CN104761935A - Antimicrobial non-viscous aqueous inorganic nano coating priming paint and preparation method thereof - Google Patents
Antimicrobial non-viscous aqueous inorganic nano coating priming paint and preparation method thereof Download PDFInfo
- Publication number
- CN104761935A CN104761935A CN201510124332.5A CN201510124332A CN104761935A CN 104761935 A CN104761935 A CN 104761935A CN 201510124332 A CN201510124332 A CN 201510124332A CN 104761935 A CN104761935 A CN 104761935A
- Authority
- CN
- China
- Prior art keywords
- inorganic nano
- priming paint
- aqueous inorganic
- nano coating
- coating priming
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention provides an antimicrobial non-viscous aqueous inorganic nano coating priming paint and a preparation method thereof. The method comprises the following steps: uniformly mixing a polymerization inhibitor, hydroxyl silicone oil and a silane coupling agent, performing a prepolymerization reaction on a mixture and the nano silica sol, filtering to obtain resin, uniformly mixing an inorganic nano filling material, color powder, deionized water, and anhydrous alcohol and using a sand milling machine for grinding to obtain a color paste, and uniformly stirring the obtained resin and color paste according to certain proportion. The antimicrobial non-viscous aqueous inorganic nano coating priming paint has the advantages that the antimicrobial non-viscous aqueous inorganic nano coating priming paint can provide ultraviolet ray shielding function, has the characteristics of sticking resistance, water resistance and good weatherability, can enhance antibiosis function, and has the advantages of easy cleaning, no sticking, antistatic performance, insulation, antifungal performance, easily available raw materials, the aqueous inorganic nano coating priming paint is an inorganic raw material, and production process is simple and is in favor of environmental protection.
Description
Technical field
The present invention relates to antibacterial, not sticky aqueous priming paint preparation field, particularly relate to a kind of easy to clean, not sticky, antibacterial, good weatherability, produce from starting material simultaneously, coating material production, coating application, to product rejection, the priming paint reclaiming environmental sound and preparation method thereof.
Background technology
The range of application of water-borne coatings is increasing, the all respects such as various household electrical appliances, the vehicles, machinery, outdoor equipment, Sports facilities, building materials, space flight are all more and more higher to the requirement of coating, as: easy to clean, adhesion, weathering resistance are strong, acid and alkali-resistance, UV resistant, anti scuffing, anti-graffiti, reduce flow resistance, anti-electrostatic, insulation, the specific function such as antimycotic, with improve people live intelligence connection, improve living environment, therefore the application prospect of water-borne coatings is boundless.
Be CN102653652B at Chinese patent Authorization Notice No., authorized announcement date on July 9th, 2014, " a kind of nano combined containing fluorocarbon coating and preparation method thereof " by name, a kind of coating improving fluorocarbon coating germ resistance, self-cleaning, anti-ultraviolet ageing of this disclosure of the invention, the making method of this coating is: first dispersion agent is dissolved with mixed solvent, add the nanometer anatase titania through surface modification, disperse; Then by PVDF, acrylic resin, aerosil, cellulose acetate, aluminium-silver slurry, successively add in above-mentioned dispersion soln and mix.The modification procedure of this nanometer anatase titania is as follows: 1, nano titanium dioxide powder is added sonic oscillation in ethanolic soln; 2, silane resin acceptor kh-550 deionized water solution is configured; 3, the solution in step 2 is added in the solution in step 1, stir, sonic oscillation 4h; 4, the solution in step 3 is carried out that ethanol is washed, washed, suction filtration, oven dry, grinding, obtain modified nano-titanium dioxide product.Mixed solvent composition comprises different fluorine that ketone, diethylene glycol ether acetic ester, 1-Methoxy-2-propyl acetate, propylene glycol phenylate, butanone, propyl carbinol, hexone.Raw material type needed for the preparation method of this coating is many, cost is higher, raw material nano titanium dioxide also needs just can reach requirement through a series for the treatment of process is modified, although the method can improve automatically cleaning, stain resistant, the resistance to UV aging of coating, but the fluorocarbon coating that polyvinylidene difluoride (PVDF) is relevant many in power house, airport, motorway, the outdoor location application such as Highrise buildings, even if be applied to automobile decoration, appliance shell afterwards, be but seldom relate in kitchen tools.
Be CN101067021A at Chinese publication number, publication date is on November 7th, 2007, in the application documents of " nanometer alumina modified polyether ketone and nanometer ceramic film paint thereof " by name, disclose a kind of nanometer alumina modified polyether ketone and nanometer ceramic film paint thereof, the making method wherein making protective system and non-stick pan coating is: 1, 3, 5-bis-(trifluoromethyl) benzene is for para benzoquinone, zinc powder, deionized water adds in three-necked bottle, stir, be warming up to 90 DEG C, underframe hydrochloric acid, reaction 6h, filtered while hot, with after example cold water washing with vacuum dehydrating at lower temperature, use re crystallization from toluene again, vacuum dehydrating at lower temperature obtains 3 again, 5-bis-(trifluoromethyl) benzene is for Resorcinol, 2, make nano aluminium oxide suspended dispersed liquid, in three-necked bottle, add nanometer (Al
2o
2)
x 2-aqueous dispersions, amphoteric dispersant, tensio-active agent, coupling agent, water-retaining agent 120 DEG C of dehydration by evaporation, 3, in three-necked bottle, 3 are added, 5-bis-(trifluoromethyl) benzene is for Resorcinol, 4, 4 ' difluoro benzophenone (DFK), nanoparticle suspension dispersion liquid and salt of wormwood, tetramethylene sulfone, toluene, under nitrogen protection warming while stirring to 130 DEG C, take out of moisture distillation in 1-2h with toluene, then add toluene and be warming up to 220 DEG C, isothermal reaction 3-4h, then be poured in ionized water, wash away ion and solvent, add MEK dilution after filtration, prepare the fluorine-containing hybrid matrix resin of nano modification.Although this japanning can be applied and the anticorrosive coating of oil field nerve oil extraction pipeline, aerospace industry installations and facilities and civilian non-stick pan, the covering with paint of decocting the kitchen tools such as frying pan, the complex manufacturing technology of this coating, and raw material mostly is organic materials.
Summary of the invention
In order to solve coating raw material complexity, the production difficult problem that operation is loaded down with trivial details, aqueous inorganic nano coating priming paint that the invention provides a kind of antibacterial non-stick and preparation method thereof, production process is simple, raw material is easy to get, and mostly be inorganic materials, coating can be applied in various household electrical appliances, the vehicles, machinery, outdoor equipment, Sports facilities, building materials, the aspects such as space equipment, product is given easy to clean while playing decoration function, adhesion, high temperature resistant, wear-resisting, anticorrosion acid and alkali-resistance, solvent resistant, UV resistant, anti scuffing, anti-graffiti, reduce flow resistance, anti-electrostatic, insulation, the specific function such as antimycotic.
A kind of aqueous inorganic nano coating priming paint of antibacterial non-stick, be made up of (by weight percentage) following feed composition: Nano silica sol 30-40 part, silane coupling agent 20-30 part, inorganic nano-filler 5-10 part, toner 2-5 part, hydroxy silicon oil 1-5 part, stopper 1-2 part, raw spirit 10-20 part, deionized water 5-10 part.
Further, described Nano silica sol is the dispersion liquid of nanometer grade silica in water.
Further, described silane coupling agent is the mixture of dimethyldimethoxysil,ne, dimethyldiethoxysilane, γ-aminopropyl triethoxysilane, γ-methacryloxypropyl trimethoxy silane, γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane.
Further, described inorganic nano-filler is the mixture of nano titanium oxide, nano-aluminium oxide, zinc phosphate, aluminium triphosphate, mica powder, and described toner is copper-chrome black, carbon black, titanium dioxide.
Further, the linear polydimethysiloxane of described hydroxy silicon oil to be end group be hydroxyl, its hydroxyl value is 10 ~ 100mgKOH/g.
Further, described stopper is formic acid, acetic acid, sulfuric acid, the mixture of hydrochloric acid or at least one.
Further, the weight percent of described stopper is 1.5 parts.
Further, the weight percent between described silane coupling agent and silicon sol is 0.5-1.0.
Further, the weight ratio between described silane coupling agent and silicon sol is 3:5.
Further, the aqueous inorganic nano coating priming paint of antibacterial non-stick is made by following processing step:
(1) by above-mentioned formula ratio, measure stopper, hydroxy silicon oil, silane coupling agent, nanometer silica gel, by stopper, part of hydroxyl silicone oil, account for 30 ~ 60% and silane coupling agent Homogeneous phase mixing of whole hydroxy silicon oil, nanometer silica gel is deposited in addition;
(2) mixture be made up of stopper, hydroxy silicon oil, silane coupling agent in (1) and nanometer silica gel are placed in deepfreeze under 5-20 degree Celsius of environment;
(3) add in paint can by the stopper processed through (2), hydroxy silicon oil, the mixture of silane coupling agent composition, nanometer silica gel, carrying out rotating speed is 30 ~ 180 revs/min, duration 4 ~ 48 hours, and temperature is the prepolymerization of 20 ~ 50 DEG C;
(4) terminate front 1h in (3) prepolymerization and add hydroxy silicon oil, account for 40 ~ 70% of hydroxy silicon oil total amount, then roll 1h, can produce resin;
(5) resin filter that 500 object filter clothes will be produced in (4) is used;
(6) by inorganic nano-filler, toner, deionized water, raw spirit Homogeneous phase mixing use sand mill to be ground to less than 20 μm, mill base can be obtained;
(7) mill base after grinding in the resin after filtration treatment in (5) and (6) is stirred with the ratio of 73:27.
The invention has the advantages that: Nano silica sol, inorganic nano-filler can provide shielding ultraviolet rays function; Hydroxy silicon oil can antiseized, waterproof; The various silane coupling agent of composition can improve weather resistance; Copper-chrome black can also strengthen antibacterial, and the metal ion containing conduction in coating, has anti-static effect; The present invention can give that product is easy to clean, not sticky, high temperature resistant, wear-resisting simultaneously, acid-alkali-corrosive-resisting, uvioresistant, anti-electrostatic, insulation, anti-fungus function, and raw material is easy to get, and does not need to carry out the troublesome operation such as modification, mostly is inorganic raw material, is conducive to environmental protection.
Embodiment
Aqueous inorganic nano coating priming paint that the invention discloses a kind of antibacterial non-stick and preparation method thereof, not only making method is simple, raw material is easy to get in this japanning, can also give that product is easy to clean, not sticky, high temperature resistant, wear-resisting, acid-alkali-corrosive-resisting, uvioresistant, anti-electrostatic, insulation, anti-fungus function, and raw material mostly is inorganic materials, environmentally friendly in the whole flow process of product rejection in production.
Be clearly and completely described to the technical scheme in the present invention below, obviously, described is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, the every other embodiment that those of ordinary skill in the art obtain under the prerequisite of not making creative work, all belongs to the scope of protection of the invention.
Raw material used in following examples is commercially available, and when not having specified otherwise, unit is (kg):
Following table lists corresponding raw material model and supplier:
Table 1
Be below specific embodiment, Detailed composition and each raw material dosage (by weight percentage) of each embodiment see the following form:
Table 2
Embodiment 1
By above-mentioned table 2 proportioning, 1.5 parts, formic acid, hydroxy silicon oil 1.5 parts and dimethyldimethoxysil,ne 24 parts are mixed, the silicon sol 40 parts of 10 nanometers is deposited in addition, and the silicon sol 40 parts refrigeration of the mixture form 1.5 parts, formic acid, hydroxy silicon oil 1.5 parts and dimethyldimethoxysil,ne 24 parts and 10 nanometers is to 5 DEG C; The mixture 1.5 parts, the formic acid refrigerated, hydroxy silicon oil 1.5 parts and dimethyldimethoxysil,ne 24 parts formed, the silicon sol 40 parts of 10 nanometers add in paint can, carry out prepolymerization, paint can is with the rotating speed of 80 revs/min, and constant temperature 35 DEG C, roll and add remaining hydroxy silicon oil 1.5 parts after 7 hours; Roll again one hour, with 500 order filter-cloth filterings, can resin be obtained; Inorganic nano-filler 6 parts and toner 2.5 parts, 7 parts, water, raw spirit 16 parts are mixed, and be ground to 18 microns with sand mill, can mill base be obtained, the mill base filtering complete resin and milled is prepared by 73:27, stir, evenly be sprayed on the aluminium of sand with the pneumatic spray gun of 1.5 bores, gauge control is 15-20 micron, and the present embodiment is 18 microns, baking is opened from low temperature, when temperature is raised to 280 DEG C, be incubated 10 minutes, cooling.
Embodiment 2
By above-mentioned table 2 proportioning, 1.5 parts, formic acid, hydroxy silicon oil 1.5 parts and dimethyldimethoxysil,ne 20 parts are mixed, the silicon sol 40 parts of 10 nanometers is deposited in addition, and the silicon sol 40 parts refrigeration of the mixture form 1.5 parts, formic acid, hydroxy silicon oil 1.5 parts and dimethyldimethoxysil,ne 20 parts and 10 nanometers is to 5 DEG C; The mixture of 1.5 parts, the formic acid refrigerated, hydroxy silicon oil 1.5 parts and dimethyldimethoxysil,ne 20 parts, the silicon sol 40 parts of 10 nanometers are added in paint can, carry out prepolymerization, paint can is with the rotating speed of 80 revs/min, and constant temperature 35 DEG C, roll and add remaining hydroxy silicon oil 1.5 parts after 7 hours; Roll again one hour, with 500 order filter-cloth filterings, can resin be obtained; Inorganic nano-filler 10 parts and toner 4.5 parts, 6 parts, water, raw spirit 15 parts are mixed, and be ground to 18 microns with sand mill, can mill base be obtained, the mill base filtering complete resin and milled is prepared by 73:27, stir, evenly be sprayed on the aluminium of sand with the pneumatic spray gun of 1.5 bores, gauge control is 15-20 micron, and the present embodiment is 18 microns, baking is opened from low temperature, when temperature is raised to 280 DEG C, be incubated 10 minutes, cooling.
Embodiment 3
By above-mentioned table 2 proportioning, 1.5 parts, formic acid, hydroxy silicon oil 1.5 parts and dimethyldimethoxysil,ne 30 parts are mixed, the silicon sol 30 parts of 10 nanometers is deposited in addition, and the silicon sol 30 parts refrigeration of the mixture form 1.5 parts, formic acid, hydroxy silicon oil 1.5 parts and dimethyldimethoxysil,ne 30 parts and 10 nanometers is to 5 DEG C; The mixture of 1.5 parts, the formic acid refrigerated, hydroxy silicon oil 1.5 parts and dimethyldimethoxysil,ne 30 parts, the silicon sol 30 parts of 10 nanometers are added in paint can, carry out prepolymerization, paint can is with the rotating speed of 80 revs/min, and constant temperature 35 DEG C, roll and add remaining hydroxy silicon oil 1.5 parts after 7 hours; Roll again one hour, with 500 order filter-cloth filterings, can resin be obtained; Inorganic nano-filler 7 parts and toner 3.5 parts, 5 parts, water, raw spirit 20 parts are mixed, and be ground to 18 microns with sand mill, can mill base be obtained, the mill base filtering complete resin and milled is prepared by 73:27, stir, evenly be sprayed on the aluminium of sand with the pneumatic spray gun of 1.5 bores, gauge control is 15-20 micron, and the present embodiment is 18 microns, baking is opened from low temperature, when temperature is raised to 280 DEG C, be incubated 10 minutes, cooling.
Gained paint film property test result is as follows:
Table 3
Detect data from table 3, preparation-obtained sample in the middle of each embodiment, in pros and cons Impact Test, bear the pros and cons surging force of 50kg/ ㎝ 2 after spraying, shock resistance is high; Can bear 7 days, polishings, hundred lattice method sticking power tests, antibacterial test, the uv-resistant test of UVA340 fluorescent tube, hardness test are enclosed in the salt solution test, 300 of 5%, all meet relevant criterion at multiple aspect of performance.
Known by above-described embodiment, advantage of the present invention is: in the present invention, Nano silica sol, inorganic nano-filler can provide shielding ultraviolet rays function; Hydroxy silicon oil can antiseized, waterproof; The various silane coupling agent of composition can improve weather resistance; Copper-chrome black can also strengthen antibacterial, can give that product is easy to clean, not sticky, high temperature resistant, wear-resisting simultaneously, acid-alkali-corrosive-resisting, uvioresistant, anti-electrostatic, insulation, anti-fungus function, and raw material is easy to get, do not need to carry out the troublesome operation such as modification, mostly be inorganic raw material, in raw material, production, use, even scrap, environment and health of human body all can not be caused to threaten.
Above content is in conjunction with concrete preferred implementation further description made for the present invention, can not assert that specific embodiment of the invention is confined to these explanations.For general technical staff of the technical field of the invention, without departing from the inventive concept of the premise, some simple deduction or replace can also be made, all should be considered as belonging to protection scope of the present invention.
Claims (10)
1. an aqueous inorganic nano coating priming paint for antibacterial non-stick, is characterized in that, be made up of (by weight percentage) following feed composition:
Nano silica sol 25-50 part, silane coupling agent 25-35 part, inorganic nano-filler 5-20 part, toner 5-15 part, hydroxy silicon oil 1-5 part, stopper 1-2 part, raw spirit 10-20 part, deionized water 5-10 part.
2. the aqueous inorganic nano coating priming paint of a kind of antibacterial non-stick according to claim 1, is characterized in that, described Nano silica sol is the dispersion liquid of nanometer grade silica in water.
3. the aqueous inorganic nano coating priming paint of a kind of antibacterial non-stick according to claim 1, it is characterized in that, described silane coupling agent is the mixture of dimethyldimethoxysil,ne, dimethyldiethoxysilane, γ-aminopropyl triethoxysilane, γ-methacryloxypropyl trimethoxy silane, γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane.
4. the aqueous inorganic nano coating priming paint of a kind of antibacterial non-stick according to claim 1, it is characterized in that, described inorganic nano-filler is the mixture of nano titanium oxide, nano-aluminium oxide, zinc phosphate, aluminium triphosphate, mica powder, and described toner is copper-chrome black, carbon black, titanium dioxide.
5. the aqueous inorganic nano coating priming paint of a kind of antibacterial non-stick according to claim 1, is characterized in that, the linear polydimethysiloxane of described hydroxy silicon oil to be end group be hydroxyl, its hydroxyl value is 10 ~ 100mgKOH/g.
6. the aqueous inorganic nano coating priming paint of a kind of antibacterial non-stick according to claim 1, is characterized in that, described stopper is formic acid, acetic acid, sulfuric acid, the mixture of hydrochloric acid or at least one.
7. the aqueous inorganic nano coating priming paint of a kind of antibacterial non-stick according to claim 1, is characterized in that, the weight percent of described stopper is 1.5 parts.
8. the aqueous inorganic nano coating priming paint of a kind of antibacterial non-stick according to claim 1, is characterized in that, the weight ratio between described silane coupling agent and silicon sol is 0.5-1.0.
9. the aqueous inorganic nano coating priming paint of a kind of antibacterial non-stick according to claim 1, is characterized in that, the weight ratio between described silane coupling agent and silicon sol is 3:5.
10., according to the aqueous inorganic nano coating priming paint of a kind of antibacterial non-stick described in claim 1 to 9, it is characterized in that, be made by following processing step:
(1) by above-mentioned formula ratio, measure stopper, hydroxy silicon oil, silane coupling agent, nanometer silica gel, by stopper, part of hydroxyl silicone oil, account for 30 ~ 60% of whole hydroxy silicon oil, and silane coupling agent Homogeneous phase mixing, Nano silica sol is deposited in addition;
(2) mixture be made up of stopper, hydroxy silicon oil, silane coupling agent in (1) and nanometer silica gel are placed in deepfreeze under 5-20 degree Celsius of environment;
(3) add in paint can by the stopper processed through (2), hydroxy silicon oil, the mixture of silane coupling agent composition, nanometer silica gel, carrying out rotating speed is 30 ~ 180 revs/min, duration 4 ~ 48 hours, and temperature is the prepolymerization of 20 ~ 50 DEG C;
(4) terminate front 1h in (3) prepolymerization and add hydroxy silicon oil, account for 40 ~ 70% of hydroxy silicon oil total amount, then roll 1h, can produce resin;
(5) resin filter that 500 object filter clothes will be produced in (4) is used;
(6) by inorganic nano-filler, toner, deionized water, raw spirit Homogeneous phase mixing use sand mill to be ground to less than 20 μm, mill base can be obtained;
(7) mill base after grinding in the resin after filtration treatment in (5) and (6) is stirred with the ratio of 73:27.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510124332.5A CN104761935A (en) | 2015-03-20 | 2015-03-20 | Antimicrobial non-viscous aqueous inorganic nano coating priming paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510124332.5A CN104761935A (en) | 2015-03-20 | 2015-03-20 | Antimicrobial non-viscous aqueous inorganic nano coating priming paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104761935A true CN104761935A (en) | 2015-07-08 |
Family
ID=53644042
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510124332.5A Pending CN104761935A (en) | 2015-03-20 | 2015-03-20 | Antimicrobial non-viscous aqueous inorganic nano coating priming paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104761935A (en) |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105062156A (en) * | 2015-07-30 | 2015-11-18 | 无锡卡秀堡辉涂料有限公司 | Ceramic paint with antibacterial function and preparation method thereof |
| CN105176149A (en) * | 2015-10-22 | 2015-12-23 | 广东美的厨房电器制造有限公司 | Coating as well as preparation method and application thereof |
| CN105238103A (en) * | 2015-10-30 | 2016-01-13 | 江门四方英特宝涂料有限公司 | Energy-saving and antibacterial nano ceramic coating |
| CN105925043A (en) * | 2016-06-07 | 2016-09-07 | 平顶山市美伊金属制品有限公司 | Non-stick pan spray coating containing absorbable zinc element |
| CN105925029A (en) * | 2016-06-07 | 2016-09-07 | 平顶山市美伊金属制品有限公司 | Non-stick pan spray coating containing absorbable iron element |
| CN105949831A (en) * | 2016-06-28 | 2016-09-21 | 佛山市珀力玛高新材料有限公司 | Ceramic coating with high hardness in hot environment |
| CN106065212A (en) * | 2016-06-07 | 2016-11-02 | 平顶山市美伊金属制品有限公司 | A kind of non-stick pan spray paint containing acceptable calcium element |
| CN106433246A (en) * | 2016-08-27 | 2017-02-22 | 惠州市博罗至诚化工有限公司 | Fireproof smoke-free wear-resisting ceramic coating |
| CN106519965A (en) * | 2016-08-27 | 2017-03-22 | 惠州市博罗至诚化工有限公司 | 9H ceramic paint |
| CN107523105A (en) * | 2017-08-29 | 2017-12-29 | 上海宜瓷龙新材料股份有限公司 | Washing machine inner tub coating composition |
| CN107868517A (en) * | 2017-09-25 | 2018-04-03 | 浙江纳美新材料股份有限公司 | A kind of aqueous color paste and preparation method for solar pipe thermal insulation coatings |
| CN108467610A (en) * | 2018-03-01 | 2018-08-31 | 广东富多新材料股份有限公司 | A kind of composite dope |
| CN108659586A (en) * | 2018-05-26 | 2018-10-16 | 湖南凯斯利新材料有限公司 | A kind of long-acting automatically cleaning aqueous inorganic ceramic coating and preparation method thereof |
| CN109054059A (en) * | 2018-06-05 | 2018-12-21 | 歌尔股份有限公司 | A kind of preparation method and vibrating diaphragm of vibrating diaphragm |
| CN109111767A (en) * | 2018-07-06 | 2019-01-01 | 北京首创纳米科技有限公司 | A kind of environmental protection coating material and preparation method thereof that changeable colour is erasable |
| CN109810573A (en) * | 2017-11-21 | 2019-05-28 | Tcl集团股份有限公司 | Inorganic nano material prints ink and its preparation method and application |
| CN111621176A (en) * | 2020-06-05 | 2020-09-04 | 韦尔狄(广州)生物工程科技有限公司 | Preparation method of efficient nano self-cleaning protective coating |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1699166A (en) * | 2005-05-23 | 2005-11-23 | 电子科技大学 | Nano organic solvent silicasol and preparation method thereof |
| WO2006049368A1 (en) * | 2004-11-06 | 2006-05-11 | Tiochem Co., Ltd. | Surface coating composition |
| CN103725052A (en) * | 2014-01-10 | 2014-04-16 | 江门四方威凯精细化工有限公司 | Water-based porcelain film coating and preparation method thereof |
-
2015
- 2015-03-20 CN CN201510124332.5A patent/CN104761935A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006049368A1 (en) * | 2004-11-06 | 2006-05-11 | Tiochem Co., Ltd. | Surface coating composition |
| CN1699166A (en) * | 2005-05-23 | 2005-11-23 | 电子科技大学 | Nano organic solvent silicasol and preparation method thereof |
| CN103725052A (en) * | 2014-01-10 | 2014-04-16 | 江门四方威凯精细化工有限公司 | Water-based porcelain film coating and preparation method thereof |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105062156A (en) * | 2015-07-30 | 2015-11-18 | 无锡卡秀堡辉涂料有限公司 | Ceramic paint with antibacterial function and preparation method thereof |
| CN105176149A (en) * | 2015-10-22 | 2015-12-23 | 广东美的厨房电器制造有限公司 | Coating as well as preparation method and application thereof |
| CN105176149B (en) * | 2015-10-22 | 2018-03-16 | 广东美的厨房电器制造有限公司 | A kind of coating and its preparation method and application |
| CN105238103A (en) * | 2015-10-30 | 2016-01-13 | 江门四方英特宝涂料有限公司 | Energy-saving and antibacterial nano ceramic coating |
| CN105925043A (en) * | 2016-06-07 | 2016-09-07 | 平顶山市美伊金属制品有限公司 | Non-stick pan spray coating containing absorbable zinc element |
| CN105925029A (en) * | 2016-06-07 | 2016-09-07 | 平顶山市美伊金属制品有限公司 | Non-stick pan spray coating containing absorbable iron element |
| CN106065212A (en) * | 2016-06-07 | 2016-11-02 | 平顶山市美伊金属制品有限公司 | A kind of non-stick pan spray paint containing acceptable calcium element |
| CN105949831A (en) * | 2016-06-28 | 2016-09-21 | 佛山市珀力玛高新材料有限公司 | Ceramic coating with high hardness in hot environment |
| CN106519965A (en) * | 2016-08-27 | 2017-03-22 | 惠州市博罗至诚化工有限公司 | 9H ceramic paint |
| CN106433246A (en) * | 2016-08-27 | 2017-02-22 | 惠州市博罗至诚化工有限公司 | Fireproof smoke-free wear-resisting ceramic coating |
| CN107523105A (en) * | 2017-08-29 | 2017-12-29 | 上海宜瓷龙新材料股份有限公司 | Washing machine inner tub coating composition |
| CN107868517A (en) * | 2017-09-25 | 2018-04-03 | 浙江纳美新材料股份有限公司 | A kind of aqueous color paste and preparation method for solar pipe thermal insulation coatings |
| CN109810573A (en) * | 2017-11-21 | 2019-05-28 | Tcl集团股份有限公司 | Inorganic nano material prints ink and its preparation method and application |
| CN108467610A (en) * | 2018-03-01 | 2018-08-31 | 广东富多新材料股份有限公司 | A kind of composite dope |
| CN108659586A (en) * | 2018-05-26 | 2018-10-16 | 湖南凯斯利新材料有限公司 | A kind of long-acting automatically cleaning aqueous inorganic ceramic coating and preparation method thereof |
| CN109054059A (en) * | 2018-06-05 | 2018-12-21 | 歌尔股份有限公司 | A kind of preparation method and vibrating diaphragm of vibrating diaphragm |
| CN109054059B (en) * | 2018-06-05 | 2022-01-07 | 歌尔股份有限公司 | Preparation method of vibrating diaphragm and vibrating diaphragm |
| CN109111767A (en) * | 2018-07-06 | 2019-01-01 | 北京首创纳米科技有限公司 | A kind of environmental protection coating material and preparation method thereof that changeable colour is erasable |
| CN111621176A (en) * | 2020-06-05 | 2020-09-04 | 韦尔狄(广州)生物工程科技有限公司 | Preparation method of efficient nano self-cleaning protective coating |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104761935A (en) | Antimicrobial non-viscous aqueous inorganic nano coating priming paint and preparation method thereof | |
| CN104761934A (en) | Antimicrobial non-viscous aqueous inorganic nano coating finishing paint and application thereof | |
| CN107573845B (en) | A kind of extra-weather-proof type cracking resistance anticorrosive paint of organosilicon | |
| CN104789123B (en) | One kind suppresses Chlorococcum growth one-component antifouling flush paint and preparation method thereof | |
| CN104231832B (en) | A kind of building glass insulating moulding coating and preparation method thereof and construction technology | |
| CN101549959B (en) | A method of nano self-cleaning glass production in the float glass production line | |
| CN103242718A (en) | Titanate coupling agent modified pollution-flashover-preventing fluorocarbon paint and preparation method thereof | |
| CN104725990B (en) | A kind of preparation method of the self-cleaning coating based on modified nano-titanium dioxide | |
| CN105440821B (en) | A kind of pump valve antirust paint | |
| CN102746768B (en) | Water-borne colorful glass paint and preparation method and application thereof | |
| CN105176211A (en) | Organic-inorganic composite thermal insulation paint and preparation method thereof | |
| CN104119470B (en) | Anticorrosive paint is by acrylic resin modified, the preparation method of copper surface anticorrosion coating | |
| CN105017955A (en) | Heat-shielding thermal-insulation paint | |
| CN104497736A (en) | Double-component transparent glass thermal-insulating coating and preparation method thereof | |
| CN104446127A (en) | Heat-insulating coating for outer walls | |
| CN103614031A (en) | High-temperature automotive intermediate paint suitable for electrostatic spraying of automatic robots and preparation method thereof | |
| CN105602329A (en) | Heat-reflection thermal insulation anti-corrosion coating and preparation method thereof | |
| CN105567058A (en) | Coil coating bonded with PVC film and preparation method thereof | |
| CN106833031A (en) | High temperature resistant weather resistant pearl pigment and preparation method thereof | |
| CN103482905B (en) | Environment-friendly ultraviolet light resistant and high-temperature resistant paint for outer walls of buildings | |
| CN103614044B (en) | For the preparation method of glass insulator antifouling work self-cleaning coating | |
| CN111732892A (en) | Household nano self-cleaning coating and preparation method thereof | |
| CN107083180A (en) | A kind of automatically cleaning reflectance coating based on strawberry type microballoon and preparation method thereof | |
| CN104774522B (en) | Heat insulation paint preparation method | |
| CN104672967A (en) | Preparation method of colored superhydrophobic coating with outstanding corrosion resistance |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150708 |
|
| RJ01 | Rejection of invention patent application after publication |