CN104610832A - 一种纳米TiO2改性聚丙烯酸酯涂饰剂 - Google Patents
一种纳米TiO2改性聚丙烯酸酯涂饰剂 Download PDFInfo
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- CN104610832A CN104610832A CN201510034169.3A CN201510034169A CN104610832A CN 104610832 A CN104610832 A CN 104610832A CN 201510034169 A CN201510034169 A CN 201510034169A CN 104610832 A CN104610832 A CN 104610832A
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 21
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- 239000003999 initiator Substances 0.000 claims abstract description 31
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- 239000000178 monomer Substances 0.000 claims abstract description 25
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000008367 deionised water Substances 0.000 claims abstract description 13
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 13
- 125000003118 aryl group Chemical group 0.000 claims abstract description 10
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- -1 alkyl methacrylate ester Chemical class 0.000 claims abstract description 9
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- 238000006243 chemical reaction Methods 0.000 claims description 28
- 238000003756 stirring Methods 0.000 claims description 28
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 16
- ZGUQGPFMMTZGBQ-UHFFFAOYSA-N [Al].[Al].[Zr] Chemical group [Al].[Al].[Zr] ZGUQGPFMMTZGBQ-UHFFFAOYSA-N 0.000 claims description 14
- 238000009413 insulation Methods 0.000 claims description 14
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- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 claims description 7
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 7
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- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 7
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 7
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 7
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- FSAJWMJJORKPKS-UHFFFAOYSA-N octadecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C=C FSAJWMJJORKPKS-UHFFFAOYSA-N 0.000 claims description 7
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 claims description 7
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 7
- 238000010792 warming Methods 0.000 claims description 7
- 239000004159 Potassium persulphate Substances 0.000 claims description 5
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 claims description 5
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 5
- 235000019394 potassium persulphate Nutrition 0.000 claims description 5
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 claims description 4
- 239000004160 Ammonium persulphate Substances 0.000 claims description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 4
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 4
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims description 4
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 3
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 claims description 2
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 claims description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 2
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 claims description 2
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 2
- 230000004048 modification Effects 0.000 abstract description 4
- 238000012986 modification Methods 0.000 abstract description 4
- 230000008859 change Effects 0.000 abstract description 2
- 238000004140 cleaning Methods 0.000 abstract description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 abstract 1
- 230000032683 aging Effects 0.000 abstract 1
- 238000004945 emulsification Methods 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000003643 water by type Substances 0.000 description 10
- 239000012764 mineral filler Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
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- 229910010413 TiO 2 Inorganic materials 0.000 description 3
- 239000002105 nanoparticle Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical class CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 2
- 239000006087 Silane Coupling Agent Substances 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
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- 229910052726 zirconium Inorganic materials 0.000 description 2
- IVORCBKUUYGUOL-UHFFFAOYSA-N 1-ethynyl-2,4-dimethoxybenzene Chemical compound COC1=CC=C(C#C)C(OC)=C1 IVORCBKUUYGUOL-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229910018580 Al—Zr Inorganic materials 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- DNXNYEBMOSARMM-UHFFFAOYSA-N alumane;zirconium Chemical compound [AlH3].[Zr] DNXNYEBMOSARMM-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical group [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
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- 235000011194 food seasoning agent Nutrition 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
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- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
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- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
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- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Polymerisation Methods In General (AREA)
- Paints Or Removers (AREA)
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CN201510034169.3A CN104610832B (zh) | 2015-01-22 | 2015-01-22 | 一种纳米TiO2改性聚丙烯酸酯涂饰剂 |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106047511A (zh) * | 2016-06-03 | 2016-10-26 | 湖州宏鑫绸厂 | 一种皮革亮洁剂 |
CN106565896A (zh) * | 2016-11-09 | 2017-04-19 | 佛山市顺德区巴德富实业有限公司 | 一种具有光致亲水效应的外墙弹性乳液及其制备方法 |
EP3173493A1 (en) * | 2015-11-18 | 2017-05-31 | Institutul National de Cercetare-Dezvoltare Pentru Textile si Pielarie (INCDTP) Sucursala Institul de Cercetare Pielarie Incaltaminte (ICPI) | Leather with self-cleaning properties and resistance to heat/fire and method of obtaining thereof |
CN108865014A (zh) * | 2018-07-05 | 2018-11-23 | 合肥萃励新材料科技有限公司 | 一种pcb用esd功能胶粘剂 |
CN110615461A (zh) * | 2019-10-29 | 2019-12-27 | 常州市卓群纳米新材料有限公司 | 一种bet:20-30分散均匀纳米氧化钐的无氨环保制备方法 |
CN111057431A (zh) * | 2019-12-12 | 2020-04-24 | 河南大学 | 十四烷基酸改性纳米二氧化钛-氧化石墨烯/多元聚合物复合皮革涂饰剂及其制备方法 |
CN111378341A (zh) * | 2020-05-12 | 2020-07-07 | 河南功能高分子膜材料创新中心有限公司 | 一种改性聚丙烯酸酯树脂 |
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WO2010004951A1 (ja) * | 2008-07-11 | 2010-01-14 | 宇部興産株式会社 | 水性ポリウレタン樹脂分散体、その製造方法、及びそれを含有する塗料組成物 |
CN101921447A (zh) * | 2010-04-16 | 2010-12-22 | 江苏大学 | 水性聚(氨酯-丙烯酸酯)/纳米二氧化钛杂化材料的制备方法 |
CN101967257A (zh) * | 2010-09-29 | 2011-02-09 | 江苏科技大学 | 无机纳米粒子改性纯丙乳液及其制备方法 |
CN102718920A (zh) * | 2012-07-04 | 2012-10-10 | 陕西科技大学 | 采用双原位同步法制备聚丙烯酸酯-纳米二氧化钛复合涂饰剂的方法 |
-
2015
- 2015-01-22 CN CN201510034169.3A patent/CN104610832B/zh not_active Expired - Fee Related
Patent Citations (4)
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WO2010004951A1 (ja) * | 2008-07-11 | 2010-01-14 | 宇部興産株式会社 | 水性ポリウレタン樹脂分散体、その製造方法、及びそれを含有する塗料組成物 |
CN101921447A (zh) * | 2010-04-16 | 2010-12-22 | 江苏大学 | 水性聚(氨酯-丙烯酸酯)/纳米二氧化钛杂化材料的制备方法 |
CN101967257A (zh) * | 2010-09-29 | 2011-02-09 | 江苏科技大学 | 无机纳米粒子改性纯丙乳液及其制备方法 |
CN102718920A (zh) * | 2012-07-04 | 2012-10-10 | 陕西科技大学 | 采用双原位同步法制备聚丙烯酸酯-纳米二氧化钛复合涂饰剂的方法 |
Non-Patent Citations (1)
Title |
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王全杰等: "纳米二氧化钛共混法改性丙烯酸树脂涂饰剂的研究", 《中国皮革》 * |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3173493A1 (en) * | 2015-11-18 | 2017-05-31 | Institutul National de Cercetare-Dezvoltare Pentru Textile si Pielarie (INCDTP) Sucursala Institul de Cercetare Pielarie Incaltaminte (ICPI) | Leather with self-cleaning properties and resistance to heat/fire and method of obtaining thereof |
CN106047511A (zh) * | 2016-06-03 | 2016-10-26 | 湖州宏鑫绸厂 | 一种皮革亮洁剂 |
CN106565896A (zh) * | 2016-11-09 | 2017-04-19 | 佛山市顺德区巴德富实业有限公司 | 一种具有光致亲水效应的外墙弹性乳液及其制备方法 |
CN108865014A (zh) * | 2018-07-05 | 2018-11-23 | 合肥萃励新材料科技有限公司 | 一种pcb用esd功能胶粘剂 |
CN110615461A (zh) * | 2019-10-29 | 2019-12-27 | 常州市卓群纳米新材料有限公司 | 一种bet:20-30分散均匀纳米氧化钐的无氨环保制备方法 |
CN110615461B (zh) * | 2019-10-29 | 2022-05-03 | 常州市卓群纳米新材料有限公司 | 一种bet:20-30分散均匀纳米氧化钐的无氨环保制备方法 |
CN111057431A (zh) * | 2019-12-12 | 2020-04-24 | 河南大学 | 十四烷基酸改性纳米二氧化钛-氧化石墨烯/多元聚合物复合皮革涂饰剂及其制备方法 |
CN111378341A (zh) * | 2020-05-12 | 2020-07-07 | 河南功能高分子膜材料创新中心有限公司 | 一种改性聚丙烯酸酯树脂 |
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