CN104945800A - High-temperature-resistant plastic suitable for lamp shade - Google Patents
High-temperature-resistant plastic suitable for lamp shade Download PDFInfo
- Publication number
- CN104945800A CN104945800A CN201510355527.0A CN201510355527A CN104945800A CN 104945800 A CN104945800 A CN 104945800A CN 201510355527 A CN201510355527 A CN 201510355527A CN 104945800 A CN104945800 A CN 104945800A
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- China
- Prior art keywords
- applicable
- lampshade
- temperature resistance
- resistance plastice
- fire retardant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/18—Homopolymers or copolymers or tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a high-temperature-resistant plastic suitable for a lamp shade. The high-temperature-resistant plastic comprises, by mass percentage, 30-60% of polytetrafluoroethylene, 20-30% of polycarbonate, 5-10% of polypropylene, 5-10% of polyetheretherketone, 5-16% of flame retardant, 8-20% of filler and 5-15% of auxiliaries. The high-temperature-resistant plastic suitable for the lamp shade can effectively improve flame retardance and high temperature resistance, guarantee good intensity and abrasion resistance and improve safety of the lamp shade in the using process. In the high-temperature-resistant plastic suitable for the lamp shade, various plant source dyes are added, have effects of coloring and are non-toxic and environmentally friendly, and plants have a certain antibacterial property.
Description
Technical field
The present invention relates to a kind of plastics, particularly relate to a kind of high-temperature resistance plastice being applicable to lampshade.
Background technology
At present, ABS is general thermoplastic engineering plastic, it is the very outstanding plastics variety of a comprehensive mechanical property, not only there is good rigidity, hardness and processing fluidity, and there is high tenacity feature, can injection moulding, extrude or thermoforming, but at present ABS resins fire retardant and resistance to elevated temperatures not good.
Summary of the invention
For above shortcomings in prior art, technical problem to be solved by this invention is to provide one and is applicable to lampshade high-temperature resistance plastice, has good resistance to elevated temperatures.
Technical problem to be solved by this invention is achieved by the following technical solution: a kind of high-temperature resistance plastice being applicable to lampshade, comprises the raw material of following mass percent: tetrafluoroethylene 30% ~ 60%, polycarbonate 20% ~ 30%, polypropylene 5% ~ 10%, polyether-ether-ketone 5% ~ 10%, fire retardant 5% ~ 16%, weighting agent 8% ~ 20% and auxiliary agent 5% ~ 15%.
Preferably, described fire retardant is phosphate type fire retardant, and described phosphate type fire retardant is the siliceous biphosphonate of polyaryl.
Preferably, also comprise vegetable dye, described vegetable dye mass percent is 3% ~ 10%, described vegetable dye extracts from the plant can extracting pigment, and the described plant containing extracting pigment comprises: one or more plants in madder, Asian puccoon, bush, indigo, safflower, pomegranate, Chinese ilex, cape jasmine, turmeric, dye yam, Turkey-galls, purple perilla.
Preferably, described auxiliary agent comprises softening agent, lubricant, stablizer and oxidation inhibitor etc.
Preferably, described weighting agent is one or two or more kinds in silicon-dioxide, aluminium hydroxide or asbestos.
Preferably, the mass percent of described silicon-dioxide, aluminium hydroxide and asbestos is about: 3:5:1.5.
Preferably, the mass percent ratio of each component is respectively: tetrafluoroethylene 40%, polycarbonate 22%, polypropylene 6%, polyether-ether-ketone 6%, fire retardant 8%, weighting agent 8%, vegetable dye 5% and auxiliary agent 5%.
The beneficial effect that the present invention reaches: a kind of high-temperature resistance plastice being applicable to lampshade of the present invention can effectively promote flame retardant of plastic and heat-resisting ability, and guarantees the intensity that plastics are good and wear resistance, adds lampshade security in use; Described a kind of high-temperature resistance plastice being applicable to lampshade, by adding various plants source dyestuff, has painted effect, nontoxic and environmental protection, and these plants have certain germ resistance simultaneously.
Embodiment
The invention will be further described below.Following examples only for technical scheme of the present invention is clearly described, and can not limit the scope of the invention with this.
Be applicable to a high-temperature resistance plastice for lampshade, comprise the raw material of following mass percent: tetrafluoroethylene 30% ~ 60%, polycarbonate 20% ~ 30%, polypropylene 5% ~ 10%, polyether-ether-ketone 5% ~ 10%, fire retardant 5% ~ 16%, weighting agent 8% ~ 20% and auxiliary agent 5% ~ 15%.
Preferably, described fire retardant is phosphate type fire retardant, and described phosphate type fire retardant is the siliceous biphosphonate of polyaryl.
Preferably, also comprise vegetable dye, described vegetable dye mass percent is 3% ~ 10%, described vegetable dye extracts from the plant can extracting pigment, and the described plant containing extracting pigment comprises: one or more plants in madder, Asian puccoon, bush, indigo, safflower, pomegranate, Chinese ilex, cape jasmine, turmeric, dye yam, Turkey-galls, purple perilla.
Preferably, described auxiliary agent comprises softening agent, lubricant, stablizer and oxidation inhibitor etc.
Preferably, described weighting agent is one or two or more kinds in silicon-dioxide, aluminium hydroxide or asbestos.
Preferably, the mass percent of described silicon-dioxide, aluminium hydroxide and asbestos is about: 3:5:1.5.
Preferably, the mass percent ratio of each component is respectively: tetrafluoroethylene 40%, polycarbonate 22%, polypropylene 6%, polyether-ether-ketone 6%, fire retardant 8%, weighting agent 8%, vegetable dye 5% and auxiliary agent 5%
The extracting method of described vegetable dye is: plant is cleaned, dry, pulverize after, under the condition of 20-50 DEG C, by the plant of having pulverized and organic solvent by 1: 50 ~ 200 solid-liquid ratio ultrasonic extraction 0.5-5h, suction filtration, filtrate is concentrated, dry, obtain powdered dye.
A kind of preparation method being applicable to the high-temperature resistance plastice of lampshade is: join in high-speed mixer by each component, rotating speed is controlled at 300 ~ 500 revs/min under room temperature, mix 10 ~ 30 minutes, proceed to after taking-up in screw extrusion press, extruding pelletization at 150 DEG C ~ 250 DEG C temperature, namely obtains the high-temperature resistance plastice being applicable to lampshade.
Embodiment 1: a kind of high-temperature resistance plastice being applicable to lampshade, comprise the raw material of following mass percent: the mass percent ratio of each component is respectively: tetrafluoroethylene 40%, polycarbonate 22%, polypropylene 6%, polyether-ether-ketone 6%, fire retardant 8%, weighting agent 8%, vegetable dye 5% and auxiliary agent 5%, described fire retardant is the siliceous biphosphonate of polyaryl, described auxiliary agent comprises softening agent, lubricant, stablizer and oxidation inhibitor etc., described silicon-dioxide, the mass percent of aluminium hydroxide and asbestos is about: 3:5:1.5, described vegetable dye extracts from madder, madder is cleaned, dry, after pulverizing, under the condition of 30 DEG C, by the madder of having pulverized and ethanol by 1: 50 solid-liquid ratio ultrasonic extraction 1h, suction filtration, filtrate is concentrated, dry, obtain powdered dye.
A kind of preparation method being applicable to the high-temperature resistance plastice of lampshade is: join in high-speed mixer by each component, rotating speed is controlled at 380 revs/min under room temperature, mix 15 minutes, proceed to after taking-up in screw extrusion press, extruding pelletization at 200 DEG C of temperature, namely obtains the high-temperature resistance plastice being applicable to lampshade.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the prerequisite not departing from the technology of the present invention principle; can also make some improvement and distortion, these improve and distortion also should be considered as protection scope of the present invention.
Claims (8)
1. be applicable to a high-temperature resistance plastice for lampshade, comprise the raw material of following mass percent: tetrafluoroethylene 30% ~ 60%, polycarbonate 20% ~ 30%, polypropylene 5% ~ 10%, polyether-ether-ketone 5% ~ 10%, fire retardant 5% ~ 16%, weighting agent 8% ~ 20% and auxiliary agent 5% ~ 15%.
2. according to a kind of high-temperature resistance plastice being applicable to lampshade described in claim 1, it is characterized in that, described fire retardant is phosphate type fire retardant, and described phosphate type fire retardant is the siliceous biphosphonate of polyaryl.
3. a kind of high-temperature resistance plastice being applicable to lampshade according to claim 2, is characterized in that, also comprise vegetable dye, and described vegetable dye mass percent is 3% ~ 10%.
4. according to a kind of high-temperature resistance plastice being applicable to lampshade described in claim 3, it is characterized in that, described vegetable dye extracts from the plant can extracting pigment, and the described plant containing extracting pigment comprises: one or more plants in madder, Asian puccoon, bush, indigo, safflower, pomegranate, Chinese ilex, cape jasmine, turmeric, dye yam, Turkey-galls, purple perilla.
5. a kind of high-temperature resistance plastice being applicable to lampshade according to claim 2, it is characterized in that, described auxiliary agent comprises softening agent, lubricant, stablizer and oxidation inhibitor etc.
6. according to a kind of high-temperature resistance plastice being applicable to lampshade described in claim 2, it is characterized in that, described weighting agent is one or two or more kinds in silicon-dioxide, aluminium hydroxide or asbestos.
7. a kind of high-temperature resistance plastice being applicable to lampshade according to claim 6, it is characterized in that, the mass percent of described silicon-dioxide, aluminium hydroxide and asbestos is about: 3:5:1.5.
8. according to a kind of high-temperature resistance plastice being applicable to lampshade described in claim 3, it is characterized in that, the mass percent ratio of each component is respectively: tetrafluoroethylene 40%, polycarbonate 22%, polypropylene 6%, polyether-ether-ketone 6%, fire retardant 8%, weighting agent 8%, vegetable dye 5%, and auxiliary agent 5%.
Priority Applications (1)
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CN201510355527.0A CN104945800A (en) | 2015-06-25 | 2015-06-25 | High-temperature-resistant plastic suitable for lamp shade |
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CN201510355527.0A CN104945800A (en) | 2015-06-25 | 2015-06-25 | High-temperature-resistant plastic suitable for lamp shade |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105713326A (en) * | 2016-03-07 | 2016-06-29 | 江西江铃李尔内饰***有限公司 | Automobile seat |
CN105860378A (en) * | 2015-12-21 | 2016-08-17 | 无锡科莱欣机电制造有限公司 | Antioxidant plastic stent for solar cell panel |
CN105924789A (en) * | 2016-06-17 | 2016-09-07 | 朱交明 | High-temperature-resistant material for LED (light-emitting diode) lampshade |
CN107936465A (en) * | 2017-12-07 | 2018-04-20 | 安徽新欧电子科技有限公司 | A kind of heat-resisting material for LED lamp cover |
CN109616267A (en) * | 2018-12-27 | 2019-04-12 | 嘉善步莱特新材料科技有限公司 | A kind of sub- production technology of colorful insulation that coloring effect is good |
CN109836738A (en) * | 2019-01-10 | 2019-06-04 | 崔兵 | A kind of high-temperature resistance plastice product and preparation method thereof |
US11118053B2 (en) | 2018-03-09 | 2021-09-14 | Ticona Llc | Polyaryletherketone/polyarylene sulfide composition |
US11352480B2 (en) | 2016-03-18 | 2022-06-07 | Ticona Llc | Polyaryletherketone composition |
CN116102835A (en) * | 2023-01-08 | 2023-05-12 | 江苏中煜橡塑科技有限公司 | Flame-retardant high-temperature-resistant fluororubber for sodium battery and processing technology thereof |
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JP2000344987A (en) * | 1999-03-26 | 2000-12-12 | Daikin Ind Ltd | Rubber composition for hard disk drive gasket |
CN101712792A (en) * | 2008-10-07 | 2010-05-26 | 金发科技股份有限公司 | Fire and heat resisting self-lubricating polycarbonate composite with nice appearance and preparation method thereof |
CN103642218A (en) * | 2013-11-18 | 2014-03-19 | 安徽宜万丰电器有限公司 | Nanometer potter's clay modified nylon material for automobile plastic members |
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2015
- 2015-06-25 CN CN201510355527.0A patent/CN104945800A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2000344987A (en) * | 1999-03-26 | 2000-12-12 | Daikin Ind Ltd | Rubber composition for hard disk drive gasket |
CN101712792A (en) * | 2008-10-07 | 2010-05-26 | 金发科技股份有限公司 | Fire and heat resisting self-lubricating polycarbonate composite with nice appearance and preparation method thereof |
CN103642218A (en) * | 2013-11-18 | 2014-03-19 | 安徽宜万丰电器有限公司 | Nanometer potter's clay modified nylon material for automobile plastic members |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105860378A (en) * | 2015-12-21 | 2016-08-17 | 无锡科莱欣机电制造有限公司 | Antioxidant plastic stent for solar cell panel |
CN105713326A (en) * | 2016-03-07 | 2016-06-29 | 江西江铃李尔内饰***有限公司 | Automobile seat |
US11352480B2 (en) | 2016-03-18 | 2022-06-07 | Ticona Llc | Polyaryletherketone composition |
CN105924789A (en) * | 2016-06-17 | 2016-09-07 | 朱交明 | High-temperature-resistant material for LED (light-emitting diode) lampshade |
CN107936465A (en) * | 2017-12-07 | 2018-04-20 | 安徽新欧电子科技有限公司 | A kind of heat-resisting material for LED lamp cover |
US11118053B2 (en) | 2018-03-09 | 2021-09-14 | Ticona Llc | Polyaryletherketone/polyarylene sulfide composition |
CN109616267A (en) * | 2018-12-27 | 2019-04-12 | 嘉善步莱特新材料科技有限公司 | A kind of sub- production technology of colorful insulation that coloring effect is good |
CN109616267B (en) * | 2018-12-27 | 2021-09-17 | 嘉善步莱特新材料科技有限公司 | Production process of colored insulator with good coloring effect |
CN109836738A (en) * | 2019-01-10 | 2019-06-04 | 崔兵 | A kind of high-temperature resistance plastice product and preparation method thereof |
CN116102835A (en) * | 2023-01-08 | 2023-05-12 | 江苏中煜橡塑科技有限公司 | Flame-retardant high-temperature-resistant fluororubber for sodium battery and processing technology thereof |
CN116102835B (en) * | 2023-01-08 | 2024-03-19 | 江苏中煜橡塑科技有限公司 | Flame-retardant high-temperature-resistant fluororubber for sodium battery and processing technology thereof |
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Application publication date: 20150930 |