CN104761946A - Water-resistant salt-spray-resistant plastic printing ink and preparation method thereof - Google Patents
Water-resistant salt-spray-resistant plastic printing ink and preparation method thereof Download PDFInfo
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- CN104761946A CN104761946A CN201510209044.XA CN201510209044A CN104761946A CN 104761946 A CN104761946 A CN 104761946A CN 201510209044 A CN201510209044 A CN 201510209044A CN 104761946 A CN104761946 A CN 104761946A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention belongs to the technical field of printing ink, and particularly relates to water-resistant salt-spray-resistant plastic printing ink and a preparation method thereof. The water-resistant salt-spray-resistant plastic printing ink comprises, by weight, 35-55 parts of chlorinated polypropylene resin, 20-40 parts of water-based acrylic resin, 10-20 parts of nanometer aluminium oxide, 5-10 parts of dimethyl silicone, 5-15 parts of isopropyl alcohol, 1-5 parts of chitosan-graphene composite materials, 1-5 parts of auxiliary agents, 1-5 parts of hollow glass micro-bead and 1-2 parts of walnut shell powder. By means of the water-resistant salt-spray-resistant plastic printing ink and the preparation method thereof, the material mutually soluble purpose is achieved, and the water resistant property and the salt-spray resistant property are good.
Description
Technical field
The present invention relates to technical field of ink, particularly relate to ink used for plastic of a kind of water-fast, salt spray resistance and preparation method thereof.
Background technology
Existing ink used for plastic is the liquid ink adopting water soluble acrylic resin, senior pigment, pure water, auxiliary agent to refine; It is good that it not only has printing effect on plastics, film, and do not fire, not quick-fried, nontoxic, health that pressman can not be damaged, to air also non-environmental-pollution.
In daily use, the frequent contact water of plastics, film or salt fog, this just requires that the ink used for plastic be printed on it also must have certain water-fast, salt fog resistance, otherwise be easy to phenomenons such as occurring layer of ink variable color, come off, along with the continuous progress of people's living standard, require constantly to promote to water-fast, the salt spray resistance of ink used for plastic itself, therefore the performance need such as water-fast, salt spray resistance of existing ink used for plastic improves.
Summary of the invention
The object of the invention is to provide a kind of water-fast, ink used for plastic that salt spray resistance is good for the deficiencies in the prior art.
Another object of the present invention is the preparation method of the ink used for plastic providing a kind of water-fast, salt spray resistance for the deficiencies in the prior art.
The present invention is achieved through the following technical solutions.
An ink used for plastic for water-fast, salt spray resistance, it comprises the raw material of following weight part: chlorinated polypropylene 35-55 part, water-borne acrylic resin 20-40 part, nano aluminium oxide 10-20 part, dimethyl silicone oil 5-10 part, Virahol 5-15 part, chitosan-graphene composite material 1-5 part, auxiliary agent 1-5 part, hollow glass micropearl 1-5 part, walnut shell flour 1-2 part.
Particularly, it comprises the raw material of following weight part: chlorinated polypropylene 35-42 part, water-borne acrylic resin 31-40 part, nano aluminium oxide 10-15 part, dimethyl silicone oil 8-10 part, Virahol 5-10 part, chitosan-graphene composite material 4-5 part, auxiliary agent 1-3 part, hollow glass micropearl 1-3 part, walnut shell flour 1-2 part.
Particularly, it comprises the raw material of following weight part: chlorinated polypropylene 43-55 part, water-borne acrylic resin 20-30 part, nano aluminium oxide 16-20 part, dimethyl silicone oil 5-7 part, Virahol 11-15 part, chitosan-graphene composite material 1-3 part, auxiliary agent 4-5 part, hollow glass micropearl 4-5 part, walnut shell flour 1-2 part.
Particularly, it comprises the raw material of following weight part: chlorinated polypropylene 40-50 part, water-borne acrylic resin 25-35 part, nano aluminium oxide 12-16 part, dimethyl silicone oil 7-9 part, Virahol 8-12 part, chitosan-graphene composite material 3-4 part, auxiliary agent 3-4 part, hollow glass micropearl 2-3 part, walnut shell flour 1-2 part.
Particularly, it also comprises glyceryl monostearate 1-3 weight part.Glyceryl monostearate and other raw material act synergistically, and improve the toughness of ink used for plastic, and ink used for plastic is uniformly dispersed, and improve the stability of ink used for plastic.
Particularly, it also comprises dextrin 1-3 weight part.Dextrin has good mobility, stronger adhesive capacity and adsorptive power, can permeate, act synergistically with other raw material, improve the physicals of ink used for plastic in raw material, improves the stability of ink used for plastic.
Particularly, auxiliary agent comprises defoamer, tensio-active agent, silicon wax emulsion.Defoamer is silicone antifoam agent or natural fats and oils; Tensio-active agent is silicon system tensio-active agent.
A kind of preparation method of ink used for plastic of water-fast, salt spray resistance, preparation process is as follows: by above-mentioned weight part, first nano aluminium oxide is mixed with Virahol, add chlorinated polypropylene, water-borne acrylic resin under whipped state, after mixing, dispersion, grinding, add chitosan-graphene composite material, ultrasonic grinding 30-40 minute, add all the other raw materials, after stirring, obtain ink used for plastic that is water-fast, salt spray resistance.
the present invention has following beneficial effect:the ink used for plastic of water-fast, salt spray resistance of the present invention, have the following advantages: (1) glycan-graphene composite material has larger specific surface area, there is between chitosan and Graphene the synergy of enhancing, chitosan-graphene composite material and walnut shell flour act synergistically and effectively inhibit the diffusion in ink used for plastic of moisture and salt fog simultaneously, have water-fast, salt spray resistance preferably.(2) synergy such as dimethyl silicone oil, hollow glass micropearl makes ink used for plastic have self-shield coating that is hydrophobic, salt fog, and have good water resistance good, dimethyl silicone oil has good adhesivity simultaneously, makes ink used for plastic have good sticking power.The each raw material of the present invention reaches the object of mutual tolerance, water-fast, salt spray resistance good.
Embodiment
Below in conjunction with embodiment, the present invention is described in detail.
embodiment 1.
An ink used for plastic for water-fast, salt spray resistance, it comprises the raw material of following weight part: chlorinated polypropylene 35 parts, water-borne acrylic resin 31 parts, nano aluminium oxide 15 parts, dimethyl silicone oil 8 parts, Virahol 10 parts, chitosan-graphene composite material 4 parts, auxiliary agent 3 parts, hollow glass micropearl 1 part, walnut shell flour 2 parts.Auxiliary agent comprises defoamer 1 part, 1 part, tensio-active agent, silicon wax emulsion 1 part.Defoamer is silicone antifoam agent (as organic silicon modified by polyether) or natural fats and oils; Tensio-active agent is silicon system tensio-active agent.
A kind of preparation method of ink used for plastic of water-fast, salt spray resistance, preparation process is as follows: by above-mentioned weight part, first nano aluminium oxide is mixed with Virahol, add chlorinated polypropylene, water-borne acrylic resin under whipped state, after mixing, dispersion, grinding, add chitosan-graphene composite material, ultrasonic grinding 30 minutes, adds all the other raw materials, after stirring, obtain ink used for plastic that is water-fast, salt spray resistance.
embodiment 2.
The difference of the present embodiment and embodiment 1 is: a kind of ink used for plastic of water-fast, salt spray resistance, it comprises the raw material of following weight part: chlorinated polypropylene 42 parts, water-borne acrylic resin 40 parts, nano aluminium oxide 10 parts, dimethyl silicone oil 10 parts, Virahol 5 parts, chitosan-graphene composite material 5 parts, auxiliary agent 1 part, hollow glass micropearl 3 parts, walnut shell flour 1 part.Auxiliary agent comprises defoamer 0.3 part, 0.4 part, tensio-active agent, silicon wax emulsion 0.3 part.
A kind of preparation method of ink used for plastic of water-fast, salt spray resistance, preparation process is as follows: by above-mentioned weight part, first nano aluminium oxide is mixed with Virahol, add chlorinated polypropylene, water-borne acrylic resin under whipped state, after mixing, dispersion, grinding, add chitosan-graphene composite material, ultrasonic grinding 33 minutes, adds all the other raw materials, after stirring, obtain ink used for plastic that is water-fast, salt spray resistance.
embodiment 3.
The difference of the present embodiment and embodiment 1 is: a kind of ink used for plastic of water-fast, salt spray resistance, it comprises the raw material of following weight part: chlorinated polypropylene 43 parts, water-borne acrylic resin 30 parts, nano aluminium oxide 16 parts, dimethyl silicone oil 7 parts, Virahol 11 parts, chitosan-graphene composite material 3 parts, auxiliary agent 4 parts, hollow glass micropearl 5 parts, walnut shell flour 1 part.Auxiliary agent comprises defoamer 2 parts, 1 part, tensio-active agent, silicon wax emulsion 1 part.
A kind of preparation method of ink used for plastic of water-fast, salt spray resistance, preparation process is as follows: by above-mentioned weight part, first nano aluminium oxide is mixed with Virahol, add chlorinated polypropylene, water-borne acrylic resin under whipped state, after mixing, dispersion, grinding, add chitosan-graphene composite material, ultrasonic grinding 35 minutes, adds all the other raw materials, after stirring, obtain ink used for plastic that is water-fast, salt spray resistance.
embodiment 4.
The difference of the present embodiment and embodiment 1 is: a kind of ink used for plastic of water-fast, salt spray resistance, it comprises the raw material of following weight part: chlorinated polypropylene 55 parts, water-borne acrylic resin 20 parts, nano aluminium oxide 20 parts, dimethyl silicone oil 5 parts, Virahol 15 parts, chitosan-graphene composite material 1 part, auxiliary agent 5 parts, hollow glass micropearl 4 parts, walnut shell flour 2 parts, glyceryl monostearate 1 part.Auxiliary agent comprises defoamer 3 parts, 1 part, tensio-active agent, silicon wax emulsion 1 part.
A kind of preparation method of ink used for plastic of water-fast, salt spray resistance, preparation process is as follows: by above-mentioned weight part, first nano aluminium oxide is mixed with Virahol, add chlorinated polypropylene, water-borne acrylic resin under whipped state, after mixing, dispersion, grinding, add chitosan-graphene composite material, ultrasonic grinding 38 minutes, adds all the other raw materials, after stirring, obtain ink used for plastic that is water-fast, salt spray resistance.
embodiment 5.
The difference of the present embodiment and embodiment 1 is: a kind of ink used for plastic of water-fast, salt spray resistance, it comprises the raw material of following weight part: chlorinated polypropylene 45 parts, water-borne acrylic resin 30 parts, nano aluminium oxide 15 parts, dimethyl silicone oil 8 parts, Virahol 10 parts, chitosan-graphene composite material 3 parts, auxiliary agent 4 parts, hollow glass micropearl 3 parts, walnut shell flour 2 parts, 2 parts, dextrin, glyceryl monostearate 2 parts.Auxiliary agent comprises defoamer 1 part, 2 parts, tensio-active agent, silicon wax emulsion 1 part.
A kind of preparation method of ink used for plastic of water-fast, salt spray resistance, preparation process is as follows: by above-mentioned weight part, first nano aluminium oxide is mixed with Virahol, add chlorinated polypropylene, water-borne acrylic resin under whipped state, after mixing, dispersion, grinding, add chitosan-graphene composite material, ultrasonic grinding 40 minutes, adds all the other raw materials, after stirring, obtain ink used for plastic that is water-fast, salt spray resistance.
Ink used for plastic that is water-fast, salt spray resistance prepared by Application Example 1-5 carries out performance measurement, as table 1.
Table 1
Finally should be noted that; above embodiment is only in order to illustrate technical scheme of the present invention; but not limiting the scope of the invention; although done to explain to the present invention with reference to preferred embodiment; those of ordinary skill in the art is to be understood that; can modify to technical scheme of the present invention or equivalent replacement, and not depart from essence and the scope of technical solution of the present invention.
Claims (8)
1. the ink used for plastic of water-fast a, salt spray resistance, it is characterized in that, it comprises the raw material of following weight part: chlorinated polypropylene 35-55 part, water-borne acrylic resin 20-40 part, nano aluminium oxide 10-20 part, dimethyl silicone oil 5-10 part, Virahol 5-15 part, chitosan-graphene composite material 1-5 part, auxiliary agent 1-5 part, hollow glass micropearl 1-5 part, walnut shell flour 1-2 part.
2. the ink used for plastic of water-fast, salt spray resistance according to claim 1, it is characterized in that, it comprises the raw material of following weight part: chlorinated polypropylene 35-42 part, water-borne acrylic resin 31-40 part, nano aluminium oxide 10-15 part, dimethyl silicone oil 8-10 part, Virahol 5-10 part, chitosan-graphene composite material 4-5 part, auxiliary agent 1-3 part, hollow glass micropearl 1-3 part, walnut shell flour 1-2 part.
3. the ink used for plastic of water-fast, salt spray resistance according to claim 1, it is characterized in that, it comprises the raw material of following weight part: chlorinated polypropylene 43-55 part, water-borne acrylic resin 20-30 part, nano aluminium oxide 16-20 part, dimethyl silicone oil 5-7 part, Virahol 11-15 part, chitosan-graphene composite material 1-3 part, auxiliary agent 4-5 part, hollow glass micropearl 4-5 part, walnut shell flour 1-2 part.
4. the ink used for plastic of water-fast, salt spray resistance according to claim 1, it is characterized in that, it comprises the raw material of following weight part: chlorinated polypropylene 40-50 part, water-borne acrylic resin 25-35 part, nano aluminium oxide 12-16 part, dimethyl silicone oil 7-9 part, Virahol 8-12 part, chitosan-graphene composite material 3-4 part, auxiliary agent 3-4 part, hollow glass micropearl 2-3 part, walnut shell flour 1-2 part.
5. the ink used for plastic of water-fast, salt spray resistance according to claim 1, it is characterized in that, it also comprises glyceryl monostearate 1-3 weight part.
6. the ink used for plastic of water-fast, salt spray resistance according to claim 1, it is characterized in that, it also comprises dextrin 1-3 weight part.
7. the ink used for plastic of water-fast, salt spray resistance according to claim 1, it is characterized in that, auxiliary agent comprises defoamer, tensio-active agent, silicon wax emulsion.
8. the preparation method of the ink used for plastic of water-fast, the salt spray resistance of claim 1 to 7 any one, it is characterized in that, preparation process is as follows: by above-mentioned weight part, first mixed with Virahol by nano aluminium oxide, chlorinated polypropylene, water-borne acrylic resin is added under whipped state, after mixing, dispersion, grinding, add chitosan-graphene composite material, ultrasonic grinding 30-40 minute, add all the other raw materials, after stirring, obtain ink used for plastic that is water-fast, salt spray resistance.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510209044.XA CN104761946A (en) | 2015-04-29 | 2015-04-29 | Water-resistant salt-spray-resistant plastic printing ink and preparation method thereof |
| PCT/CN2015/094278 WO2016173236A1 (en) | 2015-04-29 | 2015-11-11 | Water resistant and salt-fog resistant plastic printing ink and preparation method therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510209044.XA CN104761946A (en) | 2015-04-29 | 2015-04-29 | Water-resistant salt-spray-resistant plastic printing ink and preparation method thereof |
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| CN104761946A true CN104761946A (en) | 2015-07-08 |
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| CN201510209044.XA Pending CN104761946A (en) | 2015-04-29 | 2015-04-29 | Water-resistant salt-spray-resistant plastic printing ink and preparation method thereof |
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| Country | Link |
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| CN (1) | CN104761946A (en) |
| WO (1) | WO2016173236A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016173236A1 (en) * | 2015-04-29 | 2016-11-03 | 张双峰 | Water resistant and salt-fog resistant plastic printing ink and preparation method therefor |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110343421A (en) * | 2019-06-25 | 2019-10-18 | 杭州杭氧化医工程有限公司 | A kind of water-based ink and preparation method thereof with anti-microbial property |
| CN114690296B (en) * | 2020-12-29 | 2024-04-05 | 恩希爱（杭州）薄膜有限公司 | Retroreflective sheet and preparation method thereof |
| CN113337184B (en) * | 2021-06-09 | 2022-05-13 | 广州飞鹿铁路涂料与涂装有限公司 | Anticorrosive paint and preparation method thereof |
Citations (1)
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| CN1290728A (en) * | 2000-10-26 | 2001-04-11 | 中山大学 | Water ink for plastic film relief printing and its producing method |
Family Cites Families (7)
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| CN1063705A (en) * | 1991-05-08 | 1992-08-19 | 成都无线电一厂装饰研究所 | Screen printing ink for polytrimethylene |
| JP2010116459A (en) * | 2008-11-12 | 2010-05-27 | Toyo Ink Mfg Co Ltd | Water-based ink composition |
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| CN103102743B (en) * | 2012-12-12 | 2014-11-05 | 张家港威迪森化学有限公司 | Plastic ink and preparation method thereof |
| CN103555063A (en) * | 2013-11-18 | 2014-02-05 | 青岛鑫箭印刷机械有限公司 | High-temperature-resistant environment-friendly ink |
| CN104761946A (en) * | 2015-04-29 | 2015-07-08 | 林振坤 | Water-resistant salt-spray-resistant plastic printing ink and preparation method thereof |
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- 2015-04-29 CN CN201510209044.XA patent/CN104761946A/en active Pending
- 2015-11-11 WO PCT/CN2015/094278 patent/WO2016173236A1/en active Application Filing
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| CN1290728A (en) * | 2000-10-26 | 2001-04-11 | 中山大学 | Water ink for plastic film relief printing and its producing method |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2016173236A1 (en) * | 2015-04-29 | 2016-11-03 | 张双峰 | Water resistant and salt-fog resistant plastic printing ink and preparation method therefor |
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| WO2016173236A1 (en) | 2016-11-03 |
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