CN104845637A - Improvement method for saline-alkali soil rice planting - Google Patents

Improvement method for saline-alkali soil rice planting Download PDF

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Publication number
CN104845637A
CN104845637A CN201510167953.1A CN201510167953A CN104845637A CN 104845637 A CN104845637 A CN 104845637A CN 201510167953 A CN201510167953 A CN 201510167953A CN 104845637 A CN104845637 A CN 104845637A
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China
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parts
attapulgite
weathered coal
phosphogypsum
saline
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CN201510167953.1A
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高程华
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ANHUI YANGHETIAN BIOTECHNOLOGY Co Ltd
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ANHUI YANGHETIAN BIOTECHNOLOGY Co Ltd
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Abstract

The invention provides an improvement method for saline-alkali soil rice planting. A saline-alkali soil improver is composed of phosphogypsum, attapulgite, a weathered coal-sodium polyacrylate compound, black alum and a trace element compound. The method is characterized in that: by weight, the soil improver is formed by mixing 1-3 parts of phosphogypsum, 4-5 parts of attapulgite, 1-3 parts of the weathered coal-sodium polyacrylate compound, 1-2 parts of black alum and 1-2 parts of the trace element compound, attapulgite, sodium acrylate and other materials are subjected to modification, grafting and polymerization, the obtained improver has the efficacy of water retention, fertilizer maintenance, salt reduction, alkali decrease, soil loosening and the like, accordingly can improve rice field saline-alkali soil, and can be added into a fertilizer to prepare saline-alkali soil improvement fertilizer. Compared with existing methods, the method provided by the invention has the advantages of low cost, abundant raw materials and high efficiency, etc.

Description

A kind of modification method of rice in saline-alkali field plantation
Technical field
What the present invention relates to is a kind of modifying agent improving alkaline land soil performance.
Background technology
Salting of soil is a global difficult problem, and be also the major obstacle factor that restriction China's agricultural development and integration capability improve, the deterioration of the ecological environment that salinization brings, more can affect the space that the people depends on for existence and development always.So saltings control and exploitation are the problems that irrigated area agricultural development can not be ignored, the grain drop in production such as the paddy rice that agriculture plantation causes because of salinization.China's North China's modern agriculture, due to the excessive use of chemical fertilizer, causes Pedotransfer function to aggravate, and hardens serious, make salinization, alkali-affected soil constantly expands, aggravate, rice terrace is due to the needs of rice growing season, and field few time cuts off the water supply, but most of irrigation district adopts extensive style pouring farmland, in addition temperature is higher, and evaporation is very fast, and rainfall is less, make deep soil saline and alkaline on to move table poly-, cause primary salinization, rice yield declines, and salting of soil is on the rise.
At present, saline and alkali land improvement method mainly contains Physical (wholelyly and water resources industry: CN201010256362.9, CN200710179269.0 etc.), biological process (microbial inoculum: CN201010131080.6, CN201310114401.5 etc.) and chemical method (modifying agent: the CN201110095321.0 such as desulfurated plaster, sulfuric acid, furfural dregs, humic acid, animal excrement, CN200610017147.7, CN03138949.X etc.) etc.Although these measures are effective under certain condition, but separately there is limitation: water conservancy law and chemical amendments at substantial manpower and materials, phytoremediation longer and climate condition restriction consuming time, is all difficult to implement on a large scale, can not meets current China's agricultural development needs.
Close to the most existing alkaline land modifying agent of the present invention such as notification number be: 103937507A application discloses " a kind of alkaline land modifying agent, preparation method and using method thereof ", this product and production thereof, using method are have good effect at adjustment alkaline land soil saline alkali, but, this kind of product is confined to improve crop growth environment, but effectively cannot improve the ventilation property of root system plant in soil.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, provide the modification method of a kind of rice in saline-alkali field plantation, the effect such as realize water conservation, fertilizer conservation, salt reduction, pressure alkali, loosen the soil.Its main method is: be aggregated in by sodium acrylate graft on weathered coal, then with attapulgite with phosphogypsum is composite makes alkaline land modifying agent.Its cardinal principle is: cemented out by the sodium ion being adsorbed on soil colloids by the ion exchange of phosphogypsum; Water retention is played by the sodium polyacrylate be grafted on weathered coal; By phosphogypsum by the carbanion solidification (CaSO in deep subsoil water body 4=Ca 2++ SO4 2-; Ca 2++ CO 3 2-=CaCO 3), thus soil pH value falls; Soil pH is reduced and can chessom by the acidity effect of weathered coal; The effect keeping chemical fertilizer nutrient is played by attapulgite; Black alum can level of alkalinity effectively in sweetening of the soil, effectively can improve soil because of saline and alkaline degree causes soil compaction, improve Crop Root and tie up to the inner permeation functions of soil, the usage quantity of trace compound is little, but trace compound effectively can supplement and meet farm crop whole breeding times to the demand of multiple nutrient, accomplish balance fertilizing, trace element has growing of promotion crop, improve photosynthetic utilization ratio, improve the per unit area yield of paddy rice, though consumption is little, play an important role.
The present invention is achieved by the following technical solutions, a kind of modification method of rice in saline-alkali field plantation, be made up of phosphogypsum, attapulgite, weathered coal-sodium polyacrylate mixture, black alum and trace compound, it is characterized in that: according to weighing scale, mixed by 1-3 part phosphogypsum, 4-5 part attapulgite, 1-3 part weathered coal-sodium polyacrylate mixture, the black alum of 1-2 part and the trace compound of 1-2 part and form, its step is as follows:
(1) phosphogypsum powder is broken to 150-180 order stand-by;
(2) attapulgite is crushed to 150-180 order dry powder to irradiate under gamma ray (3MeV, 30kGy) and obtain stand-by in 20-30 minute;
(3) weathered coal-sodium polyacrylate mixture is by the weathered coal of 9 parts and the sodium polyacrylate Homogeneous phase mixing of 4 parts, then be added to the water and be made into the suspension liquid that concentration is 90g/L, at 40 DEG C, stir 10 minutes, thus by sodium acrylate graft copolymerization at weathered coal on the surface, dry, pulverize to 150-180 order in 70 degrees Celsius afterwards obtains stand-by;
(4) by the finess disintegrating of black alum, most 150-180 order is stand-by;
(5) trace compound is mixed by the borax of 5-7 part ammonium molybdate, 20-30 part, the zinc sulfate of 10-15 part by weight, and the fineness of trace compound is 150-180 order
(6) by weight, the trace compound Homogeneous phase mixing of the black alum 1-2 part in weathered coal-sodium polyacrylate mixture 1-3 part, (4) in the phosphogypsum 1-3 part in (1), the attapulgite 4-5 part in (2), (3) is obtained this modifying agent, the modifying agent obtained evenly is spread fertilizer over the fields on water paddy soil surface according to every mu of 15-20kg consumption, then ploughs.
A kind of modification method of rice in saline-alkali field plantation, it is characterized in that: by weight, the modifying agent obtained is added in fertilizer or urea or Chemical Mixed Fertilizer according to 5-20% ratio, namely granulation obtains alkaline land improving fertilizer, alkaline land improving urea and alkaline land improving Chemical Mixed Fertilizer, obtained improving fertilizer is evenly spread fertilizer over the fields on water paddy soil surface according to the consumption of every mu of 40-60kg, then ploughs.
The present invention has the following advantages compared to existing technology:
(1) the present invention is compared with common chemical fertilizer, apply fertilizer Deng nutrient, soil humidity more than 10% can be increased, reduce soil and be harmful to salinity (sodium ion and carbanion etc.) more than 10%, improve determining cation exchange capacity of soil more than 5%, reduce nutrient loss more than 15%, make crop yield more than 10%, the multiple efficacies such as there is significant water conservation, fertilizer conservation, salt reduction, pressure alkali, loosen the soil.
(2) phosphogypsum adopted in the present invention is mainly the by product that fertilizer plant produces phosphate fertilizer, compared with the desulfurated plaster used in existing alkaline land modifying agent patent, there is reserves large (about more than 10 times), the large advantage of cost low (low more than 50%) two.
(3) weathered coal adopted in the present invention, compared with humic acid in existing alkaline land modifying agent patent, has the advantages such as reserves are large, cost is low.
Embodiment
Elaborate to embodiments of the invention below, the present embodiment is implemented under premised on technical solution of the present invention, give detailed embodiment and concrete operating process, but protection scope of the present invention is not limited to following embodiment.
Embodiment 1
(1) phosphogypsum powder is broken to 150 orders;
(2) attapulgite (colloid, 150 orders) dry powder is irradiated 20 minutes under gamma ray (3MeV, 30kGy), attapulgite is scatter, keep nutrient effect to promote it;
(3) by weight, by the sodium acrylate Homogeneous phase mixing of the weathered coals of 9 parts (content of humic acid is 20%) with 4 parts, be then added to the water and be made into the suspension liquid that concentration is 90g/L, at 40 DEG C, stir 10 minutes, thus by sodium acrylate graft copolymerization at weathered coal on the surface.Dry, pulverize to 150 orders with 70 degrees Celsius afterwards, namely obtain weathered coal-sodium polyacrylate mixture;
(4) black alum is crushed to 150 orders;
(5) trace compound is mixed by 5 parts of ammonium molybdates, the borax of 20 parts, the zinc sulfate of 10 parts by weight, and the fineness of trace compound is 150 orders
(6) by weight, by the black alum in the attapulgite in the phosphogypsum in 1 part (1), 4 parts (2), the weathered coal-sodium polyacrylate in 2 parts (3), 1 part (4) and the trace compound Homogeneous phase mixing in 2 parts (5), namely obtain alkaline land modifying agent;
(7) modifying agent obtained in (6) is evenly spread fertilizer over the fields on water paddy soil surface according to every mu of 15kg consumption, then plough;
(8) modifying agent that also (6) can be obtained by weight 5% ratio join in fertilizer or urea or Chemical Mixed Fertilizer, obtained improving fertilizer is evenly spread fertilizer over the fields at soil surface according to every mu of 40kg consumption, then ploughs.
Embodiment 2
(1) phosphogypsum powder is broken to 170 orders;
(2) attapulgite (colloid, 170 orders) dry powder is irradiated 25 minutes under gamma ray (3MeV, 30kGy), attapulgite is scatter, keep nutrient effect to promote it;
(3) by weight, by the sodium acrylate Homogeneous phase mixing of the weathered coals of 9 parts (content of humic acid is 20%) with 4 parts, be then added to the water and be made into the suspension liquid that concentration is 90g/L, at 40 DEG C, stir 10 minutes, thus by sodium acrylate graft copolymerization at weathered coal on the surface.Dry, pulverize to 170 orders with 70 degrees Celsius afterwards, namely obtain weathered coal-sodium polyacrylate mixture;
(4) black alum is crushed to 170 orders;
(5) trace compound is mixed by 6 parts of ammonium molybdates, the borax of 25 parts, the zinc sulfate of 12 parts by weight, and the fineness of trace compound is 170 orders
(6) by weight, by the black alum in the attapulgite in the phosphogypsum in 2 parts (1), 5 parts (2), the weathered coal-sodium polyacrylate in 1 part (3), 1 part (4) and the trace compound Homogeneous phase mixing in 1 part (5), namely obtain alkaline land modifying agent;
(7) modifying agent obtained in (6) is evenly spread fertilizer over the fields on water paddy soil surface according to every mu of 17kg consumption, then plough;
(8) modifying agent that also (6) can be obtained by weight 10% ratio join in fertilizer or urea or Chemical Mixed Fertilizer, obtained improving fertilizer is evenly spread fertilizer over the fields at soil surface according to every mu of 50kg consumption, then ploughs.
Embodiment 3
(1) phosphogypsum powder is broken to 180 orders;
(2) attapulgite (colloid, 180 orders) dry powder is irradiated 30 minutes under gamma ray (3MeV, 30kGy), attapulgite is scatter, keep nutrient effect to promote it;
(3) by weight, by the sodium acrylate Homogeneous phase mixing of the weathered coals of 9 parts (content of humic acid is 20%) with 4 parts, be then added to the water and be made into the suspension liquid that concentration is 90g/L, at 40 DEG C, stir 10 minutes, thus by sodium acrylate graft copolymerization at weathered coal on the surface.Dry, pulverize to 180 orders with 70 degrees Celsius afterwards, namely obtain weathered coal-sodium polyacrylate mixture;
(4) black alum is crushed to 180 orders;
(5) trace compound is mixed by 7 parts of ammonium molybdates, the borax of 30 parts, the zinc sulfate of 15 parts by weight, and the fineness of trace compound is 180 orders
(6) by weight, by the black alum in the attapulgite in the phosphogypsum in 3 parts (1), 4 parts (2), the weathered coal-sodium polyacrylate in 1 part (3), 1 part (4) and the trace compound Homogeneous phase mixing in 1 part (5), namely obtain alkaline land modifying agent;
(7) modifying agent obtained in (6) is evenly spread fertilizer over the fields on water paddy soil surface according to every mu of 20kg consumption, then plough;
(8) modifying agent that also (6) can be obtained by weight 20% ratio join in fertilizer or urea or Chemical Mixed Fertilizer, obtained improving fertilizer is evenly spread fertilizer over the fields at soil surface according to every mu of 60kg consumption, then ploughs.
The first half of the year in 2014 adopts the modifying agent product described in embodiment 2 in Ningxia, China, the area heavier to local saltings degree has been carried out two plots of adjacent about 10 mu of rice terraces and has been tested, when autumn harvest, carried out contrast and ultimate production to the paddy rice on two pieces of ground respectively to carry out contrast and find, ultimate production increases the output of nearly 7%.As can be seen here, this product, for improving alkaline land soil and improving crop yield, has a significant effect, for this reason, this year carries out cloth experimental tests in the Dongying City area of Ningxia, China and Northern Shandong, and modifying agent is dealt into this area, uses when waiting for sowing.
Above embodiment only in order to the present invention is described and and unrestricted technical scheme described in the invention; Therefore, although this specification sheets with reference to each above-mentioned embodiment to present invention has been detailed description, those of ordinary skill in the art should be appreciated that and still can modify to the present invention or equivalent to replace; And all do not depart from technical scheme and the improvement thereof of the spirit and scope of the present invention, all should be encompassed in right of the present invention.

Claims (1)

1. the modification method of a rice in saline-alkali field plantation, be made up of phosphogypsum, attapulgite, weathered coal-sodium polyacrylate mixture, black alum and trace compound, it is characterized in that: according to weighing scale, mixed by 1-3 part phosphogypsum, 4-5 part attapulgite, 1-3 part weathered coal-sodium polyacrylate mixture, the black alum of 1-2 part and the trace compound of 1-2 part and form, its step is as follows:
(1) phosphogypsum powder is broken to 150-180 order stand-by;
(2) attapulgite is crushed to 150-180 order dry powder to irradiate under gamma ray (3MeV, 30kGy) and obtain stand-by in 20-30 minute;
(3) weathered coal-sodium polyacrylate mixture is by the weathered coal of 9 parts and the sodium acrylate Homogeneous phase mixing of 4 parts, then be added to the water and be made into the suspension liquid that concentration is 90g/L, at 40 DEG C, stir 10 minutes, thus by sodium acrylate graft copolymerization at weathered coal on the surface, dry, pulverize to 150-180 order in 70 degrees Celsius afterwards obtains stand-by;
(4) by the finess disintegrating of black alum, most 150-180 order is stand-by;
(5) trace compound is mixed by the borax of 5-7 part ammonium molybdate, 20-30 part, the zinc sulfate of 10-15 part by weight, and the fineness of trace compound is 150-180 order;
(6) by weight, black alum 1-2 part in weathered coal-sodium polyacrylate mixture 1-3 part, (4) in phosphogypsum 1-3 part in (1), the attapulgite 4-5 part in (2), (3) and the trace compound 1-2 part Homogeneous phase mixing in (5) are obtained this modifying agent, the modifying agent obtained evenly is spread fertilizer over the fields on water paddy soil surface according to every mu of 15-20kg consumption, then ploughs.
CN201510167953.1A 2015-04-10 2015-04-10 Improvement method for saline-alkali soil rice planting Pending CN104845637A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106165570A (en) * 2016-07-11 2016-11-30 山东胜伟园林科技有限公司 A kind of method utilizing desulfurated plaster improvement Rice Cropping salt-soda soil under Sprinkler Irrigation
CN106233856A (en) * 2016-07-15 2016-12-21 山东胜伟园林科技有限公司 A kind of anti-alveolitoid desulfurated plaster is for the modification method of rice terrace

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* Cited by examiner, † Cited by third party
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CN1699507A (en) * 2004-05-21 2005-11-23 中国科学院兰州化学物理研究所 Nutrient-supplying agent for improving high saline soil
CN101012380A (en) * 2007-02-16 2007-08-08 魏凤巢 Salination soil modifying agent composition and use thereof
CN101967071A (en) * 2010-10-20 2011-02-09 南京农业大学 Salt-restraining special fertilizer for seashore solonchak rapes and production process thereof
CN103937507A (en) * 2014-03-31 2014-07-23 高程华 Saline-alkali soil improver as well as preparation method and use method thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106165570A (en) * 2016-07-11 2016-11-30 山东胜伟园林科技有限公司 A kind of method utilizing desulfurated plaster improvement Rice Cropping salt-soda soil under Sprinkler Irrigation
CN106233856A (en) * 2016-07-15 2016-12-21 山东胜伟园林科技有限公司 A kind of anti-alveolitoid desulfurated plaster is for the modification method of rice terrace

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Application publication date: 20150819