CN104974600A - Water-in-water multicolor pattern paint - Google Patents
Water-in-water multicolor pattern paint Download PDFInfo
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- CN104974600A CN104974600A CN201510465509.8A CN201510465509A CN104974600A CN 104974600 A CN104974600 A CN 104974600A CN 201510465509 A CN201510465509 A CN 201510465509A CN 104974600 A CN104974600 A CN 104974600A
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Abstract
The invention discloses a water-in-water multicolor pattern paint which is prepared from distilled water, a pigment, nitrocellulose, ester gum, castor oil, butanol, butyl acetate, methyl methylisobutylacetate, methyl ethyl ether and dimethylbenzene. The product does not cake, and can form a uniform dispersion after being mixed. The pH value of the product is 7-9; and the product does not change after being immersed in water for 30-50 days, does not change after being immersed in alkali liquor for 15-35 days, and can not expose the substrate after being scrubbed 3000-5000 times. The surface drying time of the coated film is 1-2 hours, the solid drying time is 6-10 hours, and the storage time is 8-12 months. The paint can be widely produced and continuously substituted for the existing materials.
Description
Technical field
The present invention relates to technical field of coatings, particularly relate to a kind of water-in-water type multi-color decorative pattern paint.
Background technology
Water-water colorful marble paint rich color is colorful, and special color can be provided on request and emulation property high, it is unrestricted in designer, can change shape arbitrarily according to the intention of Designers.The general name of the ester class of vinylformic acid and homologue thereof.Important has methyl acrylate, soluble cotton, 2-methyl methacrylate and 2-methylcellulose Mierocrystalline cellulose etc.Can autohemagglutination or and other monomer copolymerizations, be manufacture the monomer of tackiness agent, synthetic resins, specialty elastomer and plastics.
Multicolor finish is mainly used in copys stone material effect, so also known as liquid stone, is also local horizon exterior coating.Be made up of inconsistent two phase compositions, wherein a phase dispersion medium is external phase, and another is disperse phase mutually, during application, by disposable spray finishing, just can obtain luxurious, attractive in appearance, colorful pattern.This pattern formed by disposable spray finishing is completely different from the method being completed the multicolour pattern that could be formed by multiple working procedure successively.But along with China is more and more stricter to the protection of natural resources and national environmental protection and energy saving policy, relevant laws and regulations, make the exploitation of lithotome, processing, transportation cost constantly increase, this affects the application of lithotome in building decoration field to a certain extent.
Pseudoplastic fluid is called when fluid viscosity reduces with the increase of shearing rate.The rheological behaviour of pseudoplastic fluid and its stream become path-dependent of walking, and namely have dependence to the time, therefore are referred to as thixotropic fluid.Based on the characteristic of water-miscible paint, measure viscosity number with flow cup and not there is circulation ratio, only have to measure with rotary viscosity and comprise under low shear rate and data point complete stream varied curve under high shear rate just can provide the integrity property of water-miscible paint rheological behaviour.
Oil-in-water-type, oily bag vinylformic acid, oily oil-in and water bag vinylformic acid four class can be divided into by its medium condition, best with oily bag vinylformic acid package stability, and most widely used, water bag vinylformic acid environmental protection multicolor finish is being developed in practicality.The colorful marble paint of water-water is water-based coating, meet environmental requirement, non-harmful product during construction, because containing supra polymer element, construct after complete drying, have wear-resistant, wash away the characteristic changed with uviolizing, antistatic, high temperature resistant, acid rain resistant, waterproof, anti-be full of cracks, high strength, resistance to long-term multiple weather condition, property retention is constant, is easy to maintenance and cleaning, self-cleaning is excellent, multicolour once sprays, constructs easily, is a kind of excellent water tolerance, weathering resistance, a coating material.
Multicolor finish is the new decorative material for building of beautifying hotel, movie theatre, entertainment place, shop, office building, house etc.Water-water multicolor finish is a kind of series product of Environmental Protective Water-paint system, is born for meeting the building external paint market of development now.That the pigment of modified resin and the good stability obtained with High-tech Research And Development is made, full water-based, the colorful granite coating of disposable spray finishing, the color produced is more true to nature, more durable, by the granite sample that Designers provides, emulator can reach 99%, is the best product of alternative exterior wall grouan, therefore also known as liquid stone.The performance of nitrocotton unpigmented rubber affects by atomic number of alkyl carbon object in its principal monomer alkyl acrylate.Rubber based on soluble cotton, oil resistant, thermotolerance are better; And the rubber based on butyl acrylate, because atomic number of alkyl carbon object increases, the shielding effect of ester group polar group is increased, therefore water tolerance is made to make moderate progress, simultaneously due to shielding effect, reduce power between rubber molecule, increase inner plasticity, thus temperature limit of brittleness is reduced, winter hardiness is better.If by above-mentioned two kinds of monomers and use, then can obtain the rubber between both performances.
1843, first find that acrolein oxidation generates vinylformic acid.1931, Rohm and Haas Company (US) Independenec Mall West, Philadelphia, Pennsy Lvania 1 of the U.S. succeeded in developing cyanoethanol hydrolysis acrylic acid process processed, is industrial unique production method for a long time.Nineteen thirty-nine, fritz W.J. thunder is worn and has been invented Carbonylation of Acetylene legal system vinylformic acid, within 1954, establishes full scale plant in the U.S..Meanwhile also successfully develop acrylonitrile hydrolysis acrylic acid process.Build up from U.S. combinating carbide company in 1969 with after propylene oxidation legal system vinylformic acid full scale plant, various countries adopt this method to produce in succession.In recent years, oxidation of propylene had carried out many improvement at catalyzer and process aspect, had become and had produced acrylic acid main method.Water-water multicolor finish is a kind of series product of Environmental Protective Water-paint system, is born for meeting the building external paint market of development now.That the pigment of modified resin and the good stability obtained with High-tech Research And Development is made, full water-based, the colorful granite coating of disposable spray finishing, the color produced is more true to nature, more durable, by the granite sample that Designers provides, emulator can reach 99%, is the best product of alternative exterior wall grouan.
Summary of the invention
The invention provides the multicolor finish that a kind of fast drying and period of storage are long, solve the technical problems such as the dry slow and period of storage of existing multicolor finish is short.
The present invention is by the following technical solutions: a kind of water-in-water type multi-color decorative pattern paint, it is as follows that mass fraction proportioning pressed by its raw material: distilled water 100 parts, pigment 1-5 part, soluble cotton 15-55 part, ester gum 10-50 part, Viscotrol C 2-6 part, butanols 4-8 part, butylacetate 10-15 part, methyl tert-butyl acetic acid methyl ester 5-25 part, methyl ethyl ether 6-14 part, dimethylbenzene 18-22 part.
As a preferred technical solution of the present invention: it is as follows that mass fraction proportioning pressed by the raw material of described water-in-water type multi-color decorative pattern paint: distilled water 100 parts, pigment 2-4 part, soluble cotton 25-45 part, ester gum 20-40 part, Viscotrol C 3-5 part, butanols 5-7 part, butylacetate 12-14 part, methyl tert-butyl acetic acid methyl ester 10-20 part, methyl ethyl ether 8-12 part, dimethylbenzene 19-21 part.
As a preferred technical solution of the present invention: it is as follows that mass fraction proportioning pressed by the raw material of described water-in-water type multi-color decorative pattern paint: distilled water 100 parts, pigment 3 parts, soluble cotton 35 parts, ester gum 40 parts, Viscotrol C 4 parts, 6 parts, butanols, butylacetate 13 parts, methyl tert-butyl acetic acid methyl ester 15 parts, methyl ethyl ether 10 parts, dimethylbenzene 20 parts.
As a preferred technical solution of the present invention: described pigment adopts red iron oxide or phthalocyanine blue.
Beneficial effect: a kind of water-in-water type multi-color decorative pattern paint of the present invention adopts above technical scheme compared with prior art, has following technique effect: 1, product is without caking, uniformly dispersion after mixing; 2, pH7-9, soaks 30-50d in water unchanged, soaks 15-35d in alkali lye and does not come off, and resistance to shampooing 3000-5000 time is not show-through; 3, film surface drying 1-2h, does solid work 6-10h, 8-12 month storage period, smears flat smooth, uniform color, the widespread production not division of history into periods can replace current material.
Embodiment
Below in conjunction with example, the invention will be further described, and embodiment, only for the present invention will be described, does not form the restriction to right, and other alternative means that it may occur to persons skilled in the art that, all within the scope of the claims in the present invention.
Embodiment 1:
Distilled water 100 parts is taken, red iron oxide 1 part, soluble cotton 15 parts, ester gum 10 parts according to mass fraction proportioning, Viscotrol C 2 parts, 4 parts, butanols, butylacetate 10 parts, methyl tert-butyl acetic acid methyl ester 5 parts, methyl ethyl ether 6 parts, dimethylbenzene 18 parts, is uniformly mixed in a kettle..
Product pH7, soaks 30d in water unchanged, soaks 15d in alkali lye and does not come off, and resistance to shampooing 3000 times is not show-through; Film surface drying 2h, does solid work 10h, 8 months storage periods.
Embodiment 2:
Distilled water 100 parts is taken, red iron oxide 5 parts, soluble cotton 55 parts, ester gum 50 parts according to mass fraction proportioning, Viscotrol C 6 parts, 8 parts, butanols, butylacetate 15 parts, methyl tert-butyl acetic acid methyl ester 25 parts, methyl ethyl ether 14 parts, dimethylbenzene 22 parts, is uniformly mixed in a kettle..
Product pH9, soaks 50d in water unchanged, soaks 15d in alkali lye and does not come off, and resistance to shampooing 3000 times is not show-through; Film surface drying 2h, does solid work 10h, 8-1 month storage period.
Embodiment 3:
Distilled water 100 parts is taken, red iron oxide 2 parts, soluble cotton 25 parts, ester gum 20 parts according to mass fraction proportioning, Viscotrol C 3 parts, 5 parts, butanols, butylacetate 12 parts, methyl tert-butyl acetic acid methyl ester 10 parts, methyl ethyl ether 8 parts, dimethylbenzene 19 parts, is uniformly mixed in a kettle..
Product pH9, soaks 50d in water unchanged, soaks 35d in alkali lye and does not come off, and resistance to shampooing 3000 times is not show-through; Film surface drying 1h, does solid work 10h, 8 months storage periods.
Embodiment 4:
Distilled water 100 parts is taken, phthalocyanine blue 4 parts, soluble cotton 45 parts, ester gum 40 parts according to mass fraction proportioning, Viscotrol C 5 parts, 7 parts, butanols, butylacetate 14 parts, methyl tert-butyl acetic acid methyl ester 20 parts, methyl ethyl ether 12 parts, dimethylbenzene 21 parts, is uniformly mixed in a kettle..
Product pH7, soaks 50d in water unchanged, soaks 35d in alkali lye and does not come off, and resistance to shampooing 5000 times is not show-through; Film surface drying 2h, does solid work 6h, 12 months storage periods.
Embodiment 5:
Distilled water 100 parts is taken, phthalocyanine blue 3 parts, soluble cotton 35 parts, ester gum 40 parts according to mass fraction proportioning, Viscotrol C 4 parts, 6 parts, butanols, butylacetate 13 parts, methyl tert-butyl acetic acid methyl ester 15 parts, methyl ethyl ether 10 parts, dimethylbenzene 20 parts, is uniformly mixed in a kettle..
Product pH9, soaks 50d in water unchanged, soaks 35d in alkali lye and does not come off, and resistance to shampooing 5000 times is not show-through; Film surface drying 1h, does solid work 6h, 12 months storage periods.
Claims (4)
1. a water-in-water type multi-color decorative pattern paint, it is characterized in that, it is as follows that mass fraction proportioning pressed by the raw material of described water-in-water type multi-color decorative pattern paint: distilled water 100 parts, pigment 1-5 part, soluble cotton 15-55 part, ester gum 10-50 part, Viscotrol C 2-6 part, butanols 4-8 part, butylacetate 10-15 part, methyl tert-butyl acetic acid methyl ester 5-25 part, methyl ethyl ether 6-14 part, dimethylbenzene 18-22 part.
2. a kind of water-in-water type multi-color decorative pattern paint according to claim 1, it is characterized in that, it is as follows that mass fraction proportioning pressed by the raw material of described water-in-water type multi-color decorative pattern paint: distilled water 100 parts, pigment 2-4 part, soluble cotton 25-45 part, ester gum 20-40 part, Viscotrol C 3-5 part, butanols 5-7 part, butylacetate 12-14 part, methyl tert-butyl acetic acid methyl ester 10-20 part, methyl ethyl ether 8-12 part, dimethylbenzene 19-21 part.
3. a kind of water-in-water type multi-color decorative pattern paint according to claim 2, it is characterized in that, it is as follows that mass fraction proportioning pressed by the raw material of described water-in-water type multi-color decorative pattern paint: distilled water 100 parts, pigment 3 parts, soluble cotton 35 parts, ester gum 40 parts, Viscotrol C 4 parts, 6 parts, butanols, butylacetate 13 parts, methyl tert-butyl acetic acid methyl ester 15 parts, methyl ethyl ether 10 parts, dimethylbenzene 20 parts.
4. a kind of water-in-water type multi-color decorative pattern paint according to claim 1, is characterized in that: described pigment adopts red iron oxide or phthalocyanine blue.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510465509.8A CN104974600A (en) | 2015-08-03 | 2015-08-03 | Water-in-water multicolor pattern paint |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510465509.8A CN104974600A (en) | 2015-08-03 | 2015-08-03 | Water-in-water multicolor pattern paint |
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| Publication Number | Publication Date |
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| CN104974600A true CN104974600A (en) | 2015-10-14 |
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| CN201510465509.8A Pending CN104974600A (en) | 2015-08-03 | 2015-08-03 | Water-in-water multicolor pattern paint |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103525301A (en) * | 2013-10-21 | 2014-01-22 | 陆君军 | Aqueous ester gum environment-friendly paint |
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2015
- 2015-08-03 CN CN201510465509.8A patent/CN104974600A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103525301A (en) * | 2013-10-21 | 2014-01-22 | 陆君军 | Aqueous ester gum environment-friendly paint |
Non-Patent Citations (1)
| Title |
|---|
| 周学良等: "《精品化工产品手册·涂料》", 31 May 2002 * |
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Application publication date: 20151014 |
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