CN104831541B - Visible infrared anti-false shipping mark and preparation method thereof - Google Patents

Visible infrared anti-false shipping mark and preparation method thereof Download PDF

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Publication number
CN104831541B
CN104831541B CN201510218399.5A CN201510218399A CN104831541B CN 104831541 B CN104831541 B CN 104831541B CN 201510218399 A CN201510218399 A CN 201510218399A CN 104831541 B CN104831541 B CN 104831541B
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Prior art keywords
visible
false
shipping mark
visible red
infrared anti
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CN104831541A (en
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王国忠
程福奎
薛矛
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Guangdong Kangpai Huanchuang Technology Co ltd
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Guangdong Esquel Textiles Co Ltd
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Abstract

The invention discloses infrared anti-false shipping mark seen from one, including base material, being coated with the outer security coating of visible red on described base material, the raw material composition of the percentage by weight of the outer security coating of described visible red is as follows: the outer anti-counterfeiting combination 0.1 3% of visible red, anti-settling agent 0.3 1%, ink or polyurethane coating or acrylate paint 96 99.6%;The outer anti-counterfeiting combination of described visible red is made up of sodium fluoride, yttrium fluoride and fluorination ytterbium.The present invention uses the outer security coating of specific visible red, the button prepared is under the Infrared irradiation of 980nm specific wavelength, macroscopic obvious bright spot can be produced, this bright spot is not that the strongest open air can recognize at daylight lamp and light, without identifying in dark surrounds, there is good antifalse effect.

Description

Visible infrared anti-false shipping mark and preparation method thereof
Technical field
The present invention relates to garment accessories technical field, particularly relate to infrared anti-false shipping mark and preparation side thereof seen from one Method.
Background technology
At present, most of reputable brand owners all put in the construction of brand image and value the substantial amounts of time and Huge financial resources, but low-quality goods infringement brand image damage brand value so that brand owner suffers heavy losses.The opposing party Face, the raising of production technology and universal fraud threshold is reduced day by day, high-tech development makes common anti-counterfeiting technology hands Section becomes easily to imitate and crack.As noctilucence is false proof, Ultraluminescence is false proof, the counterfeit protection measures that the false proof grade of temperature sensing color changing is common, institute The raw material of the anti-fake scheme implemented is easy to get, and is easily cracked and copys.Particularly in clothing and garment accessories field, the brand of personation Clothing are becoming increasingly rampant and brand business there is no effective anti-counterfeit recognition means.Patent application (publication number cn101864605A, Publication date 20101020) disclose a kind of near-infrared absorption counterfeit fiber and preparation method thereof, disclose a kind of employing near-infrared The method of anti-false fiber prepared by absorbing material, it is provided that a kind of anti-counterfeit recognition means.
It is therefore desirable to take more effective anti-counterfeiting technology.
Summary of the invention
Based on this, it is an object of the invention to provide infrared anti-false shipping mark seen from one.
Concrete technical scheme is as follows:
A kind of visible infrared anti-false shipping mark, including base material, described base material is coated with the outer security coating of visible red, described can The raw material composition of the percentage by weight of the outer security coating of show is as follows:
Outer anti-counterfeiting combination 0.1-3% of visible red
Anti-settling agent 0.3-1%
Ink or polyurethane coating or acrylate paint 96-99.6%;
The outer anti-counterfeiting combination of described visible red is made up of sodium fluoride, yttrium fluoride and fluorination ytterbium.
Wherein in an embodiment, the outer anti-counterfeiting combination of described visible red is 18.5~21.5:56.0 by weight part ratio ~the sodium fluoride of 58.0:20.5~25.5, yttrium fluoride and fluorination ytterbium composition.
An embodiment is marine wherein, and described ink is nylon ink, water-based polyurethane ink or UV ink.
Wherein in an embodiment, described anti-settling agent be castor oil derivative, organic modified bentonite, Tissuemat E, Superfine silicon dioxide or montmorillonite organic derivative.
Wherein in an embodiment, the material of described base material is selected from cotton, woven dacron or cotton-polyester blend cloth.
It is a further object of the present invention to provide the preparation method of above-mentioned visible infrared anti-false shipping mark.
Concrete technical scheme is as follows:
The preparation method of above-mentioned visible infrared anti-false shipping mark, comprises the steps:
(1) base material is carried out pretreatment, it is ensured that substrate surface is the most pollution-free;
(2) by each component mixing and stirring in outer for above-mentioned visible red security coating, employing silk screen printing or spraying Mode is coated in described substrate surface, i.e. obtains described visible infrared anti-false shipping mark after natural drying.
Wherein in an embodiment, the thickness of the outer security coating of described visible red is 10-100 μm.
Beneficial effects of the present invention is as follows:
The present invention uses the outer security coating of specific visible red, and the button prepared is infrared 980nm specific wavelength Under light irradiates, can produce macroscopic obvious bright spot, this bright spot can in the open air that daylight lamp and light are not the strongest Recognize, it is not necessary to identify in dark surrounds, there is good antifalse effect.
Accompanying drawing explanation
Fig. 1 is the structural representation of infrared anti-false shipping mark seen from embodiment 1;
Fig. 2 is the photo figure in 980nm infrared light detection of the infrared anti-false shipping mark seen from embodiment 1;
Fig. 3 is the photo figure in 980nm infrared light detection of the infrared anti-false shipping mark seen from embodiment 2.
Detailed description of the invention
By the following examples the application is further elaborated.
Ink is nylon ink, water-based polyurethane ink or UV ink, purchased from middle benefit ink.
Anti-settling agent is that castor oil derivative, organic modified bentonite, Tissuemat E, superfine silicon dioxide or montmorillonite are organic Derivant, commercially available.
Polyurethane coating or acrylate paint, purchased from China's painting.
Embodiment 1
A kind of silk-screen of the present embodiment has the visible infrared anti-false shipping mark of white pattern, comprises cotton base material and thickness is 100 μ M is printed on the outer security coating (as shown in Figure 1) of visible red of white pattern.
The raw material composition of the percentage by weight of the outer security coating of described visible red is as follows:
The outer anti-counterfeiting combination 2% of visible red
Anti-settling agent 1%
Ink or polyurethane coating or acrylate paint 97%;
The outer anti-counterfeiting combination of described visible red is the sodium fluoride of 20.5:57:22.5, yttrium fluoride and fluorination ytterbium by weight part ratio Composition.
The preparation method of above-mentioned visible infrared anti-false shipping mark, comprises the steps:
(1) base material treatment: base material is carried out pretreatment, it is ensured that substrate surface is the most pollution-free;
(2) printing: stir after each raw material mixing of outer for above-mentioned visible red security coating, pass through screen printing mode Print or be sprayed on step (1) pretreated shipping mark surface.
(3) molding: step (2) is printed or the shipping mark natural drying that sprayed i.e. obtain described in there is visible infrared anti-false effect The shipping mark of fruit.
Detection: use the iraser pen of 980nm to detect, obvious bright spot can be seen from naked eyes, as shown in Figure 2.
Embodiment 2
A kind of false proof shipping mark being printed with red pattern of the present embodiment, comprises woven dacron or polycot blend fabric and thickness is 10 ~100um is printed on the outer security coating of visible red of red pattern.
The raw material composition of the percentage by weight of the outer security coating of described visible red is as follows:
The outer anti-counterfeiting combination 1% of visible red
Anti-settling agent 0.5%
Ink or polyurethane coating or acrylate paint 98.5%;
The outer anti-counterfeiting combination of described visible red is the sodium fluoride of 18.5:56:25.5, yttrium fluoride and fluorination ytterbium by weight part ratio Composition.
The preparation method of above-mentioned visible infrared anti-false shipping mark, comprises the steps:
(1) base material treatment: base material is carried out pretreatment, it is ensured that substrate surface is the most pollution-free;
(2) printing: stir after each raw material mixing of outer for above-mentioned visible red security coating, pass through screen printing mode Print or be sprayed on step (1) pretreated shipping mark surface.
(3) molding: step (2) is printed or the shipping mark natural drying that sprayed i.e. obtain described in there is visible infrared anti-false effect The shipping mark of fruit.
Detection: use the iraser pen of 980nm to detect, obvious bright spot can be seen from naked eyes, as shown in Figure 3
Comparative example 1
A kind of silk-screen of the present embodiment has the visible infrared anti-false shipping mark of white pattern, comprises cotton base material and thickness is 100 μ M is printed on the outer security coating of visible red of white pattern.
The raw material composition of the percentage by weight of the outer security coating of described visible red is as follows:
Visible infrared anti-false powder 2%
Anti-settling agent 1%
Ink or polyurethane coating or acrylate paint 97%;
Described visible infrared anti-false powder is compounds.
The preparation method of above-mentioned visible infrared anti-false shipping mark, comprises the steps:
(1) base material treatment: base material is carried out pretreatment, it is ensured that substrate surface is the most pollution-free;
(2) printing: stir after each raw material mixing of outer for above-mentioned visible red security coating, pass through screen printing mode Print or be sprayed on step (1) pretreated shipping mark surface.
(3) molding: step (2) is printed or the shipping mark natural drying that sprayed i.e. obtain described in there is visible infrared anti-false effect The shipping mark of fruit.
Detection: use the iraser pen of 980nm to detect, find no obvious bright spot.
Comparative example 2
A kind of silk-screen of the present embodiment has the visible infrared anti-false shipping mark of blue colored pattern, comprises cotton base material and thickness is 100 μm are printed on the outer security coating of visible red of blue color patterns.
The raw material composition of the percentage by weight of the outer security coating of described visible red is as follows:
The outer anti-counterfeiting combination 2% of visible red
Anti-settling agent 1%
Ink or polyurethane coating or acrylate paint 97%;
The outer anti-counterfeiting combination of described visible red is the sodium fluoride of 15:40:45, yttrium fluoride and fluorination ytterbium group by weight part ratio Become.
The preparation method of above-mentioned visible infrared anti-false shipping mark, comprises the steps:
(1) base material treatment: base material is carried out pretreatment, it is ensured that substrate surface is the most pollution-free;
(2) printing: stir after each raw material mixing of outer for above-mentioned visible red security coating, pass through screen printing mode Print or be sprayed on step (1) pretreated shipping mark surface.
(3) molding: step (2) is printed or the shipping mark natural drying that sprayed i.e. obtain described in there is visible infrared anti-false effect The shipping mark of fruit.
Detection: use the iraser pen of 980nm to detect, obvious bright spot could be found in dark surrounds.
Each technical characteristic of embodiment described above can combine arbitrarily, for making description succinct, not to above-mentioned reality The all possible combination of each technical characteristic executed in example is all described, but, as long as the combination of these technical characteristics is not deposited In contradiction, all it is considered to be the scope that this specification is recorded.
Embodiment described above only have expressed the several embodiments of the present invention, and it describes more concrete and detailed, but also Can not therefore be construed as limiting the scope of the patent.It should be pointed out that, come for those of ordinary skill in the art Saying, without departing from the inventive concept of the premise, it is also possible to make some deformation and improvement, these broadly fall into the protection of the present invention Scope.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.

Claims (7)

1. infrared anti-false shipping mark seen from a kind, it is characterised in that include base material, described base material is coated with visible infrared anti-false and is coated with Layer, the raw material composition of the percentage by weight of the outer security coating of described visible red is as follows:
Outer anti-counterfeiting combination 0.1-3% of visible red
Anti-settling agent 0.3-1%
Ink or polyurethane coating or acrylate paint 96-99.6%;
The outer anti-counterfeiting combination of described visible red is made up of sodium fluoride, yttrium fluoride and fluorination ytterbium.
Visible infrared anti-false shipping mark the most according to claim 1, it is characterised in that the outer anti-counterfeiting combination of described visible red by Weight part ratio is sodium fluoride, yttrium fluoride and the fluorination ytterbium composition of 18.5~21.5:56.0~58.0:20.5~25.5.
3. according to the visible infrared anti-false shipping mark described in any one of claim 1-2, it is characterised in that described ink is nylon oil Ink, water-based polyurethane ink or UV ink.
4. according to the visible infrared anti-false shipping mark described in any one of claim 1-2, it is characterised in that described anti-settling agent is Semen Ricini Oil derivant, organic modified bentonite, Tissuemat E, superfine silicon dioxide or montmorillonite organic derivative.
5. according to the visible infrared anti-false shipping mark described in any one of claim 1-2, it is characterised in that the material choosing of described base material From cotton, woven dacron or cotton-polyester blend cloth.
6. according to the preparation method of the visible infrared anti-false shipping mark described in any one of claim 1-5, it is characterised in that include as Lower step:
(1) base material is carried out pretreatment, it is ensured that substrate surface is the most pollution-free;
(2) by each component mixing and stirring in outer for the visible red described in any one of claim 1-5 security coating, silk is used The mode of wire mark brush or spraying is coated in described substrate surface, i.e. obtains described visible infrared anti-false shipping mark after natural drying.
Preparation method the most according to claim 6, it is characterised in that the thickness of the outer security coating of described visible red is 10- 100μm。
CN201510218399.5A 2015-04-30 2015-04-30 Visible infrared anti-false shipping mark and preparation method thereof Active CN104831541B (en)

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CN105525417B (en) * 2016-02-23 2017-08-25 广东溢达纺织有限公司 Terylene woven label and preparation method thereof
CN105908513B (en) * 2016-06-27 2018-04-17 广东溢达纺织有限公司 False proof yarn and preparation method thereof

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CN1157462C (en) * 2002-04-15 2004-07-14 清华大学 Nano-class conversion fluorescence material on fluoride matrix and its preparing process
US8389958B2 (en) * 2009-03-18 2013-03-05 Duke University Up and down conversion systems for production of emitted light from various energy sources
CN101864605A (en) * 2010-06-09 2010-10-20 蚌埠市瑞进防伪材料科技有限公司 Near-infrared absorption counterfeit fiber and preparation method thereof
KR20120015111A (en) * 2010-08-11 2012-02-21 고려대학교 산학협력단 Energy up-conversion materials for dye-sensitized solar cells
KR20140145836A (en) * 2013-06-14 2014-12-24 한국조폐공사 Manufacturing Method of Functional Rregenerated Cellulose Fiber

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Effective date of registration: 20230310

Address after: No. 38, Mingli Road, Hecheng Street, Gaoming District, Foshan City, Guangdong Province, 528500 (residence application)

Patentee after: Guangdong Kangpai Huanchuang Technology Co.,Ltd.

Address before: 528500 Guangdong city of Foshan province river export processing zone

Patentee before: Guangdong Esquel Textile Co.,Ltd.

TR01 Transfer of patent right