CN104845428B - Compositions of additives, adiabatic coating and purposes - Google Patents
Compositions of additives, adiabatic coating and purposes Download PDFInfo
- Publication number
- CN104845428B CN104845428B CN201510295734.1A CN201510295734A CN104845428B CN 104845428 B CN104845428 B CN 104845428B CN 201510295734 A CN201510295734 A CN 201510295734A CN 104845428 B CN104845428 B CN 104845428B
- Authority
- CN
- China
- Prior art keywords
- parts
- microns
- cenosphere
- resin
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 76
- 239000011248 coating agent Substances 0.000 title claims abstract description 72
- 239000000203 mixture Substances 0.000 title claims abstract description 65
- 239000000654 additive Substances 0.000 title claims abstract description 30
- 239000000919 ceramic Substances 0.000 claims abstract description 34
- 239000000843 powder Substances 0.000 claims abstract description 28
- 239000003973 paint Substances 0.000 claims abstract description 25
- 230000005855 radiation Effects 0.000 claims abstract description 25
- 238000009413 insulation Methods 0.000 claims abstract description 16
- 239000011159 matrix material Substances 0.000 claims abstract description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 36
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 30
- 229920005989 resin Polymers 0.000 claims description 30
- 239000011347 resin Substances 0.000 claims description 30
- 239000002245 particle Substances 0.000 claims description 19
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 16
- -1 lithopone Chemical compound 0.000 claims description 16
- 239000004408 titanium dioxide Substances 0.000 claims description 15
- 239000000049 pigment Substances 0.000 claims description 14
- 239000000377 silicon dioxide Substances 0.000 claims description 14
- 239000002270 dispersing agent Substances 0.000 claims description 13
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 239000013530 defoamer Substances 0.000 claims description 10
- 239000000945 filler Substances 0.000 claims description 10
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 claims description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
- 239000000395 magnesium oxide Substances 0.000 claims description 8
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 7
- 229920000178 Acrylic resin Polymers 0.000 claims description 6
- 239000004925 Acrylic resin Substances 0.000 claims description 6
- 241000209094 Oryza Species 0.000 claims description 6
- 235000007164 Oryza sativa Nutrition 0.000 claims description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 6
- 235000009566 rice Nutrition 0.000 claims description 6
- 239000000080 wetting agent Substances 0.000 claims description 6
- 239000011787 zinc oxide Substances 0.000 claims description 6
- 239000012752 auxiliary agent Substances 0.000 claims description 5
- 239000003755 preservative agent Substances 0.000 claims description 5
- 230000002335 preservative effect Effects 0.000 claims description 5
- 238000002310 reflectometry Methods 0.000 claims description 5
- 239000002562 thickening agent Substances 0.000 claims description 5
- 239000005995 Aluminium silicate Substances 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 4
- 229920005749 polyurethane resin Polymers 0.000 claims description 4
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims description 4
- 229920000180 alkyd Polymers 0.000 claims description 3
- 229910052793 cadmium Inorganic materials 0.000 claims description 3
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- ZLFVRXUOSPRRKQ-UHFFFAOYSA-N chembl2138372 Chemical compound [O-][N+](=O)C1=CC(C)=CC=C1N=NC1=C(O)C=CC2=CC=CC=C12 ZLFVRXUOSPRRKQ-UHFFFAOYSA-N 0.000 claims description 3
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000003822 epoxy resin Substances 0.000 claims description 3
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 3
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 3
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 claims description 3
- 229920000647 polyepoxide Polymers 0.000 claims description 3
- 239000010456 wollastonite Substances 0.000 claims description 3
- 229910052882 wollastonite Inorganic materials 0.000 claims description 3
- LRWQWQFSOAMWKT-UHFFFAOYSA-N [Cd].[Mo] Chemical compound [Cd].[Mo] LRWQWQFSOAMWKT-UHFFFAOYSA-N 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 230000029219 regulation of pH Effects 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 abstract description 11
- 229910052749 magnesium Inorganic materials 0.000 abstract description 11
- 150000001875 compounds Chemical class 0.000 abstract description 10
- 229910052708 sodium Inorganic materials 0.000 abstract description 8
- 229910052791 calcium Inorganic materials 0.000 abstract description 6
- 229910052804 chromium Inorganic materials 0.000 abstract description 6
- 229910052802 copper Inorganic materials 0.000 abstract description 6
- 229910052742 iron Inorganic materials 0.000 abstract description 6
- 229910052748 manganese Inorganic materials 0.000 abstract description 6
- 229910052700 potassium Inorganic materials 0.000 abstract description 6
- 239000002994 raw material Substances 0.000 abstract description 6
- 229910052710 silicon Inorganic materials 0.000 abstract description 4
- 239000010703 silicon Substances 0.000 abstract description 4
- 235000010215 titanium dioxide Nutrition 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 150000003839 salts Chemical class 0.000 description 11
- 239000011777 magnesium Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- 239000007864 aqueous solution Substances 0.000 description 7
- 238000001354 calcination Methods 0.000 description 7
- 239000000839 emulsion Substances 0.000 description 7
- 239000011521 glass Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 239000011575 calcium Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- DCKVFVYPWDKYDN-UHFFFAOYSA-L oxygen(2-);titanium(4+);sulfate Chemical compound [O-2].[Ti+4].[O-]S([O-])(=O)=O DCKVFVYPWDKYDN-UHFFFAOYSA-L 0.000 description 5
- 229910000348 titanium sulfate Inorganic materials 0.000 description 5
- 235000014692 zinc oxide Nutrition 0.000 description 5
- 239000004115 Sodium Silicate Substances 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000011651 chromium Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000011572 manganese Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229920000058 polyacrylate Polymers 0.000 description 4
- 235000019795 sodium metasilicate Nutrition 0.000 description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 4
- 229910052911 sodium silicate Inorganic materials 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- QDZRBIRIPNZRSG-UHFFFAOYSA-N titanium nitrate Chemical compound [O-][N+](=O)O[Ti](O[N+]([O-])=O)(O[N+]([O-])=O)O[N+]([O-])=O QDZRBIRIPNZRSG-UHFFFAOYSA-N 0.000 description 4
- 238000012546 transfer Methods 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000003002 pH adjusting agent Substances 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- 229920002367 Polyisobutene Polymers 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000005253 cladding Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 150000002688 maleic acid derivatives Chemical class 0.000 description 2
- 239000011325 microbead Substances 0.000 description 2
- 239000004005 microsphere Substances 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- 229920005573 silicon-containing polymer Polymers 0.000 description 2
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 2
- JMXKSZRRTHPKDL-UHFFFAOYSA-N titanium ethoxide Chemical compound [Ti+4].CC[O-].CC[O-].CC[O-].CC[O-] JMXKSZRRTHPKDL-UHFFFAOYSA-N 0.000 description 2
- WNJSKZBEWNVKGU-UHFFFAOYSA-N 2,2-dimethoxyethylbenzene Chemical compound COC(OC)CC1=CC=CC=C1 WNJSKZBEWNVKGU-UHFFFAOYSA-N 0.000 description 1
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- CFKMVGJGLGKFKI-UHFFFAOYSA-N 4-chloro-m-cresol Chemical class CC1=CC(O)=CC=C1Cl CFKMVGJGLGKFKI-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- ZVXSESPJMKNIQA-YXMSTPNBSA-N Lys-Thr-Pro-Pro Chemical compound NCCCC[C@H](N)C(=O)N[C@@H]([C@H](O)C)C(=O)N1CCC[C@H]1C(=O)N1[C@H](C(O)=O)CCC1 ZVXSESPJMKNIQA-YXMSTPNBSA-N 0.000 description 1
- 241000276489 Merlangius merlangus Species 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- DIFFLMNDXWOKQJ-UHFFFAOYSA-N [K].O[Si](O)(O)O Chemical compound [K].O[Si](O)(O)O DIFFLMNDXWOKQJ-UHFFFAOYSA-N 0.000 description 1
- HGWOWDFNMKCVLG-UHFFFAOYSA-N [O--].[O--].[Ti+4].[Ti+4] Chemical compound [O--].[O--].[Ti+4].[Ti+4] HGWOWDFNMKCVLG-UHFFFAOYSA-N 0.000 description 1
- OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical compound [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000008431 aliphatic amides Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- CJOBVZJTOIVNNF-UHFFFAOYSA-N cadmium sulfide Chemical compound [Cd]=S CJOBVZJTOIVNNF-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000008264 cloud Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- CKKXWJDFFQPBQL-UAIGNFCESA-N diazanium;(z)-but-2-enedioate Chemical compound [NH4+].[NH4+].[O-]C(=O)\C=C/C([O-])=O CKKXWJDFFQPBQL-UAIGNFCESA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- TVHALOSDPLTTSR-UHFFFAOYSA-H hexasodium;[oxido-[oxido(phosphonatooxy)phosphoryl]oxyphosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O TVHALOSDPLTTSR-UHFFFAOYSA-H 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N n-propyl alcohol Natural products CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000005543 nano-size silicon particle Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000001053 orange pigment Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000011224 oxide ceramic Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 230000000191 radiation effect Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 230000011514 reflex Effects 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000019830 sodium polyphosphate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical group 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- UBZYKBZMAMTNKW-UHFFFAOYSA-J titanium tetrabromide Chemical compound Br[Ti](Br)(Br)Br UBZYKBZMAMTNKW-UHFFFAOYSA-J 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- XROWMBWRMNHXMF-UHFFFAOYSA-J titanium tetrafluoride Chemical compound [F-].[F-].[F-].[F-].[Ti+4] XROWMBWRMNHXMF-UHFFFAOYSA-J 0.000 description 1
- HDUMBHAAKGUHAR-UHFFFAOYSA-J titanium(4+);disulfate Chemical class [Ti+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O HDUMBHAAKGUHAR-UHFFFAOYSA-J 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 238000002371 ultraviolet--visible spectrum Methods 0.000 description 1
- YEIGUXGHHKAURB-UHFFFAOYSA-N viridine Natural products O=C1C2=C3CCC(=O)C3=CC=C2C2(C)C(O)C(OC)C(=O)C3=COC1=C23 YEIGUXGHHKAURB-UHFFFAOYSA-N 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of compositions of additives, adiabatic coating and purposes.The compositions of additives of the present invention includes the raw material of following parts by weight：5 20 parts of cladded type ceramic hollow microballon, 5 20 parts of far infrared radiation powder, 5 15 parts of infrared reflecting paint；Wherein, the cladded type ceramic hollow microballon includes cenosphere matrix and clad, and the clad includes following components：1) titanyl compound；2) oxide of silicon；3) oxide of at least two elements in Al, Na, K, Ca, Cr, Mn, Fe, Co, Cu, Mg.The compositions of additives and coating of the present invention has excellent thermal-insulation function.
Description
Technical field
The present invention relates to a kind of compositions of additives, adiabatic coating and purposes, it is used for adiabatic add more particularly, to a kind of
Plus agent composition, the adiabatic coating comprising said composition.
Background technology
Nature is to conduct, convection current and three kinds of modes of radiation earthward object transfer heat energy.In order to slow down or prevent these
Heat transfer in the surfaces externally and internally of building, it is necessary to set heat-insulating material, and reaching improves the purpose of thermal environment and the saving energy.
Adiabatic coating is a kind of widely used Novel heat insulation energy-saving material of construction industry.
In adiabatic coating formula system, except base-material (base resin), auxiliary agent (dispersant, defoamer, coalescents
Deng) beyond, it must also add pigment and filler.These pigment, filler some have and one of three kinds of transfer modes of heat energy phase
The characteristics of correspondence, they provide thermal-insulation function for coating.For example, rutile type titanium white be exactly it is extraordinary to visible ray and
Near infrared light has the white color stuffing that strong reflection is acted on.Far infrared radiation powder then has coating can be by the thermal energy radiation of absorption
Go out to reach the function of quick heat radiating.But in actual applications, they all have thermal-insulation function single limitation relatively, and lead
Hot coefficient is big, without hindrance adiabatic conduction function.
CN103589254A discloses a kind of environment-friendly reflective thermal insulation paint, including weather-proof emulsion, specular reflecting materials,
Hollow glass microbead, hollow ceramic microspheres, nano silicon, nano titanium oxide, coalescents, ultra-violet absorber, water
With other auxiliary agents etc..The thermal insulation paint has certain exterior-wall heat insulation thermal-insulation function, but is due to using undressed
Hollow glass microbead, hollow ceramic microspheres, heat-insulating property can not still meet the requirement of practical application.
CN102391754A discloses a kind of pair of coating modification hollow glass micropearl adiabatic coating, and its raw material includes：Organosilicon
Modified styrene-acrylic emulsion 20%~30%, double coating modification hollow glass micropearls 9%~13%, rutile titanium dioxide 8%
~12%, talcum powder 5%~8%, coarse whiting 17%~23%, ethylene glycol 1.5%~2%, hydroxymethyl cellulose 0.13%~
0.2%, dispersant 0.6%~1%, defoamer 0.35~0.45%, wetting agent 0.15%~0.19%, multifunctional assistant
0.08%~0.13%, coalescents 1.0%~1.5%, water surplus.The hollow glass that the coating is pre-processed using double cladding process
Microballon, complex process, but its heat-insulating property are still needed raising.
The content of the invention
The first object of the present invention is to provide a kind of compositions of additives, and the compositions of additives has excellent thermal insulation
Function.
The second object of the present invention is to provide a kind of adiabatic coating, and the adiabatic coating possesses excellent heat-insulating property.
The third object of the present invention is the purposes that the compositions of additives described in offer is applied in coating, to apply
The heat-insulating property of material is more preferably.
The present invention provides a kind of compositions of additives, and described composition includes the component of following parts by weight：Cladded type is made pottery
5-20 parts of porcelain cenosphere, 5-20 parts of far infrared radiation powder, and 5-15 parts of infrared reflecting paint；Wherein, the cladded type ceramics
Cenosphere includes cenosphere matrix and clad, and the clad includes following components：1) titanyl compound, 2) silicon oxygen
Compound, and the 3) oxide of at least two elements in Al, Na, K, Ca, Cr, Mn, Fe, Co, Cu, Mg.
According to composition of the present invention, it is preferable that described clad includes following components：Titanium dioxide, dioxy
SiClx, aluminum oxide and magnesia.
According to composition of the present invention, it is preferable that the particle diameter of described cenosphere matrix is 40~120 microns,
The thickness of clad is 1~2 micron.
According to composition of the present invention, it is preferable that hemisphere of the far infrared radiation powder under 8-14 micron wave lengths
Emissivity is more than 85%.
According to composition of the present invention, it is preferable that the infrared reflecting paint is anti-under 0.8-2.5 micron wave lengths
Rate is penetrated more than 80%.
According to composition of the present invention, it is preferable that described composition includes the component of following parts by weight：Cladded type
8-16 parts of ceramic hollow microballon, 8-16 parts of far infrared radiation powder, and 5-12 parts of infrared reflecting paint.
According to composition of the present invention, it is preferable that described composition is thermal insulation compositions of additives.
The present invention also provides a kind of adiabatic coating, and the adiabatic coating includes the component of following parts by weight：Base resin 20-
30 parts, 8-24 parts of pigment, 5-35 parts of filler, 2-8 parts of coating additive, 5-20 parts of cladded type ceramic hollow microballon, far infrared radiation
5-20 parts of powder, and 5-15 parts of infrared reflecting paint；Wherein, the cladded type ceramic hollow microballon includes cenosphere matrix and bag
Coating, the clad includes following components：1) titanyl compound, 2) silicon oxide, and 3) selected from Al, Na, K, Ca, Cr,
The oxide of at least two elements in Mn, Fe, Co, Cu, Mg.
According to adiabatic coating of the present invention, it is preferable that described base resin is aqua type resin or solvent-borne type tree
Fat, described aqua type resin is in acrylic resin, organosilicon modified crylic acid resin and Styrene-acrylic copolymer
It is any one or more, described solvent type resin is in fluorocarbon resin, polyurethane resin, epoxy resin and alkyd resin
It is any one or more；Described pigment is selected from titanium dioxide, zinc oxide, lithopone, iron oxide red, toluidine red, cadmium red, molybdenum cadmium
One or more in orange, chrome yellow, iron oxide yellow, chrome green, chrome oxide green, dark green, barba hispanica, phthalocyanine blue, iron oxide black, carbon black；
The one kind or many of described filler in calcium carbonate, talcum powder, kaolin, barium sulfate, silica, wollastonite, mica powder
Kind；Described auxiliary agent is selected from dispersant, wetting agent, thickener, coalescents, defoamer, preservative, levelling agent and pH adjusting agent
In one or more.
The present invention also provides the purposes of above-mentioned compositions of additives, and described composition is applied in adiabatic coating.
Because containing novel cladded type ceramic hollow microballon composition, compositions of additives of the invention is not only to visible ray
There is reflex near infrared light, and centering, far infrared have intense radiation effect, are particularly the hair in 8-14 micrometer features wavelength
The rate of penetrating reaches more than 85%.In addition, the cladded type ceramic hollow microballon of the hollow structure contained by the composition of the present invention is assigned
Coating has iris action to heat transfer.Far infrared radiation powder contained by the composition of the present invention is to remote in atmospheric environment
Infrared emanation has the strong transmitting effect in 8-14 micron of characteristic wavelength, the heat energy Rapid radiating of coating absorption is gone out.This
Outside, the infrared reflecting paint contained by composition of the invention has strong reflection effect for visible ray and near infrared light.This hair
Bright composition simultaneously comprising above-mentioned three kinds of components, can by air thermal source (near-infrared thermal source in sunshine and
The mid and far infrared radiant heat source of surrounding environment) material list for the coating for being coated with the composition comprising the present invention is barred from longer
Face, makes the material surface form preferably " thermal insulation " coating.
The compositions of additives of the present invention can be sufficiently mixed with various basic coatings of different nature, while not changing base
Other physical and chemical properties of plinth coating.The compositions of additives of the present invention is suitable in various adiabatic coatings, especially fits
For adiabatic coating for building.When the adiabatic coating of the present invention is painted on the surface on external wall and roof, it can hinder first
Near infrared ray (0.8-2.5 microns) thermal source of exterior wall surface from sunshine is kept off to enter in wall.When remote red in surrounding environment
When external sort algorithm is absorbed by the coating, the coating distributes heat with strong into air " infrared window " (8-14 microns)
Effect, so that exterior wall surface fast cooling.
Embodiment
Not therefore the embodiment to the present invention is described in further details below, but protection scope of the present invention
It is any way limited.
" cladded type ceramic hollow microballon " of the present invention refers to the cenosphere that clad is ceramic material.
Unless specifically stated otherwise, " part " of the invention represents parts by weight.
<Compositions of additives>
The compositions of additives of the present invention includes 5-20 part of cladded type ceramic hollow microballon, 5-20 parts of far infrared radiation powder with
5-15 parts of infrared reflecting paint.Preferably, compositions of additives of the invention is composed of the following components：Cladded type ceramic hollow is micro-
5-20 parts of pearl, 5-20 parts of far infrared radiation powder, 5-15 parts of infrared reflecting paint.According to the preferred embodiment of the present invention, cladding
The consumption of type ceramic hollow microballon is preferably 8-16 parts, more preferably 9-13 parts；The consumption of far infrared radiation powder is preferably 8-16
Part, more preferably 9-13 parts；The consumption of infrared reflecting paint is preferably 5-12 parts, more preferably 6-9 parts.
The cladded type ceramic hollow microballon of the present invention includes cenosphere matrix and clad.The cenosphere base of the present invention
Body can be hollow glass bead or ceramic hollow microballon, preferably ceramic hollow microballon.The present invention hollow glass bead or
Ceramic hollow microballon can use those known in the art, commercially can freely buy.
In the present invention, the particle diameter of described cenosphere matrix can be 40~120 microns.Above-mentioned particle diameter represents hollow
The average grain diameter of microballon, is measured using sieve method.The cenosphere matrix of the present invention can include at least two particle diameters
Cenosphere, preferably includes the cenosphere of three kinds of particle diameters.The particle diameter of three kinds of cenospheres is respectively 40~60 microns, 70~90
Micron and 100~120 microns；Preferably, the particle diameter of three kinds of cenospheres is respectively 40~50 microns, 80~90 microns and 110
~120 microns；It is highly preferred that the particle diameter of three kinds of cenospheres is respectively 40~45 microns, 80~85 microns and 105~120 micro-
Rice.The cenosphere matched somebody with somebody using above-mentioned level can form most fine and close hollow coating, increase to different wave length sun luminous reflectanc,
So as to play a part of adiabatic conduction.
In the present invention, the thickness of the clad of the cladded type ceramic hollow microballon can be 1~2 micron, be preferably
1.2~1.8 microns.The clad is the clad of ceramic base.The clad includes following components：1) titanyl compound；
2) oxide of silicon；3) oxide of at least two elements in Al, Na, K, Ca, Cr, Mn, Fe, Co, Cu, Mg.
The component 1 of the present invention) it is titanyl compound, usually titanium dioxide.Titanium dioxide is by calcining corresponding salt
Class material is obtained.
The component 2 of the present invention) be silicon oxide, usually silica.Silica is by calcining corresponding salt
Class material (such as silicate) is obtained.
The component 3 of the present invention) at least two elements in Al, Na, K, Ca, Cr, Mn, Fe, Co, Cu, Mg oxidation
Thing.These oxides are obtained by calcining corresponding salts substances.The component 3 of the present invention) it preferably is selected from Al, Mg, Na
The oxide of the oxide of at least two elements, more preferably two comprising Al, Mg kind element.It is specific real according to one of the present invention
Apply mode, component 3 of the invention) include aluminum oxide and magnesia.
According to the specific embodiment of the present invention, clad of the invention preferably include titanium dioxide, silica,
Aluminum oxide and magnesia.The clad of the present invention is more preferably made up of following components：Titanium dioxide, silica, aluminum oxide and
Magnesia.
Method acquisition can be prepared by the following procedure in the cladded type ceramic hollow microballon of the present invention：1) cenosphere matrix is added
In the compound water solution for entering titanium, regulation pH is 9-10, be preferably 9.5-10 after add silicate solutions, stirring 20-60 minutes,
It is preferred that 30-60 minutes, pH is adjusted outside heating is added to 3-4,3.5-4, then stirred with 30-80 revs/min of mixing speed
Mix 40-90 minutes, preferably 60-80 minutes, ultrasonic vibration is sufficiently mixed uniformly while stirring, is then adjusted pH to 7 and is obtained
Primary product.2) by step 1) Primary product calcined to form cladded type ceramic hollow microballon.Calcining can be divided into two
The individual stage is carried out：It is 350~500 DEG C, is preferably 400~450 DEG C and calcines 2-4 hours in calcining heat, then heat to 550~
700 DEG C, preferably 600~650 DEG C are calcined 2-3 hours.Product after calcining is come out of the stove, and natural cooling obtains product.In the present invention
In, it is preferable that the compound water solution of titanium can be titanium sulfate aqueous solution, the Titanium Nitrate aqueous solution, the halide solution of titanium；It is excellent
Elect titanium sulfate aqueous solution, more preferably the Titanium Nitrate aqueous solution, titanium sulfate aqueous solution as.In the present invention, the halide of titanium includes
But it is not limited to titanium chloride, titanium bromide, titanium fluoride.In the present invention, it is preferred to, described silicate can be sodium metasilicate, silicic acid
Potassium etc., preferably sodium metasilicate.In the present invention, it is preferred to, the outside heating be selected from Al, Na, K, Ca, Cr, Mn, Fe, Co,
The water soluble salt of at least two elements in Cu, Mg.Preferably, the outside heating can be in Al, Na, Mg at least
The water soluble salt of two kinds of elements, the more preferably salt including Al, Mg.The above-mentioned salt of the present invention is water-soluble salt, is, for example,
Sulfate, hydrochloride, nitrate, phosphate etc., it is preferable that described salt is hydrochloride, nitrate etc..According to the one of the present invention
Individual embodiment, the outside heating includes aluminum halide and magnesium halide, such as aluminium chloride and magnesium chloride.
The far infrared radiation powder of the present invention is preferably that the hemispherical emissivity under 8-14 micron wave lengths is more than 85%, preferably greatly
In 90%.The far infrared radiation powder of the present invention can be conventional commercial product.The far infrared radiation powder of the present invention can also serve as reasons
The product that aluminum oxide, silica, magnesia, zinc oxide are obtained through synthesis in solid state.
Reflectivity of the infrared reflecting paint of the present invention under near-infrared (0.8-2.5 microns) wavelength is preferably greater than 80%,
More preferably greater than 85%.The infrared reflecting paint of the present invention can be using conventional commercially available prod.The infrared external reflection face of the present invention
Material can also be coated with silica titanium dioxide granule.
According to the preferred embodiment of the present invention, compositions of additives of the invention is only micro- by above-mentioned cladded type ceramic hollow
Pearl, three kinds of component compositions of far infrared radiation powder and infrared reflecting paint.
The preparation method of compositions of additives of the present invention is method commonly used in the art, for example can be by by each group
Part is mixed to get.
The compositions of additives of the present invention can be added to any synthetic resin emulsion basic coating or solvent-borne type base
In plinth coating, make coating that there is excellent heat-insulating property.Meanwhile, compositions of additives of the invention can be with various heterogeneitys
Basic coating be sufficiently mixed, and do not change other physical and chemical properties of basic coating.
<Adiabatic coating>
The adiabatic coating of the present invention includes basic coating and above-mentioned compositions of additives.The adiabatic coating of the present invention includes
The component of following parts by weight：20-30 parts of base resin；8-24 parts of pigment；5-35 parts of filler；2-8 parts of coating additive；Cladded type is made pottery
5-20 parts of porcelain cenosphere；5-20 parts of far infrared radiation powder；With 5-15 parts of infrared reflecting paint.Implemented according to currently preferred
Mode, the adiabatic coating contains the component of following parts by weight in：20-30 parts of resin；8-18 parts of pigment；10-32 parts of filler；
2-8 parts of coating additive；8-16 parts of ceramic hollow microballon；8-16 parts of far infrared radiation powder；With 5-12 parts of infrared reflecting paint.Optionally
Ground, adiabatic coating of the invention also includes 20-40 parts of water or organic solvent.
In the present invention, the base resin can be aqua type resin or solvent type resin, and according to the type of resin
Selection is used as solvent (decentralized medium) using water or organic solvent.When from aqua type resin, aqua type resin dispersion is in water
Middle basis of formation resin emulsion, or directly use aqua type resin emulsion.The aqua type resin of the present invention is selected from acrylic resin, had
Any of machine fluorine-silicon modified acrylic resin and Styrene-acrylic copolymer or any mixture.Preferably, it is of the invention
Aqua type resin is selected from any of acrylic resin, organosilicon modified crylic acid resin or the mixture of the two.The present invention
Solvent type resin be selected from any of fluorocarbon resin, polyurethane resin, epoxy resin and alkyd resin or any mixture.
Organic solvent can select those commonly used in the art, repeat no more.
In the present invention, the pigment is selected from this area any conventional use of coating pigment or pigment composition.For example,
Chinese white：Titanium dioxide, zinc oxide, lithopone；Red pigment：Iron oxide red, toluidine red, cadmium red etc.；Orange pigment：Molybdenum
Cadmium orange；Yellow uitramarine chrome yellow, iron oxide yellow, Fast Yellow G；Viridine green：Chrome green, chrome oxide green, dark green etc.；Blue face
Material：Barba hispanica, ultramarine, phthalocyanine blue etc.；Black pigment：Iron oxide black, carbon black etc.；Or the mixture of above-mentioned various pigment.In addition, can also adopt
With commercially available various mill bases.Preferably, the pigment uses titanium dioxide, more preferably rutile type titanium white.
In the present invention, the filler is selected from calcium carbonate, talcum powder, kaolin, barium sulfate, silica, wollastonite, cloud
One kind or any combination in female powder.According to the preferred embodiment of the present invention, the filler is in kaolin or calcium carbonate
Any or mixture of the two.
In the present invention, the auxiliary agent is selected from dispersant, wetting agent, thickener, coalescents, defoamer, preservative, stream
Any of flat agent and pH adjusting agent or its any combination.
The dispersant of the present invention can be those commonly used in the art, for example, may be selected from inorganic dispersant, organic point
Powder or high polymer dispersant.The inorganic dispersant such as Quadrafos, such as calgon, sodium polyphosphate are (for example
Calgon N, German BK Giulini chemical companies product), PTPP (KTPP) and tetrapotassium pyrophosphate (TKPP).It is described
Organic dispersing agent such as polyacrylate, polystyrene/maleic acid salt, polyisobutene maleic acid salt and
AMP-95 (2- amino-2-methyl 1- propyl alcohol) etc..Salt described in the organic dispersing agent is preferably sodium salt and ammonium salt.According to this hair
It is bright preferred embodiment, the dispersant be ammonium salt dispersant, such as ammonium polyacrylate salt, polystyrene/maleic acid
Ammonium salt, polyisobutene maleic acid ammonium salt.
The present invention wetting agent selected from polysiloxanes, polysiloxane polyether copolymer, Organic fluoride in polymer-modified one
Plant or arbitrary composition.BYK-306, BYK- of commercial goods, such as BYK chemical companies of Germany may be selected in the wetting agent of the present invention
307th, the product such as BYK-330, BYK-333, BYK-341, BYK-344, BYK-310.
The thickener of the present invention is selected from inorganic thickening agent (such as bentonite, attapulgite), cellulose family (such as hydroxyl second
Element, carboxymethyl cellulose etc.), polyacrylate (polyacrylic acid saline solution and acrylic acid ester emulsion), association type polyurethane
Thick dose, association type PPG etc..
The coalescents of the present invention are selected from Lauryl Alcohol ester (also known as alcohol ester 12), ethylene glycol phenyl ether, propane diols phenylate, two different
One kind or any mixture in butyl dibasic acid ester.Preferably, the coalescents use Lauryl Alcohol ester.
The present invention defoamer be nonionic surface active agent, may be selected mineral oil antifoam agent, organic silicon defoamer and
Not any of silicon-containing polymer defoamer.The mineral oil antifoam agent of the present invention is generally by groups such as carrier, activating agent, solvents
Into.Carrier is water, hydrocarbon ils, fatty alcohol etc.；Activating agent is selected from wax, silicone oil, aliphatic amide, fatty acid ester, high average molecular matter
Measure polyethylene glycol, natural oil, metallic soap, hydrophobic silica etc..The organic silicon defoamer of the present invention includes poly dimethyl
Siloxanes or modified dimethyl polysiloxane.The example of the not silicon-containing polymer class defoamer of the present invention is polyether type polymer.
The preservative of the present invention can select the conventional preservative in this area, preferably 3- methyl -4- chloro-phenols.
The example of the pH adjusting agent of the present invention is 2-amino-2-methyl-1-propanol, ammoniacal liquor etc..
The levelling agent of the present invention can be modified polyorganosiloxane (such as Levaslip 432, Elementis companies), poly- third
Olefin(e) acid ester (such as BYK-S706, German BYK chemical companies), acrylate copolymer (such as BYK-350, BYK-356,
BYK-359, BYK-361N, German BYK chemical companies), (such as BYK-388, German BYK chemistry are public for fluorine richness polyacrylate
Department).
The adiabatic coating of the present invention can be obtained by conventional method, such as above-mentioned each component is well mixed.
<The purposes of compositions of additives>
The compositions of additives of the present invention may apply in various coating, for example, can be added to outer surface of building
Heat reflection adiabatic coating, metal base outer surface heat reflection adiabatic coating, roof color steel tile surface heat reflection adiabatic coating,
Oil storage tank outer surface heat reflection adiabatic coating, air accumulator outer surface heat reflection adiabatic coating, rail truck outer surface heat
Reflective insulation coating, outer surface of automobile heat reflection adiabatic coating, ship outer surface heat reflection adiabatic coating etc..
Below by way of specific embodiment, the present invention is described in detail.
<Method of testing>
Following preparation example, the method for testing of embodiment are described as follows：
According to standard GB/T/T 25261-2010《Reflective heat-insulation paint for building》The coating of following examples is carried out
Traditional performance is tested.
According to People's Republic of China (PRC) building industry professional standard JG/T 235-2008《Architectural reflective heat-insulation paint》Rule
Fixed " the heat-insulated temperature difference " to coating is tested.
According to People's Republic of China (PRC) professional standard JGJ/T 287-2014《Buildings Heat Reflection coating saves examination criteria》
(implementing from 1 day June in 2015) is tested the sun reflectivity and hemispherical emissivity of coating.The test of hemispherical emissivity is adopted
Use infrared spectrophotometer.
According to People's Republic of China (PRC) building industry professional standard JG/T 235-2014《Architectural reflective heat-insulation paint》Rule
The fixed near-infrared reflection ratio to coating is tested.
According to standard GB/T/T 10294-88《Technology of Steady State Thermal Resistance of Thermal Insulating Material and the measure Guarded hot plate about characteristic》
Make the test of adiabatic coating thermal conductivity factor.
Adiabatic coating spectrophotometric data (8-14 micron wavebands emissivity) uses ET10 portable infrared spectral emissivities
Instrument (Beijing An Zhou Science and Technology Ltd.s) is measured.
<Raw material explanation>
Following preparation example, the raw material of embodiment are described as follows：
Polyurethane resin：Guangdong waterproof Yue Feng building materials Co., Ltd component A, Guangdong is high by 911；
Silicone acrylic emulsion：Shanghai Bao Lijia Chemical Co., Ltd.s, BLJ-KD96；
Siloxane-Oxyalkylene Copolymers：Guangzhou Si Luoke Chemical Co., Ltd, Silok 304；
Far infrared radiation powder, preparation method is as follows：
By aluminum oxide, silica, magnesia, zinc oxide according to weight ratio be 40:40:10:10 are weighed, and mixing is obtained
Compound；The compound is through 16 hours (compounds of wet ball grinding：Ball：Water weight ratio is 1:2:1.5) after, 1300~1400
Synthesis in solid state 4 hours at DEG C, obtain transition metal oxide ceramics, are cooled to room temperature, grind to form fine powder, sieve, obtain after burning till
To the far infrared radiation powder (particle diameter is 10-30 μm).
Infrared reflecting paint, preparation method is as follows：
1) tetraethyl titanate is dissolved among ethanol, is configured to 6wt.% solution A；Prepare 0.1M Lutensol
ON50 (BASF) aqueous surfactant solutions B；Take solution B to be dissolved among ethanol, be configured to the solution that concentration is 0.7wt.%
C；Solution A is uniformly mixed with solution C, mixing quality ratio is 1:3, this mixed solution is heated to react 3h at 60 DEG C, afterwards
Product is centrifuged, wash, dried, titanium dioxide granule is finally given.
2) by titanium dioxide granule by ultrasonic disperse among ethanol, be prepared into concentration be 1wt% dispersion liquid, afterwards
Ammoniacal liquor is added as catalyst, the ratio that catalyst accounts for gross mass is 1.5wt%, is eventually adding tetraethoxysilane to titanium dioxide
Titanium is coated, and reaction temperature is 50 DEG C, and product is centrifuged, washed, dried by reaction time 3h, is calcined at 450 DEG C
2h, obtains the particle of coated with silica titanium dioxide.The median of the particle is 1.2 μm, under 0.8-2.5 micron wave lengths
Reflectivity be 86.5%.
Other raw materials are commercially available prod.
Preparation example 1
By titanium sulfate aqueous solution is added according to the ceramic hollow microballon being well mixed shown in table 1, (58 parts of titanium sulfates add 500
The aqueous solution of part industrial tap water formation) in fully soak, then add sodium hydroxide regulation pH to 10；It is sufficiently mixed uniform add
Enter sodium metasilicate to stir 30 minutes；Magnesium chloride and aluminium chloride are sequentially added after pH is adjusted into 4 again, with 60 revs/min of mixing speed
Stirring 60 minutes, ultrasonic vibration while stirring；Then use in sodium hydroxide and pH to 7, continue to stir 60 minutes, filter, wash
Wash, dry after move into high-temperature resistant container, be placed in high temperature resistance furnace calcine, calcining heat be 400 DEG C at calcine 4 hours, so
After be warming up to 600 DEG C and calcine 2 hours, natural cooling of coming out of the stove obtains cladded type ceramic hollow microballon, and coating thickness is 1.5 micro-
Rice.
Table 1
| Raw material | Consumption (parts by weight) |
| Ceramic hollow microballon 1 (40 microns) | 20 |
| Ceramic hollow microballon 2 (80 microns) | 15 |
| Ceramic hollow microballon 3 (120 microns) | 15 |
| Titanium sulfate | 58 |
| Sodium metasilicate | 5 |
| Magnesium chloride | 5 |
| Aluminium chloride | 2 |
| Industrial deionized water | 500 |
Embodiment 1- solvent-borne type adiabatic coatings
<Dispensing information>
First component：
Component B：
Hexamethylene group diisocyanate.
First component：Component B=13:1.
Above-mentioned each component is stirred scattered, stirring toning, the examination and test of products, filtering, packaging.
Embodiment 2- aqua type adiabatic coatings
<Dispensing information>
By above-mentioned each component be stirred it is scattered, mix colours, filter and package.
The performance test results of above-described embodiment 1 and the adiabatic coating of embodiment 2 are shown in Table 2 and table 3 respectively.
Table 2
Table 3
Claims (10)
1. a kind of compositions of additives, it is characterised in that described composition includes the component of following parts by weight：
5-20 parts of cladded type ceramic hollow microballon,
5-20 parts of far infrared radiation powder, and
5-15 parts of infrared reflecting paint；
Wherein, the cladded type ceramic hollow microballon includes cenosphere matrix and clad；Described clad includes following
Component：Titanium dioxide, silica, aluminum oxide and magnesia, the thickness of the clad is 1~2 micron；Described is hollow micro-
Pearl matrix includes the cenosphere of three kinds of particle diameters, the particle diameter of the cenosphere be respectively 40~60 microns, 70~90 microns and
100~120 microns；
Wherein, hemispherical emissivity of the far infrared radiation powder under 8-14 micron wave lengths is more than 85%；
Wherein, reflectivity of the infrared reflecting paint under 0.8-2.5 micron wave lengths is more than 80%.
2. composition according to claim 1, it is characterised in that described composition includes the component of following parts by weight：
8-16 parts of cladded type ceramic hollow microballon,
8-16 parts of far infrared radiation powder, and
5-12 parts of infrared reflecting paint.
3. composition according to claim 1, it is characterised in that the particle diameter of the cenosphere is respectively 40~50 micro-
Rice, 80~90 microns and 110~120 microns.
4. composition according to claim 1, it is characterised in that the particle diameter of the cenosphere is respectively 40~45 micro-
Rice, 80~85 microns and 105~120 microns.
5. the composition according to any one of Claims 1 to 4, it is characterised in that described composition adds for thermal insulation
Agent composition.
6. a kind of adiabatic coating, it is characterised in that the adiabatic coating includes the component of following parts by weight：
20-30 parts of base resin,
8-24 parts of pigment,
20-35 parts of filler,
2-8 parts of coating additive,
5-20 parts of cladded type ceramic hollow microballon,
5-20 parts of far infrared radiation powder, and
5-15 parts of infrared reflecting paint；
Wherein, the cladded type ceramic hollow microballon includes cenosphere matrix and clad, and described clad includes following
Component：Titanium dioxide, silica, aluminum oxide and magnesia, the thickness of the clad is 1~2 micron；Described is hollow micro-
Pearl matrix includes the cenosphere of three kinds of particle diameters, the particle diameter of the cenosphere be respectively 40~60 microns, 70~90 microns and
100~120 microns；
Wherein, hemispherical emissivity of the far infrared radiation powder under 8-14 micron wave lengths is more than 85%；
Wherein, reflectivity of the infrared reflecting paint under 0.8-2.5 micron wave lengths is more than 80%.
7. adiabatic coating according to claim 6, it is characterised in that the particle diameter of the cenosphere is respectively 40~50 micro-
Rice, 80~90 microns and 110~120 microns.
8. adiabatic coating according to claim 6, it is characterised in that the particle diameter of the cenosphere is respectively 40~45 micro-
Rice, 80~85 microns and 105~120 microns.
9. the adiabatic coating according to any one of claim 6~8, it is characterised in that：
Described base resin is aqua type resin or solvent type resin, and described aqua type resin is selected from acrylic resin, had
Any of machine fluorine-silicon modified acrylic resin and Styrene-acrylic copolymer are a variety of, and described solvent type resin is selected from
Any of fluorocarbon resin, polyurethane resin, epoxy resin and alkyd resin are a variety of；
Described pigment be selected from titanium dioxide, zinc oxide, lithopone, iron oxide red, toluidine red, cadmium red, molybdenum cadmium orange, chrome yellow,
One or more in iron oxide yellow, chrome green, chrome oxide green, dark green, barba hispanica, phthalocyanine blue, iron oxide black, carbon black；
The one kind of described filler in calcium carbonate, talcum powder, kaolin, barium sulfate, silica, wollastonite, mica powder
Or it is a variety of；
Described auxiliary agent is selected from dispersant, wetting agent, thickener, coalescents, defoamer, preservative, levelling agent and pH regulations
One or more in agent.
10. the purposes of the composition according to any one of Claims 1 to 5, it is characterised in that described composition is applied to
In adiabatic coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510295734.1A CN104845428B (en) | 2015-06-02 | 2015-06-02 | Compositions of additives, adiabatic coating and purposes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510295734.1A CN104845428B (en) | 2015-06-02 | 2015-06-02 | Compositions of additives, adiabatic coating and purposes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104845428A CN104845428A (en) | 2015-08-19 |
| CN104845428B true CN104845428B (en) | 2017-10-31 |
Family
ID=53845436
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510295734.1A Active CN104845428B (en) | 2015-06-02 | 2015-06-02 | Compositions of additives, adiabatic coating and purposes |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104845428B (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107446163A (en) * | 2017-07-17 | 2017-12-08 | 太原理工大学 | A kind of coal fly ash hollow micro bead Surface coating nano-sized magnesium hydroxide composite powder material and preparation method thereof |
| CN109135482B (en) * | 2018-06-29 | 2020-10-13 | 安徽天锦云漆业有限公司 | Environment-friendly anti-aging exterior wall coating |
| CN109065815B (en) * | 2018-08-14 | 2022-03-15 | 宜春清陶能源科技有限公司 | Functional ceramic and attapulgite characteristic combined coating diaphragm and preparation process thereof |
| CN109251619A (en) * | 2018-09-17 | 2019-01-22 | 浙江纺织服装职业技术学院 | Water-thinned wall paint and preparation method thereof |
| CN111410856A (en) * | 2020-03-27 | 2020-07-14 | 河南宣和钧釉环保材料有限公司 | Inorganic reflective heat-insulating coating and preparation method thereof |
| CN111544607A (en) * | 2020-05-11 | 2020-08-18 | 常州市金坛区人民医院 | Disinfection cabinet for hospital |
| CN112341914A (en) * | 2020-11-04 | 2021-02-09 | 中建二局第一建筑工程有限公司 | Heat insulation coating and preparation method thereof |
| CN112708293A (en) * | 2021-01-12 | 2021-04-27 | 上海涂固安高科技有限公司 | Formula of oil-water dual-purpose heat-insulation composite material powder |
| CN113462272B (en) * | 2021-06-15 | 2022-04-19 | 厦门双瑞船舶涂料有限公司 | Heat-insulating radiation-proof coating and preparation method thereof |
| CN114437625A (en) * | 2022-02-28 | 2022-05-06 | 陈军 | Heat-insulation nano coating and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101824270B (en) * | 2010-04-30 | 2012-07-11 | 长沙新凯化工有限公司 | Waterborne heat-insulating flame-retardant multifunctional nano coating and preparation method thereof |
| CN102352160B (en) * | 2011-11-17 | 2013-08-14 | 上海材料研究所 | Water-based thermal-insulation paint for cement encaustic tiles and roofs and preparation method thereof |
| CN104496328A (en) * | 2014-12-31 | 2015-04-08 | 上海墙特节能材料有限公司 | Inorganic dry powder reflective heat insulating coating |
-
2015
- 2015-06-02 CN CN201510295734.1A patent/CN104845428B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN104845428A (en) | 2015-08-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104845428B (en) | Compositions of additives, adiabatic coating and purposes | |
| CN104861757B (en) | Cladded type ceramic hollow microballon and method and purposes | |
| CN105331220B (en) | A kind of composite metal roof insulation water-repellent paint and preparation method thereof | |
| CN102352160B (en) | Water-based thermal-insulation paint for cement encaustic tiles and roofs and preparation method thereof | |
| CN102391754B (en) | Double-coated hollow glass microbead heat-insulated coating and preparation method thereof | |
| CN106700789A (en) | Waterborne energy-saving building coating and preparation method thereof | |
| CN101423686B (en) | Solvent type heat insulation fluorocarbon exterior wall coating | |
| Thongkanluang et al. | Preparation of NIR reflective brown pigment | |
| WO2017028471A1 (en) | Water-based reflective heat-insulating faux stone texture coating system for construction and preparation method thereof | |
| CN106398405B (en) | Interior wall heat-insulating coating and preparation method and application thereof | |
| CN106380977A (en) | Hydrophobic heat-insulation coating and preparation method therof | |
| CN105860717B (en) | Colour reflective insulating moulding coating and its preparation, construction method | |
| CN106084962A (en) | Adiabatic compositions of additives and purposes | |
| CN105176211A (en) | Organic-inorganic composite thermal insulation paint and preparation method thereof | |
| CN105086560B (en) | Heat reflectivity, imitation stone effect coating system | |
| CN106007571A (en) | Inorganic dry powder heat insulation paint | |
| CN102719153A (en) | Reflective heat insulation coating and preparation method thereof | |
| CN106380972A (en) | Colorful multi-layer paint with thermal insulation function and preparation method thereof | |
| CN104530889A (en) | Heat-insulating heat-preserving coating and preparation method thereof | |
| CN105602329A (en) | Heat-reflection thermal insulation anti-corrosion coating and preparation method thereof | |
| CN100547038C (en) | A kind of preparation method of titania-silica color glaze pigment-filler for ceramic | |
| CN108102482A (en) | A kind of reflective heat-insulation paint and preparation method thereof | |
| CN1318523C (en) | Process for preparing thermal-insulating coating | |
| CN108659657A (en) | A kind of building external paint and its application | |
| CN111073422A (en) | Water-based reflective heat-insulating coating for buildings and processing method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| EXSB | Decision made by sipo to initiate substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160527 Address after: 210036, room 4, 2206 moonlight Plaza, Gulou District, Nanjing, Jiangsu, Longjiang Applicant after: Zhao Shilin Applicant after: Zhou Haiyan Address before: 210036, room 4, 2206 moonlight Plaza, Gulou District, Nanjing, Jiangsu, Longjiang Applicant before: Zhao Shilin |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20201201 Address after: 226300, Jiangsu, Nantong, Tongzhou District Town, West Court cotton industry zone Patentee after: NANTONG LEJIA PAINT Co.,Ltd. Address before: 210036, room 4, 2206 moonlight Plaza, Gulou District, Nanjing, Jiangsu, Longjiang Patentee before: Zhao Shilin Patentee before: Zhou Haiyan |
|
| TR01 | Transfer of patent right |