CN104693930B - 水分散氟硅改性丙烯酸树脂涂料及制备和在铝型材的应用 - Google Patents
水分散氟硅改性丙烯酸树脂涂料及制备和在铝型材的应用 Download PDFInfo
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- CN104693930B CN104693930B CN201510141857.XA CN201510141857A CN104693930B CN 104693930 B CN104693930 B CN 104693930B CN 201510141857 A CN201510141857 A CN 201510141857A CN 104693930 B CN104693930 B CN 104693930B
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- water
- acrylic resin
- modified acrylic
- silicone modified
- fluorinated silicone
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- 239000004925 Acrylic resin Substances 0.000 title claims abstract description 92
- 229920000178 Acrylic resin Polymers 0.000 title claims abstract description 92
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 87
- 229920001296 polysiloxane Polymers 0.000 title claims abstract description 87
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 40
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 229910052731 fluorine Inorganic materials 0.000 title claims abstract description 34
- 239000011737 fluorine Substances 0.000 title claims abstract description 34
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 25
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 238000000576 coating method Methods 0.000 title claims abstract description 25
- 239000011248 coating agent Substances 0.000 title abstract description 18
- 238000002360 preparation method Methods 0.000 title abstract description 8
- 239000003973 paint Substances 0.000 claims abstract description 55
- 239000002966 varnish Substances 0.000 claims abstract description 31
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 29
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 claims abstract description 29
- 229920003180 amino resin Polymers 0.000 claims abstract description 24
- 239000006229 carbon black Substances 0.000 claims abstract description 20
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims abstract description 14
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002270 dispersing agent Substances 0.000 claims abstract description 9
- 230000000694 effects Effects 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 239000006185 dispersion Substances 0.000 claims description 114
- 238000003756 stirring Methods 0.000 claims description 44
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 29
- 229910052710 silicon Inorganic materials 0.000 claims description 29
- 239000010703 silicon Substances 0.000 claims description 29
- 239000003054 catalyst Substances 0.000 claims description 28
- 239000004411 aluminium Substances 0.000 claims description 21
- 238000001914 filtration Methods 0.000 claims description 19
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 12
- 239000013530 defoamer Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- ZHPNWZCWUUJAJC-UHFFFAOYSA-N fluorosilicon Chemical compound [Si]F ZHPNWZCWUUJAJC-UHFFFAOYSA-N 0.000 claims description 3
- UYTPUPDQBNUYGX-UHFFFAOYSA-N guanine Chemical compound O=C1NC(N)=NC2=C1N=CN2 UYTPUPDQBNUYGX-UHFFFAOYSA-N 0.000 claims description 3
- 229920003275 CYMEL® 325 Polymers 0.000 claims description 2
- 235000019241 carbon black Nutrition 0.000 claims 4
- 238000001802 infusion Methods 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 229910052751 metal Inorganic materials 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 abstract description 3
- 239000000706 filtrate Substances 0.000 abstract 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 235000019441 ethanol Nutrition 0.000 abstract 1
- 239000003643 water by type Substances 0.000 description 20
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 17
- 239000004744 fabric Substances 0.000 description 15
- 239000011324 bead Substances 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 11
- 239000008367 deionised water Substances 0.000 description 11
- 229910021641 deionized water Inorganic materials 0.000 description 11
- 239000000686 essence Substances 0.000 description 11
- 230000037452 priming Effects 0.000 description 10
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 238000011017 operating method Methods 0.000 description 5
- 239000002904 solvent Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000011056 performance test Methods 0.000 description 3
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 229910018557 Si O Inorganic materials 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- 241000255964 Pieridae Species 0.000 description 1
- VDRSDNINOSAWIV-UHFFFAOYSA-N [F].[Si] Chemical compound [F].[Si] VDRSDNINOSAWIV-UHFFFAOYSA-N 0.000 description 1
- 230000003679 aging effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010504 bond cleavage reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
Description
60°光泽 | 硬度 | 冲击强度 | 附着力 | 耐溶剂 | 耐盐雾 | 耐老化 | |
实施例1 | 90 | H | ○ | 5B | ○ | ○ | ΔE<3.0 |
实施例2 | 88 | H | ○ | 5B | ○ | ○ | ΔE<3.0 |
实施例3 | 87 | H | ○ | 5B | ○ | ○ | ΔE<3.0 |
实施例4 | 91 | H | ○ | 5B | ○ | ○ | ΔE<3.0 |
实施例5 | 90 | H | ○ | 5B | ○ | ○ | ΔE<3.0 |
实施例6 | 89 | H | ○ | 5B | ○ | ○ | ΔE<3.0 |
实施例7 | 89 | H | ○ | 5B | ○ | ○ | ΔE<3.0 |
实施例8 | 90 | H | ○ | 5B | ○ | ○ | ΔE<3.0 |
实施例9 | 86 | H | ○ | 5B | ○ | ○ | ΔE<3.0 |
实施例10 | 85 | H | ○ | 5B | ○ | ○ | ΔE<3.0 |
对比例1 | 90 | HB | ○ | 5B | × | × | ΔE<3.0 |
对比例2 | 87 | 2H | × | 4B | ○ | ○ | ΔE<3.0 |
对比例3 | 88 | 2H | × | 4B | ○ | ○ | ΔE<3.0 |
对比例4 | 89 | F | × | 5B | × | × | ΔE<3.0 |
对比例5 | 87 | 2H | × | 5B | ○ | ○ | ΔE>5.0 |
Claims (10)
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CN201510141857.XA CN104693930B (zh) | 2015-03-27 | 2015-03-27 | 水分散氟硅改性丙烯酸树脂涂料及制备和在铝型材的应用 |
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CN104693930A CN104693930A (zh) | 2015-06-10 |
CN104693930B true CN104693930B (zh) | 2017-05-10 |
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Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107418325A (zh) * | 2015-08-20 | 2017-12-01 | 陈燕 | 氟硅改性丙烯酸树脂涂料及制备 |
CN105038352A (zh) * | 2015-09-02 | 2015-11-11 | 太仓市金新涂料有限公司 | 一种压花装饰板用改性丙烯酸树脂节能环保涂料 |
CN107189611A (zh) * | 2017-05-23 | 2017-09-22 | 安徽黑钰颜料新材料有限公司 | 一种黑色高装饰性涂料、涂装方法及其应用 |
CN107177267A (zh) * | 2017-06-30 | 2017-09-19 | 苏州日新水性涂料有限公司 | 一种可剥离水漆 |
CN112662285A (zh) * | 2020-12-18 | 2021-04-16 | 力同化工(佛山)有限公司 | 一种纳米环保纯黑涂料 |
CN116004070A (zh) * | 2022-12-27 | 2023-04-25 | 河北环亚石油钻采科技股份有限公司 | 一种用于抽油杆的防腐耐高温高分子膜材料及其制备工艺 |
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CN1580154A (zh) * | 2004-05-18 | 2005-02-16 | 大连振邦氟涂料股份有限公司 | 一种氟碳涂料及其制备方法 |
CN101899251B (zh) * | 2010-08-10 | 2012-11-07 | 上海琥达投资发展有限公司 | 复合材料卫生洁具表面涂装用涂料及其制备方法 |
CN103831183B (zh) * | 2014-03-20 | 2016-04-20 | 湖州巨力铝型材有限公司 | 一种表面雕花的隔热铝型材 |
CN104194532A (zh) * | 2014-08-24 | 2014-12-10 | 湖南至诚涂料有限公司 | 一种水分散型树脂漆及其制备方法 |
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Address after: 510000, No. 62 Xinye Road, Guangzhou Economic and Technological Development Zone, Luogang District, Guangzhou City, Guangdong Province Patentee after: Guangzhou Huigu New Materials Technology Co.,Ltd. Country or region after: China Address before: No. 62 Yonghe Xinye Road, Luogang District, Guangzhou City, Guangdong Province, 511356 Patentee before: GUANGZHOU HUMAN CHEM Co.,Ltd. Country or region before: China |
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Address after: No. 62 Xinye Road, Guangzhou Economic and Technological Development Zone, Guangzhou City, Guangdong Province, 510000 Patentee after: Guangzhou Huigu New Materials Technology Co.,Ltd. Country or region after: China Address before: 510000, No. 62 Xinye Road, Guangzhou Economic and Technological Development Zone, Luogang District, Guangzhou City, Guangdong Province Patentee before: Guangzhou Huigu New Materials Technology Co.,Ltd. Country or region before: China |
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