CN104923286A - 一种炼厂碳四馏分生产mtbe用催化剂 - Google Patents
一种炼厂碳四馏分生产mtbe用催化剂 Download PDFInfo
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- CN104923286A CN104923286A CN201510270608.0A CN201510270608A CN104923286A CN 104923286 A CN104923286 A CN 104923286A CN 201510270608 A CN201510270608 A CN 201510270608A CN 104923286 A CN104923286 A CN 104923286A
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- 239000003054 catalyst Substances 0.000 title claims abstract description 33
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 title claims abstract description 24
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 16
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 10
- 239000002808 molecular sieve Substances 0.000 claims abstract description 10
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 10
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims abstract description 9
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 6
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 5
- 239000000853 adhesive Substances 0.000 claims abstract description 5
- 230000001070 adhesive effect Effects 0.000 claims abstract description 5
- 230000002860 competitive effect Effects 0.000 claims abstract description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000010457 zeolite Substances 0.000 claims abstract description 5
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims abstract description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000011975 tartaric acid Substances 0.000 claims abstract description 4
- 235000002906 tartaric acid Nutrition 0.000 claims abstract description 4
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims abstract description 3
- 235000015165 citric acid Nutrition 0.000 claims abstract description 3
- 235000011167 hydrochloric acid Nutrition 0.000 claims abstract description 3
- 239000004310 lactic acid Substances 0.000 claims abstract description 3
- 235000014655 lactic acid Nutrition 0.000 claims abstract description 3
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 3
- 235000006408 oxalic acid Nutrition 0.000 claims abstract description 3
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 3
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000011787 zinc oxide Substances 0.000 claims abstract description 3
- 239000008367 deionised water Substances 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- 238000002803 maceration Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 238000000465 moulding Methods 0.000 claims description 5
- 238000007493 shaping process Methods 0.000 claims description 5
- 239000002156 adsorbate Substances 0.000 claims description 4
- 238000001802 infusion Methods 0.000 claims description 3
- 239000000306 component Substances 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 2
- 230000003197 catalytic effect Effects 0.000 abstract description 5
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 238000003786 synthesis reaction Methods 0.000 abstract description 2
- 239000004480 active ingredient Substances 0.000 abstract 3
- 238000005470 impregnation Methods 0.000 abstract 2
- 239000003463 adsorbent Substances 0.000 abstract 1
- 239000004408 titanium dioxide Substances 0.000 abstract 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 4
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000899793 Hypsophrys nicaraguensis Species 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000001994 activation Methods 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 235000013847 iso-butane Nutrition 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N sec-butylidene Natural products CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105709835A (zh) * | 2016-01-22 | 2016-06-29 | 张玲 | 一种气相异丁烯生产mtbe催化剂的制备方法 |
CN107185563A (zh) * | 2017-05-08 | 2017-09-22 | 安徽海德石油化工有限公司 | 一种利用炼厂碳四馏分生产烷基化汽油用催化剂 |
CN107519911A (zh) * | 2016-06-21 | 2017-12-29 | 华东理工大学 | 一种利用有机小分子添加剂制备镍基催化剂及其在甲烷化反应中的应用 |
CN110639607A (zh) * | 2019-09-23 | 2020-01-03 | 新奥科技发展有限公司 | 催化乙炔直接制备苯乙烯的催化剂及其制备方法与应用 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB201814932D0 (en) * | 2018-09-13 | 2018-10-31 | Univ Manchester | Zeolite modification process and product thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5176719A (en) * | 1988-04-11 | 1993-01-05 | Mobil Oil Corporation | Upgrading C4 mixed hydrocarbons by transhydrogenation and isobutene etherification |
CN1352231A (zh) * | 2000-11-08 | 2002-06-05 | 中国石油化工股份有限公司 | 临氢降凝催化剂及其制备方法 |
CN102372608A (zh) * | 2010-08-19 | 2012-03-14 | 中国石油化工股份有限公司 | 一种混合碳四利用方法 |
US20130172644A1 (en) * | 2011-12-28 | 2013-07-04 | Shell Oil Company | Process for preparing lower olefins from an oxygenate |
-
2015
- 2015-05-25 CN CN201510270608.0A patent/CN104923286B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5176719A (en) * | 1988-04-11 | 1993-01-05 | Mobil Oil Corporation | Upgrading C4 mixed hydrocarbons by transhydrogenation and isobutene etherification |
CN1352231A (zh) * | 2000-11-08 | 2002-06-05 | 中国石油化工股份有限公司 | 临氢降凝催化剂及其制备方法 |
CN102372608A (zh) * | 2010-08-19 | 2012-03-14 | 中国石油化工股份有限公司 | 一种混合碳四利用方法 |
US20130172644A1 (en) * | 2011-12-28 | 2013-07-04 | Shell Oil Company | Process for preparing lower olefins from an oxygenate |
Non-Patent Citations (5)
Title |
---|
AHMED K.ABOUL-GHEIT ET AL.: "Production of environmentally friendly octane booster(methyl-t-butylether,MTBE) using zeolite catalysts", 《STUDIES IN SURFACE SCIENCE AND CATALYSIS》 * |
张继光: "《催化剂制备过程技术》", 30 June 2004, 中国石化出版社 * |
强根荣等: "《综合化学实验》", 31 August 2010, 化学工业出版社 * |
李永红等: "合成甲基叔丁基醚的分子筛催化剂研究", 《催化学报》 * |
胡津仙等: "ZSM-5沸石酸性对合成甲基叔丁基醚的影响", 《石油学报(石油加工)》 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105709835A (zh) * | 2016-01-22 | 2016-06-29 | 张玲 | 一种气相异丁烯生产mtbe催化剂的制备方法 |
CN107519911A (zh) * | 2016-06-21 | 2017-12-29 | 华东理工大学 | 一种利用有机小分子添加剂制备镍基催化剂及其在甲烷化反应中的应用 |
CN107519911B (zh) * | 2016-06-21 | 2020-05-08 | 华东理工大学 | 一种利用有机小分子添加剂制备镍基催化剂及其在甲烷化反应中的应用 |
CN107185563A (zh) * | 2017-05-08 | 2017-09-22 | 安徽海德石油化工有限公司 | 一种利用炼厂碳四馏分生产烷基化汽油用催化剂 |
CN110639607A (zh) * | 2019-09-23 | 2020-01-03 | 新奥科技发展有限公司 | 催化乙炔直接制备苯乙烯的催化剂及其制备方法与应用 |
CN110639607B (zh) * | 2019-09-23 | 2022-05-31 | 新奥科技发展有限公司 | 催化乙炔直接制备苯乙烯的催化剂及其制备方法与应用 |
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