CN105152267A - 一种用煅烧褐铁矿深度去除水中磷的方法 - Google Patents
一种用煅烧褐铁矿深度去除水中磷的方法 Download PDFInfo
- Publication number
- CN105152267A CN105152267A CN201510582091.9A CN201510582091A CN105152267A CN 105152267 A CN105152267 A CN 105152267A CN 201510582091 A CN201510582091 A CN 201510582091A CN 105152267 A CN105152267 A CN 105152267A
- Authority
- CN
- China
- Prior art keywords
- limonite
- phosphorus
- calcining
- water
- phosphorous removal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 72
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 title claims abstract description 52
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 239000011574 phosphorus Substances 0.000 title claims abstract description 44
- 229910052698 phosphorus Inorganic materials 0.000 title claims abstract description 44
- 238000000034 method Methods 0.000 title claims abstract description 25
- 238000001354 calcination Methods 0.000 claims abstract description 34
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000010865 sewage Substances 0.000 claims abstract description 14
- 238000001179 sorption measurement Methods 0.000 claims abstract description 13
- 239000002245 particle Substances 0.000 claims abstract description 11
- 230000000694 effects Effects 0.000 claims abstract description 8
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 27
- 239000013618 particulate matter Substances 0.000 claims description 23
- 239000007788 liquid Substances 0.000 claims description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 17
- 239000011259 mixed solution Substances 0.000 claims description 14
- 238000001556 precipitation Methods 0.000 claims description 13
- 239000007864 aqueous solution Substances 0.000 claims description 9
- 229910052742 iron Inorganic materials 0.000 claims description 9
- 230000008929 regeneration Effects 0.000 claims description 9
- 238000011069 regeneration method Methods 0.000 claims description 9
- 239000000243 solution Substances 0.000 claims description 8
- 239000000969 carrier Substances 0.000 claims description 6
- 239000010440 gypsum Substances 0.000 claims description 6
- 229910052602 gypsum Inorganic materials 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- 229910052588 hydroxylapatite Inorganic materials 0.000 claims description 5
- 239000005416 organic matter Substances 0.000 claims description 5
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- 238000012545 processing Methods 0.000 claims description 5
- 230000001376 precipitating effect Effects 0.000 claims description 4
- 239000002352 surface water Substances 0.000 claims description 4
- ZQBZAOZWBKABNC-UHFFFAOYSA-N [P].[Ca] Chemical compound [P].[Ca] ZQBZAOZWBKABNC-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 238000006477 desulfuration reaction Methods 0.000 claims description 3
- 230000023556 desulfurization Effects 0.000 claims description 3
- 150000003016 phosphoric acids Chemical class 0.000 claims description 3
- 238000012216 screening Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000009825 accumulation Methods 0.000 claims description 2
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 claims description 2
- 238000004090 dissolution Methods 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 230000003993 interaction Effects 0.000 claims description 2
- 238000012856 packing Methods 0.000 claims description 2
- 238000001914 filtration Methods 0.000 abstract description 2
- 239000003673 groundwater Substances 0.000 abstract 1
- 229910052595 hematite Inorganic materials 0.000 abstract 1
- 239000011019 hematite Substances 0.000 abstract 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 abstract 1
- 230000014759 maintenance of location Effects 0.000 abstract 1
- JBJWASZNUJCEKT-UHFFFAOYSA-M sodium;hydroxide;hydrate Chemical compound O.[OH-].[Na+] JBJWASZNUJCEKT-UHFFFAOYSA-M 0.000 abstract 1
- 239000003463 adsorbent Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- -1 aluminum ion Chemical class 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 230000000274 adsorptive effect Effects 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 229960000892 attapulgite Drugs 0.000 description 2
- 239000001506 calcium phosphate Substances 0.000 description 2
- 229910000389 calcium phosphate Inorganic materials 0.000 description 2
- 235000011010 calcium phosphates Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000012851 eutrophication Methods 0.000 description 2
- 229910052746 lanthanum Inorganic materials 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 229910052625 palygorskite Inorganic materials 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 2
- 238000003911 water pollution Methods 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 159000000013 aluminium salts Chemical class 0.000 description 1
- 229910000329 aluminium sulfate Inorganic materials 0.000 description 1
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000031018 biological processes and functions Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 239000003034 coal gas Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000010815 organic waste Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- DJFBJKSMACBYBD-UHFFFAOYSA-N phosphane;hydrate Chemical compound O.P DJFBJKSMACBYBD-UHFFFAOYSA-N 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Water Treatment By Sorption (AREA)
- Removal Of Specific Substances (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Description
Claims (2)
Priority Applications (1)
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CN201510582091.9A CN105152267B (zh) | 2015-09-11 | 2015-09-11 | 一种用煅烧褐铁矿深度去除水中磷的方法 |
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CN201510582091.9A CN105152267B (zh) | 2015-09-11 | 2015-09-11 | 一种用煅烧褐铁矿深度去除水中磷的方法 |
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CN105152267A true CN105152267A (zh) | 2015-12-16 |
CN105152267B CN105152267B (zh) | 2017-05-31 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111039658A (zh) * | 2019-12-31 | 2020-04-21 | 广东省水利水电科学研究院 | 一种除磷陶粒及其制备方法 |
CN113244880A (zh) * | 2021-06-16 | 2021-08-13 | 南通大学 | 一种高效除磷的烧结陶粒、其制备方法及其再生方法 |
CN115805054A (zh) * | 2021-09-14 | 2023-03-17 | 中国地质大学(北京) | 一种以针铁矿为原料的prb填充柱介质材料 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009106898A (ja) * | 2007-10-31 | 2009-05-21 | Kurita Water Ind Ltd | 水処理方法及び水処理装置 |
JP2009148660A (ja) * | 2007-12-19 | 2009-07-09 | Miura Co Ltd | 水処理システム |
CN103316585A (zh) * | 2013-07-07 | 2013-09-25 | 合肥工业大学 | 一种纳米化矿物材料净化气体中有机污染物的方法 |
CN103803703A (zh) * | 2014-02-25 | 2014-05-21 | 合肥工业大学 | 一种纳米铁与微生物协同作用同步脱氮除磷的方法 |
-
2015
- 2015-09-11 CN CN201510582091.9A patent/CN105152267B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009106898A (ja) * | 2007-10-31 | 2009-05-21 | Kurita Water Ind Ltd | 水処理方法及び水処理装置 |
JP2009148660A (ja) * | 2007-12-19 | 2009-07-09 | Miura Co Ltd | 水処理システム |
CN103316585A (zh) * | 2013-07-07 | 2013-09-25 | 合肥工业大学 | 一种纳米化矿物材料净化气体中有机污染物的方法 |
CN103803703A (zh) * | 2014-02-25 | 2014-05-21 | 合肥工业大学 | 一种纳米铁与微生物协同作用同步脱氮除磷的方法 |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111039658A (zh) * | 2019-12-31 | 2020-04-21 | 广东省水利水电科学研究院 | 一种除磷陶粒及其制备方法 |
CN113244880A (zh) * | 2021-06-16 | 2021-08-13 | 南通大学 | 一种高效除磷的烧结陶粒、其制备方法及其再生方法 |
CN115805054A (zh) * | 2021-09-14 | 2023-03-17 | 中国地质大学(北京) | 一种以针铁矿为原料的prb填充柱介质材料 |
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CN105152267B (zh) | 2017-05-31 |
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Denomination of invention: Method for deeply removing phosphorus in water by using calcined limonite Effective date of registration: 20190409 Granted publication date: 20170531 Pledgee: Huizhou bank Limited by Share Ltd. Lu'an Shunda branch Pledgor: ANHUI MEIZIRAN ENVIRONMENT TECHNOLOGY Co.,Ltd. Registration number: 2019340000189 |
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Denomination of invention: A method for deep phosphorus removal from water by calcined limonite Effective date of registration: 20211229 Granted publication date: 20170531 Pledgee: Huishang Bank Co.,Ltd. Lu'an Jinzhai sub branch Pledgor: ANHUI MEIZIRAN ENVIRONMENT TECHNOLOGY Co.,Ltd. Registration number: Y2021980016714 |
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Date of cancellation: 20230423 Granted publication date: 20170531 Pledgee: Huishang Bank Co.,Ltd. Lu'an Jinzhai sub branch Pledgor: ANHUI MEIZIRAN ENVIRONMENT TECHNOLOGY Co.,Ltd. Registration number: Y2021980016714 |