CN105097131A - Production process for flexible copper-clad aluminum wire with diameter of below 0.4 millimeter - Google Patents
Production process for flexible copper-clad aluminum wire with diameter of below 0.4 millimeter Download PDFInfo
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- CN105097131A CN105097131A CN201510406257.1A CN201510406257A CN105097131A CN 105097131 A CN105097131 A CN 105097131A CN 201510406257 A CN201510406257 A CN 201510406257A CN 105097131 A CN105097131 A CN 105097131A
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Abstract
The invention relates to a production process for a metal composite wire. A production process for a flexible copper-clad aluminum wire with a diameter of below 0.4 millimeter sequentially comprises the following steps of pre-treatment on an aluminum rod, cladding, welding, continuous drawing, intermediate drawing, tube unwinding, slight drawing, secondary tube unwinding, oxidation prevention, drying, wire gathering and package. The production process for the flexible copper-clad aluminum wire with the diameter of below 0.4 millimeter has the advantages that the copper-clad aluminum wire is high in binding force and high in consistence, the problem of return loss of a semiconductor structure can be reduced, production cost is saved, product quality is high, and elongation rate is more uniform and stable.
Description
Technical field
The present invention relates to a kind of production technology of metal compound wire, particularly a kind of production technology of copper cover aluminum.
Background technology
Copper-clad aluminum conductor is using aluminium bar as heart yearn, and concentric coated layers of copper, makes it in drawing process, realize metallurgical binding, and obtain the bimetallic composite conductor of stable performance.Copper cover aluminum possesses the satisfactory electrical conductivity of copper and the lightweight advantage of aluminium simultaneously, is the preferred material of electric wire in inner conductor and electric equipment; In addition because it has good ductility and machinability, thus deep processing bare wire and tinned wire, the enamelled wire etc. of all size can be become further; Copper-clad aluminum conductor is widely used in the fields such as communication, control system, electric equipment, automatics as braid shielded line, is the favorable substitutes of pure copper wire.Copper cover aluminum maintains the original advantage of the pure copper wire such as conductivity, magnetic conductivity, to possess simultaneously lightweight, be convenient to the advantages such as transport and construction, its density is only 37% ~ 40% of pure copper wire, its length be equal quality, equivalent diameter pure copper wire length 2.5-2.7 doubly, this will reduce production cost greatly, therefore use copper-clad aluminum conductor to carry out alternative pure copper wire, there is obvious economic benefit.
The copper cover aluminum production method having realized large-scale production at present mainly contains galvanoplastic and tube-weld cladding technique.Galvanoplastic adopt chemical electrolysis method layers of copper on aluminum core line plated surface, the method technique is simple, line speed is fast, be convenient to produce in enormous quantities, its deficiency existed is that to be only suitable for production of copper content lower, general < 8%, the copper cover aluminum that coating is thinner, and the layers of copper that there is product is in process of production coarse, concentricity is bad and the shortcoming such as environmental pollution.Tube-weld cladding technique is surface-treated aluminium bar and the cleaned copper strips such as to scrape through scraping, turning or plane for material, adopt clad welded, then after drawing and heat treatment, prepare required copper-clad aluminum conductor, its production process comprises: pretreatment-clad welded-mono-draws-anneals-mono-draw-connect draw-anneal.There is following problem in the method that above-mentioned tube-weld cladding technique prepares copper cover aluminum: one, requires high to aluminium rod surface, the defects such as pull bar surface should be cleaned, smooth rounding, size uniform; Two, production line length is long, requires high to factory building; Three, in production process, wire-drawing process is many, and product surface damage is many, and the defect such as punching dew aluminium etc. produced cannot Timeliness coverage, and production efficiency is low, and scrappage is large.In addition, the follow-up drawing in above-mentioned patent also fully openly after clad welded and heat treatment process, but follow-up drawing and heat treatment process have a great impact capability and performances such as the adhesion of copper cover aluminum, tensile strength and elongation.
Summary of the invention
The object of the invention is to solve Problems existing in existing copper alclad production technology, it is simple that a kind of production equipment is disclosed, production efficiency is high, copper layer thickness can accurately control and thickness is even, product surface fineness is good, the production technology of the soft state copper cover aluminum of below wire diameter 0.4mm of adhesion, tensile strength and good percentage elongation.
In order to realize foregoing invention object, the present invention adopts following technical scheme.
The production technology of the soft state copper cover aluminum of below wire diameter 0.4mm, comprises the following steps: successively
(1) aluminium bar preliminary treatment: be first that the aluminium bar of 15mm is drawn to wire diameter 12.5-13.8mm by wire diameter; With the sodium hydrate aqueous solution of 5%-7%, alkali cleaning is carried out to aluminium bar again, remove aluminium rod surface lubricant and oxide; Alkali cleaning temperature is between 35 DEG C-45 DEG C, and the alkali cleaning time is between 15-25 minute; Then wash, between washing temperature 15 DEG C-25 DEG C, remove the alkali lye of aluminium rod surface attachment; And moisture residual for aluminium rod surface is dried, for the coated operation in lower road provides dry aluminium bar;
(2) clad welded, polishes to pretreated aluminium bar, and simultaneously copper brush forward polishing, by copper strips bristle, is removed aluminium bar and copper strip surface greasy dirt and oxide-film, increased the roughness of aluminium bar and copper strip surface, the adhesion of raising aluminium bar and copper strips; Send in laminating case by copper strips and aluminium bar, the vertical forming wheel in laminating case and horizontal form wheel make copper strips be coated on aluminium rod surface uniformly, pass into argon gas, make two kinds of metal materials not oxidized in laminating process in laminating case by air inlet simultaneously; Enter weld zone, welding gun place, weld zone argon gas, as protection gas, continuously welds with the weld seam of pulsed tungsten argon arc welding by metal material, enters cooling zone after welding, and cooling zone passes into argon gas as protection gas, finally by coated good copper cover aluminum take-up; After being covered to complete, copper-clad aluminum conductor is through being 15mm, and the layers of copper volume ratio of copper cover aluminum is 8%-20%;
(3) connect and draw, by coated good copper cover aluminum directly companys of feeding draw equipment to carry out drawing, connect to draw and equipment installs air-cooled and water-cooled two kinds of cooling devices, control copper cover aluminum surface temperature is no more than 50 degrees Celsius; First even draws operation that copper cover aluminum wire diameter is pulled to 9.2mm, and per pass mould successively decreases by 0.40mm equal difference; Second even draws operation that copper cover aluminum wire diameter is pulled to 5.1-5.6mm, and per pass mould successively decreases by 0.30mm equal difference; Copper cover aluminum wire diameter is pulled to 3.2-4.7mm by three process, and per pass mould successively decreases by 0.20mm equal difference; Copper cover aluminum wire diameter is drawn to 1.2-2.0mm by the 4th procedure, and per pass mould successively decreases by 0.20mm equal difference; First, second procedure adopts viscosity to be 800-1000mm
2the wire drawing oil of/s is as drawing lubricant, and the 3rd, the 4th procedure adopts the emulsion of concentration>=6% as drawing lubricant, and wire-drawing lubrication liquid temp is between 20-60 DEG C;
(4) draw in, draw equipment in the copper cover aluminum of Lian Lahou being sent into, wire diameter is drawn to 0.40-0.816mm, and per pass mould joins mould by 8%-17% draft, adopts the emulsion of concentration >=6% as drawing lubricant;
(5) pipe moves back, by draw after copper cover aluminum tubular annealing, tubular annealing divides three sections of furnace temperature, and back segment furnace temperature is higher than leading portion furnace temperature, and first paragraph furnace temperature is at 380 DEG C-390 DEG C, and second segment furnace temperature is at 390 DEG C-400 DEG C, and the 3rd section of furnace temperature is at 400 DEG C-415 DEG C;
(6) littlely to draw, by through in draw after copper cover aluminum send into and littlely draw equipment, be drawn to wire diameter 0.12-0.39mm through the little equipment that draws, per pass mould joins mould by 8%-17%mm draft;
(7) secondary pipe moves back, and the copper cover aluminum after little drawing is carried out tubular annealing, and tubular annealing divides three sections of furnace temperature, and back segment furnace temperature is higher than leading portion furnace temperature;
(8) anti-oxidation and dry, the copper cover aluminum of being stepped back by pipe carries out anti-oxidation process, avoids finished product to produce oxidation because being exposed to for a long time in air;
(9) take-up packaging.
As preferably, first, second procedure adopts 820 wire drawings oil or KJ-6100 metal wire-drawing oil as drawing lubricant, and 820 wire drawings oil viscosityes are higher, and Applicable temperature, at 30-60 DEG C, uses when applicable summer produces; KJ-6100 metal wire-drawing oil viscosity is higher, and Applicable temperature, at 20-50 DEG C, uses when applicable winter produces.
Adopt the production technology of the soft state copper cover aluminum of below wire diameter 0.4mm of technique scheme, its beneficial effect is as follows: 1, during copper strips bristle, copper brush answers forward to polish, because oppositely during polishing, frictional force is large, surface temperature is high, there will be copper strip surface oxidization condition, affect the adhesion at layers of copper and aluminium interface; In addition, when oppositely polishing, copper strip surface is strip texture, and during forward polishing, copper strip surface is uniform point-like texture, point-like texture is conducive to improving the contact area between layers of copper and aluminium, in follow-up drawing process, be conducive to the phase counterdiffusion between bimetallic, improve its adhesion; 2, the present invention is through process optimization, and copper strips and aluminium bar, after clad welded, directly enter several and even draw operation, singly be pulled through journey and generally adopt formula take-up, easily squeeze wound at the effect lower surface of upper tractive effort, and connect take-up when being pulled through Cheng Caiyong whereabouts, effectively can avoid squeezing and hinder problem; Operation is drawn simultaneously through several mould by the company of this large span in addition, and when total draught is larger, drawing process also once completes, and copper cover aluminum consistency is good, therefore can reduce the appearance of conductor structure return loss SR problem; Moreover the company's of employing drawing process, can reduce and singly draw operation many, the problem that frequency of changing planes is high, enhance productivity, save production cost, be conducive to reducing copper cover aluminum surface in process of changing planes simultaneously and the situation such as to damage, thus ensure product quality; 3, wire rod after drawing adopts tubular annealing, and tubular annealing can meet the synchronous unwrapping wire of a large amount of Coating Aluminum Weir Materials with Copper Layer, annealing and take-up, and under copper cover aluminum moment in the process run is in identical annealing conditions, therefore the elongation of copper cover aluminum is more uniform and stable; 4, the copper cover aluminum product surface light through anti-oxidation and dry process stepped back by pipe, places the generation that the several months also there will not be oxidizing blackening situation.
Embodiment
The production technology of the soft state copper cover aluminum of below wire diameter 0.4mm, comprises the following steps: successively
(1) aluminium bar preliminary treatment: be first that the aluminium bar of 15mm is drawn to wire diameter 12.5-13.8mm by wire diameter; With the sodium hydrate aqueous solution of 5%-7%, alkali cleaning is carried out to aluminium bar again, remove aluminium rod surface lubricant and oxide; Alkali cleaning temperature is between 35 DEG C-45 DEG C, and the alkali cleaning time is between 15-25 minute; Then wash, between washing temperature 15 DEG C-25 DEG C, remove the alkali lye of aluminium rod surface attachment; And moisture residual for aluminium rod surface is dried, for the coated operation in lower road provides dry aluminium bar;
(2) clad welded, polishes to pretreated aluminium bar, and simultaneously copper brush forward polishing, by copper strips bristle, is removed aluminium bar and copper strip surface greasy dirt and oxide-film, increased the roughness of aluminium bar and copper strip surface, the adhesion of raising aluminium bar and copper strips; Aluminium bar bristle technique is compared with aluminium bar peeling technique, and bristle technique can increase the roughness of aluminium rod surface, improves the adhesion of aluminium bar and copper strips, can reduce the leakage aluminium situation of product, ensures product quality.Copper brush forward is polished, because frictional force is large when oppositely polishing, surface temperature is high, there will be copper strip surface oxidization condition, affects the adhesion at layers of copper and aluminium interface; In addition, when oppositely polishing, copper strip surface is strip texture, and during forward polishing, copper strip surface is uniform point-like texture, point-like texture is conducive to improving the contact area between layers of copper and aluminium, in follow-up drawing process, be conducive to the phase counterdiffusion between bimetallic, improve its adhesion; Send in laminating case by copper strips and aluminium bar, the vertical forming wheel in laminating case and horizontal form wheel make copper strips be coated on aluminium rod surface uniformly, pass into argon gas, make two kinds of metal materials not oxidized in laminating process in laminating case by air inlet simultaneously; Enter weld zone, welding gun place, weld zone argon gas is as protection gas, continuously weld with the weld seam of pulsed tungsten argon arc welding by metal material, cooling zone is entered after welding, cooling zone passes into argon gas as protection gas, prevent the metal surface of welding rear high temperature oxidized, finally by coated good copper cover aluminum take-up; After being covered to complete, copper-clad aluminum conductor is through being 15mm, and the layers of copper volume ratio of copper cover aluminum is 8%-20%;
(3) connect and draw, by coated good copper cover aluminum directly companys of feeding draw equipment to carry out drawing, connect to draw and equipment installs air-cooled and water-cooled two kinds of cooling devices, control copper cover aluminum surface temperature is no more than 50 degrees Celsius; Two kinds of cooling devices improve the cooling effect connecting and draw equipment, prevent equipment drawing reel and Coating Aluminum Weir Materials with Copper Layer temperature too high, air-cooled is from the lateral surface of reel to reel and the blowing of copper cover aluminum surface, water-cooled is by installing water pipe in reel inside, adopt circulating water, prevent copper cover aluminum surface from producing oxidation; Can prevent in addition because wire temperature is high, affect wire drawing oil lubrication effect, damage wire-drawing die, causes copper cover aluminum galled spots; First even draws operation that copper cover aluminum wire diameter is pulled to 9.2mm, and per pass mould successively decreases by 0.40mm equal difference; Second even draws operation that copper cover aluminum wire diameter is pulled to 5.1-5.6mm, and per pass mould successively decreases by 0.30mm equal difference, can ensure the conjugation of copper cover aluminum; Copper cover aluminum wire diameter is pulled to 3.2-4.7mm by three process, and per pass mould successively decreases by 0.20mm equal difference; Copper cover aluminum wire diameter is drawn to 1.2-2.0mm by the 4th procedure, and per pass mould successively decreases by 0.20mm equal difference; First, second procedure employing viscosity is that the wire drawing of 800-1000mm2/s is oily as drawing lubricant, and the 3rd, the 4th procedure adopts the emulsion of concentration >=6% as drawing lubricant, and wire-drawing lubrication liquid temp is between 20-60 DEG C; First, second procedure adopts 820 wire drawing oil or KJ-6100 metal wire-drawing oil as drawing lubricant, and 820 wire drawing oil viscosityes are higher, and Applicable temperature, at 30-60 DEG C, uses when applicable summer produces; KJ-6100 metal wire-drawing oil viscosity is higher, and Applicable temperature, at 20-50 DEG C, uses when applicable winter produces; Adopt emulsion as drawing lubricant, copper cover aluminum surface and oil contaminant is few, is easy to the cleaning of rear road, prevents the unclean product of copper cover aluminum surface clean from flowing into customers' place, causes adhesion in client's electric cable foaming process bad.Singly be pulled through journey and generally adopt formula take-up, easily squeeze wound at the effect lower surface of upper tractive effort, and connect take-up when being pulled through Cheng Caiyong whereabouts, effectively can avoid squeezing and hinder problem; Operation is drawn simultaneously through several mould by the company of this large span in addition, and when total draught is larger, drawing process also once completes, and copper cover aluminum consistency is good, therefore can reduce the appearance of conductor structure return loss SRL problem; Moreover the company's of employing drawing process, can reduce and singly draw operation many, the problem that frequency of changing planes is high, enhance productivity, save production cost, be conducive to reducing copper cover aluminum surface in process of changing planes simultaneously and the situation such as to damage, thus ensure product quality;
(4) draw in, draw equipment in the copper cover aluminum of Lian Lahou being sent into, wire diameter is drawn to 0.40-0.816mm, and per pass mould joins mould by 8%-17% draft, adopts the emulsion of concentration >=6% as drawing lubricant; Draft represents that copper cover aluminum is after drawing, hundred river ratios of the sectional area before absolute value and drawing that sectional area reduces;
(5) pipe moves back, by draw after copper cover aluminum tubular annealing, tubular annealing divides three sections of furnace temperature, and back segment furnace temperature is higher than leading portion furnace temperature, and first paragraph furnace temperature is at 380 DEG C-390 DEG C, and second segment furnace temperature is at 390 DEG C-400 DEG C, and the 3rd section of furnace temperature is at 400 DEG C-415 DEG C;
(6) littlely to draw, by through in draw after copper cover aluminum send into and littlely draw equipment, be drawn to wire diameter 0.12-0.39mm through the little equipment that draws, per pass mould joins mould by 8%-17%mm draft;
(7) pipe moves back, and the copper cover aluminum after little drawing is carried out tubular annealing, and tubular annealing divides three sections of furnace temperature, and back segment furnace temperature is higher than leading portion furnace temperature;
(8) anti-oxidation and dry, the copper cover aluminum of being stepped back by pipe carries out anti-oxidation process, avoids finished product to produce oxidation because being exposed to for a long time in air;
(9) take-up packaging.
The copper cover aluminum of different wire diameter, pipe moves back temperature and payingoff speed is different, and wire diameter is thicker, and payingoff speed requires slower, table specific as follows,
Claims (2)
1. the production technology of the soft state copper cover aluminum of below wire diameter 0.4mm, is characterized in that comprising the following steps: successively
(1) aluminium bar preliminary treatment: be first that the aluminium bar of 15mm is drawn to wire diameter 12.5-13.8mm by wire diameter; With the sodium hydrate aqueous solution of 5%-7%, alkali cleaning is carried out to aluminium bar again, remove aluminium rod surface lubricant and oxide; Alkali cleaning temperature is between 35 DEG C-45 DEG C, and the alkali cleaning time is between 15-25 minute; Then wash, between washing temperature 15 DEG C-25 DEG C, remove the alkali lye of aluminium rod surface attachment; And moisture residual for aluminium rod surface is dried;
(2) clad welded, polishes to pretreated aluminium bar, and simultaneously copper brush forward polishing, by copper strips bristle, is removed aluminium bar and copper strip surface greasy dirt and oxide-film, increased the roughness of aluminium bar and copper strip surface, the adhesion of raising aluminium bar and copper strips; Send in laminating case by copper strips and aluminium bar, the vertical forming wheel in laminating case and horizontal form wheel make copper strips be coated on aluminium rod surface uniformly, pass into argon gas, make two kinds of metal materials not oxidized in laminating process in laminating case by air inlet simultaneously; Enter weld zone, welding gun place, weld zone argon gas, as protection gas, continuously welds with the weld seam of pulsed tungsten argon arc welding by metal material, enters cooling zone after welding, and cooling zone passes into argon gas as protection gas, finally by coated good copper cover aluminum take-up; After being covered to complete, copper-clad aluminum conductor is through being 15mm, and the layers of copper volume ratio of copper cover aluminum is 8%-20%;
(3) connect and draw, by coated good copper cover aluminum directly companys of feeding draw equipment to carry out drawing, connect to draw and equipment installs air-cooled and water-cooled two kinds of cooling devices, control copper cover aluminum surface temperature is no more than 50 degrees Celsius; First even draws operation that copper cover aluminum wire diameter is pulled to 9.2mm, and per pass mould successively decreases by 0.40mm equal difference; Second even draws operation that copper cover aluminum wire diameter is pulled to 5.1-5.6mm, and per pass mould successively decreases by 0.30mm equal difference; Copper cover aluminum wire diameter is pulled to 3.2-4.7mm by three process, and per pass mould successively decreases by 0.20mm equal difference; Copper cover aluminum wire diameter is drawn to 1.2-2.0mm by the 4th procedure, and per pass mould successively decreases by 0.20mm equal difference; First, second procedure adopts viscosity to be 800-1000mm
2the wire drawing oil of/s is as drawing lubricant, and the 3rd, the 4th procedure adopts the emulsion of concentration>=6% as drawing lubricant, and wire-drawing lubrication liquid temp is between 20-60 DEG C;
(4) draw in, draw equipment in the copper cover aluminum of Lian Lahou being sent into, wire diameter is drawn to 0.40-0.816mm, and per pass mould joins mould by 8%-17% draft, adopts the emulsion of concentration >=6% as drawing lubricant;
(5) pipe moves back, by draw after copper cover aluminum tubular annealing, tubular annealing divides three sections of furnace temperature, and back segment furnace temperature is higher than leading portion furnace temperature, and first paragraph furnace temperature is at 380 DEG C-390 DEG C, and second segment furnace temperature is at 390 DEG C-400 DEG C, and the 3rd section of furnace temperature is at 400 DEG C-415 DEG C;
(6) littlely to draw, by through in draw after copper cover aluminum send into and littlely draw equipment, be drawn to wire diameter 0.12-0.39mm through the little equipment that draws, per pass mould joins mould by 8%-17%mm draft;
(7) pipe moves back, and the copper cover aluminum after little drawing is carried out tubular annealing, and tubular annealing divides three sections of furnace temperature, and back segment furnace temperature is higher than leading portion furnace temperature;
(8) anti-oxidation and dry, the copper cover aluminum of being stepped back by pipe carries out anti-oxidation process;
(9) take-up packaging.
2. the production technology of the soft state copper cover aluminum of below wire diameter 0.4mm according to claim 1, is characterized in that first, second procedure adopts 820 wire drawing oil or KJ-6100 metal wire-drawing oil as drawing lubricant.
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| CN201510406257.1A CN105097131A (en) | 2015-07-10 | 2015-07-10 | Production process for flexible copper-clad aluminum wire with diameter of below 0.4 millimeter |
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| CN201510406257.1A CN105097131A (en) | 2015-07-10 | 2015-07-10 | Production process for flexible copper-clad aluminum wire with diameter of below 0.4 millimeter |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110349692A (en) * | 2019-07-19 | 2019-10-18 | 深圳市爱因派科技有限公司 | A kind of motor windings precision traverse preparation process of service robot |
| CN112658050A (en) * | 2020-12-24 | 2021-04-16 | 无锡市红年金属制品科技有限公司 | Processing technology of copper-clad aluminum wire |
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| CN1283856A (en) * | 2000-09-08 | 2001-02-14 | 曲均绪 | Technology for making electrically conductive bimetal steel-in-copper wire |
| CN1851833A (en) * | 2006-05-23 | 2006-10-25 | 金亚东 | Aluminium in copper alloy line, and its preparing method and production apparatus |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110349692A (en) * | 2019-07-19 | 2019-10-18 | 深圳市爱因派科技有限公司 | A kind of motor windings precision traverse preparation process of service robot |
| CN110349692B (en) * | 2019-07-19 | 2020-11-06 | 深圳市爱因派科技有限公司 | Preparation process of motor winding precision wire of service robot |
| CN112658050A (en) * | 2020-12-24 | 2021-04-16 | 无锡市红年金属制品科技有限公司 | Processing technology of copper-clad aluminum wire |
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