CN104311961A - Fiber enhanced nozzle - Google Patents
Fiber enhanced nozzle Download PDFInfo
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- CN104311961A CN104311961A CN201410591632.XA CN201410591632A CN104311961A CN 104311961 A CN104311961 A CN 104311961A CN 201410591632 A CN201410591632 A CN 201410591632A CN 104311961 A CN104311961 A CN 104311961A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/068—Ultra high molecular weight polyethylene
Abstract
The invention discloses a fiber enhanced nozzle which is prepared from the following raw materials in parts by weight: 0.4-1 part of metastannic acid, 2-3 parts of calcium ricinoleate, 1-2 parts of sodium fluoborate, 2-4 parts of aluminium nitride, 4-6 parts of polytetrafluoroethylene fibers, 0.5-1 part of alkenyl succinic anhydride, 2-3 parts of dimethyl glutarate, 91-100 parts of ultrahigh molecular weight polyethylene, 0.4-1 part of polyimide, 1-2 parts of tetrabutylammonium bromide, 1-2 parts of triethylene glycol, 10-14 parts of graphite powder, 0.4-1 part of molybdenum oxide, 5-6 parts of a highly resistant auxiliary, 0.3-1 part of methyl ethyl ketoxime, 0.3-0.5 part of T800 carbon fibers, 0.7-2 parts of valerian oil and 2-3 parts of dioctyl azelate. By adding the highly resistant auxiliary, esterified butyraldehyde has good flexibility and flexural property and an emulsion adhesive can be used for promoting compatibility of materials and improving the mobility of a melt; by blending and modifying a methyl methacrylate-butadiene-styrene terpolymer which is softened with esterified butyraldehyde and emulsion adhesive, the surface resistance of a finished product is extremely improved.
Description
Technical field
The present invention relates generally to plastic applications, particularly relates to a kind of fiber reinforcement type nozzle.
Background technology
Nozzle is parts very crucial in the equipment such as a variety of spray, spraying, oil spout, sandblasting, spraying, play an important role, nozzle application in the industry widely, material is from stainless steel, plastics to silicon carbide, polytetrafluoroethylene, PP(engineering plastics), aluminium alloy and wolfram steel etc., range of application is generally commonly used in the industry-by-industries such as automobile, plating, surface treatment, high pressure cleaning, dedusting, cooling, desulfurization, humidification, stirring, gardens.
Summary of the invention
The object of the invention is just to provide a kind of fiber reinforcement type nozzle.
The present invention is achieved by the following technical solutions:
A kind of fiber reinforcement type nozzle, is characterized in that what it was made up of the raw material of following weight parts:
Metastannic acid 0.4-1, calcium ricinoleate 2-3, Sodium tetrafluoroborate 1-2, aluminium nitride 2-4, polytetrafluoroethylene fiber 4-6, alkenyl succinic anhydride 0.5-1, Methyl glutarate 2-3, ultrahigh molecular weight polyethylene(UHMWPE) 91-100, polyimide 0.4-1, Tetrabutyl amonium bromide 1-2, triglycol 1-2, Graphite Powder 99 10-14, molybdenum oxide 0.4-1, high resistance auxiliary agent 5-6, methyl ethyl ketoxime 0.3-1, T800 carbon fiber 0.3-0.5, valerian oil 0.7-2, dioctyl azelate 2-3;
Described high resistance auxiliary agent is made up of the raw material of following weight parts:
Neusilin 3-4, MBS terpolymer 30-40, polyvinyl butyral acetal 6-9, Sodium dodecylbenzene sulfonate 1-2, TriMethylolPropane(TMP) 0.4-1, nylon acid methyl esters 2-3, phytinic acid 0.6-1;
Polyvinyl butyral acetal is heated to 60-65 DEG C, adds nylon acid methyl esters, insulated and stirred 6-10 minute, be cooled to normal temperature, obtain esterification butyral;
Sodium dodecylbenzene sulfonate is joined in 8-10 times of water, stir, add neusilin, phytinic acid, be uniformly mixed, obtain emulsion adhesive;
Each raw material after above-mentioned process is mixed with MBS terpolymer, send into reactor, stir, dewatered drying, adds TriMethylolPropane(TMP), at pressure 1.8-1.9MPa, temperature 84-90 DEG C, be uniformly mixed 1-2 hour, cooling discharging, abrasive dust, obtains described high resistance auxiliary agent.
A preparation method for fiber reinforcement type nozzle as claimed in claim 1, is characterized in that comprising the following steps:
Mixed with T800 carbon fiber, polytetrafluoroethylene fiber by aluminium nitride, be heated to 120-130 DEG C, insulation mixing 10-20 minute, reduction temperature is 80-90 DEG C, adds dioctyl azelate, is uniformly mixed 6-10 minute, obtains esterification conjugated fibre;
The 10-20% getting above-mentioned ultrahigh molecular weight polyethylene(UHMWPE) weight mixes with Graphite Powder 99, and add calcium ricinoleate, esterification conjugated fibre after stirring, ball milling is even;
Sodium tetrafluoroborate is mixed with triglycol, molybdenum oxide, after stirring, adds polyimide, be heated to 50-60 DEG C, 30-50 rev/min of dispersed with stirring 5-10 minute;
Mixed with each raw material of residue by each raw material after above-mentioned process, send in rubber mixing machine, mixing 2-3 hour at 135-140 DEG C, is placed in injection moulding machine, is processed into described fiber reinforcement type nozzle.
Advantage of the present invention is:
The high resistance auxiliary agent added in the present invention: wherein esterification butyral has good flexibility and flexibility, emulsion adhesive can promote the consistency of storeroom, and improves the mobility of melt; By softening for MBS terpolymer rear and esterification butyral, emulsion adhesive blending and modifying, greatly improve the surface resistive of finished product;
The esterification conjugated fibre quality added in nozzle of the present invention is light, density is low, and intensity is high, effectively can improve the consistency with various storeroom, improves the surface resistive of finished product, strengthens the over-all properties of finished product.
Embodiment
Embodiment 1
A kind of fiber reinforcement type nozzle, is characterized in that what it was made up of the raw material of following weight parts:
Metastannic acid 0.4, calcium ricinoleate 3, Sodium tetrafluoroborate 2, aluminium nitride 4, polytetrafluoroethylene fiber 6, alkenyl succinic anhydride 0.5, Methyl glutarate 3, ultrahigh molecular weight polyethylene(UHMWPE) 100, polyimide 0.4, Tetrabutyl amonium bromide 2, triglycol 2, Graphite Powder 99 14, molybdenum oxide 0.4, high resistance auxiliary agent 6, methyl ethyl ketoxime 0.3, T800 carbon fiber 0.5, valerian oil 0.7, dioctyl azelate 3;
Described high resistance auxiliary agent is made up of the raw material of following weight parts:
Neusilin 4, MBS terpolymer 40, polyvinyl butyral acetal 6, Sodium dodecylbenzene sulfonate 2, TriMethylolPropane(TMP) 0.4, nylon acid methyl esters 3, phytinic acid 0.6;
Polyvinyl butyral acetal is heated to 65 DEG C, adds nylon acid methyl esters, insulated and stirred 6-10 minute, be cooled to normal temperature, obtain esterification butyral;
Sodium dodecylbenzene sulfonate is joined in 10 times of water, stir, add neusilin, phytinic acid, be uniformly mixed, obtain emulsion adhesive;
Each raw material after above-mentioned process is mixed with MBS terpolymer, send into reactor, stir, dewatered drying, adds TriMethylolPropane(TMP), at pressure 1.9MPa, temperature 90 DEG C, be uniformly mixed 2 hours, cooling discharging, abrasive dust, obtains described high resistance auxiliary agent.
A preparation method for fiber reinforcement type nozzle, is characterized in that comprising the following steps:
Mixed with T800 carbon fiber, polytetrafluoroethylene fiber by aluminium nitride, be heated to 130 DEG C, insulation mixing 20 minutes, reducing temperature is 90 DEG C, adds dioctyl azelate, is uniformly mixed 10 minutes, obtain esterification conjugated fibre;
Get above-mentioned ultrahigh molecular weight polyethylene(UHMWPE) weight 20% mixes with Graphite Powder 99, and add calcium ricinoleate, esterification conjugated fibre after stirring, ball milling is even;
Sodium tetrafluoroborate is mixed with triglycol, molybdenum oxide, after stirring, adds polyimide, be heated to 60 DEG C, 50 revs/min of dispersed with stirring 10 minutes;
Each raw material after above-mentioned process mix with residue each raw material, in feeding rubber mixing machine, at 140 DEG C mixing 3 hours, is placed in injection moulding machine, is processed into described fiber reinforcement type nozzle.
Performance test: tensile strength 31.6MPa.
Claims (2)
1. a fiber reinforcement type nozzle, is characterized in that what it was made up of the raw material of following weight parts:
Metastannic acid 0.4-1, calcium ricinoleate 2-3, Sodium tetrafluoroborate 1-2, aluminium nitride 2-4, polytetrafluoroethylene fiber 4-6, alkenyl succinic anhydride 0.5-1, Methyl glutarate 2-3, ultrahigh molecular weight polyethylene(UHMWPE) 91-100, polyimide 0.4-1, Tetrabutyl amonium bromide 1-2, triglycol 1-2, Graphite Powder 99 10-14, molybdenum oxide 0.4-1, high resistance auxiliary agent 5-6, methyl ethyl ketoxime 0.3-1, T800 carbon fiber 0.3-0.5, valerian oil 0.7-2, dioctyl azelate 2-3;
Described high resistance auxiliary agent is made up of the raw material of following weight parts:
Neusilin 3-4, MBS terpolymer 30-40, polyvinyl butyral acetal 6-9, Sodium dodecylbenzene sulfonate 1-2, TriMethylolPropane(TMP) 0.4-1, nylon acid methyl esters 2-3, phytinic acid 0.6-1;
Polyvinyl butyral acetal is heated to 60-65 DEG C, adds nylon acid methyl esters, insulated and stirred 6-10 minute, be cooled to normal temperature, obtain esterification butyral;
Sodium dodecylbenzene sulfonate is joined in 8-10 times of water, stir, add neusilin, phytinic acid, be uniformly mixed, obtain emulsion adhesive;
Each raw material after above-mentioned process is mixed with MBS terpolymer, send into reactor, stir, dewatered drying, adds TriMethylolPropane(TMP), at pressure 1.8-1.9MPa, temperature 84-90 DEG C, be uniformly mixed 1-2 hour, cooling discharging, abrasive dust, obtains described high resistance auxiliary agent.
2. a preparation method for fiber reinforcement type nozzle as claimed in claim 1, is characterized in that comprising the following steps:
Mixed with T800 carbon fiber, polytetrafluoroethylene fiber by aluminium nitride, be heated to 120-130 DEG C, insulation mixing 10-20 minute, reduction temperature is 80-90 DEG C, adds dioctyl azelate, is uniformly mixed 6-10 minute, obtains esterification conjugated fibre;
The 10-20% getting above-mentioned ultrahigh molecular weight polyethylene(UHMWPE) weight mixes with Graphite Powder 99, and add calcium ricinoleate, esterification conjugated fibre after stirring, ball milling is even;
Sodium tetrafluoroborate is mixed with triglycol, molybdenum oxide, after stirring, adds polyimide, be heated to 50-60 DEG C, 30-50 rev/min of dispersed with stirring 5-10 minute;
Mixed with each raw material of residue by each raw material after above-mentioned process, send in rubber mixing machine, mixing 2-3 hour at 135-140 DEG C, is placed in injection moulding machine, is processed into described fiber reinforcement type nozzle.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410591632.XA CN104311961A (en) | 2014-10-29 | 2014-10-29 | Fiber enhanced nozzle |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410591632.XA CN104311961A (en) | 2014-10-29 | 2014-10-29 | Fiber enhanced nozzle |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104311961A true CN104311961A (en) | 2015-01-28 |
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ID=52367287
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410591632.XA Pending CN104311961A (en) | 2014-10-29 | 2014-10-29 | Fiber enhanced nozzle |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104311961A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104774382A (en) * | 2015-03-26 | 2015-07-15 | 安徽海纳川塑业科技有限公司 | Vehicle polypropylene composite material containing cobalt and zirconium |
| CN104774379A (en) * | 2015-03-26 | 2015-07-15 | 安徽海纳川塑业科技有限公司 | Nanometer micro-foaming polypropylene composite material |
| CN104774378A (en) * | 2015-03-26 | 2015-07-15 | 安徽海纳川塑业科技有限公司 | Stable polypropylene composite material for household electric appliances |
| CN106396686A (en) * | 2016-08-26 | 2017-02-15 | 桐城市明丽碳化硼制品有限公司 | Fiber-reinforced boron carbide nozzle |
| CN106396685A (en) * | 2016-08-26 | 2017-02-15 | 桐城市明丽碳化硼制品有限公司 | Germanium oxide flame-resistant weather-resistant nozzle |
| CN106431451A (en) * | 2016-08-26 | 2017-02-22 | 桐城市明丽碳化硼制品有限公司 | Ceramic nozzle compounded by boron carbide and tungsten carbide |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1034009A (en) * | 1987-11-05 | 1989-07-19 | 三井石油化学工业株式会社 | The olefin resin composition that is used for injection moulding |
| CN101434723A (en) * | 2007-11-16 | 2009-05-20 | 上海化工研究院 | Antistatic halogen-free flame-retardant ultra-high molecular weight polyvinyl composite |
| CN101463156A (en) * | 2007-12-19 | 2009-06-24 | 上海化工研究院天地科技发展有限公司 | Superhigh molecular weight polyethylene material and preparation thereof |
| CN101469089A (en) * | 2008-06-19 | 2009-07-01 | 上海化工研究院 | Halogen-free polyvinyl composite for manufacturing pipes and manufacturing method thereof |
| CN102827476A (en) * | 2012-09-05 | 2012-12-19 | 中国科学院长春应用化学研究所 | Composite material and preparation method thereof |
| CN102936370A (en) * | 2011-08-15 | 2013-02-20 | 辽宁辽杰科技有限公司 | Continuous fiber reinforced thermoplastic resin prepreg tape and preparation method thereof |
-
2014
- 2014-10-29 CN CN201410591632.XA patent/CN104311961A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1034009A (en) * | 1987-11-05 | 1989-07-19 | 三井石油化学工业株式会社 | The olefin resin composition that is used for injection moulding |
| CN101434723A (en) * | 2007-11-16 | 2009-05-20 | 上海化工研究院 | Antistatic halogen-free flame-retardant ultra-high molecular weight polyvinyl composite |
| CN101463156A (en) * | 2007-12-19 | 2009-06-24 | 上海化工研究院天地科技发展有限公司 | Superhigh molecular weight polyethylene material and preparation thereof |
| CN101469089A (en) * | 2008-06-19 | 2009-07-01 | 上海化工研究院 | Halogen-free polyvinyl composite for manufacturing pipes and manufacturing method thereof |
| CN102936370A (en) * | 2011-08-15 | 2013-02-20 | 辽宁辽杰科技有限公司 | Continuous fiber reinforced thermoplastic resin prepreg tape and preparation method thereof |
| CN102827476A (en) * | 2012-09-05 | 2012-12-19 | 中国科学院长春应用化学研究所 | Composite material and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104774382A (en) * | 2015-03-26 | 2015-07-15 | 安徽海纳川塑业科技有限公司 | Vehicle polypropylene composite material containing cobalt and zirconium |
| CN104774379A (en) * | 2015-03-26 | 2015-07-15 | 安徽海纳川塑业科技有限公司 | Nanometer micro-foaming polypropylene composite material |
| CN104774378A (en) * | 2015-03-26 | 2015-07-15 | 安徽海纳川塑业科技有限公司 | Stable polypropylene composite material for household electric appliances |
| CN106396686A (en) * | 2016-08-26 | 2017-02-15 | 桐城市明丽碳化硼制品有限公司 | Fiber-reinforced boron carbide nozzle |
| CN106396685A (en) * | 2016-08-26 | 2017-02-15 | 桐城市明丽碳化硼制品有限公司 | Germanium oxide flame-resistant weather-resistant nozzle |
| CN106431451A (en) * | 2016-08-26 | 2017-02-22 | 桐城市明丽碳化硼制品有限公司 | Ceramic nozzle compounded by boron carbide and tungsten carbide |
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Application publication date: 20150128 |
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