CN104673031B - Coating material for inorganic non-metallic or metallic surfaces - Google Patents

Coating material for inorganic non-metallic or metallic surfaces Download PDF

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CN104673031B
CN104673031B CN201510058034.0A CN201510058034A CN104673031B CN 104673031 B CN104673031 B CN 104673031B CN 201510058034 A CN201510058034 A CN 201510058034A CN 104673031 B CN104673031 B CN 104673031B
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agent
mass ratio
linan
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dispersant
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CN104673031A (en
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张泽荣
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
    • C09D5/084—Inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention relates to a coating material for inorganic non-metallic or metallic surfaces. The coating material comprises a priming material and a facing material, wherein the priming material is prepared from the following raw materials in percentage by weight: 20-50% of a water-based resin emulsion, 10-40% of an inorganic heat insulating micropowder or mineral micropowder, 0.1-5% of an additive and the balance of water, and the facing material is prepared from the following raw materials in percentage by weight: 5-20% of hollow beads, 5-20% of nano titanium dioxide, 5-20% of a mineral micropowder or metal micropowder, 0.1-10% of silica aerogel, 5-50% of a mixed aqueous polymer emulsion, 0.1-10% of an additive, 0-10% of a pigment or color paste and the balance of water. The coating material provided by the invention is an environment-friendly aqueous emulsion, has multiple functions of reflecting, insulating heat, self-cleaning, resisting corrosion, weathering, acids, alkalis and water and thoroughly overcomes the defects of the existing facing protection coatings which are poor in functions of reflecting, heat insulating, secondary heat insulating, self-cleaning and corrosion, weathering, acid, alkali and water resisting.

Description

A kind of coating material for inorganic non-metallic surface or metal surface
Technical field
The present invention relates to a kind of coating material for inorganic non-metallic surface or metal surface, belong to chemical material neck Domain.
Background technology
With scientific and technical progress, various energy-saving materials emerge in an endless stream, and wherein, heat insulating coatings are as power saving function The typical case of coating, by the common concern of insider and obtain obvious development.The Main Function of heat insulating coatings is resistance The only intrusion that is lost and stoping extraneous solar energy of self heat.Especially southern area illumination is strong, temperature is high, and rainwater is many, It is thus desirable to the coating of good heat-insulation effect, to stop the invasion of extraneous solar energy intercept heat transmission.
Reflective insulation is mainly reflected sunlight heat, and the transmission of sunlight heat and radiation typically can be divided into four by wavelength Point, wherein, 10～400 μm of ultraviolet region wavelength, account for the 5% of sunlight heat；400～720 μm of visible region wavelength, accounts for too The 45% of solar heat；720～2500 μm of far red light area, accounts for more than 2500 μm of the 45% mid and far infrared light area of sunlight heat, Account for the 5% of sunlight heat.Therefore, any reflection heat resistant material can reflect away more than 85% sunlight heat, intercept simultaneously Transmitting and having long-term weatherability of sunlight heat remainder heat energy is exactly to be worth using for reference the quality product promoted.
Existing reflective insulation class coating or patent, including there being fluorine-containing cf key in the material molecule of disposal of pollutants to environment Solvent material, substantially disclosure satisfy that requirement in terms of sunlight heat reflection, but for penetrating and absorbed sunlight heat Lack enough obstructing capacities, especially in material molecule, the compound coat of not fluorine-containing cf key is easily aging, some are deficient for weatherability Lack, color is single, increased many uncertain maintenance costs and potential safety hazard.
Content of the invention
The technical problem to be solved is to provide a kind of coating for inorganic non-metallic surface or metal surface Material, this coating material is a kind of aqueous emulsion ep-type material, has reflection, adiabatic, anti-corrosion, acid and alkali-resistance, waterproof, self-cleaning, resistance to Hou Xing etc. is multi-functional, thoroughly solve the reflective insulation of existing facing protective coating, secondary adiabatic, anti-corrosion, acid and alkali-resistance, waterproof, Self-cleaning, weather-proof sex chromosome mosaicism.
The technical scheme is that a kind of be used for inorganic non-metallic surface or metal surface Coating material, including facing primer and facing layer material, wherein,
Based on the percentage composition of facing primer raw material gross weight, it is made up of the following raw material:
Resin aqueous emulsion 20～50%, inorganic thermal insulation micropowder and mineral micro powder 10～40%, additive 0.1～5%, remaining Measure as tap water,
Based on the percentage composition of facing layer material raw material gross weight, it is made up of the following raw material:
Hollow beads 5～20%, nano titanium oxide 5～20%, mineral micro powder and metal fine powder 5～20%, silicon airsetting Glue 0.1～10%, polymer mixed aqueous emulsion 5～50%, auxiliary agent 0.1～10%, pigment or mill base 0～10%, clout is water.
On the basis of technique scheme, the present invention can also do following improvement.
Further, in the raw material of facing primer forms, described resin aqueous emulsion is pure-acrylic emulsion, silicone acrylic emulsion One of or two kinds of mixture；
Further, in the raw material of facing primer forms, described inorganic thermal insulation micropowder and breeze micropowder are aluminium powder, weigh The mixture of one or more of spar, cordierite, mica powder, kieselguhr, particle diameter is 100nm～20 μm；
Further, in the raw material of facing primer forms, described additive is dispersant, levelling agent, preservative, anti- The mixture of one or more of water preparation.
Further, in the raw material of facing layer material forms, described hollow beads are floating bead, glass microballoon, ceramic fine bead One or more of mixture；
Further, in the raw material of facing layer material forms, described mineral micro powder and metal fine powder are barite, violet is blue or green The mixture of one or more of stone, aluminium powder, particle diameter is 100nm～20 μm.
Further, in the raw material of facing layer material forms, described silica aerogel is that German hoechst company produces；
Further, facing layer material raw material form in, described polymer mixed aqueous emulsion be polymer pure-acrylic emulsion, The mixture of one or more of silicone acrylic emulsion, polymerization fluorine emulsion；
Further, in the raw material of facing layer material forms, described auxiliary agent is dispersant, levelling agent, rheological agent, defoamer One or more of mixture.
The invention has the beneficial effects as follows:
The facing primer that the present invention provides is with the heat-insulated micropowder of resin aqueous emulsion composite inorganic, breeze micropowder, interpolation Agent and water composition, through brushing construction form auxiliary reflective insulation layer, this auxiliary reflective insulation layer, have auxiliary reflection, heat-insulated, anti- Corruption, acid and alkali-resistance, water-proof function, can be bondd with basic unit and finish coat in perfection；
Facing layer material with hollow beads, nano titanium oxide, mineral micro powder and metal fine powder for reflected radiation material, with Silica aerogel is adiabator, with polymer mixed aqueous emulsion as film former, adds colorant or pigment, is aided with auxiliary agent, through brushing Construction form heat reflecting and insulating layer, this coating have suppression solar radiant heat, infrared radiant heat, cut-off heat conduction reflection exhausted Hot merit energy, has the multi-functional ring of anti-corrosion, acid and alkali-resistance, splendid resistance to water, overlength weatherability, self-cleaning and contaminated resistance simultaneously Water-retaining property coating.
Brief description
Fig. 1 is a kind of composite coating structure schematic diagram for inorganic non-metallic surface or metal surface；
In accompanying drawing, the list of parts representated by each label is as follows:
1st, basic unit, 2, facing bottom, 3, finish coat.
Specific embodiment
Hereinafter the principle and feature of the present invention is described, example is served only for explaining the present invention, is not intended to limit Determine the scope of the present invention.
In example below, silica aerogel used is that German hoechst company produces；
The raw material composition of 13 embodiment facing bottoms of table and performance test
Wherein, resin aqueous emulsion is made up of with silicone acrylic emulsion 1:1 in mass ratio pure-acrylic emulsion；
Inorganic thermal insulation micropowder and mineral micro powder are by aluminium powder, barite, cordierite, mica powder, kieselguhr 1:1 in mass ratio: 1:1:1 forms, particle diameter 100nm～20 μm；
Additive is made up of dispersant, levelling agent, preservative, waterproofing agent 4:3:2:1 in mass ratio, and dispersant is Linan ring Space dispersant 300, levelling agent is Linan global non-organic silicon levelling agent 358, and preservative is Linan global preservative tm-8, waterproof Agent is German watt gram waterproofing agent of organosilicon.
By the raw material mix homogeneously in table 1, form auxiliary reflective insulation layer through brushing construction, measure auxiliary reflective insulation layer Performance indications as shown in table 1.
The raw material composition of 23 embodiment finish coats of table and performance test
Hollow beads are made up of floating bead, glass microballoon, ceramic fine bead 1:1:1 in mass ratio；
Mineral micro powder and metal fine powder are made up of barite, cordierite, aluminium powder 3:3:4 in mass ratio；
Aqueous polymer dispersion is by polymer pure-acrylic emulsion, silicone acrylic emulsion, polymerization fluorine emulsion 3.5:3.5:3 group in mass ratio Become；
Auxiliary agent is made up of dispersant, levelling agent, rheological agent, defoamer 4:3:2:1 in mass ratio, and dispersant is that Linan is global Dispersant 300, levelling agent is Linan global non-organic silicon levelling agent 358, and rheological agent is organobentonite, and defoamer is Linan ring Space defoamer ac-202.
By the raw material mix homogeneously in table 2, form heat reflecting and insulating layer through brushing construction, measure the property of heat reflecting and insulating layer Energy index is as shown in table 2.
As shown in figure 1, a kind of composite coating structure for inorganic non-metallic surface or metal surface, by basic unit 1, facing Bottom 2 and finish coat 3 form, wherein,
Basic unit 1 is Inorganic Non-metallic Materials or metal material, basic unit should be cleared up during construction,
Facing bottom 2, takes the facing primer of above-described embodiment preparation, electric stirring, batch extension or roller coating construction, coating Surface in basic unit.
Finish coat 3, when facing bottom moisture content is less than 5%, takes the facing layer material of above-described embodiment preparation, electric mixing Mix, carry out roller coating construction, be coated on facing bottom.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all spirit in the present invention and Within principle, any modification, equivalent substitution and improvement made etc., should be included within the scope of the present invention.

Claims (3)

1. a kind of coating material for inorganic non-metallic surface or metal surface is it is characterised in that include facing primer And facing layer material, wherein,
Based on the percentage composition of facing primer raw material gross weight, it is made up of the following raw material:
Resin aqueous emulsion 33%, inorganic thermal insulation micropowder and mineral micro powder 46%, additive 4.5%, water surplus from the beginning, wherein, Resin aqueous emulsion is made up of with silicone acrylic emulsion 1:1 in mass ratio pure-acrylic emulsion, inorganic thermal insulation micropowder and mineral micro powder by aluminium powder, Barite, cordierite, mica powder, kieselguhr 1:1:1:1:1 in mass ratio forms, particle diameter 100nm～20 μm, and additive is by disperseing Agent, levelling agent, preservative, waterproofing agent 4:3:2:1 in mass ratio forms, and dispersant is the global dispersant in Linan 300, and levelling agent is Linan global non-organic silicon levelling agent 358, preservative is Linan global preservative tm-8, and waterproofing agent is that German watt gram organosilicon is prevented Water preparation；
Based on the percentage composition of facing layer material raw material gross weight, it is made up of the following raw material:
Hollow beads 7.5%, nanometer tio221%, mineral micro powder and metal fine powder 24%, silica aerogel 4.5%, polymer water and milk Liquid 36%, auxiliary agent 0.5%, water surplus, wherein, hollow beads are by floating bead, glass microballoon, ceramic fine bead 1:1:1 group in mass ratio Become, mineral micro powder and metal fine powder are made up of barite, cordierite, aluminium powder 3:3:4 in mass ratio, aqueous polymer dispersion is by being polymerized Thing pure-acrylic emulsion, silicone acrylic emulsion, polymerization fluorine emulsion 3.5:3.5:3 in mass ratio composition, auxiliary agent is by dispersant, levelling agent, rheology Agent, defoamer 4:3:2:1 in mass ratio forms, and dispersant is the global dispersant in Linan 300, and levelling agent is the global non-organic in Linan Silicon levelling agent 358, rheological agent is organobentonite, and defoamer is Linan global defoamer ac-202, and silica aerogel used is moral Hoechst company of state produces.
2. a kind of coating material for inorganic non-metallic surface or metal surface is it is characterised in that include facing primer And facing layer material, wherein,
Based on the percentage composition of facing primer raw material gross weight, it is made up of the following raw material:
Resin aqueous emulsion 42%, inorganic thermal insulation micropowder and mineral micro powder 43%, additive 4%, water surplus from the beginning, wherein, water Property resin emulsion be made up of with silicone acrylic emulsion 1:1 in mass ratio pure-acrylic emulsion, inorganic thermal insulation micropowder and mineral micro powder are by aluminium powder, weight Spar, cordierite, mica powder, kieselguhr 1:1:1:1:1 in mass ratio forms, particle diameter 100nm～20 μm, and additive is by disperseing Agent, levelling agent, preservative, waterproofing agent 4:3:2:1 in mass ratio forms, and dispersant is the global dispersant in Linan 300, and levelling agent is Linan global non-organic silicon levelling agent 358, preservative is Linan global preservative tm-8, and waterproofing agent is that German watt gram organosilicon is prevented Water preparation；
Based on the percentage composition of facing layer material raw material gross weight, it is made up of the following raw material:
Hollow beads 9.8%, nanometer tio214%, mineral micro powder and metal fine powder 21%, silica aerogel 6.2%, polymer water and milk Liquid 40%, auxiliary agent 0.5%, pigment or mill base 2%, water surplus, wherein, hollow beads are pressed by floating bead, glass microballoon, ceramic fine bead Mass ratio 1:1:1 forms, and mineral micro powder and metal fine powder are made up of barite, cordierite, aluminium powder 3:3:4 in mass ratio, polymerization Thing aqueous emulsion is made up of polymer pure-acrylic emulsion, silicone acrylic emulsion, polymerization fluorine emulsion 3.5:3.5:3 in mass ratio, and auxiliary agent is by disperseing Agent, levelling agent, rheological agent, defoamer 4:3:2:1 in mass ratio forms, and dispersant is the global dispersant in Linan 300, and levelling agent is Linan global non-organic silicon levelling agent 358, rheological agent is organobentonite, and defoamer is Linan global defoamer ac-202, institute It is that German hoechst company produces with silica aerogel.
3. a kind of coating material for inorganic non-metallic surface or metal surface is it is characterised in that include facing primer And facing layer material, wherein,
Based on the percentage composition of facing primer raw material gross weight, it is made up of the following raw material:
Resin aqueous emulsion 47%, inorganic thermal insulation micropowder and mineral micro powder 40%, additive 3.5%, water surplus from the beginning, wherein, Resin aqueous emulsion is made up of with silicone acrylic emulsion 1:1 in mass ratio pure-acrylic emulsion, inorganic thermal insulation micropowder and mineral micro powder by aluminium powder, Barite, cordierite, mica powder, kieselguhr 1:1:1:1:1 in mass ratio forms, particle diameter 100nm～20 μm, and additive is by disperseing Agent, levelling agent, preservative, waterproofing agent 4:3:2:1 in mass ratio forms, and dispersant is the global dispersant in Linan 300, and levelling agent is Linan global non-organic silicon levelling agent 358, preservative is Linan global preservative tm-8, and waterproofing agent is that German watt gram organosilicon is prevented Water preparation；
Based on the percentage composition of facing layer material raw material gross weight, it is made up of the following raw material:
Hollow beads 12%, nanometer tio210.5%, mineral micro powder and metal fine powder 15%, silica aerogel 7.5%, polymer water Emulsion 44%, auxiliary agent 0.5%, pigment or mill base 5%, water surplus, hollow beads press matter by floating bead, glass microballoon, ceramic fine bead Than 1:1:1 composition, mineral micro powder and metal fine powder are made up of amount barite, cordierite, aluminium powder 3:3:4 in mass ratio, polymer Aqueous emulsion by polymer pure-acrylic emulsion, silicone acrylic emulsion, polymerization fluorine emulsion 3.5:3.5:3 in mass ratio form, auxiliary agent by dispersant, Levelling agent, rheological agent, defoamer 4:3:2:1 in mass ratio forms, and dispersant is the global dispersant in Linan 300, and levelling agent is to face Pacify global non-organic silicon levelling agent 358, rheological agent is organobentonite, defoamer is Linan global defoamer ac-202, used Silica aerogel is that German hoechst company produces.
CN201510058034.0A 2015-02-04 2015-02-04 Coating material for inorganic non-metallic or metallic surfaces Expired - Fee Related CN104673031B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106978027A (en) * 2017-04-12 2017-07-25 孙静 A kind of insulating mold coating and preparation method thereof
CN107476520A (en) * 2017-08-07 2017-12-15 万卓（江苏）新材料有限公司 A kind of orienting reflex light porcelain tendre ornament materials and preparation method thereof
CN111410910A (en) * 2020-05-19 2020-07-14 苏州德加画材科技有限公司 Antifouling self-cleaning coating and preparation method thereof
CN113136073B (en) * 2021-04-21 2022-10-14 上海新意达塑料托盘有限公司 Low-temperature-resistant impact-resistant polypropylene elastomer material and preparation method thereof

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CN101712835A (en) * 2008-10-08 2010-05-26 上海汇丽涂料有限公司 Heat reflection paint with hollow glass microballoon
CN102864883A (en) * 2011-07-07 2013-01-09 广东华润涂料有限公司 Heat insulating coat system for building wall
CN103725124A (en) * 2013-08-02 2014-04-16 太仓派欧技术咨询服务有限公司 High-radiation heat-insulated coating

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Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
CN101712835A (en) * 2008-10-08 2010-05-26 上海汇丽涂料有限公司 Heat reflection paint with hollow glass microballoon
CN102864883A (en) * 2011-07-07 2013-01-09 广东华润涂料有限公司 Heat insulating coat system for building wall
CN103725124A (en) * 2013-08-02 2014-04-16 太仓派欧技术咨询服务有限公司 High-radiation heat-insulated coating

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