CN104804522A - Environment-friendly ultraviolet-curing pad-printing ink - Google Patents
Environment-friendly ultraviolet-curing pad-printing ink Download PDFInfo
- Publication number
- CN104804522A CN104804522A CN201510171763.7A CN201510171763A CN104804522A CN 104804522 A CN104804522 A CN 104804522A CN 201510171763 A CN201510171763 A CN 201510171763A CN 104804522 A CN104804522 A CN 104804522A
- Authority
- CN
- China
- Prior art keywords
- parts
- resin
- printing ink
- pad
- transfer printing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000007649 pad printing Methods 0.000 title abstract description 6
- 229920005989 resin Polymers 0.000 claims abstract description 22
- 239000011347 resin Substances 0.000 claims abstract description 22
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229920003180 amino resin Polymers 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 6
- 239000003822 epoxy resin Substances 0.000 claims abstract description 6
- 239000003999 initiator Substances 0.000 claims abstract description 6
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 6
- -1 polyoxyethylene Polymers 0.000 claims description 23
- 238000010023 transfer printing Methods 0.000 claims description 22
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 15
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 8
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 7
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 7
- 239000013530 defoamer Substances 0.000 claims description 5
- 229920006241 epoxy vinyl ester resin Polymers 0.000 claims description 5
- BSZXAFXFTLXUFV-UHFFFAOYSA-N 1-phenylethylbenzene Chemical compound C=1C=CC=CC=1C(C)C1=CC=CC=C1 BSZXAFXFTLXUFV-UHFFFAOYSA-N 0.000 claims description 4
- YIKSHDNOAYSSPX-UHFFFAOYSA-N 1-propan-2-ylthioxanthen-9-one Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C=CC=C2C(C)C YIKSHDNOAYSSPX-UHFFFAOYSA-N 0.000 claims description 4
- GZVHEAJQGPRDLQ-UHFFFAOYSA-N 6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 GZVHEAJQGPRDLQ-UHFFFAOYSA-N 0.000 claims description 4
- 229920000877 Melamine resin Polymers 0.000 claims description 4
- 239000004640 Melamine resin Substances 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 4
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 4
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 claims description 4
- MDFFNEOEWAXZRQ-UHFFFAOYSA-N aminyl Chemical compound [NH2] MDFFNEOEWAXZRQ-UHFFFAOYSA-N 0.000 claims description 4
- 125000005375 organosiloxane group Chemical group 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- 229920000570 polyether Polymers 0.000 claims description 4
- 229920006305 unsaturated polyester Polymers 0.000 claims description 4
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 claims description 3
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 3
- 239000012965 benzophenone Substances 0.000 claims description 2
- 239000002904 solvent Substances 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000007639 printing Methods 0.000 abstract description 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 230000007794 irritation Effects 0.000 abstract 1
- 231100000956 nontoxicity Toxicity 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 27
- 238000004500 asepsis Methods 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 235000019633 pungent taste Nutrition 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses an environment-friendly ultraviolet curing pad printing ink which comprises the following components in parts by weight: 20-30 parts of epoxy resin, 25-35 parts of amino resin, 10-20 parts of modified acrylic UV resin, 5-15 parts of ultraviolet initiator, 1-10 parts of toner, 3-8 parts of defoaming agent and 2-6 parts of flatting agent. The environment-friendly ultraviolet curing pad printing ink prepared by the invention can replace the traditional solvent type ink, has the advantages of environmental protection, no toxicity, high curing speed, no harm and irritation to human bodies, low production cost and the like, and is suitable for the printing fields of floors, furniture, decorative plates and the like.
Description
Technical field
The present invention relates to UV curable ink field, particularly relating to a kind of environment-friendly type ultraviolet-curing can pad-transfer printing ink.
Background technology
Pad-transfer printing ink is the dyestuff with special property is the main pattern, word etc. that are imprinted on special paper made, can make it to transfer to the ink that other base materials get on because of heating.
Ultraviolet light polymerization pad-transfer printing ink refers under uviolizing, utilizes the UV-light of different wave length and energy to make ink film forming and dry ink.Its major advantage is: set time is short, therefore need not use and dust, can enhance productivity; Just can be dry owing to heating, so do not need baking oven, compared with heat set inks, significantly can reduce time of drying, save energy consumption; The various resistances of printing are good, and after dry, ink film is solid; Due to the good stability of ink on machine, so the stable in properties of printed matter.
But the cost of ultraviolet light polymerization pad-transfer printing ink is higher, some components in ink are irritant to skin; Ultraviolet radiation can produce ozone, and ultraviolet generating portion has a small amount of X-ray, and these are harmful to human body, and these shortcomings limit the widespread use of ultraviolet light polymerization pad-transfer printing ink.
Summary of the invention
The object of the invention is to overcome the deficiency that above-mentioned prior art exists, provide a kind of non-volatility solvent, environment-protecting asepsis, curing speed fast, to human body fanout free region and the low ultraviolet curing pad printing ink of price.
For achieving the above object, the present invention is achieved by the following technical solutions:
A kind of ultraviolet curing pad printing ink, meter comprises following component by weight: epoxy resin 20 ~ 30 parts, 25 ~ 35 parts, aminoresin, modified acroleic acid UV resin 10 ~ 20 parts, ultraviolet initiator 5 ~ 15 parts, toner 1 ~ 10 part, defoamer 3 ~ 8 parts, flow agent 2 ~ 6 parts.
Preferably, described epoxy resin is at least one in Epocryl, epoxy vinyl ester resin.
Preferably, described aminoresin is at least one in urea-formaldehyde resin, melamine resin, benzoguanamine resin.
Preferably, described modified acroleic acid UV resin is at least one in organosilicon-modified acrylic UV resin, epoxy-modified acrylic acid UV resin, unsaturated polyester modified acrylic Acid UV resin.
Preferably, described ultraviolet initiator is at least one in diphenylethan, 2,4 dihydroxyl benzophenone, alpha-hydroxyalkyl benzophenone, isopropyl thioxanthone.
Preferably, described defoamer is at least one in polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether, polyoxyethylene polyoxypropylene glyceryl ether, polydimethylsiloxane.
Preferably, described flow agent is at least one in polydimethylsiloxane, polyether polyester modified organic silicon oxygen alkane, alkyl-modified organo-siloxane.
Beneficial effect of the present invention:
Compared with prior art, environment-friendly type ultraviolet-curing pad-transfer printing ink prepared by the present invention, traditional solvent type ink can be replaced, have environment-protecting asepsis, curing speed fast, to advantages such as human body fanout free region and pungency, production cost are low, be applicable to the print fields such as floor, furniture and decorative sheet.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.Following examples will contribute to those skilled in the art and understand the present invention further, but not limit the present invention in any form.It should be pointed out that to those skilled in the art, without departing from the inventive concept of the premise, some distortion and improvement can also be made.These all belong to protection scope of the present invention.
A kind of ultraviolet curing pad printing ink, meter comprises following component by weight: epoxy resin 20 ~ 30 parts, 25 ~ 35 parts, aminoresin, modified acroleic acid UV resin 10 ~ 20 parts, ultraviolet initiator 5 ~ 15 parts, toner 1 ~ 10 part, defoamer 3 ~ 8 parts, flow agent 2 ~ 6 parts.
Environment-friendly type ultraviolet-curing prepared by the present invention can pad-transfer printing ink, have non-volatility solvent, environment-protecting asepsis, curing speed fast, to human body fanout free region and the advantage such as price is low.
Embodiment 1
Environment-friendly type ultraviolet-curing of the present invention can pad-transfer printing ink, and meter comprises following component by weight: Epocryl 20 parts, urea-formaldehyde resin 35 parts, organosilicon-modified acrylic UV resin 10 parts, diphenylethan 15 parts, toner 10 parts, polyoxyethylene polyoxy propyl alcohol amidogen ether 8 parts, polydimethylsiloxane 2 parts.
Embodiment 2
Environment-friendly type ultraviolet-curing of the present invention can pad-transfer printing ink, and meter comprises following component by weight: epoxy vinyl ester resin 30 parts, melamine resin 25 parts, epoxy-modified acrylic acid UV resin 20 parts, alpha-hydroxyalkyl benzophenone 5 parts, toner 1 part, polypropylene glycerol aether 3 parts, 6 parts, polyether polyester modified organic silicon oxygen alkane.
Embodiment 3
Environment-friendly type ultraviolet-curing of the present invention can pad-transfer printing ink, meter comprises following component by weight: Epocryl 25 parts, benzoguanamine resin 30 parts, unsaturated polyester modified acrylic Acid UV resin 15 parts, 2,4 dihydroxyl benzophenone 10 parts, toner 5 parts, polyoxyethylene polyoxypropylene glyceryl ether 5 parts, alkyl-modified organo-siloxane 4 parts.
Embodiment 4
Environment-friendly type ultraviolet-curing of the present invention can pad-transfer printing ink, and meter comprises following component by weight: epoxy vinyl ester resin 22 parts, melamine resin 27 parts, epoxy-modified acrylic acid UV resin 11 parts, isopropyl thioxanthone 6 parts, toner 3 parts, polypropylene glycerol aether 4 parts, 3 parts, polyether polyester modified organic silicon oxygen alkane.
Embodiment 5
Environment-friendly type ultraviolet-curing of the present invention can pad-transfer printing ink, and meter comprises following component by weight: Epocryl 28 parts, benzoguanamine resin 33 parts, unsaturated polyester modified acrylic Acid UV resin 18 parts, isopropyl thioxanthone 13 parts, toner 9 parts, polydimethylsiloxane 7 parts, alkyl-modified organo-siloxane 5 parts.
Embodiment 6
Environment-friendly type ultraviolet-curing of the present invention can pad-transfer printing ink, and meter comprises following component by weight: epoxy vinyl ester resin 20 parts, urea-formaldehyde resin 28 parts, organosilicon-modified acrylic UV resin 16 parts, diphenylethan 7 parts, toner 10 parts, polyoxyethylene polyoxy propyl alcohol amidogen ether 6 parts, polydimethylsiloxane 5 parts.
Performance test
Basic mechanical design feature of the present invention is as shown in table 1:
Table 1
As seen from Table 1, the environment-friendly type ultraviolet-curing prepared of the present invention can have the advantages such as environment-protecting asepsis, curing speed be fast by pad-transfer printing ink.
Above specific embodiments of the invention are described.It is to be appreciated that the present invention is not limited to above-mentioned particular implementation, those skilled in the art can make various distortion or amendment within the scope of the claims, and this does not affect flesh and blood of the present invention.
Claims (7)
1. an environment-friendly type ultraviolet-curing can pad-transfer printing ink, it is characterized in that, meter comprises following component by weight: epoxy resin 20 ~ 30 parts, 25 ~ 35 parts, aminoresin, modified acroleic acid UV resin 10 ~ 20 parts, ultraviolet initiator 5 ~ 15 parts, toner 1 ~ 10 part, defoamer 3 ~ 8 parts, flow agent 2 ~ 6 parts.
2. pad-transfer printing ink according to claim 1, is characterized in that: described epoxy resin is at least one in Epocryl, epoxy vinyl ester resin.
3. pad-transfer printing ink according to claim 1, is characterized in that: described aminoresin is at least one in urea-formaldehyde resin, melamine resin, benzoguanamine resin.
4. pad-transfer printing ink according to claim 1, is characterized in that: described modified acroleic acid UV resin is at least one in organosilicon-modified acrylic UV resin, epoxy-modified acrylic acid UV resin, unsaturated polyester modified acrylic Acid UV resin.
5. pad-transfer printing ink according to claim 1, is characterized in that: described ultraviolet initiator is at least one in diphenylethan, 2,4 dihydroxyl benzophenone, alpha-hydroxyalkyl benzophenone, isopropyl thioxanthone.
6. pad-transfer printing ink according to claim 1, is characterized in that: described defoamer is at least one in polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether, polyoxyethylene polyoxypropylene glyceryl ether, polydimethylsiloxane.
7. pad-transfer printing ink according to claim 1, is characterized in that: described flow agent is at least one in polydimethylsiloxane, polyether polyester modified organic silicon oxygen alkane, alkyl-modified organo-siloxane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510171763.7A CN104804522A (en) | 2015-04-13 | 2015-04-13 | Environment-friendly ultraviolet-curing pad-printing ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510171763.7A CN104804522A (en) | 2015-04-13 | 2015-04-13 | Environment-friendly ultraviolet-curing pad-printing ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104804522A true CN104804522A (en) | 2015-07-29 |
Family
ID=53689735
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510171763.7A Pending CN104804522A (en) | 2015-04-13 | 2015-04-13 | Environment-friendly ultraviolet-curing pad-printing ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104804522A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110834482A (en) * | 2019-10-28 | 2020-02-25 | 东莞市锐嘉精密机械制造有限公司 | Method for conducting screen printing and frosting on surface of metal base material |
| CN113527831A (en) * | 2021-08-13 | 2021-10-22 | 深圳市纵维立方科技有限公司 | Photosensitive resin, preparation method and forming method of photosensitive resin |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102250508A (en) * | 2011-01-19 | 2011-11-23 | 一可油墨涂料（深圳）有限公司 | Ultraviolet curing pad printing ink |
| CN103666068A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Energy-saving and environment-friendly UV-cured printing ink |
-
2015
- 2015-04-13 CN CN201510171763.7A patent/CN104804522A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102250508A (en) * | 2011-01-19 | 2011-11-23 | 一可油墨涂料（深圳）有限公司 | Ultraviolet curing pad printing ink |
| CN103666068A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Energy-saving and environment-friendly UV-cured printing ink |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110834482A (en) * | 2019-10-28 | 2020-02-25 | 东莞市锐嘉精密机械制造有限公司 | Method for conducting screen printing and frosting on surface of metal base material |
| CN113527831A (en) * | 2021-08-13 | 2021-10-22 | 深圳市纵维立方科技有限公司 | Photosensitive resin, preparation method and forming method of photosensitive resin |
| CN113527831B (en) * | 2021-08-13 | 2023-08-18 | 深圳市纵维立方科技有限公司 | Photosensitive resin, preparation method and forming method of photosensitive resin |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150729 |
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| WD01 | Invention patent application deemed withdrawn after publication |