains modification tiny balloon.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (8)
1. a high-performance refractory computer cable, it is characterized in that, comprise cable core, cable core comprises three insulated conductors, insulated conductor comprises conductor (1) and is coated on conductor (1) insulation layer outward (2), at cable core outer coated screen layer (3) and restrictive coating (4) successively, wherein restrictive coating (4) adopts modified polyvinyl chloride material to make.
2. high-performance refractory computer cable according to claim 1, it is characterized in that, the raw material of modified polyvinyl chloride material comprises by weight: polyvinyl chloride 20-40 part, chloroprene rubber 20-30 part, isoprene-isobutylene rubber 18-26 part, chloroprene rubber 5-15 part, silicon rubber 15-30 part, sulphur 0.5-1.8 part, vulcanizing agent HTDM0.5-1.4 part, accelerator CZ 1-2 part, vulcanization accelerator TMTD 0.2-0.8 part, antioxidant A 1.5-3 part, antioxidant D 1-3 part, antioxidant 4010NA 0.5-1.8 part, Tritolyl Phosphate 1-3 part, trioctyl phosphate 1-3 part, dioctyl sebacate 1-1.8 part, coumarone indene resin 0.5-1.4 part, sepiolite 20-30 part, halloysite 5-15 part, zinc oxide 1-2 part, modification tiny balloon 30-40 part, RF-90 resin 0.5-2.5 part, hexamethoxymethyl melamine resin 1-3 part, zirconium white 0.5-2.5 part.
3. high-performance refractory computer cable according to claim 2, is characterized in that, in the preparation process of modification tiny balloon: sent into by hollow glass micro-ball in hydrochloric acid, reflux, washing, and drying obtains pre-treatment material; By beta-cyclodextrin, MALEIC ANHYDRIDE, pre-treatment abrasive lapping evenly, send in reactor and heat, stir; dinethylformamide, triethylamine, kaolin, the stirring of 3-glycydoxy Trimethoxy silane is added under nitrogen protection; cleaning, dry, obtain modification tiny balloon.
4. the high-performance refractory computer cable according to Claims 2 or 3, it is characterized in that, in the preparation process of modification tiny balloon: by weight 60-80 part hollow glass micro-ball is sent in 100-120 part hydrochloric acid, the concentration of hydrochloric acid is 0.8-1.5mol/L, reflux 1-3h, washing, drying obtains pre-treatment material; By weight that 20-30 part beta-cyclodextrin, 30-50 part MALEIC ANHYDRIDE, 70-100 part pre-treatment abrasive lapping is even; be heated to 95-98 DEG C in feeding reactor stir; churning time is 15-30min; 70-80 part dinethylformamide, 2-5 part triethylamine, 30-40 part kaolin, 0.5-2.5 part 3-glycydoxy Trimethoxy silane stirring at normal temperature 20-30h is added under nitrogen protection; ultrasonic cleaning; drying, obtains modification tiny balloon.
5. the high-performance refractory computer cable according to any one of claim 2-4, is characterized in that, the weight ratio of sulphur, vulcanizing agent HTDM, accelerator CZ and vulcanization accelerator TMTD is 1.2-1.5:0.6-1:1.3-1.5:0.3-0.5.
6. the high-performance refractory computer cable according to any one of claim 2-5, is characterized in that, the weight ratio of sepiolite, halloysite and modification tiny balloon is 24-26:10-13:34-36.
7. the high-performance refractory computer cable according to any one of claim 2-6, is characterized in that, the weight ratio of polyvinyl chloride, chloroprene rubber, isoprene-isobutylene rubber, chloroprene rubber and silicon rubber is 30-34:22-25:20-24:8-13:20-24.
8. the high-performance refractory computer cable according to any one of claim 2-7, it is characterized in that, the raw material of modified polyvinyl chloride material comprises by weight: polyvinyl chloride 30-34 part, chloroprene rubber 22-25 part, isoprene-isobutylene rubber 20-24 part, chloroprene rubber 8-13 part, silicon rubber 20-24 part, sulphur 1.2-1.5 part, vulcanizing agent HTDM0.6-1 part, accelerator CZ 1.3-1.5 part, vulcanization accelerator TMTD 0.3-0.5 part, antioxidant A 1.8-2.3 part, antioxidant D 2-2.6 part, antioxidant 4010NA 1-1.3 part, Tritolyl Phosphate 1.5-2.2 part, trioctyl phosphate 2-2.6 part, dioctyl sebacate 1.2-1.4 part, coumarone indene resin 0.8-1 part, sepiolite 24-26 part, halloysite 10-13 part, zinc oxide 1.3-1.6 part, modification tiny balloon 34-36 part, RF-90 resin 1-1.8 part, hexamethoxymethyl melamine resin 1.4-1.9 part, zirconium white 1-1.6 part.
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CN106117824A (en) * | 2016-07-25 | 2016-11-16 | 安徽德源电缆集团有限公司 | A kind of preparation method of ethylene propylene rubber insulated electric cable with silicon rubber sheath material |
CN106117825A (en) * | 2016-07-25 | 2016-11-16 | 安徽德源电缆集团有限公司 | A kind of preparation method of ethylene propylene rubber insulated polychloroprene sheathed cable sheath material |
CN106188887A (en) * | 2016-07-25 | 2016-12-07 | 安徽德源电缆集团有限公司 | A kind of preparation method of EP rubbers cable insulation material |
CN106229027A (en) * | 2016-08-15 | 2016-12-14 | 吴显峰 | A kind of rare earth aluminum alloy conductor magnesium oxide insulated fireproof cable |
CN106221050A (en) * | 2016-08-15 | 2016-12-14 | 吴显峰 | A kind of fireproof high-temperature resistant combined wear-resistant tensile removal cable |
CN106317680A (en) * | 2016-08-15 | 2017-01-11 | 吴显峰 | Low-smoke halogen-free flame-retardant mobile cable for robot |
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Cited By (6)
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CN106117824A (en) * | 2016-07-25 | 2016-11-16 | 安徽德源电缆集团有限公司 | A kind of preparation method of ethylene propylene rubber insulated electric cable with silicon rubber sheath material |
CN106117825A (en) * | 2016-07-25 | 2016-11-16 | 安徽德源电缆集团有限公司 | A kind of preparation method of ethylene propylene rubber insulated polychloroprene sheathed cable sheath material |
CN106188887A (en) * | 2016-07-25 | 2016-12-07 | 安徽德源电缆集团有限公司 | A kind of preparation method of EP rubbers cable insulation material |
CN106229027A (en) * | 2016-08-15 | 2016-12-14 | 吴显峰 | A kind of rare earth aluminum alloy conductor magnesium oxide insulated fireproof cable |
CN106221050A (en) * | 2016-08-15 | 2016-12-14 | 吴显峰 | A kind of fireproof high-temperature resistant combined wear-resistant tensile removal cable |
CN106317680A (en) * | 2016-08-15 | 2017-01-11 | 吴显峰 | Low-smoke halogen-free flame-retardant mobile cable for robot |
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