CN104830578A - High-efficiency toilet cleaning agent and preparation method thereof - Google Patents
High-efficiency toilet cleaning agent and preparation method thereof Download PDFInfo
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- CN104830578A CN104830578A CN201510216596.3A CN201510216596A CN104830578A CN 104830578 A CN104830578 A CN 104830578A CN 201510216596 A CN201510216596 A CN 201510216596A CN 104830578 A CN104830578 A CN 104830578A
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Abstract
The invention specifically relates to a high-efficiency toilet cleaning agent and a preparation method thereof, belonging to the field of cleaning agents. The toilet cleaning agent provided by the invention is composed of iso-alcohol polyoxyethylene ether, (Z)-2,2'-(octadec-9-enylimino)bisethanol, oxalic acid, (hydroxyethylidene)diphosphonic acid, citric acid, sodium chloride, hydrogen peroxide and essence. The preparation method for the toilet cleaning agent comprises the following steps: adding water to dissolve oxalic acid and (Z)-2,2'-(octadec-9-enylimino)bisethanol; then adding iso-alcohol polyoxyethylene ether and carrying out uniform mixing; and adding citric acid, sodium chloride, (hydroxyethylidene)diphosphonic acid, hydrogen peroxide and essence and carrying out uniform mixing under stirring until a transparent liquid is obtained. The toilet cleaning agent provided by the invention has the advantages of exclusion of any inorganic acid, low corrosivity, mildness, environment friendliness, good wall adhesion performance, good cleaning effect and sterilization and disinfection effects; and after usage of the toilet cleaning agent, the porcelain surface of a water closet pan reflects weak blue light, which endows people with comfortability, so requirements of modern people are better met and popularization and utilization of the toilet cleaning agent are facilitated.
Description
Technical field
The invention belongs to sanitising agent field, be specifically related to a kind of efficient cleaning agent and preparation method thereof.
Background technology
Along with the development of society and the raising of people's living standard, people also propose higher requirement to quality of life, especially require higher to living environment.Cleaning agent is the requisite magic weapon in clean lavatory in daily life, and at present, the cleaning agent of market is broadly divided into three major types: acidic products, neutral products, basic prod, wherein best with the cleaning performance of acidic products.Except the clean of glaze porcelain sanitary equipment and taste removal can be used for, outside the organism of removing body discharges, the iron rust of tap water, incrustation scale can also be removed, there is biocidal efficacies and kill the effects such as hiding bacterium.
But the acidic substance mainly mineral acid of current acid cleaning agent, as adopted the lower and cleaning effect preferably raw material of the cost such as hydrochloric acid, phosphoric acid in inorganic acid salt more, but these mineral acids have severe corrosive, if Long Term Contact or suction, great impact can be caused on the healthy of human body.Therefore, research and develop a kind of cleaning effect good, pollute little, cleaning agent human body not being existed to harm is the difficult problem needing solution badly.
Summary of the invention
In order to the cleaning agent corrodibility solving prior art is comparatively large, the defect that pungency is strong, the object of the present invention is to provide a kind of efficient cleaning agent and preparation method thereof, to solve above defect.
The efficient cleaning agent of one provided by the invention, described cleaning agent comprises following component and mass percent thereof:
Isomeric alcohol polyethenoxy ether 1.0-6.0%, oleyl amine polyoxyethylene (2) ether 0.5-3.0%, oxalic acid 1.0-5.0%, hydroxy ethylidene-diphosphate 0.1-5.0%, citric acid 0.5-4%, sodium-chlor 0.1-2.0%, hydrogen peroxidase 10 .1-2.0%, essence 0.05-2.5%, water 70.5-96.65%.
Preferably, efficient cleaning agent of the present invention comprises following component and mass percent thereof:
Isomeric alcohol polyethenoxy ether 1.0-4.0%, oleyl amine polyoxyethylene (2) ether 0.5-2.0%, oxalic acid 1-4%; Hydroxy ethylidene-diphosphate 1.0-4.0%, citric acid 0.5-2.0%, sodium-chlor 0.1-1.0%, hydrogen peroxidase 10 .1-1.0%, essence 0.1-1.0%, water 80-95%.
Further, the formula of efficient cleaning agent the best of the present invention is as follows:
Isomeric alcohol polyethenoxy ether 2%, oleyl amine polyoxyethylene (2) ether 1.0%, oxalic acid 3.0%; Hydroxy ethylidene-diphosphate 2.0%, citric acid 1.0%, sodium-chlor 0.5%, hydrogen peroxidase 10 .5%, essence 0.5%, water 89.5%.
Isomeric alcohol polyethenoxy ether in efficient cleaning agent of the present invention is the one in isomery ten polyoxyethylenated alcohol, isomery undecyl alcohol Soxylat A 25-7 and isomerous tridecanol polyoxyethylene ether, is preferably isomerous tridecanol polyoxyethylene ether.
Preferably, in efficient cleaning agent of the present invention, the concentration of hydrogen peroxide is 27% or 35%, and preferred concentration is 27%.
In addition, the present invention also provides a kind of preparation method preparing efficient cleaning agent, comprises the following steps:
A) oxalic acid and oleyl amine polyoxyethylene (2) ether are added water and be stirred into transparent liquid, obtain the mixed solution of oxalic acid and oleyl amine polyoxyethylene (2) ether;
B) by steps A) mixed solution that obtains adds isomeric alcohol polyethenoxy ether while stirring, and is stirred into transparent liquid, obtains isomeric alcohol polyethenoxy ether mixed solution;
C) by step B) add citric acid, sodium-chlor, hydroxy ethylidene-diphosphate, hydrogen peroxide and essence while stirring after the mixed solution that obtains, and be stirred into transparent liquid, to obtain final product.
In cleaning agent of the present invention, isomeric alcohol polyethenoxy ether is that tensio-active agent is a kind of, and have emulsifying capacity strong, surfactivity is high, the advantage of anti-hard water, in wider pH value range chemical stability and Environmental compatibility good, be widely used in family expenses and industrial washing field.Isomeric alcohol polyethenoxy ether has better infiltration, decontamination and forming process than fatty alcohol-polyoxyethylene ether, has better cleaning effect.
Oleyl amine polyoxyethylene (2) ether in cleaning agent of the present invention, English (Z)-2,2'-(octadec-9-enylimino) bisethanol by name, No. CAS is 13127-82-7, and molecular formula is C
22h
45nO
2, molecular weight is 355.5982.The Main Function of oleyl amine polyoxyethylene (2) ether bubbles, and regulates the viscosity of cleaning agent, make cleaning agent have good wall built-up; Oxalic acid can remove the spot that oxygenant cannot be removed, and hydrogen peroxide is then to remove the spot that oxalic acid and reductive agent cannot remove, so oxalic acid and hydrogen peroxide conbined usage, can all spots of more effective removal, reach the effect of all-round decontamination.Hydroxy ethylidene-diphosphate has the effect of stable peroxide hydrogen, strengthens the cleaning effect of cleaning agent of the present invention.
Compared with prior art, efficient cleaning agent of the present invention has following advantage:
(1) efficient cleaning agent of the present invention is not containing mineral acid, and corrodibility is low, gentle environmental protection, has wall built-up good, and cleaning effect is strong, and having the advantage of disinfection effect concurrently, is the cleaning agent of environment-friendly high-efficiency;
(2) efficient cleaning agent of the present invention both contained oxygenant containing reductive agent simultaneously, can remove various spot comprehensively, and the water closet pan porcelain facing after washing can be made to reflect faint blue light, increased the whiteness of washing rear porcelain facing.
embodiment:
Below by way of the description of embodiment, the invention will be further described, but this is not limitation of the present invention, those skilled in the art are according to basic thought of the present invention, various amendment or improvement can be made, but only otherwise depart from basic thought of the present invention, all within the scope of the present invention.
embodiment 1,efficient cleaning agent of the present invention
Cleaning agent comprises following component and mass percent thereof: isomeric alcohol polyethenoxy ether 1.0%, oleyl amine polyoxyethylene (2) ether 3.0%, oxalic acid 1.0%, hydroxy ethylidene-diphosphate 0.1%, citric acid 0.5%, sodium-chlor 2.0%, 35% hydrogen peroxide 2.0%, essence 2.5%, water 87.9%.
Preparation method:
A) take 879g water and add oxalic acid 10g and oleyl amine polyoxyethylene (2) ether 30g while stirring, and be stirred into transparent liquid, obtain the mixed solution of oxalic acid and oleyl amine polyoxyethylene (2) ether;
B) by steps A) mixed solution that obtains adds isomery ten polyoxyethylenated alcohol 10g while stirring, and is stirred into transparent liquid, obtains isomery ten polyoxyethylenated alcohol mixed solution;
C) by step B) add citric acid 5g, sodium-chlor 20g, hydroxy ethylidene-diphosphate 1g, 35% hydrogen peroxide 20g and essence 25g while stirring successively after the mixed solution that obtains, and be stirred into transparent liquid, to obtain final product.
embodiment 2,efficient cleaning agent of the present invention
Cleaning agent comprises following component and mass percent thereof: isomeric alcohol polyethenoxy ether 2.0%, oleyl amine polyoxyethylene (2) ether 1.0%, oxalic acid 1.0%, hydroxy ethylidene-diphosphate 2.0%, citric acid 1.0%, sodium-chlor 0.5%, 27% hydrogen peroxidase 10 .5%, essence 0.5%, water 91.5%.
Preparation method is as embodiment 1.
embodiment 3,efficient cleaning agent of the present invention
Cleaning agent comprises following component and mass percent thereof: isomeric alcohol polyethenoxy ether 3.0%, oleyl amine polyoxyethylene (2) ether 5.0%, oxalic acid 5.0%, hydroxy ethylidene-diphosphate 2.0%, citric acid 0.5%, sodium-chlor 2.0%, 35% hydrogen peroxidase 10 .1%, essence 0.05%, water 83.85%.
Preparation method is as embodiment 1.
comparative example one,a kind of cleaning agent
The composition of cleaning agent:
The mass percent of oxalic acid is the mass percent of 0,27% hydrogen peroxide is 1.5%, and all the other compositions and preparation technology are as embodiment 2.
comparative example two,a kind of cleaning agent
The composition of cleaning agent:
The mass percent of 27% hydrogen peroxide is 0, and the mass percent of oxalic acid is 1.5%, and all the other compositions and preparation technology are as embodiment 2.
comparative example three,a kind of cleaning agent
The composition of cleaning agent:
Oxalic acid mass percent is 0, and citric acid mass percent is 0, adds the hydrochloric acid that mass percent is 1.5%, and all the other compositions and preparation technology are as embodiment 2.
test example 1,cleaning agent corrosion resistance measurement is tested
1, testing method: the corrodibility to ceramic tile and cast iron of testing cleaning agent prepared by the cleaning agent of the embodiment of the present invention 1, embodiment 2 and embodiment 3 preparation and comparative example three according to GB/T 21241-2007 " sanitary ware clean-out system ".According to GB/T 21241-2007 " sanitary ware clean-out system " regulation, urinal and toilet tailored version cleaning agent, qualified to ceramic tile corrodibility, Z
30iron corrosion Ji other≤1 grade, rank is higher, and corrodibility is stronger.
2, detected result display: it is qualified that 4 sections of cleaning agent are all judged to be the corrodibility of ceramic tile, but there are differences corrosion of metal, and result is as shown in table 1:
Table 1 cleaning agent corrosion resistance measurement testing data
| Index | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example three |
| Ceramic tile | Qualified | Qualified | Qualified | Qualified |
| Z 30 Iron corrosion rank | 0 grade of corrosion | 0 grade of corrosion | 0 grade of corrosion | 1 grade of corrosion |
From table 1, cleaning agent prepared by embodiment of the present invention 1-3 is all qualified to the corrodibility of ceramic tile, to Z
30iron corrosion rank is 0 grade, and comparative example a pair Z
30iron corrosion rank is 1 grade, to Z
30there is larger corrodibility in cast iron, proves that cleaning agent prepared by the present invention and hydrochloric cleaning agent have the low advantage of corrodibility, be conducive to the promotion and application of this cleaning agent.
test example 2,cleaning agent cleaning effect determination test
1, test materials: the cleaning agent of the embodiment of the present invention 1, embodiment 2, embodiment 3, comparative example one, comparative example two and comparative example three preparation.
2, subjects: the porcelain facing using artificial urine process, makes porcelain facing cover the spot of last layer yellow.
3, test method: cleaning agent embodiment 1, embodiment 2, embodiment 3, comparative example one, comparative example two and comparative example three prepared is sprayed onto the porcelain facing that 6 pieces indicate sample 1, sample 2, sample 3, sample 4, sample 5 and sample 6 respectively respectively simultaneously, rinse with clear water simultaneously, observe the cleaning situation of 6 pieces of porcelain facings; Use the porcelain facing whiteness after portable whiteness instrument test processes simultaneously.
4, test-results:
4.1, sprayed the porcelain facing of cleaning agent, with the naked eye can see that some solids foul are along with under liquid stream, and the color of porcelain facing has bleached, after use is rinsed with clear water, porcelain facing is rinsed well substantially;
4.2, porcelain facing brightness results is as shown in table 2, wherein control group is the porcelain facing without cleaning agent process, sample 1 is the porcelain facing of the cleaning agent process through embodiment 1 preparation, sample 2 is porcelain facings of the cleaning agent process through embodiment 2 preparation, sample 3 is porcelain facings of the cleaning agent process through embodiment 3 preparation, sample 4 is porcelain facings of the cleaning agent process through comparative example one preparation, and sample 5 is porcelain facings of the cleaning agent process through comparative example two preparation, and sample 6 is porcelain facings of the cleaning agent process through comparative example three preparation.
Table 2 the present invention efficient cleaning agent cleaning effect testing data
| Index | Control group | Sample 1 | Sample 2 | Sample 3 | Sample 4 | Sample 5 | Sample 6 |
| Whiteness | 85 | 80.5 | 83.4 | 81.2 | 72.4 | 73.2 | 76.2 |
From above-mentioned table 2,
1) by sample 1-3 compared with sample 6, the whiteness of the cleaning porcelain facing of cleaning agent prepared by the present invention is more effective than hydrochloric cleaning agent, and cleaning agent corrodibility of the present invention is low, gentle environmental protection, have wall built-up good, cleaning effect is good, have the advantage of disinfection effect concurrently, the water closet pan porcelain facing after washing can be made to reflect faint blue light simultaneously, to a kind of comfort of people, more can meet the requirement of modern;
2) by sample 1-3 compared with sample 4-5, prove oxalic acid and hydrogen peroxide conbined usage, can all spots of more effective removal, reach the effect of all-round decontamination, be used alone oxalic acid or hydrogen peroxide, its cleaning effect can decline greatly.
Claims (8)
1. an efficient cleaning agent, is characterized in that, comprises following component and mass percent thereof:
Isomeric alcohol polyethenoxy ether 1.0-6.0%, oleyl amine polyoxyethylene (2) ether 0.5-3.0%, oxalic acid 1.0-5.0%, hydroxy ethylidene-diphosphate 0.1-5.0%, citric acid 0.5-4.0%, sodium-chlor 0.1-2.0%, hydrogen peroxidase 10 .1-2.0%, essence 0.05-2.5%, water 70.5-96.65%.
2. efficient cleaning agent as claimed in claim 1, it is characterized in that, described cleaning agent comprises following component and mass percent thereof:
Isomeric alcohol polyethenoxy ether 1.0-4.0%, oleyl amine polyoxyethylene (2) ether 0.5-2.0%, oxalic acid 1.0-4.0%, hydroxy ethylidene-diphosphate 1.0-4.0%, citric acid 0.5-2.0%, sodium-chlor 0.1-1.0%, hydrogen peroxidase 10 .1-1.0%, essence 0.1-1.0%, water 80-95%.
3. efficient cleaning agent as claimed in claim 1 or 2, it is characterized in that, described cleaning agent comprises following component and mass percent thereof:
Isomeric alcohol polyethenoxy ether 2.0%, oleyl amine polyoxyethylene (2) ether 1.0%, oxalic acid 3.0%, hydroxy ethylidene-diphosphate 2.0%, citric acid 1.0%, sodium-chlor 0.5%, hydrogen peroxidase 10 .5%, essence 0.5%, water 89.5%.
4. efficient cleaning agent as claimed in claim 1, it is characterized in that, described isomeric alcohol polyethenoxy ether is the one in isomery ten polyoxyethylenated alcohol, isomery undecyl alcohol Soxylat A 25-7 and isomerous tridecanol polyoxyethylene ether.
5. efficient cleaning agent as claimed in claim 4, it is characterized in that, described isomeric alcohol polyethenoxy ether is isomerous tridecanol polyoxyethylene ether.
6. efficient cleaning agent as claimed in claim 1, it is characterized in that, the concentration of described hydrogen peroxide is 27% or 35%.
7. efficient cleaning agent as claimed in claim 6, it is characterized in that, the concentration of described hydrogen peroxide is 27%.
8. a preparation method for efficient cleaning agent as claimed in claim 1, is characterized in that, comprise the following steps:
A) oxalic acid and oleyl amine polyoxyethylene (2) ether are added to the water, are stirred into transparent liquid, the mixed solution of oxalic acid and oleyl amine polyoxyethylene (2) ether must be contained;
B) by steps A) mixed solution that obtains adds isomeric alcohol polyethenoxy ether while stirring, and is stirred into the mixed solution of transparent liquid;
C) by step B) add citric acid, sodium-chlor, hydroxy ethylidene-diphosphate, hydrogen peroxide and essence while stirring after the mixed solution that obtains, and be stirred into transparent liquid, to obtain final product.
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Cited By (7)
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| CN106281784A (en) * | 2016-08-25 | 2017-01-04 | 仇颖超 | A kind of preparation method of efficient detergent for toilet |
| CN106350242A (en) * | 2016-08-30 | 2017-01-25 | 武汉金泉环保有限公司 | Mobile toilet detergent |
| CN107674770A (en) * | 2017-10-26 | 2018-02-09 | 桂林大创科技有限公司 | A kind of efficiently detergent for toilet and preparation method thereof |
| CN108659971A (en) * | 2018-06-15 | 2018-10-16 | 河北晨晨环境科技股份有限公司 | Detergent for toilet and preparation method thereof |
| CN110257183A (en) * | 2019-06-27 | 2019-09-20 | 广州珺凯清洁剂有限公司 | A kind of cleaning toilet aromatic |
| CN113583762A (en) * | 2021-09-10 | 2021-11-02 | 湖南金裕环保科技有限公司 | High-alkali-resistant low-foam surfactant and preparation method thereof |
| CN114698634A (en) * | 2022-03-09 | 2022-07-05 | 四川科宏达集团有限责任公司 | Application of isomeric tridecanol polyoxyethylene ether in iodine disinfectant and application method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106281784A (en) * | 2016-08-25 | 2017-01-04 | 仇颖超 | A kind of preparation method of efficient detergent for toilet |
| CN106350242A (en) * | 2016-08-30 | 2017-01-25 | 武汉金泉环保有限公司 | Mobile toilet detergent |
| CN107674770A (en) * | 2017-10-26 | 2018-02-09 | 桂林大创科技有限公司 | A kind of efficiently detergent for toilet and preparation method thereof |
| CN108659971A (en) * | 2018-06-15 | 2018-10-16 | 河北晨晨环境科技股份有限公司 | Detergent for toilet and preparation method thereof |
| CN110257183A (en) * | 2019-06-27 | 2019-09-20 | 广州珺凯清洁剂有限公司 | A kind of cleaning toilet aromatic |
| CN113583762A (en) * | 2021-09-10 | 2021-11-02 | 湖南金裕环保科技有限公司 | High-alkali-resistant low-foam surfactant and preparation method thereof |
| CN114698634A (en) * | 2022-03-09 | 2022-07-05 | 四川科宏达集团有限责任公司 | Application of isomeric tridecanol polyoxyethylene ether in iodine disinfectant and application method thereof |
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