CN104585216B - A kind of miticide composition of containing pyriminostrobin - Google Patents

A kind of miticide composition of containing pyriminostrobin Download PDF

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CN104585216B
CN104585216B CN201510036019.6A CN201510036019A CN104585216B CN 104585216 B CN104585216 B CN 104585216B CN 201510036019 A CN201510036019 A CN 201510036019A CN 104585216 B CN104585216 B CN 104585216B
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pyriminostrobin
mite
active component
test
active
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CN104585216A (en
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张秋芳
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Shanxi Thompson Biological Technology Co Ltd
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Shanxi Thompson Biological Technology Co Ltd
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Abstract

The invention discloses a kind of miticide composition of containing pyriminostrobin, the miticide composition containing active components A and active component B, wherein active components A are selected from following any one compound selected from pyriminostrobin, active component B:Bifenazate, Hexythiazox, Envidor, fenpyroximate or fenisobromolate, and active components A and the weight ratio of active component B are 1 ︰, 80~60 ︰ 1.The present composition has potentiation to the various evil mites for endangering agricultural production, reduces pesticide usage amount, reduces pesticide and stays residual on crop, alleviates environmental pollution, and to person poultry safety, Environmental compatibility is good, and evil mite is not likely to produce Drug resistance.

Description

A kind of miticide composition of containing pyriminostrobin
The application is divisional application, and original application is the entitled of Shanxi Thompson Biological Technology Co., Ltd.'s submission:It is " a kind of The patent of the miticide composition of containing pyriminostrobin ", Application No.:201210591603.4, the applying date is:2012.12.29
Technical field
The invention belongs to technical field of pesticide, is related to a kind of miticide composition of containing pyriminostrobin answering in crops evil mite With.
Background technology
Pyriminostrobin (Pyriminostrobin) chemical name:2- tertiary butyl -5- (4- tertiary butyl benzylthios) -4- chlorine pyridazines - 3 (2H) -one, molecular formula:C23H18Cl2F3N3O4.If the medicament to Panonychus citri, red spider into, young demodicid mite be respectively provided with preventing and treating well Effect, and it is demonstrated by excellent ovicidal activity.
Bifenazate (Bifenazate) molecular formula:C17H20N2O3.It is a kind of new selective foliar spray mite killing Agent, it is effective to each life stage of demodicid mite.With ovicidal activity and to knocking down rapidly activity into demodicid mite, pole is affected on predatory mite It is little, it is very suitable for the comprehensive control of insect, plant is not poisoned.
Hexythiazox (Hexythiazox) molecular formula:C17H21C1N2O2S;The new acaricide of Thiazolidine ketone, to plant epidermis Layer has preferable penetrance, but without Uptake and translocation effect.There is to various plants evil mite strong ovicidal, the spy of children mite is killed Property, to invalid into demodicid mite, but touch the ovum produced by the female adult worm of medicinal liquid there is the effect for suppressing hatching.The medicine belongs to non-temperature sensitive type and kills Demodicid mite agent, without significant difference, the longevity of residure is long for the effect used in high temperature or low temperature, is positively retained at 50 days or so.
Envidor (Spirodiclofen) molecular formula:C21H24Cl2O4, chemical name:3- (2,4 dichloro benzene base) -2- oxygen - 1- oxygen spiral shell [4.5] decyl- 3- alkene -4- bases-ST20 ester;With the brand-new mechanism of action, show to suppress lipid Synthesis.By tagging, each stage of development to demodicid mite is all effective, including ovum.
Fenpyroximate (Fenpyroximate) molecular formula:C24H27N3O4, chemical name:(E) -4 [1,3- dimethyl-(5- benzene Oxy-1 H- pyrazolyls) methene ammonia oxygen methyl] -1,1 dimethylethyl esters of benzoic acid;Pathogenic bacteria mycelia is prevented to invade neighbouring health thin Born of the same parents, and generation disease-resistant gene can be induced.Mite class can be directly killed during high dose, mite class decortication can be suppressed during low dosage or laid eggs. With knocking down and suppressing decorticating, without systemic action.
Fenisobromolate (Bromopropylate) molecular formula:C17H16Br2O3, chemical name:4,4'- dibromo diphenylglycollic acids are different Propyl ester;A kind of mite killing spectrum is wide, the acaricide that lasting period length, toxicity are low, safer to natural enemy, Apiss and crop.It is contact compared with By force, without absorbability, to having certain lethal effect into, deutonymph and ovum.Temperature change affects little to drug effect.The medicine is applied to The crops such as Cotton Gossypii, fruit tree, vegetable and tea, can prevent and treat various evil mites such as tetranychid, wart demodicid mite, line demodicid mite.Evil mite is to the medicine and three chlorbensides Alcohol has cross resistance, during use it is noted that.
However, in the real process of agricultural production, preventing and treating evil mite and being easiest to generate the problem that the drug-fast product of evil mite It is raw.Different cultivars composition is compounded, and is to prevent and treat the very common method of resistance evil mite.Heterogeneity is compounded, according to reality Application effect, judges that certain compounding is potentiation, adds and or antagonism.In most cases, the compounding effect of pesticide All be additive effect, really have the compounding of potentiation seldom, especially potentiation clearly, co-toxicity coefficient it is very high Compounding is just less.Study through inventor, find pyriminostrobin and Bifenazate, Hexythiazox, Envidor, fenpyroximate or bromine demodicid mite Can produce good potentiation after ester compounding, and with regard to pyriminostrobin and Bifenazate, Hexythiazox, Envidor, fenpyroximate or The relevant report of fenisobromolate compounding is not yet disclosed.
The content of the invention
The purpose of the present invention is to propose to a kind of with synergistic function, use cost is low, preventive effect is good containing pyriminostrobin Miticide composition.
The miticide composition of containing pyriminostrobin proposed by the present invention contains active components A and active component B, active components A with Active component B weight ratio is 1 ︰, 80~60 ︰ 1, and described active components A is selected from pyriminostrobin, active component B selected from Bifenazate, One of Hexythiazox, Envidor, fenpyroximate or fenisobromolate are planted, active components A and the preferred weight ratios of active component B be 1 ︰ 60~ 40 ︰ 1;More preferably pyriminostrobin and the weight ratio of Bifenazate are 1 ︰, 20~20 ︰ 1, and pyriminostrobin is 1 ︰ with the weight ratio of Hexythiazox 20~20 ︰ 1, pyriminostrobin are 1 ︰, 20~20 ︰ 1 with the weight ratio of Envidor, and pyriminostrobin is 1 ︰, 15~25 ︰ with the weight ratio of fenpyroximate 1, pyriminostrobin is 1 ︰, 25~15 ︰ 1 with the weight ratio of fenisobromolate;More preferably the weight ratio of pyriminostrobin and Bifenazate be 1 ︰ 9~ 9 ︰ 1, the weight ratio of pyriminostrobin and Hexythiazox is 1 ︰, 9~9 ︰ 1, and the weight ratio of pyriminostrobin and Envidor is 1 ︰, 9~9 ︰ 1, pyriminostrobin Weight ratio with fenpyroximate is 1 ︰, 4~14 ︰ 1, and pyriminostrobin is 1 ︰, 14~4 ︰ 1 with the weight ratio of fenisobromolate.
The miticide composition of containing pyriminostrobin proposed by the present invention is used for the purposes for preventing and treating evil mite on crops, described farming Thing includes cereal crops, legume crop, fibre crops, sugar crop, melon crop, fruits crop, dry fruit crop, hobby Crop, root crop, oil crop, flower crop, medicinal crop, crop, green manure pasture crop;Described evil mite bag Include Panonychus citri, yellow spider, red spider, tetranychus viennensis, rust mite, beginning tetranychid, wart demodicid mite, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, Shenmu-Yanan railway.
Active components A, the weight ratio of active component B are 1 ︰, 80~60 ︰ 1.The weight hundred of active component generally in compositionss Divide content for the 0.5%~90% of gross weight, preferably 5%~80%.According to different preparation types, active component content Scope is different.Generally, liquid preparation contains by weight 1%~70% active substance, and preferably 5%~50%; Solid preparation contains by weight 5%~80% active substance, and preferably 10%~80%.
At least contain a kind of surfactant in the miticide composition of the present invention, active component is in water when being beneficial to administration Dispersion.Surface-active contents for total formulation weight 5%~30%, balance of solid or liquid diluent.
Surfactant selected by the miticide composition of the present invention is known in those skilled in the art:Can be selected from One or more in dispersant, wetting agent, binding agent or defoamer.According to different dosage form, can also contain in preparation capable Disintegrating agent, antifreeze well known to field technique personnel etc..
The miticide composition of the present invention can be being diluted using front Jing or directly used by user.Its preparation can be by usual Processing method known in those skilled in the art prepare, will after active substance mixed with liquid flux or solid carrier, Add one or more in surfactant such as dispersant, stabilizer, wetting agent, binding agent, defoamer etc..
The miticide composition of the present invention, can be processed into acceptable dosage form on any pesticide, on demand wherein more preferably Dosage form it is outstanding for wettable powder, water dispersible granules, suspending agent, suspension emulsion aqueous emulsion, microemulsion, microcapsule suspending agent or microcapsule Floating-suspending agent, can also make soluble liquid, soluble powder.
Compositionss include following constituent content when making wettable powder:Active components A 1%~60%, active component B1%~80%, dispersant 2%~10%, wetting agent 2%~10%, filler surplus.
Compositionss include following constituent content when making water dispersible granules:Active components A 1%~60%, active component More than B1%~80%, dispersant 3%~12%, wetting agent 1%~8%, disintegrating agent 1%~10%, binding agent 0~8%, filler Amount.
Compositionss include following constituent content when making suspending agent:Active components A 0.5%~50%, active component B0.5%~50%, dispersant 2%~10%, wetting agent 2%~10%, defoamer 0.01%~2%, thickening agent 0~2%, Antifreeze 0~8%, deionized water adds to 100%.
Compositionss include following constituent content when making aqueous emulsion:Active components A 0.5%~50%, active component B0.5%~50%, solvent 1%~30%, emulsifying agent 1%~15%, antifreeze 0~8%, thickening agent 0~2%, defoamer 0.01%~2%, deionized water supplies surplus.
Compositionss include following constituent content when making microemulsion:Active components A 0.5%~50%, active component B0.5%~50%, solvent 1%~30%, emulsifying agent 3%~25%, antifreeze 0~8%, defoamer 0.01%~2%, go Ionized water supplies surplus.
Compositionss include following constituent content when making microcapsule suspending agent:Active components A 0.5%~50%, active component B0.5%~50%, macromolecule cyst material 2%~10%, dispersant 1%~10%, organic solvent 1%~10%, emulsifying agent 1%~7%, defoamer 0.01%~2%, pH adjusting agent 0.01%~5%, deionized water add to 100%.
The wettable powder the key technical indexes of the present invention:
The water dispersible granules the key technical indexes of the present invention:
The suspending agent the key technical indexes of the present invention:
The aqueous emulsion the key technical indexes of the present invention:
The microemulsion the key technical indexes of the present invention:
The microcapsule suspending agent the key technical indexes of the present invention:
It is an advantage of the current invention that:
(1) after pyriminostrobin is compounded with Bifenazate, Hexythiazox, Envidor, fenpyroximate or fenisobromolate, with obvious potentiation And lasting effect;(2) to cereal crops, legume crop, fibre crops, sugar crop, melon crop, fruits crop, dry fruit On class crop, hobby crop, root crop, oil crop, flower crop, medicinal crop, crop, green manure pasture crop Evil mite have greater activity;(3) pesticide usage amount is reduced, reduces residual quantity of the pesticide on crop, alleviate environment Pollution;(4) to person poultry safety, Environmental compatibility is good;And preparation adhesion strength strengthens, resistance of rainwater washing against.
Specific embodiment
With reference to embodiment to further instruction of the present invention, the percentage ratio in embodiment is weight percentage, but The invention is not limited in this.
Application Example one
1~16 wettable powder of embodiment
By pyriminostrobin, active component B, dispersant, wetting agent, filler mix homogeneously in mixed cylinder, Jing jet mills Remix after crushing uniform, you can wettable powder product of the present invention is obtained, 1 is specifically shown in Table.
1 embodiment of table, 1~16 each component and weight portion
1732 water dispersible granules of embodiment
Pyriminostrobin, active component B, dispersant, wetting agent, disintegrating agent, filler etc. together Jing comminution by gas stream are needed Particle diameter, add other auxiliary agents such as binding agent (can plus can be not added with), obtain materials of pelletizing.Item is quantitatively sent into fluid bed system In grain drying machine after granulation and drying, you can water dispersible granules product of the present invention is obtained, 2 are specifically shown in Table.
2 embodiment of table, 17~32 each component and weight portion
33~48 suspending agent of embodiment
By dispersant, wetting agent, defoamer, thickening agent (can plus can be not added with), antifreeze (can plus can be not added with), through at a high speed Shear-mixed is uniform, adds pyriminostrobin, active component B, and ball milling 2~3 hours in ball mill make diameter of particle all at 5 μm Hereinafter, surplus deionized water is supplied, you can suspending agent product of the present invention is obtained, 3 are specifically shown in Table.
3 embodiment of table, 33~48 each component and weight portion
49~59 aqueous emulsion of embodiment
Pyriminostrobin, active component B, solvent, emulsifying agent are added together, make to be dissolved into homogeneous oil phase;By deionized water, resist Jelly agent (can plus can be not added with), thickening agent (can plus can be not added with), defoamer are mixed, into homogeneous water phase.Under high velocity agitation, Water is added to into oil phase, surplus deionized water is supplied;Aqueous emulsion product of the present invention is can be prepared by, 4 are specifically shown in Table.
4 embodiment of table, 49~59 each component and weight portion
Bifenazate, Hexythiazox, Envidor, fenpyroximate or fenisobromolate in table 1~4 are exchanged, novel formulation can be obtained.
60~62 microemulsion of embodiment
Pyriminostrobin, active component B, solvent, emulsifying agent, antifreeze (can plus can be not added with), defoamer are sufficiently mixed into equal Even transparent oil phase, is slowly added into deionized water under agitation, forms Water in Oil emulsion, then agitated heating, is allowed to fast Fast phase inversion is cooled to room temperature and makes up to balance into oil-in-water type, and Jing is filtered, and surplus deionized water is supplied;Can be prepared by this Bright described microemulsion product, is specifically shown in Table 5.
5 embodiment of table, 60~62 each component and weight portion
Embodiment 63,64 microcapsule suspending agents
By pyriminostrobin, active component B, macromolecule cyst material, solvent mixing, make to be dissolved into homogeneous oil phase, in shearing bar Under part, during oil phase is added to containing emulsifying agent, pH adjusting agent, the aqueous phase solution of dispersant, surplus deionized water is supplied, and two Plant material to react in oil-water interfaces, form high score ascus wall, make the well dispersed microcapsule suspending agent of the present composition Product.6 are shown in Table specifically.
6 embodiment 63 of table, 64 each components and weight portion
The embodiment of the present invention is the method combined using Toxicity Determination and field test.First pass through indoor virulence survey It is fixed, clear and definite two kinds of medicaments compound by a certain percentage after co-toxicity coefficient (CTC), CTC < 80 are antagonism, 80≤CTC≤120 For summation action, CTC > 120 are potentiation, on this basis, then carry out field test.
Test method:The mother solution of each mixed agent is diluted to into five series concentrations respectively during test, is respectively placed in beaker It is standby.Using the method that leaf is followed by demodicid mite is first soaked, by the blade of the same size not in contact with any medicament in the medicinal liquid for having configured Take out after immersion 5s, dry naturally, be put in foster demodicid mite box, then connect demodicid mite young for examination, raise under the conditions of 25 DEG C, often process 3 Secondary repetition, it is 50 often to repeat examination demodicid mite number used, while setting blank, checks dead demodicid mite number in 72h, calculates mortality rate and correction Mortality rate, tries to achieve virulence regression equation and calculates LC50Value.If control mortality rate is more than 10%, it is considered as invalid test.Calculate public Formula is as follows:
Evil mite corrected mortality is converted into into probit value (y), concentration for the treatment of (μ g/ml) is converted into logarithm value (x), with minimum Square law draws virulence regression equation, and thus calculates the value of every kind of medicament, calculates common poison system according to the abundant equations of Sun Yun Number CTC.Computing formula is following, and (with pyriminostrobin as standard agent, its toxicity index is for 100):
TI × the P of theoretical toxicity index (the TTI)=pyriminostrobin of MPyriminostrobinTI × the P of+effective active composition BEffective active compositionB
In formula:Mixture of the M for different ratio
PEffective active compositionB is effective active composition B ratio shared in the composition
PPyriminostrobinFor pyriminostrobin ratio shared in the composition
B is planted selected from one of Bifenazate, Hexythiazox, Envidor, fenpyroximate or fenisobromolate.
Application Example two:
For trying evil mite:Apple tree red spider
Test medicine is provided by Shanxi Thompson Biological Technology Co., Ltd..
EXPERIMENTAL DESIGN:The effective of pyriminostrobin and Bifenazate active compound and the two different ratio mixture is determined through pilot study Lethasl concentration scope.Toxicity test result
7 pyriminostrobin of table compounds the toxicity test analysis of results table to apple tree red spider with Bifenazate
As shown in Table 7, to apple tree red spider proportioning in 1 80~60 ︰ 1 of ︰, co-toxicity coefficient is equal for pyriminostrobin and Bifenazate More than 120, illustrate that both show potentiation at the mixture in the range of 1 ︰, 80~60 ︰ 1, when matching somebody with somebody for pyriminostrobin and Bifenazate Than in 1 20~20 ︰ 1 of ︰, potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 215.Wherein when pyriminostrobin and biphenyl hydrazine Ester weight ratio is 1:When 2, co-toxicity coefficient is maximum, and potentiation is the most obvious.Jing applicant's test finds pyriminostrobin and Bifenazate Proportioning is 20:1、15:1、10:1、8:1、6:1、5:1、4:1、3:1、2:1、1:1、1:2、1:3、1:4、1:5、1:6、1:8、1: 10、1:12、1:14、1:15、1:To the Panonychus citri in various crop, yellow spider, red spider, tetranychus viennensis, rust mite, beginning when 20 Tetranychid, wart demodicid mite, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, the preventing and treating of Shenmu-Yanan railway have obvious potentiation, altogether poison system Number is all higher than 120.
Application Example three
For trying evil mite:Citrus red mite
Test medicine is provided by Shanxi Thompson Biological Technology Co., Ltd..
EXPERIMENTAL DESIGN:Effective cause of pyriminostrobin and Hexythiazox active compound and the two different ratio mixture is determined through pilot study Dead concentration range.
8 pyriminostrobin of table compounds the toxicity test analysis of results table to citrus red mite with Hexythiazox
As shown in Table 8, to citrus red mite proportioning in 1 80~60 ︰ 1 of ︰, co-toxicity coefficient is all higher than for pyriminostrobin and Hexythiazox 120, illustrate that both show potentiation at the mixture in the range of 1 ︰, 80~60 ︰ 1, when the proportioning of pyriminostrobin and Hexythiazox is in 1 ︰ During 20~20 ︰ 1, potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 215.Wherein when pyriminostrobin and Hexythiazox weight ratio For 2:When 1, co-toxicity coefficient is maximum, and potentiation is the most obvious.Jing applicant's test finds that pyriminostrobin is 20 with Hexythiazox proportioning: 1、15:1、10:1、8:1、6:1、5:1、4:1、3:1、2:1、1:1、1:2、1:3、1:4、1:5、1:6、1:8、1:10、1:12、1: 14、1:15、1:When 20 to the Panonychus citri in various crop, yellow spider, red spider, tetranychus viennensis, rust mite, beginning tetranychid, wart demodicid mite, Yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, the preventing and treating of Shenmu-Yanan railway have obvious potentiation, and co-toxicity coefficient is all higher than 120。
Application Example four
For trying evil mite:Citrus red mite
Test medicine is provided by Shanxi Thompson Biological Technology Co., Ltd..
EXPERIMENTAL DESIGN:Effective cause of pyriminostrobin and Envidor active compound and the two different ratio mixture is determined through pilot study Dead concentration range.
9 pyriminostrobin of table compounds the toxicity test analysis of results table to citrus red mite with Envidor
Reagent agent Proportioning LC50(ug/mL) Co-toxicity coefficient (CTC)
Pyriminostrobin - 1.50 -
Envidor - 1.28 -
Phonetic Man An ︰ Envidors 60∶1 0.82 185.94
Phonetic Man An ︰ Envidors 40∶1 0.78 197.06
Phonetic Man An ︰ Envidors 20∶1 0.72 218.62
Phonetic Man An ︰ Envidors 9∶1 0.73 228.01
Phonetic Man An ︰ Envidors 5∶1 0.77 233.22
Phonetic Man An ︰ Envidors 1∶1 1.15 257.85
Phonetic Man An ︰ Envidors 1∶5 3.55 239.49
Phonetic Man An ︰ Envidors 1∶9 6.02 225.40
Phonetic Man An ︰ Envidors 1∶20 11.85 215.35
Phonetic Man An ︰ Envidors 1∶40 21.55 194.30
Phonetic Man An ︰ Envidors 1∶60 27.88 192.70
Phonetic Man An ︰ Envidors 1∶80 33.01 189.97
As shown in Table 9, to citrus red mite proportioning in 1 80~60 ︰ 1 of ︰, co-toxicity coefficient is all higher than for pyriminostrobin and Envidor 120, illustrate that both show potentiation at the mixture in the range of 1 ︰, 80~60 ︰ 1, when the proportioning of pyriminostrobin and Envidor is in 1 ︰ During 20~20 ︰ 1, potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 215, wherein when pyriminostrobin and Envidor weight ratio For 1:When 1, co-toxicity coefficient is maximum, and potentiation is the most obvious.Jing applicant's test finds that pyriminostrobin is 20 with Envidor proportioning: 1、15:1、10:1、8:1、6:1、5:1、4:1、3:1、2:1、1:1、1:2、1:3、1:4、1:5、1:6、1:8、1:10、1:12、1: 14、1:15、1:When 20 to the Panonychus citri in various crop, yellow spider, red spider, tetranychus viennensis, rust mite, beginning tetranychid, wart demodicid mite, Yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, the preventing and treating of Shenmu-Yanan railway have obvious potentiation, and co-toxicity coefficient is all higher than 120。
Application Example five
For trying evil mite:Apple tree red spider
Test medicine is provided by Shanxi Thompson Biological Technology Co., Ltd..
EXPERIMENTAL DESIGN:Effective cause of pyriminostrobin and fenpyroximate active compound and the two different ratio mixture is determined through pilot study Dead concentration range.
10 pyriminostrobin of table compounds the toxicity test analysis of results table to apple tree red spider with fenpyroximate
Reagent agent Proportioning LC50(ug/mL) Co-toxicity coefficient (CTC)
Pyriminostrobin - 1.55 -
Fenpyroximate - 0.56 -
Phonetic Man An ︰ fenpyroximates 60∶1 0.79 199.38
Phonetic Man An ︰ fenpyroximates 40∶1 0.79 200.97
Phonetic Man An ︰ fenpyroximates 25∶1 0.74 217.60
Phonetic Man An ︰ fenpyroximates 14∶1 0.72 230.20
Phonetic Man An ︰ fenpyroximates 10∶1 0.73 232.92
Phonetic Man An ︰ fenpyroximates 5∶1 0.77 240.23
Phonetic Man An ︰ fenpyroximates 3∶1 0.81 252.81
Phonetic Man An ︰ fenpyroximates 1∶1 1.22 247.25
Phonetic Man An ︰ fenpyroximates 1∶4 3.01 231.81
Phonetic Man An ︰ fenpyroximates 1∶15 7.88 222.39
Phonetic Man An ︰ fenpyroximates 1∶20 10.01 209.31
Phonetic Man An ︰ fenpyroximates 1∶40 16.54 182.34
Phonetic Man An ︰ fenpyroximates 1∶60 19.56 181.67
Phonetic Man An ︰ fenpyroximates 1∶80 21.56 181.17
As shown in Table 10, to apple tree red spider proportioning in 1 80~60 ︰ 1 of ︰, co-toxicity coefficient is equal for pyriminostrobin and fenpyroximate More than 120, illustrate that both show potentiation at the mixture in the range of 1 ︰, 80~60 ︰ 1, when pyriminostrobin and the proportioning of fenpyroximate In 1 15~25 ︰ 1 of ︰, potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 215.Wherein when pyriminostrobin and fenpyroximate weight Amount is than being 3:When 1, co-toxicity coefficient is maximum, and potentiation is the most obvious.Jing applicant's test finds that pyriminostrobin with fenpyroximate proportioning is 25:1、20:1、15:1、10:1、8:1、6:1、5:1、4:1、3:1、2:1、1:1、1:2、1:3、1:4、1:5、1:6、1:8、1:10、 1:12、1:14、1:To the Panonychus citri in various crop, yellow spider, red spider, tetranychus viennensis, rust mite, beginning tetranychid, wart when 15 Demodicid mite, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, the preventing and treating of Shenmu-Yanan railway have obvious potentiation, and co-toxicity coefficient is all higher than 120。
Application Example six
For trying evil mite:Mandarin tree red spider
Test medicine is provided by Shanxi Thompson Biological Technology Co., Ltd..
11 pyriminostrobin of table compounds the toxicity test analysis of results table to mandarin tree red spider with fenisobromolate
As shown in Table 11, to mandarin tree red spider proportioning in 1 80~60 ︰ 1 of ︰, co-toxicity coefficient is equal for pyriminostrobin and fenisobromolate More than 120, illustrate that both show potentiation at the mixture in the range of 1 ︰, 80~60 ︰ 1, when pyriminostrobin and the proportioning of fenisobromolate In 1 25~15 ︰ 1 of ︰, potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 215, wherein when pyriminostrobin and fenisobromolate weight Amount is than being 1:When 6, co-toxicity coefficient is maximum, and potentiation is the most obvious.Jing applicant's test finds that pyriminostrobin with fenisobromolate proportioning is 15:1、10:1、5:1、4:1、3:1、2:1、1:1、1:2、1:3、1:4、1:5、1:6、1:7、1:8、1:9、1:10、1:12、1:14、 1:15、1:20、1:It is yellow to the red spider in various crop, yellow spider, rust mite, Panonychus citri, wart demodicid mite, tetranychus viennensis, tea when 25 Demodicid mite, Tetranychus cinnabarinus, Tetranychus urticae, beginning tetranychid, the preventing and treating of Shenmu-Yanan railway have obvious potentiation, and co-toxicity coefficient is all higher than 120。
Effect experiment part:Test medicine is researched and developed by Shanxi Thompson Biological Technology Co., Ltd., is provided, comparison medicament 15% pyriminostrobin soluble concentrate (autogamy), 43% Bifenazate suspending agent (commercial), 5% Hexythiazox cream (commercial), 240g/l Envidor suspension emulsion (commercial), 5% Enpyfoximate dispersant (commercial), 500 g/l of fenisobromolate cream (commercial).
Seven pyriminostrobin of Application Example and active component B and its compounding preventing and treating mandarin tree red spider test of pesticide effectiveness, this test Shaanxi Province Hanzhong suburban area is arranged in, and mandarin tree red spider damage index of spider mites is investigated before medicine, early period of origination dispenser is done harm in demodicid mite, after dispenser Investigate damage index of spider mites and calculate preventive effect within 3 days, 15 days, 30 days.Result of the test is as follows:
12 pyriminostrobin of table and active component B and its compounding preventing and treating mandarin tree red spider test of pesticide effectiveness
As can be seen from Table 12, mandarin tree red spider, prevention effect can effectively be prevented and treated after pyriminostrobin and active component B compoundings The preventive effect of single dose is superior to, and preventive effect phase is long.Target crop is had no adverse effects in test scope of medication.
Eight pyriminostrobin of Application Example and active component B and its compounding preventing and treating apple tree red spider test of pesticide effectiveness, this test Shaanxi Province Weinan City Dali County is arranged in, and apple tree red spider damage index of spider mites is investigated before medicine, early period of origination dispenser, dispenser is done harm in demodicid mite Investigate damage index of spider mites and calculate preventive effect within 3 days afterwards, 15 days, 30 days.Result of the test is as follows:
13 pyriminostrobin of table and active component B and its compounding preventing and treating apple tree red spider test of pesticide effectiveness
As can be seen from Table 13, energy effectively preventing and treating apple-tree red spider, prevention effect after pyriminostrobin is compounded with active component B The preventive effect of single dose is superior to, and preventive effect phase is long.Target crop is had no adverse effects in test scope of medication.
Nine pyriminostrobin of Application Example and active component B and its compounding preventing and treating peach tree red spider test of pesticide effectiveness, this test peace Shaanxi Province Weinan City Dali County is come, and peach tree red spider damage index of spider mites is investigated before medicine, early period of origination dispenser is done harm in demodicid mite, 3 after dispenser My god, 15 days, investigation in 30 days damage index of spider mites calculate preventive effect.Result of the test is as follows:
14 pyriminostrobin of table and active component B and its compounding preventing and treating peach tree red spider test of pesticide effectiveness
As can be seen from Table 14, peach tree red spider can effectively be prevented and treated after pyriminostrobin and active component B compoundings, prevention effect is equal Better than the preventive effect of single dose, and preventive effect phase is long.Target crop is had no adverse effects in test scope of medication.
Ten pyriminostrobin of Application Example and active component B and its compounding preventing and treating mandarin tree blister mite test of pesticide effectiveness, this test Shaanxi Province's Hanzhong City is arranged in, and mandarin tree blister mite damage index of spider mites is investigated before medicine, early period of origination dispenser is done harm in demodicid mite, 3 days after dispenser, Investigate damage index of spider mites and calculate preventive effect within 15 days, 30 days.Result of the test is as follows:
15 pyriminostrobin of table and active component B and its compounding preventing and treating mandarin tree blister mite test of pesticide effectiveness
As can be seen from Table 15, mandarin tree blister mite, prevention effect can effectively be prevented and treated after pyriminostrobin and active component B compoundings The preventive effect of single dose is superior to, and preventive effect phase is long.Target crop is had no adverse effects in test scope of medication.
11 pyriminostrobin of Application Example and active component B and its compounding preventing and treating cotton red spider test of pesticide effectiveness, this test Shaanxi Province Weinan City Pucheng County is arranged in, and cotton red spider damage index of spider mites is investigated before medicine, early period of origination dispenser is done harm in demodicid mite, after dispenser Investigate damage index of spider mites and calculate preventive effect within 3 days, 15 days, 30 days.Result of the test is as follows:
16 pyriminostrobin of table and active component B and its compounding preventing and treating cotton red spider test of pesticide effectiveness
As can be seen from Table 16, cotton red spider can effectively be prevented and treated after pyriminostrobin and active component B compoundings, prevention effect is equal Better than the preventive effect of single dose, and preventive effect phase is long.Target crop is had no adverse effects in test scope of medication.
12 pyriminostrobin of Application Example and active component B and its compounding preventing and treating wheat red spider test of pesticide effectiveness, this test Shaanxi Province's Hanzhong City is arranged in, and wheat red spider damage index of spider mites is investigated before medicine, early period of origination dispenser is done harm in demodicid mite, 3 days after dispenser, 15 My god, investigation in 30 days damage index of spider mites calculate preventive effect.Result of the test is as follows:
17 pyriminostrobin of table and active component B and its compounding preventing and treating wheat red spider test of pesticide effectiveness
As can be seen from Table 17, wheat red spider can effectively be prevented and treated after pyriminostrobin and active component B compoundings, prevention effect is equal Better than the preventive effect of single dose, and preventive effect phase is long.Target crop is had no adverse effects in test scope of medication.
Test through different places throughout the country afterwards draws, pyriminostrobin and Bifenazate, Hexythiazox, Envidor, azoles Demodicid mite ester or fenisobromolate compounding after to the Panonychus citri in various crop, yellow spider, red spider, tetranychus viennensis, rust mite, beginning tetranychid, The preventive effect of the common evil mite such as wart demodicid mite, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae or Shenmu-Yanan railway more than 95%, better than list Agent preventive effect, potentiation are obvious.

Claims (7)

1. a kind of miticide composition of containing pyriminostrobin, effective active composition are active components A and active component B, it is characterised in that: Described active components A is pyriminostrobin, and active component B is selected from one of Hexythiazox, fenpyroximate or fenisobromolate kind, wherein pyriminostrobin Weight ratio with Hexythiazox is 60:1~40:1、15:1~9:1、6:1~4:1, pyriminostrobin is 60 with the weight ratio of fenpyroximate:1 ~3:1, pyriminostrobin is 60 with the weight ratio of fenisobromolate:1~1:6.
2. the miticide composition of containing pyriminostrobin according to claim 1, it is characterised in that:Compositionss make wettable powder Agent, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent.
3. the miticide composition of containing pyriminostrobin according to claim 2 is used for the purposes for preventing and treating evil mite on crops.
4. purposes according to claim 3, it is characterised in that described evil mite is rust mite, beginning tetranychid, yellow tea mite or god Ze Shi tetranychids.
5. purposes according to claim 3, it is characterised in that described evil mite is red spider.
6. purposes according to claim 3, it is characterised in that described evil mite is yellow spider.
7. purposes according to claim 3, it is characterised in that described evil mite is Tetranychus urticae.
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