CN104559038A - Plastic cap master batch for producing wine bottles - Google Patents
Plastic cap master batch for producing wine bottles Download PDFInfo
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- CN104559038A CN104559038A CN201510041013.8A CN201510041013A CN104559038A CN 104559038 A CN104559038 A CN 104559038A CN 201510041013 A CN201510041013 A CN 201510041013A CN 104559038 A CN104559038 A CN 104559038A
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Abstract
The invention discloses a plastic cap master batch for producing wine bottles, which is prepared from the following raw materials in parts by weight: 100-105 parts of ABS (acrylonitrile-butadiene-styrene), 1-2 parts of cedar wood oil, 6-8 parts of polytetrafluoroethylene, 1-2 parts of alumina-silicate ceramic fiber, 2-4 parts of metastannic acid, 0.3-1 part of dibasic lead phosphite, 1-2 parts of isopropanol, 1-2 parts of glyceryl carboxylate, 1-2 parts of calcium propionate, 0.3-0.5 part of ethyl maltol, 2-4 parts of sodium myristate soap, 2-3 parts of ester gum, 0.1-0.2 part of lithium naphthenate, 10-12 parts of pyrauxite, 3-5 parts of tributyl citrate and 1-2 parts of toughening filler. The plastic cap master batch has strong effects on controlling bacteria and preventing mildew, and has the advantages of high processability, high stretching resistance, high tear resistance and high surface strength; the added toughening filler can effectively enhance the surface impact resistance and bearing strength; and thus, the plastic cap master batch is especially suitable for producing plastic caps of wine bottles.
Description
Technical field
The present invention relates generally to plastic cover field, particularly relates to a kind of plastic cover masterbatch producing bottle.
Background technology
There is a lot of deficiencies as the plastic cover of bottle in tradition, some much higher hards, easily cause unexpected injury to human body, have high temperature resistant, preservative property are bad, more serious is exactly stopping property difference, causes leakage, and easily threads off under pressure.
Summary of the invention
The object of the invention is just to provide a kind of plastic cover masterbatch producing bottle.
The present invention is achieved by the following technical solutions:
Produce a plastic cover masterbatch for bottle, it is characterized in that what it was made up of the raw material of following weight parts:
ABS100-105, cedar(wood)oil 1-2, tetrafluoroethylene 6-8, alumina-silicate ceramic fibre 1-2, metastannic acid 2-4, dibasic lead phosphite 0.3-1, Virahol 1-2, short and long-chain acyl triglyceride molecules 1-2, calcium propionate 1-2, veltol plus 0.3-0.5, tetradecanoic acid soda soap 2-4, ester gum 2-3, naphthenic acid lithium 0.1-0.2, agalmatolite 10-12, tributyl citrate 3-5, toughness reinforcing filler 1-2;
Described toughness reinforcing filler is made up of the raw material of following weight parts:
Graphene oxide 40-50, nano titanium oxide 1-2, tributyl citrate 1-2, polyvinyl butyral acetal 2-3, tripoly phosphate sodium STPP 6-10, tetraethoxy 1-2, needle-like nano calcium carbonate 0.4-1, deionized water 90-100, silane coupling agent KH560 0.1-0.2;
Preparation method is after graphene oxide and methyl methacrylate are uniformly mixed 20-30 minute, then adds graphene oxide, needle-like nano calcium carbonate, polyvinyl butyral acetal, is heated to 45-55 DEG C, stirs 10-20 minute, must stir material; Other remaining component mix and blend, after 10-20 minute, adds stirring material and mixes and get final product.
2, a preparation method for the plastic cover masterbatch of production bottle as claimed in claim 1, is characterized in that comprising the following steps:
By tetrafluoroethylene, tributyl citrate mixing, insulated and stirred 5-10 minute at 60-70 DEG C, obtains esterification ethene;
Agalmatolite is calcined 1-2 hour at 600-700 DEG C, with calcium propionate mixing abrasive dust after discharging cooling, adds Virahol, short and long-chain acyl triglyceride molecules, stir;
Each raw material after above-mentioned process is mixed with each raw material of residue, through melting mixing, extruding pelletization after stirring, obtains described masterbatch.
Advantage of the present invention is:
The toughness reinforcing filler that the present invention adds is based on graphene oxide, there is excellent tensile strength and toughness, through the process of ABS high glue powder, surface strength can be improved further, the polyvinyl butyral acetal improving methyl methacrylate introducing has excellent flexibility and flexibility, further increases toughening effect.
Plastic cover masterbatch of the present invention has the effect of potent anti-bacteria and mildew-resistant, processing characteristics is strong, stretch-proof, tear strength are strong, surface strength is high, the toughness reinforcing filler added can effectively improve surperficial shock resistance and bearing resistance, be particularly suitable for the plastic cover producing bottle, resistance to air loss is good, and not easily threads off.
Embodiment
Embodiment 1
Produce a plastic cover masterbatch for bottle, it is characterized in that what it was made up of the raw material of following weight parts:
ABS105, cedar(wood)oil 1, tetrafluoroethylene 8, alumina-silicate ceramic fibre 1, metastannic acid 4, dibasic lead phosphite 0.3, Virahol 1, short and long-chain acyl triglyceride molecules 2, calcium propionate 2, veltol plus 0.5, tetradecanoic acid soda soap 2, ester gum 2, naphthenic acid lithium 0.2, agalmatolite 12, tributyl citrate 5, toughness reinforcing filler 1;
Described toughness reinforcing filler is made up of the raw material of following weight parts:
Graphene oxide 50, nano titanium oxide 1, tributyl citrate 1, polyvinyl butyral acetal 23, tripoly phosphate sodium STPP 10, tetraethoxy 1-2, needle-like nano calcium carbonate 0.4, deionized water 100, silane coupling agent KH560 0.2;
Preparation method is after graphene oxide and methyl methacrylate are uniformly mixed 20-30 minute, then adds graphene oxide, needle-like nano calcium carbonate, polyvinyl butyral acetal, is heated to 45-55 DEG C, stirs 10-20 minute, must stir material; Other remaining component mix and blend, after 10-20 minute, adds stirring material and mixes and get final product.
Produce a preparation method for the plastic cover masterbatch of bottle, comprise the following steps:
By tetrafluoroethylene, tributyl citrate mixing, at 70 DEG C, insulated and stirred 10 minutes, obtains esterification ethene;
Agalmatolite is calcined 2 hours at 700 DEG C, with calcium propionate mixing abrasive dust after discharging cooling, adds Virahol, short and long-chain acyl triglyceride molecules, stir;
Each raw material after above-mentioned process is mixed with each raw material of residue, through melting mixing, extruding pelletization after stirring, obtains described masterbatch.
Performance test:
Tensile strength MPa:40-42;
Shock strength J/m:120-124;
Vertical combustion rank UL-94: V0.
Claims (2)
1. produce a plastic cover masterbatch for bottle, it is characterized in that what it was made up of the raw material of following weight parts:
ABS100-105, cedar(wood)oil 1-2, tetrafluoroethylene 6-8, alumina-silicate ceramic fibre 1-2, metastannic acid 2-4, dibasic lead phosphite 0.3-1, Virahol 1-2, short and long-chain acyl triglyceride molecules 1-2, calcium propionate 1-2, veltol plus 0.3-0.5, tetradecanoic acid soda soap 2-4, ester gum 2-3, naphthenic acid lithium 0.1-0.2, agalmatolite 10-12, tributyl citrate 3-5, toughness reinforcing filler 1-2;
Described toughness reinforcing filler is made up of the raw material of following weight parts:
Graphene oxide 40-50, nano titanium oxide 1-2, tributyl citrate 1-2, polyvinyl butyral acetal 2-3, tripoly phosphate sodium STPP 6-10, tetraethoxy 1-2, needle-like nano calcium carbonate 0.4-1, deionized water 90-100, silane coupling agent KH560 0.1-0.2;
Preparation method is after graphene oxide and methyl methacrylate are uniformly mixed 20-30 minute, then adds graphene oxide, needle-like nano calcium carbonate, polyvinyl butyral acetal, is heated to 45-55 DEG C, stirs 10-20 minute, must stir material; Other remaining component mix and blend, after 10-20 minute, adds stirring material and mixes and get final product.
2. the preparation method producing the plastic cover masterbatch of bottle as claimed in claim 1, is characterized in that comprising the following steps:
By tetrafluoroethylene, tributyl citrate mixing, insulated and stirred 5-10 minute at 60-70 DEG C, obtains esterification ethene;
Agalmatolite is calcined 1-2 hour at 600-700 DEG C, with calcium propionate mixing abrasive dust after discharging cooling, adds Virahol, short and long-chain acyl triglyceride molecules, stir;
Each raw material after above-mentioned process is mixed with each raw material of residue, through melting mixing, extruding pelletization after stirring, obtains described masterbatch.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510041013.8A CN104559038A (en) | 2015-01-27 | 2015-01-27 | Plastic cap master batch for producing wine bottles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510041013.8A CN104559038A (en) | 2015-01-27 | 2015-01-27 | Plastic cap master batch for producing wine bottles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104559038A true CN104559038A (en) | 2015-04-29 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510041013.8A Pending CN104559038A (en) | 2015-01-27 | 2015-01-27 | Plastic cap master batch for producing wine bottles |
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| CN (1) | CN104559038A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105440561A (en) * | 2015-12-17 | 2016-03-30 | 东莞市卡尔文塑胶科技有限公司 | Corrosion-resistant flexibilizer, and preparation method thereof |
| CN107619618A (en) * | 2017-10-30 | 2018-01-23 | 成都新柯力化工科技有限公司 | It is a kind of to improve graphene method dispersed in coating |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1623862A (en) * | 2004-06-09 | 2005-06-08 | 东莞市金富实业有限公司 | Long-acting antibiosis plastic container cover and its mfg. process |
| CN101323695A (en) * | 2008-08-04 | 2008-12-17 | 四川省隆鑫科技包装有限公司 | ABS modified plastic for battle cap |
| CN103980653A (en) * | 2014-05-27 | 2014-08-13 | 东莞市金富实业有限公司 | High-strength antibacterial plastic bottle cap and manufacturing process thereof |
| CN103980655A (en) * | 2014-06-12 | 2014-08-13 | 东莞市金富实业有限公司 | Antibacterial plastic bottle cap and manufacturing process thereof |
-
2015
- 2015-01-27 CN CN201510041013.8A patent/CN104559038A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1623862A (en) * | 2004-06-09 | 2005-06-08 | 东莞市金富实业有限公司 | Long-acting antibiosis plastic container cover and its mfg. process |
| CN101323695A (en) * | 2008-08-04 | 2008-12-17 | 四川省隆鑫科技包装有限公司 | ABS modified plastic for battle cap |
| CN103980653A (en) * | 2014-05-27 | 2014-08-13 | 东莞市金富实业有限公司 | High-strength antibacterial plastic bottle cap and manufacturing process thereof |
| CN103980655A (en) * | 2014-06-12 | 2014-08-13 | 东莞市金富实业有限公司 | Antibacterial plastic bottle cap and manufacturing process thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105440561A (en) * | 2015-12-17 | 2016-03-30 | 东莞市卡尔文塑胶科技有限公司 | Corrosion-resistant flexibilizer, and preparation method thereof |
| CN107619618A (en) * | 2017-10-30 | 2018-01-23 | 成都新柯力化工科技有限公司 | It is a kind of to improve graphene method dispersed in coating |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150429 |