CN104894876A - Novel light, thin, breathable and uvioresistant fabric - Google Patents
Novel light, thin, breathable and uvioresistant fabric Download PDFInfo
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- CN104894876A CN104894876A CN201510331228.3A CN201510331228A CN104894876A CN 104894876 A CN104894876 A CN 104894876A CN 201510331228 A CN201510331228 A CN 201510331228A CN 104894876 A CN104894876 A CN 104894876A
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Abstract
The invention provides a novel light, thin, breathable and uvioresistant fabric which comprises a light, thin and high-density ramie fabric and a transparent nano-modified organic-inorganic composite coating. The ramie fabric subjected to bio-enzyme treatment is subjected to plasma modification, and then is immersed into the nano-modified organic-inorganic composite coating, and the light, thin, breathable and uvioresistant fabric is obtained through one-time immersing and one-time rolling, wherein the nano-modified organic-inorganic composite coating comprises the following main components: nano organic silica sol, nanometer oxide sol, a dispersing agent, a film forming matter and a solvent. The uvioresistant fabric prepared by the invention is light, thin and breathable, and has excellent ultraviolet resistance.
Description
Technical field:
The invention belongs to textile material technical field, be specifically related to a kind of frivolous ventilative uvioresistant fabrics.
Background technology:
The health of suitable Ultraviolet radiation to the mankind is useful, but excessive be exposed to the sun skin, glasses or even the immune system that can injure the mankind.Therefore hot summer, the sun protection clothing of beautiful fashion again becomes the favorite of numerous women, and various sun protection clothing is also operated and gives birth to, but although sun protection clothing kind is in the market more, sun-screening function is limited, and because do not have unified surface, sun-proof result level is uneven.
The clothing of antiultraviolet not only will keep out ultraviolet, also will reduce the risk that skin is exposed to the sun, therefore need clothing fiber can reflect, absorb and disperse wavelength.The processing of the intertexture form of the ability and ultraviolet resistance of antiultraviolet clothes and the type of fiber, yarn, thickness and density, wet-treating and fabric is closely bound up.The large multi-density of current sun protection clothing material is large, and color is dark, comparatively thick and heavy, although sun-proof result is good, wears unsightly uncomfortable.
The disclosed hierarchical coating uvioresistant composite material of Chinese patent CN 102416735B (publication date 2012.4.18), this composite material part is bottom, intermediate layer and skin, bottom is bamboo fibre, acid fiber by polylactic, milk protein fiber, woven fabric prepared by chitin fiber and supermolecule weight polyethylene fiber, intermediate layer is the double-deck warp-knitted fabric that ultra-thin tissue and ultra-thin mock leno weave are formed, the non-woven fabrics fabric that skin is prepared for doughnut, carry out by viscose fibre the connection that is interweaved between treble cloths, and fill fire-retardant powder at three interlayers, obtain air-moisture-permeable, moisture absorption is breathed freely, Antistatic radiation-proof uvioresistant, comfortable excellent composite fabric.The disclosed sol-gel anti UV finishing liquid of Chinese patent CN 1614133A (publication date 2005.5.11) and preparing the application in anti-UV fabric, using the Nano sol of the stable transparent of titaniferous as raw material, fabric is arranged, directly form nanogel particle at fabric face, give the uvioresistant performance of fabric excellence, overcome the conventional nano particle shortcoming that easily gathering, easily migration and adhesion are weak on fabric, give play to the performance that nano particle is special simultaneously.From above-mentioned prior art, preparation uvioresistant fabric is normally set about from fibrous raw material and postfinishing process, and the uvioresistant fabric of preparation is too thick and heavy, and airtight moisture-inhibiting, comfort level is not good enough.
Transparent composite coating combines with fabric by the present invention, covers transparent uvioresistant coating at the fabric face that quality is light, on the basis of giving the excellent rate of ultraviolet shield of fabric, ensures the frivolous comfortable ventilating of fabric.
Summary of the invention:
The technical problem to be solved in the present invention is to provide a kind of novel frivolous ventilative uvioresistant fabrics, first the frivolous high density fabric of quality is prepared, then nano modified polyurethane paint is firmly coated in fabric face equably by fabric face after hydrophilic treatment, form the UV-resistant layer of the frivolous densification of one deck, obtain frivolous ventilative uvioresistant fabric.
For solving the problems of the technologies described above, technical scheme of the present invention is:
A kind of novel frivolous ventilative uvioresistant fabrics, it is characterized in that, described uvioresistant fabrics comprises frivolous high density fabric and clear coat, described frivolous high density fabric is ramie fabric, described clear coat is the Organic-inorganic composite coating of nano modification, and described ramie fabric is the ultra-thin ramie fabric of high-count and high-density.
Preferably, described ramie fabric is through the ramie fabric of cellulase treatment.
Preferably, the component in the Organic-inorganic composite coating of described nano modification and consumption, by weight, comprising:
Preferably, in described nano-organosilicon colloidal sol, organosilyl content is 5-15%, and average grain diameter is 20-50nm.
Preferably, described nano-oxide colloidal sol is the mixture of nano alumina sol and nano silicon dioxide sol, the volume ratio of described nano alumina sol and nano silicon dioxide sol is 1:0.5-1.5, and the average grain diameter of described nano silicon dioxide sol is 150nm.
Preferably, described dispersant is macromolecule dispersing agent, is polysiloxane-based or maleic anhydride class.
Preferably, described film forming matter is diethylene glycol ether or butyl glycol ether.
Preferably, described solvent is ethanol.
Preferably, described ramie fabric, after plasma modification, immerses the Organic-inorganic composite coating of nano modification, and a leaching one is rolled, and obtains frivolous ventilative uvioresistant fabrics.
Compared with prior art, the present invention has following beneficial effect:
(1) the present invention adopts ramie fabric as raw material, the ultraviolet penetrance of ramee is less than 0.6%, anti-uv-ray is cotton 41.7 times, therefore the effective shielding of ultraviolet of ramie fabric energy is to the radiation of human body, any stimulation can not be produced to skin, and ramie fabric to have moisture absorption loose wet fast, good luster, well-pressed ventilative characteristic, is especially suitable for use as summer clothes.
(2) ramie fabric adopted in the present invention is through cellulase treatment, can be the deliquescing of fabric face filoplume, reduce filoplume fluffy, then improved the hydrophily on ramie fabric surface by Cement Composite Treated by Plasma, improve with coating in conjunction with dynamics, improve the uniformity of coating.
(3) the Organic-inorganic composite coating of the nano modification adopted in the present invention, containing multiple nano material, nano-organosilicon colloidal sol nontoxic pollution-free, belong to green material, good stability, the surface tension of solution can be reduced, nano alumina sol can reduce the electrostatic of system, give antistatic property, the chemical stability of nano titanic oxide sol is good, anti-uv-ray is strong, transparent thread is excellent, coordinate corresponding film forming agent and solvent, make the uvioresistant performance of the Organic-inorganic composite coating of the nano modification prepared in the present invention good, green, transparent, also possesses certain antistatic property.
(4) fabric of frivolous ventilative uvioresistant fabrics prepared of the present invention and coating all possess excellent uvioresistant performance, and fabric is frivolous ventilative, and coating transparent is frivolous, and therefore the uvioresistant fabrics prepared of the present invention is frivolous ventilative, also uvioresistant.
Detailed description of the invention:
Describe the present invention in detail below in conjunction with specific embodiment, be used for explaining the present invention in this illustrative examples of the present invention and explanation, but not as a limitation of the invention.
Embodiment 1:
A kind of novel frivolous ventilative uvioresistant fabrics comprises the Organic-inorganic composite coating of the ultra-thin ramie fabric of high-count and high-density and transparent nano modification.The ramie fabric of cellulase treatment, after plasma modification, immerses the Organic-inorganic composite coating of nano modification, and a leaching one is rolled, and obtains frivolous ventilative uvioresistant fabrics.
Component in the Organic-inorganic composite coating of wherein nano modification and consumption, by weight, comprise: 1 part of content is the nano-organosilicon colloidal sol of the 20-50nm of 15%, 10 parts of volume ratios are the mixture of the nano alumina sol of 1:0.5 and the nano silicon dioxide sol of 150nm, the polysiloxane-based macromolecule dispersing agent of 10 parts, the alcohol solvent of 3 parts of diethylene glycol ether film forming matters and 60 parts.
Embodiment 2:
A kind of novel frivolous ventilative uvioresistant fabrics comprises the Organic-inorganic composite coating of the ultra-thin ramie fabric of high-count and high-density and transparent nano modification.The ramie fabric of cellulase treatment, after plasma modification, immerses the Organic-inorganic composite coating of nano modification, and a leaching one is rolled, and obtains frivolous ventilative uvioresistant fabrics.
Component in the Organic-inorganic composite coating of wherein nano modification and consumption, by weight, comprise: 10 parts of content are the nano-organosilicon colloidal sol of the 20-50nm of 5%, 1 part of volume ratio is the mixture of the nano alumina sol of 1:1.5 and the nano silicon dioxide sol of 150nm, the maleic anhydride family macromolecule dispersant of 5 parts, the alcohol solvent of 9 parts of butyl glycol ether film forming matters and 80 parts.
Embodiment 3:
A kind of novel frivolous ventilative uvioresistant fabrics comprises the Organic-inorganic composite coating of the ultra-thin ramie fabric of high-count and high-density and transparent nano modification.The ramie fabric of cellulase treatment, after plasma modification, immerses the Organic-inorganic composite coating of nano modification, and a leaching one is rolled, and obtains frivolous ventilative uvioresistant fabrics.
Component in the Organic-inorganic composite coating of wherein nano modification and consumption, by weight, comprise: 5 parts of content are the nano-organosilicon colloidal sol of the 20-50nm of 8%, 5 parts of volume ratios are the mixture of the nano alumina sol of 1:0.7 and the nano silicon dioxide sol of 150nm, the maleic anhydride family macromolecule dispersant of 8 parts, the alcohol solvent of 6 parts of butyl glycol ether film forming matters and 70 parts.
Embodiment 4:
A kind of novel frivolous ventilative uvioresistant fabrics comprises the Organic-inorganic composite coating of the ultra-thin ramie fabric of high-count and high-density and transparent nano modification.The ramie fabric of cellulase treatment, after plasma modification, immerses the Organic-inorganic composite coating of nano modification, and a leaching one is rolled, and obtains frivolous ventilative uvioresistant fabrics.
Component in the Organic-inorganic composite coating of wherein nano modification and consumption, by weight, comprise: 3 parts of content are the nano-organosilicon colloidal sol of the 20-50nm of 12%, 7 parts of volume ratios are the mixture of the nano alumina sol of 1:1 and the nano silicon dioxide sol of 150nm, the maleic anhydride family macromolecule dispersant of 6 parts, the alcohol solvent of 6 parts of diethylene glycol ether film forming matters and 60-80 part.
Embodiment 5:
A kind of novel frivolous ventilative uvioresistant fabrics comprises the Organic-inorganic composite coating of the ultra-thin ramie fabric of high-count and high-density and transparent nano modification.The ramie fabric of cellulase treatment, after plasma modification, immerses the Organic-inorganic composite coating of nano modification, and a leaching one is rolled, and obtains frivolous ventilative uvioresistant fabrics.
Component in the Organic-inorganic composite coating of wherein nano modification and consumption, by weight, comprise: 10 parts of content are the nano-organosilicon colloidal sol of the 20-50nm of 15%, 10 parts of volume ratios are the mixture of the nano alumina sol of 1:1.5 and the nano silicon dioxide sol of 150nm, the polysiloxane-based macromolecule dispersing agent of 10 parts, the alcohol solvent of 9 parts of butyl glycol ether film forming matters and 80 parts.
Embodiment 6:
A kind of novel frivolous ventilative uvioresistant fabrics comprises the Organic-inorganic composite coating of the ultra-thin ramie fabric of high-count and high-density and transparent nano modification.The ramie fabric of cellulase treatment, after plasma modification, immerses the Organic-inorganic composite coating of nano modification, and a leaching one is rolled, and obtains frivolous ventilative uvioresistant fabrics.
Component in the Organic-inorganic composite coating of wherein nano modification and consumption, by weight, comprise: 9 parts of content are the nano-organosilicon colloidal sol of the 20-50nm of 8%, 4 parts of volume ratios are the mixture of the nano alumina sol of 1:1.2 and the nano silicon dioxide sol of 150nm, the polysiloxane-based macromolecule dispersing agent of 7 parts, the alcohol solvent of 6 parts of butyl glycol ether film forming matters and 75 parts.
After testing, the result of the grammes per square metre of the frivolous ventilative uvioresistant fabrics prepared of embodiment 1-6, UPF and UVA is as follows:
As seen from the above table, frivolous ventilative uvioresistant fabrics prepared by the present invention is frivolous ventilative, and anti-ultraviolet property is excellent, meets the standard of ultraviolet resistant textiles.
Above-described embodiment is illustrative principle of the present invention and effect thereof only, but not for limiting the present invention.Any person skilled in the art scholar all without prejudice under spirit of the present invention and category, can modify above-described embodiment or changes.Therefore, such as have in art usually know the knowledgeable do not depart from complete under disclosed spirit and technological thought all equivalence modify or change, must be contained by claim of the present invention.
Claims (9)
1. a novel frivolous ventilative uvioresistant fabrics, it is characterized in that: described uvioresistant fabrics comprises frivolous high density fabric and clear coat, described frivolous high density fabric is ramie fabric, described clear coat is the Organic-inorganic composite coating of nano modification, and described ramie fabric is the ultra-thin ramie fabric of high-count and high-density.
2. a kind of novel frivolous ventilative uvioresistant fabrics according to claim 1, is characterized in that: described ramie fabric is through the ramie fabric of cellulase treatment.
3. a kind of novel frivolous ventilative uvioresistant fabrics according to claim 1, is characterized in that: the component in the Organic-inorganic composite coating of described nano modification and consumption, by weight, comprising:
。
4. a kind of novel frivolous ventilative uvioresistant fabrics according to claim 3, it is characterized in that: in described nano-organosilicon colloidal sol, organosilyl content is 5-15%, average grain diameter is 20-50nm.
5. a kind of novel frivolous ventilative uvioresistant fabrics according to claim 3, it is characterized in that: described nano-oxide colloidal sol is the mixture of nano alumina sol and nano silicon dioxide sol, the volume ratio of described nano alumina sol and nano silicon dioxide sol is 1:0.5-1.5, and the average grain diameter of described nano silicon dioxide sol is 150nm.
6. a kind of novel frivolous ventilative uvioresistant fabrics according to claim 3, is characterized in that: described dispersant is macromolecule dispersing agent, is polysiloxane-based or maleic anhydride class.
7. a kind of novel frivolous ventilative uvioresistant fabrics according to claim 3, is characterized in that: described film forming matter is diethylene glycol ether or butyl glycol ether.
8. a kind of novel frivolous ventilative uvioresistant fabrics according to claim 3, is characterized in that: described solvent is ethanol.
9. a kind of novel frivolous ventilative uvioresistant fabrics according to claim 1, it is characterized in that: described ramie fabric is after plasma modification, immerse the Organic-inorganic composite coating of nano modification, a leaching one is rolled, and obtains frivolous ventilative uvioresistant fabrics.
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105755808A (en) * | 2016-03-14 | 2016-07-13 | 湖州新创丝织品有限公司 | Anti-ultraviolet finishing method for hemp fabrics |
| CN105780253A (en) * | 2016-03-30 | 2016-07-20 | 江阴芗菲服饰有限公司 | Anti-reflecting scraper bar coating type ramie fabric |
| CN106480581A (en) * | 2016-09-21 | 2017-03-08 | 东莞市联洲知识产权运营管理有限公司 | A kind of high intensity light and thin fabric of waterproof UV resistance and preparation method thereof |
| CN107189600A (en) * | 2017-05-31 | 2017-09-22 | 句容市恒鑫遮阳科技有限公司 | A kind of outdoor heat insulation and heat control coating used for textiles and preparation method thereof |
| CN107338649A (en) * | 2017-07-25 | 2017-11-10 | 安徽亚源印染有限公司 | A kind of ramie viscose rayon cotton interwoven fabric with excellent water proofing property |
| CN107938327A (en) * | 2017-11-30 | 2018-04-20 | 安徽中福毛纺制帽有限公司 | A kind of special antibiotic finishing solution of wool cap |
| CN108677532A (en) * | 2018-04-30 | 2018-10-19 | 安徽恒益纺织科技有限公司 | A kind of antiultraviolet auxiliary agent for textile fabric |
| CN108842250A (en) * | 2018-06-09 | 2018-11-20 | 浙江立天股份有限公司 | A kind of regeneration dyed yarn production technology |
| CN110629550A (en) * | 2019-10-15 | 2019-12-31 | 东北林业大学 | Method for grafting linen with maleic anhydride through photocatalysis |
| CN114941241A (en) * | 2022-06-23 | 2022-08-26 | 蔡轩 | Sun-proof fabric with good air permeability and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105755808A (en) * | 2016-03-14 | 2016-07-13 | 湖州新创丝织品有限公司 | Anti-ultraviolet finishing method for hemp fabrics |
| CN105780253A (en) * | 2016-03-30 | 2016-07-20 | 江阴芗菲服饰有限公司 | Anti-reflecting scraper bar coating type ramie fabric |
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| CN106480581A (en) * | 2016-09-21 | 2017-03-08 | 东莞市联洲知识产权运营管理有限公司 | A kind of high intensity light and thin fabric of waterproof UV resistance and preparation method thereof |
| CN107189600A (en) * | 2017-05-31 | 2017-09-22 | 句容市恒鑫遮阳科技有限公司 | A kind of outdoor heat insulation and heat control coating used for textiles and preparation method thereof |
| CN107338649A (en) * | 2017-07-25 | 2017-11-10 | 安徽亚源印染有限公司 | A kind of ramie viscose rayon cotton interwoven fabric with excellent water proofing property |
| CN107938327A (en) * | 2017-11-30 | 2018-04-20 | 安徽中福毛纺制帽有限公司 | A kind of special antibiotic finishing solution of wool cap |
| CN108677532A (en) * | 2018-04-30 | 2018-10-19 | 安徽恒益纺织科技有限公司 | A kind of antiultraviolet auxiliary agent for textile fabric |
| CN108842250A (en) * | 2018-06-09 | 2018-11-20 | 浙江立天股份有限公司 | A kind of regeneration dyed yarn production technology |
| CN110629550A (en) * | 2019-10-15 | 2019-12-31 | 东北林业大学 | Method for grafting linen with maleic anhydride through photocatalysis |
| CN110629550B (en) * | 2019-10-15 | 2021-11-09 | 东北林业大学 | Method for grafting linen with maleic anhydride through photocatalysis |
| CN114941241A (en) * | 2022-06-23 | 2022-08-26 | 蔡轩 | Sun-proof fabric with good air permeability and preparation method thereof |
| CN114941241B (en) * | 2022-06-23 | 2024-04-19 | 苏州西铁牛电子商务有限公司 | Sun-proof fabric with good air permeability and preparation method thereof |
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