CN105062313A - Waterborne epoxy resin coating for ships - Google Patents
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- CN105062313A CN105062313A CN201510475951.9A CN201510475951A CN105062313A CN 105062313 A CN105062313 A CN 105062313A CN 201510475951 A CN201510475951 A CN 201510475951A CN 105062313 A CN105062313 A CN 105062313A
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Abstract
The invention discloses a waterborne epoxy resin coating for ships. The waterborne epoxy resin coating comprises a component A and a component B, wherein the weight ratio of the component A to the component B is (95-110) to (0.5-1.8). The component A comprises the raw materials in parts by weight: 20-30 parts of epoxy resin E-44, 15-25 parts of siloxane modified epoxy resin, 5-15 parts of novolac epoxy resin, 1-5 parts of allyl glycidyl ether, 5-10 parts of aluminum silicate, 3-8 parts of polypyrrole hollow balls, 3-6 parts of a quartz powder, 2-6 parts of titanium dioxide microspheres, 2-6 parts of kaolin, 2-5 parts of lithium-based bentonite, 0.5-1.5 parts of zinc oxide, 2-5 parts of barium metaborate, 1-2 parts of micaceous iron oxide, 5-15 parts of poly(vinyl alcohol), 1-2 parts of polytetrafluoroethylene, 1-2 parts of emulsified silicone oil, 1-2 parts of a wetting agent, 1-2 parts of castor oil, and 15-30 parts of deionized water. The component B comprises the raw materials in parts by weight: 20-40 parts of cyclohexane tricarboxylic acid anhydride, 5-15 parts of m-xylylenediamine, 2-8 parts of propylene glycol methyl ether acetate, 2-8 parts of texanol ester alcohol, and 15-25 parts of deionized water.
Description
Technical field
The present invention relates to marine finish technical field, particularly relate to a kind of marine water epoxypaint.
Background technology
Along with the development of shipping industry, hull bottom, inner cabin of ship due to long-term submergence in the seawater, the original preservative coat of structure is wrecked, produces corrosion, and these structures are difficult to move to land and keep in repair.In order to extend the work-ing life of these boats and ships, ensure safety in production, need at employing marine surface coating anticorrosive coating, to prevent the corrosion of all kinds of water surrounding, the mechanical property of current marine finish, corrosion resistance nature and sticking power also do not reach demand.
Summary of the invention
The present invention proposes a kind of marine water epoxypaint, mechanical property is good, and erosion resistance and sticking power are very excellent.
A kind of marine water epoxypaint that the present invention proposes, comprise component A and B component, the weight ratio of component A and B component is 95-110:0.5-1.8;
The raw material of component A comprises by weight: epoxy resin E-44 20-30 part, silicone-modified epoxy resin 15-25 part, novolac epoxy 5-15 part, glycidyl allyl ether 1-5 part, pure aluminium silicate 5-10 part, polypyrrole hollow ball 3-8 part, silica powder 3-6 part, titanium dioxide microballoon sphere 2-6 part, kaolin 2-6 part, lithium bentonite 2-5 part, zinc oxide 0.5-1.5 part, barium metaborate 2-5 part, iron mica 1-2 part, polyvinyl alcohol 5-15 part, tetrafluoroethylene 1-2 part, silicone emulsion 1-2 part, wetting agent 1-2 part, Viscotrol C 1-2 part, deionized water 15-30 part,
The raw material of B component comprises by weight: cyclohexanetricarboxylic acid's acid anhydride 20-40 part, m-xylene diamine 5-15 part, 1-Methoxy-2-propyl acetate 2-8 part, alcohol ester 12 2-8 part, deionized water 15-25 part.
Preferably, pure aluminium silicate is superfine alumina silicate, and its pH value is 10-10.5.
Preferably, in silicone-modified epoxy resin, by weight by 100 parts of bisphenol-S diglycidyl ethers, 2-5 part polysiloxane is sent in 80-140 part xylene solution and is stirred, whipping temp is 50-58 DEG C, churning time is 45-60min, add 20-40 part polytetrahydrofuran polyol to continue to stir 20-35min, whipping temp is 70-78 DEG C, add 1-2 part propenyl triethoxyl silane, 1-2 part aminopropyl triethoxysilane continues to stir 5-15min, whipping temp is 85-90 DEG C, filter, send in vacuum drying oven and carry out drying, drying temperature is 100-115 DEG C, time of drying is 2-8h, pulverize, obtain silicone-modified epoxy resin.
Preferably, in bisphenol-S diglycidyl ether, epoxy equivalent (weight) is 280-300g/mol, and softening temperature is 93-96 DEG C.
Preferably, in component A, the weight ratio of epoxy resin E-44, silicone-modified epoxy resin and novolac epoxy is 24-26:20-23:8-12.
Preferably, in component A, the weight ratio of pure aluminium silicate, polypyrrole hollow ball, silica powder, titanium dioxide microballoon sphere, kaolin and lithium bentonite is 6-8:4-6:4-5:3-4:4-5:3-4.
Preferably, in component A, the weight ratio of polyvinyl alcohol, tetrafluoroethylene, silicone emulsion, wetting agent and Viscotrol C is 10-12:1.6-1.8:1.2-1.4:1.4-1.8:1.1-1.3.
Preferably, the raw material of component A comprises by weight: epoxy resin E-44 24-26 part, silicone-modified epoxy resin 20-23 part, novolac epoxy 8-12 part, glycidyl allyl ether 2-3 part, pure aluminium silicate 6-8 part, polypyrrole hollow ball 4-6 part, silica powder 4-5 part, titanium dioxide microballoon sphere 3-4 part, kaolin 4-5 part, lithium bentonite 3-4 part, zinc oxide 1-1.2 part, barium metaborate 3-4.5 part, iron mica 1.4-1.6 part, polyvinyl alcohol 10-12 part, tetrafluoroethylene 1.6-1.8 part, silicone emulsion 1.2-1.4 part, wetting agent 1.4-1.8 part, Viscotrol C 1.1-1.3 part, deionized water 20-24 part.
Preferably, the raw material of B component comprises by weight: cyclohexanetricarboxylic acid's acid anhydride 30-36 part, m-xylene diamine 10-12 part, 1-Methoxy-2-propyl acetate 4-6 part, alcohol ester 12 4-6 part, deionized water 20-24 part.
In the present invention, the preparation process of component A is: by epoxy resin E-44, silicone-modified epoxy resin, novolac epoxy, glycidyl allyl ether, pure aluminium silicate, polypyrrole hollow ball, iron mica, zinc oxide, barium metaborate, polyvinyl alcohol, tetrafluoroethylene, silicone emulsion, wetting agent, Viscotrol C, deionized water mixes in rear feeding three-roller and grinds, extremely wherein solids particle diameter is 10-30 μm, add silica powder again, titanium dioxide microballoon sphere, kaolin, lithium bentonite stirs, add polypyrrole hollow ball to stir, filter, obtain component A,
The preparation process of B component is: cyclohexanetricarboxylic acid's acid anhydride, m-xylene diamine, 1-Methoxy-2-propyl acetate, alcohol ester 12, deionized water are mixed, obtain B component.
In the present invention, adopt epoxy resin E-44, silicone-modified epoxy resin and novolac epoxy are as major ingredient, and adopt cyclohexanetricarboxylic acid's acid anhydride, benzene dimethylamine synergy solidifying agent, the sticking power of goods and coated substrate is fabulous, excellent in mechanical performance, and corrosion resistance nature is better, add polypyrrole hollow ball, silica powder, titanium dioxide microballoon sphere, kaolin and lithium bentonite are as filler, Mechanical Properties of Products is good, to coated substrate strong adhesion, and levelling property is better, wherein the cavity of polypyrrole hollow ball inner sealing has deformability, with epoxy resin E-44, silicone-modified epoxy resin and novolac epoxy synergy can obviously strengthen goods impact strength and toughness, mechanical property is better, and can not move in reproduced goods, mechanical property is lasting, act synergistically with titanium dioxide microballoon sphere, also coating and flow leveling can significantly be improved, lithium bentonite is laminate structure, with polypyrrole hollow ball, silica powder, titanium dioxide microballoon sphere, kaolin acting in conjunction, lithium bentonite can make storeroom viscosity increase, and at epoxy resin E-44, the particle surface formation solvation film of silicone-modified epoxy resin and novolac epoxy and dimensional network structure are to support and to stop polypyrrole hollow ball, silica powder, titanium dioxide microballoon sphere, kaolin sinks, not only can strengthen the bonding force of goods and coated substrate, and it is also very excellent at wet substrate surface sticking power, in silicone-modified epoxy resin, containing-SO in bisphenol-S diglycidyl ether
2-, its polarity is extremely strong, interacts with polysiloxane, and adopts consistency and the bonding force of both polytetrahydrofuran polyol, propenyl triethoxyl silane, aminopropyl triethoxysilane promotions, goods not only mechanical property are fabulous, and sticking power and antiseptic property strengthen further.
Rotproofness of the present invention, sticking power and mechanical property are fabulous, and levelling property is excellent, and smooth coating is smooth, has good protection effect to applied material surface.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
A kind of marine water epoxypaint, comprise component A and B component, the weight ratio of component A and B component is 108:0.5;
The raw material of component A comprises by weight: epoxy resin E-44 30 parts, silicone-modified epoxy resin 16 parts, novolac epoxy 15 parts, glycidyl allyl ether 1 part, pure aluminium silicate 10 parts, polypyrrole hollow ball 3.4 parts, silica powder 6 parts, titanium dioxide microballoon sphere 2 parts, kaolin 6 parts, lithium bentonite 2.1 parts, 1.5 parts, zinc oxide, barium metaborate 2 parts, iron mica 2 parts, polyvinyl alcohol 5 parts, tetrafluoroethylene 1.8 parts, silicone emulsion 1 part, wetting agent 2 parts, Viscotrol C 1 part, deionized water 30 parts;
The raw material of B component comprises by weight: cyclohexanetricarboxylic acid's acid anhydride 20 parts, m-xylene diamine 14 parts, 1-Methoxy-2-propyl acetate 2 parts, alcohol ester 12 parts, deionized water 15 parts.
Embodiment 2
A kind of marine water epoxypaint, comprise component A and B component, the weight ratio of component A and B component is 96:1.8;
The raw material of component A comprises by weight: epoxy resin E-44 21 parts, silicone-modified epoxy resin 25 parts, novolac epoxy 5 parts, glycidyl allyl ether 5 parts, pure aluminium silicate 5.2 parts, polypyrrole hollow ball 8 parts, silica powder 3 parts, titanium dioxide microballoon sphere 6 parts, kaolin 2.3 parts, lithium bentonite 5 parts, 0.5 part, zinc oxide, barium metaborate 5 parts, iron mica 1.2 parts, polyvinyl alcohol 15 parts, tetrafluoroethylene 1 part, silicone emulsion 2 parts, wetting agent 1.2 parts, Viscotrol C 2 parts, deionized water 15 parts;
The raw material of B component comprises by weight: cyclohexanetricarboxylic acid's acid anhydride 40 parts, m-xylene diamine 6 parts, 1-Methoxy-2-propyl acetate 8 parts, alcohol ester 12 parts, deionized water 25 parts.
Embodiment 3
A kind of marine water epoxypaint, comprise component A and B component, the weight ratio of component A and B component is 100:1;
The raw material of component A comprises by weight: epoxy resin E-44 25.8 parts, silicone-modified epoxy resin 20 parts, novolac epoxy 12 parts, glycidyl allyl ether 2 parts, pure aluminium silicate 7.9 parts, polypyrrole hollow ball 4 parts, silica powder 5 parts, titanium dioxide microballoon sphere 3 parts, kaolin 4.95 parts, lithium bentonite 3 parts, 1.2 parts, zinc oxide, barium metaborate 3 parts, iron mica 1.58 parts, polyvinyl alcohol 10 parts, tetrafluoroethylene 1.8 parts, silicone emulsion 1.2 parts, wetting agent 1.7 parts, Viscotrol C 1.1 parts, deionized water 24 parts;
The raw material of B component comprises by weight: cyclohexanetricarboxylic acid's acid anhydride 30 parts, m-xylene diamine 11.9 parts, 1-Methoxy-2-propyl acetate 4 parts, alcohol ester 12 parts, deionized water 20 parts.
Pure aluminium silicate is superfine alumina silicate, and its pH value is 10.4.
In silicone-modified epoxy resin, by weight by 100 parts of bisphenol-S diglycidyl ethers, 2 parts of polysiloxane are sent in 140 parts of xylene solutions and are stirred, whipping temp is 50 DEG C, churning time is 59min, add 20 parts of polytetrahydrofuran polyol to continue to stir 35min, whipping temp is 70 DEG C, add 1.9 parts of propenyl triethoxyl silanes, 1 part of aminopropyl triethoxysilane continues to stir 15min, whipping temp is 85 DEG C, filter, send in vacuum drying oven and carry out drying, drying temperature is 114 DEG C, time of drying is 2h, pulverize, obtain silicone-modified epoxy resin.
In bisphenol-S diglycidyl ether, epoxy equivalent (weight) is 300g/mol, and softening temperature is 93 DEG C.
The preparation process of component A is: by epoxy resin E-44, silicone-modified epoxy resin, novolac epoxy, glycidyl allyl ether, pure aluminium silicate, polypyrrole hollow ball, iron mica, zinc oxide, barium metaborate, polyvinyl alcohol, tetrafluoroethylene, silicone emulsion, wetting agent, Viscotrol C, deionized water mixes in rear feeding three-roller and grinds, extremely wherein solids particle diameter is 10-30 μm, add silica powder again, titanium dioxide microballoon sphere, kaolin, lithium bentonite stirs, add polypyrrole hollow ball to stir, filter, obtain component A,
The preparation process of B component is: cyclohexanetricarboxylic acid's acid anhydride, m-xylene diamine, 1-Methoxy-2-propyl acetate, alcohol ester 12, deionized water are mixed, obtain B component.
Embodiment 4
A kind of marine water epoxypaint, comprise component A and B component, the weight ratio of component A and B component is 100:2;
The raw material of component A comprises by weight: epoxy resin E-44 24.5 parts, silicone-modified epoxy resin 23 parts, novolac epoxy 8 parts, glycidyl allyl ether 3 parts, pure aluminium silicate 6.2 parts, polypyrrole hollow ball 6 parts, silica powder 4 parts, titanium dioxide microballoon sphere 4 parts, kaolin 4.1 parts, lithium bentonite 4 parts, 1 part, zinc oxide, barium metaborate 4.5 parts, iron mica 1.42 parts, polyvinyl alcohol 12 parts, tetrafluoroethylene 1.6 parts, silicone emulsion 1.4 parts, wetting agent 1.42 parts, Viscotrol C 1.3 parts, deionized water 20 parts;
The raw material of B component comprises by weight: cyclohexanetricarboxylic acid's acid anhydride 36 parts, m-xylene diamine 10.2 parts, 1-Methoxy-2-propyl acetate 6 parts, alcohol ester 12 parts, deionized water 24 parts.
Pure aluminium silicate is superfine alumina silicate, and its pH value is 10.1.
In silicone-modified epoxy resin, by weight by 100 parts of bisphenol-S diglycidyl ethers, 5 parts of polysiloxane are sent in 80 parts of xylene solutions and are stirred, whipping temp is 58 DEG C, churning time is 46min, add 40 parts of polytetrahydrofuran polyol to continue to stir 20min, whipping temp is 78 DEG C, add 1.2 parts of propenyl triethoxyl silanes, 2 parts of aminopropyl triethoxysilanes continue to stir 5min, whipping temp is 90 DEG C, filter, send in vacuum drying oven and carry out drying, drying temperature is 102 DEG C, time of drying is 8h, pulverize, obtain silicone-modified epoxy resin.
In bisphenol-S diglycidyl ether, epoxy equivalent (weight) is 280g/mol, and softening temperature is 96 DEG C.
The preparation process of component A is: by epoxy resin E-44, silicone-modified epoxy resin, novolac epoxy, glycidyl allyl ether, pure aluminium silicate, polypyrrole hollow ball, iron mica, zinc oxide, barium metaborate, polyvinyl alcohol, tetrafluoroethylene, silicone emulsion, wetting agent, Viscotrol C, deionized water mixes in rear feeding three-roller and grinds, extremely wherein solids particle diameter is 10-30 μm, add silica powder again, titanium dioxide microballoon sphere, kaolin, lithium bentonite stirs, add polypyrrole hollow ball to stir, filter, obtain component A,
The preparation process of B component is: cyclohexanetricarboxylic acid's acid anhydride, m-xylene diamine, 1-Methoxy-2-propyl acetate, alcohol ester 12, deionized water are mixed, obtain B component.
Embodiment 5
A kind of marine water epoxypaint, comprise component A and B component, the weight ratio of component A and B component is 100:1.2;
The raw material of component A comprises by weight: epoxy resin E-44 25.4 parts, silicone-modified epoxy resin 22.6 parts, novolac epoxy 11 parts, glycidyl allyl ether 2.6 parts, pure aluminium silicate 7.6 parts, polypyrrole hollow ball 5.2 parts, silica powder 4.5 parts, titanium dioxide microballoon sphere 3.6 parts, kaolin 4.6 parts, lithium bentonite 3.2 parts, 1.15 parts, zinc oxide, barium metaborate 4.2 parts, iron mica 1.55 parts, polyvinyl alcohol 11 parts, tetrafluoroethylene 1.72 parts, silicone emulsion 1.3 parts, wetting agent 1.6 parts, Viscotrol C 1.18 parts, deionized water 22 parts;
The raw material of B component comprises by weight: cyclohexanetricarboxylic acid's acid anhydride 34 parts, m-xylene diamine 11.5 parts, 1-Methoxy-2-propyl acetate 5.5 parts, alcohol ester 12 parts, deionized water 22 parts.
Pure aluminium silicate is superfine alumina silicate, and its pH value is 10.3.
In silicone-modified epoxy resin, by weight by 100 parts of bisphenol-S diglycidyl ethers, 2.5 parts of polysiloxane are sent in 120 parts of xylene solutions and are stirred, whipping temp is 54 DEG C, churning time is 55min, add 46 parts of polytetrahydrofuran polyol to continue to stir 32min, whipping temp is 74 DEG C, add 1.5 parts of propenyl triethoxyl silanes, 1.36 parts of aminopropyl triethoxysilanes continue to stir 12min, whipping temp is 88 DEG C, filter, send in vacuum drying oven and carry out drying, drying temperature is 112 DEG C, time of drying is 6h, pulverize, obtain silicone-modified epoxy resin.
In bisphenol-S diglycidyl ether, epoxy equivalent (weight) is 295g/mol, and softening temperature is 95 DEG C.
The preparation process of component A is: by epoxy resin E-44, silicone-modified epoxy resin, novolac epoxy, glycidyl allyl ether, pure aluminium silicate, polypyrrole hollow ball, iron mica, zinc oxide, barium metaborate, polyvinyl alcohol, tetrafluoroethylene, silicone emulsion, wetting agent, Viscotrol C, deionized water mixes in rear feeding three-roller and grinds, extremely wherein solids particle diameter is 10-30 μm, add silica powder again, titanium dioxide microballoon sphere, kaolin, lithium bentonite stirs, add polypyrrole hollow ball to stir, filter, obtain component A,
The preparation process of B component is: cyclohexanetricarboxylic acid's acid anhydride, m-xylene diamine, 1-Methoxy-2-propyl acetate, alcohol ester 12, deionized water are mixed, obtain B component.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (9)
1. a marine water epoxypaint, is characterized in that, comprises component A and B component, and the weight ratio of component A and B component is 95-110:0.5-1.8;
The raw material of component A comprises by weight: epoxy resin E-44 20-30 part, silicone-modified epoxy resin 15-25 part, novolac epoxy 5-15 part, glycidyl allyl ether 1-5 part, pure aluminium silicate 5-10 part, polypyrrole hollow ball 3-8 part, silica powder 3-6 part, titanium dioxide microballoon sphere 2-6 part, kaolin 2-6 part, lithium bentonite 2-5 part, zinc oxide 0.5-1.5 part, barium metaborate 2-5 part, iron mica 1-2 part, polyvinyl alcohol 5-15 part, tetrafluoroethylene 1-2 part, silicone emulsion 1-2 part, wetting agent 1-2 part, Viscotrol C 1-2 part, deionized water 15-30 part,
The raw material of B component comprises by weight: cyclohexanetricarboxylic acid's acid anhydride 20-40 part, m-xylene diamine 5-15 part, 1-Methoxy-2-propyl acetate 2-8 part, alcohol ester 12 2-8 part, deionized water 15-25 part.
2. marine water epoxypaint according to claim 1, is characterized in that, pure aluminium silicate is superfine alumina silicate, and its pH value is 10-10.5.
3. marine water epoxypaint according to claim 1 and 2, it is characterized in that, in silicone-modified epoxy resin, by weight by 100 parts of bisphenol-S diglycidyl ethers, 2-5 part polysiloxane is sent in 80-140 part xylene solution and is stirred, whipping temp is 50-58 DEG C, churning time is 45-60min, add 20-40 part polytetrahydrofuran polyol to continue to stir 20-35min, whipping temp is 70-78 DEG C, add 1-2 part propenyl triethoxyl silane, 1-2 part aminopropyl triethoxysilane continues to stir 5-15min, whipping temp is 85-90 DEG C, filter, send in vacuum drying oven and carry out drying, drying temperature is 100-115 DEG C, time of drying is 2-8h, pulverize, obtain silicone-modified epoxy resin.
4. marine water epoxypaint according to claim 3, is characterized in that, in bisphenol-S diglycidyl ether, epoxy equivalent (weight) is 280-300g/mol, and softening temperature is 93-96 DEG C.
5. the marine water epoxypaint according to any one of claim 1-4, is characterized in that, in component A, the weight ratio of epoxy resin E-44, silicone-modified epoxy resin and novolac epoxy is 24-26:20-23:8-12.
6. the marine water epoxypaint according to any one of claim 1-5, it is characterized in that, in component A, the weight ratio of pure aluminium silicate, polypyrrole hollow ball, silica powder, titanium dioxide microballoon sphere, kaolin and lithium bentonite is 6-8:4-6:4-5:3-4:4-5:3-4.
7. the marine water epoxypaint according to any one of claim 1-6, it is characterized in that, in component A, the weight ratio of polyvinyl alcohol, tetrafluoroethylene, silicone emulsion, wetting agent and Viscotrol C is 10-12:1.6-1.8:1.2-1.4:1.4-1.8:1.1-1.3.
8. the marine water epoxypaint according to any one of claim 1-7, it is characterized in that, the raw material of component A comprises by weight: epoxy resin E-44 24-26 part, silicone-modified epoxy resin 20-23 part, novolac epoxy 8-12 part, glycidyl allyl ether 2-3 part, pure aluminium silicate 6-8 part, polypyrrole hollow ball 4-6 part, silica powder 4-5 part, titanium dioxide microballoon sphere 3-4 part, kaolin 4-5 part, lithium bentonite 3-4 part, zinc oxide 1-1.2 part, barium metaborate 3-4.5 part, iron mica 1.4-1.6 part, polyvinyl alcohol 10-12 part, tetrafluoroethylene 1.6-1.8 part, silicone emulsion 1.2-1.4 part, wetting agent 1.4-1.8 part, Viscotrol C 1.1-1.3 part, deionized water 20-24 part.
9. the marine water epoxypaint according to any one of claim 1-8, it is characterized in that, the raw material of B component comprises by weight: cyclohexanetricarboxylic acid's acid anhydride 30-36 part, m-xylene diamine 10-12 part, 1-Methoxy-2-propyl acetate 4-6 part, alcohol ester 12 4-6 part, deionized water 20-24 part.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510475951.9A CN105062313A (en) | 2015-08-05 | 2015-08-05 | Waterborne epoxy resin coating for ships |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510475951.9A CN105062313A (en) | 2015-08-05 | 2015-08-05 | Waterborne epoxy resin coating for ships |
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| CN105062313A true CN105062313A (en) | 2015-11-18 |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105949957A (en) * | 2016-06-17 | 2016-09-21 | 枞阳县新天地高新材料有限公司 | Waterborne epoxy resin paint |
| CN106189691A (en) * | 2016-07-19 | 2016-12-07 | 成都拜迪新材料有限公司 | The 25 type passenger vehicles preparation method of waterborne organic silicon modified epoxy anticorrosive paint |
| CN106349888A (en) * | 2016-08-27 | 2017-01-25 | 安徽省金盾涂料有限责任公司 | Anticorrosive epoxy coating resistant to high and low temperatures |
| CN106366844A (en) * | 2016-08-27 | 2017-02-01 | 安徽省金盾涂料有限责任公司 | High-adhesion epoxy paint with excellent mechanical properties |
| CN106675284A (en) * | 2016-12-23 | 2017-05-17 | 安徽国威电动车制造有限公司 | Oil paint on electric vehicle container |
| CN109609005A (en) * | 2018-10-31 | 2019-04-12 | 安徽开林新材料股份有限公司 | A kind of dual-component aqueous polyurethane woodwork coating |
| WO2021035905A1 (en) * | 2019-08-27 | 2021-03-04 | 中国船舶重工集团公司第七二五研究所 | Anti-rust weather-resistant functional gradient type bottom-face integrated coating, and method for preparing coating layer |
| CN115820082A (en) * | 2022-11-24 | 2023-03-21 | 国网浙江省电力有限公司超高压分公司 | Thermosensitive color-changing temperature-indicating coating and preparation method thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105949957A (en) * | 2016-06-17 | 2016-09-21 | 枞阳县新天地高新材料有限公司 | Waterborne epoxy resin paint |
| CN106189691A (en) * | 2016-07-19 | 2016-12-07 | 成都拜迪新材料有限公司 | The 25 type passenger vehicles preparation method of waterborne organic silicon modified epoxy anticorrosive paint |
| CN106349888A (en) * | 2016-08-27 | 2017-01-25 | 安徽省金盾涂料有限责任公司 | Anticorrosive epoxy coating resistant to high and low temperatures |
| CN106366844A (en) * | 2016-08-27 | 2017-02-01 | 安徽省金盾涂料有限责任公司 | High-adhesion epoxy paint with excellent mechanical properties |
| CN106675284A (en) * | 2016-12-23 | 2017-05-17 | 安徽国威电动车制造有限公司 | Oil paint on electric vehicle container |
| CN109609005A (en) * | 2018-10-31 | 2019-04-12 | 安徽开林新材料股份有限公司 | A kind of dual-component aqueous polyurethane woodwork coating |
| WO2021035905A1 (en) * | 2019-08-27 | 2021-03-04 | 中国船舶重工集团公司第七二五研究所 | Anti-rust weather-resistant functional gradient type bottom-face integrated coating, and method for preparing coating layer |
| CN115820082A (en) * | 2022-11-24 | 2023-03-21 | 国网浙江省电力有限公司超高压分公司 | Thermosensitive color-changing temperature-indicating coating and preparation method thereof |
| CN115820082B (en) * | 2022-11-24 | 2023-09-08 | 国网浙江省电力有限公司超高压分公司 | Thermochromic temperature-indicating paint and preparation method thereof |
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