CN104533043A - Decoration board and preparation method thereof - Google Patents
Decoration board and preparation method thereof Download PDFInfo
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- CN104533043A CN104533043A CN201410724885.XA CN201410724885A CN104533043A CN 104533043 A CN104533043 A CN 104533043A CN 201410724885 A CN201410724885 A CN 201410724885A CN 104533043 A CN104533043 A CN 104533043A
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Abstract
The invention relates to a decoration board and a preparation method thereof, and belongs to the building material field. The decoration board comprises a base material, an ultraviolet light solidification adhering ground paint layer, an ultraviolet light solidification pressure sensitive hot melt adhesive layer and a decoration face, wherein the ultraviolet light solidification pressure sensitive hot melt adhesive layer is prepared on the ultraviolet light solidification adhering ground paint layer after ultraviolet light solidification adhering ground paint is prepared on the base material, and the decoration face is tightly pressed against the surface of the ultraviolet light solidification pressure sensitive hot melt adhesive layer under action of temperature pressure. The decoration board has excellent adhering force for decoration fabrics, is good in initial adhesion and excellent in peeling strength, and can be used in the home decoration industry decoration board field. The preparation method of the decoration board has the advantages of needing a small production area, being low in equipment investment, high in production efficiency, small in energy consumption, free of pollution, simple in technology and excellent in paint film performance and the like, and thereby is obvious in superiority by using ultraviolet light polymerization hot melt adhesive to prepare the decoration board.
Description
Technical field
The invention belongs to building material field, relate to a kind of decorative panel, particularly relate to a kind of ultraviolet light polymerization hot-melt pressure sensitive glue-line that utilizes and connect novel decorative plate of base material and decorative cover and preparation method thereof.
Background technology
In modern family property, cabinet, cupboard, table, bed adopt decorative panel to process more.This decorative panel is a kind of artificial board, and with multiple special paper after chemical treatment, the composite material made with HTHP binder, plate mask has various wood grain or pattern, and light is smooth, bright in colour attractive in appearance.
Notification number is that the Chinese patent of CN 2680478Y discloses a kind of paper surface paint coated pit surface wood decorative board, and its primary structure is that woodgrained paper is combined on wood substrate by melt viscosity.The PUR that above-mentioned patent is used have bonding soon, containing features such as solvent, pollution-free, no drying process and applicability are wide, so be widely used in decorative panel field.But existing PUR is a kind of plastic adhesive, in certain temperature range, its physical state changes with temperature change, its bonding process chemical crosslinking does not occur or crosslink density is low, cause heat resistance after PUR cooling curing, water resistance is relatively poor, the problem that adhesion strength is not high, limits its range of application to a certain extent.
Notification number is that the Chinese patent of CN 203267350 U discloses a kind of ultraviolet light polymerization face aluminium sheet, its structure is, aluminium basal plate overlays melamine gum dipped paper, described melamine gum dipped paper adheres to ultraviolet light polymerization laser film described in one deck, scribble ultraviolet cured primer layer and UV-curable finish coat layer successively above described laser film, this patent medium ultraviolet photo-curing material mainly plays and improves case hardness, scratch resistance and effect easy to clean.
Summary of the invention
The technical problem to be solved in the present invention is, in prior art, base material is connected instability with decorative cover, easily causes the quality problems such as cracking, cokled surface.The invention discloses a kind of novel decorative plate, this decorative panel has excellent adhesive power to decorative fabric, and initial bonding strength is good, peel strength is excellent, can be applicable to Decoration Industry decorative panel field.
For solving the problem, technical scheme of the present invention is as follows.
The present invention relates to a kind of decorative panel, described decorative panel comprises base material, ultraviolet light polymerization adhesion primer layer, ultraviolet light polymerization hot-melt pressure sensitive glue-line, decorative cover, after base material is prepared ultraviolet light polymerization adhesion primer, prime coat is prepared ultraviolet light polymerization hot-melt pressure sensitive glue-line, and decorative cover overlays in ultraviolet light polymerization hot-melt pressure sensitive glue-line surface.
Preferred version of the present invention is, described ultraviolet light polymerization pressure-sensitive hot melt adhesive by weight percentage, comprise following composition, acrylic ester prepolymer 10 ~ 80%, tackifier 5 ~ 35%, acrylate monomer 5 ~ 50%, light trigger 1 ~ 5%, auxiliary agent 0 ~ 5% and filler 0 ~ 50%.
Preferred version of the present invention is, described ultraviolet light polymerization PUR thickness is 10 ~ 100 μm.
Preferred version of the present invention is, described ultraviolet light polymerization adhesion primer by weight percentage, comprises following composition, the mixture of acrylic ester prepolymer 10 ~ 80%, acrylate monomer 5 ~ 50%, light trigger 1 ~ 5%, auxiliary agent 0 ~ 2% and filler 5 ~ 50%.
Preferred version of the present invention is, the thickness of described ultraviolet light polymerization adhesion primer layer is 10 ~ 100 μm.
Wherein, acrylic ester prepolymer is the mixture of one or more in epoxy acrylate, urethane acrylate, polyester acrylate, amino acrylates, acrylate copolymer.
Wherein, acrylate monomer is: butyl acrylate, Isooctyl acrylate monomer, (methyl) hydroxy-ethyl acrylate, (methyl) hydroxypropyl acrylate, (methyl) iso-bornyl acrylate, two contracting three propyl alcohol diacrylates, one contracting two propyl alcohol diacrylates, propylene glycol diacrylate, (the third oxidation) neopentylglycol diacrylate, different certain herbaceous plants with big flowers base acrylate, 1, 6 hexanediyl esters, two (diethylene glycol) diacrylate of phthalic acid, trimethylolpropane triacrylate, (ethoxyquin) trimethylolpropane triacrylate, (the third oxidation) trimethylolpropane triacrylate, pentaerythritol triacrylate, dipentaerythritol triacrylate, the mixture of one or more in dipentaerythritol tetraacrylate.
Wherein, light trigger is the mixture of one or more in Ciba 1173, the Ciba 184 of Qi Ba fine chemistry company of Switzerland, Ciba 369, Ciba 907, Ciba 819, Ciba 651, TPO, ITX.
Wherein, auxiliary agent is the mixture of one or more in levelling agent, defoamer, adhesion promoter, photosensitivity promotor, wetting dispersing agent.
Wherein, filler is the mixture of one or more in French chalk, flatting silica, anti-scratch wax powder, blanc fixe, swell soil.
Wherein, tackifier are the mixture of one or more in rosin, Foral, rosin ester, hydrogenated wood rosin glycerol ester, terpene resin and Petropols.
Preferred version of the present invention is, described base material is the one in fiber reinforcement magnesium oxide plate, fiber reinforced cement board, fiber reinforced calcium silicate board, lightweight chloro-magnesium cement plate, magnesite board, glass magnesium plate or gypsum plank.
Preferred version of the present invention is, described decorative cover is the one in melamine impregnated paper, Poly paper, PU paper, wallpaper, PVC film or transfer film.
The invention still further relates to the preparation method of this decorative panel, described method comprises following preparation process:
1) decorative panel substrate surface treatment;
2) application ultraviolet light polymerization adhesion primer posterior photocuring on decorative panel substrate surface;
3) after ultraviolet light polymerization adhesion primer coating surface application ultraviolet light polymerization pressure-sensitive hot melt adhesive, second time photocuring is carried out;
4) under pressure, temperature action, decorative cover is overlayed in ultraviolet light polymerization pressure-sensitive hot melt adhesive surface.
The preferred version of this preparation method is, preparation process 3) in, after ultraviolet light polymerization adhesion primer coating surface application ultraviolet light polymerization pressure-sensitive hot melt adhesive, carry out infrared levelling or natural levelling technique; Wherein infrared levelling infrared levelling temperature is adjusted to 20 ~ 150 DEG C, flow time 0.1 ~ 10 minute.
The preferred version of this preparation method is, preparation process 4) described in temperature be 100 ~ 300 DEG C, pressure is 0.5 ~ 100MPa.
The preferred version of this preparation method is, preparation process 2) or 3) described in ultraviolet curing process be adopt the ultraviolet tube of 1 ~ 63 ~ 20kw and the metal halogen fluorescent tube of 0 ~ 33 ~ 20kw to irradiate, irradiate speed 1 ~ 20 m/min.
Ultraviolet light polymerization pressure-sensitive hot melt adhesive is a kind of novel bonding adhesive, and under UV-irradiation, PUR generation photopolymerization reaction, so have very excellent adhesion strength to bonding substrates.Existing PUR is be viscoelastic state after at high temperature melting thus be connected with fabric by base material, this process is a physical change process, both connections only have intermolecular force, and photocuring PUR becomes solid-state chemical polymerization from liquid state after photocuring, at high temperature melting, be connected with fabric by base material, the existing intermolecular force of both connections has chemical bond again, thus better than existing PUR switching performance.This decorative panel has excellent adhesive power to decorative fabric, and initial bonding strength is good, peel strength is excellent, can be applicable to Decoration Industry decorative panel field.
The features such as needed for preparation technology of the present invention, production site is little, equipment investment is low, production efficiency is high, less energy consumption, pollution-free, dress technique is simple, and paint film property is excellent, therefore, adopt ultraviolet light polymerization PUR to prepare decorative panel advantage clearly.
Accompanying drawing explanation
Fig. 1 is the structure sectional view of decorative panel of the present invention.
In figure, 1 is decorative panel base material; 2 is ultraviolet light polymerization adhesion primer layer; 3 ultraviolet light polymerization hot-melt pressure sensitive glue-lines; 4 is decorative panel decorative cover.
Detailed description of the invention
Embodiment 1. marbling melamine impregnated paper decorative panel
Decorative panel base material is fiber reinforced cement board, first base material 1 is removed surface dirt, again at decorative panel substrate surface roller coat one deck ultraviolet light polymerization adhesion primer 2, thickness is 20 μm, enter and 2 7.5kw ultraviolet lights (high-pressure sodium lamp) are housed, irradiation speed is the photo solidification machine of 8 ms/min, after solidification, be the ultraviolet light polymerization pressure-sensitive hot melt adhesive 3 of 25 μm again in ultraviolet light polymerization adhesion primer surface roller coating a layer thickness, levelling 1 minute under the infrared levelling line that temperature is 80 DEG C, enter and 2 16.8kw ultraviolet lights (high-pressure sodium lamp) and 2 16.8kw metal halid lamps (Iodine gallium light) are housed, irradiation speed is the photo solidification machine of 8 ms/min, after solidification, on ultraviolet light polymerization pressure-sensitive hot melt adhesive, post one deck be again printed on marbled melamine impregnated paper 4, then it is 180 DEG C in temperature, pressure is extrude 30s under the moulding press of 50MPa, take out, room temperature cools, after cooling, criterion of acceptability is reached through test rating, packaging, obtain marbling melamine paper decorative panel finished product.
The percentage by weight of ultraviolet light polymerization adhesion primer consists of: urethane acrylate 25%, epoxy acrylate 20%, hydroxyethyl methacrylate 30%, iso-bornyl acrylate 10%, French chalk 5%, Ciba 1,173 5%, levelling agent 1%, adhesion promoter 2.5%, defoamer 1%, wetting dispersing agent 0.5%.
The percentage by weight of ultra-violet curing pressure-sensitive hot melt adhesive consists of: epoxy acrylate 10%, urethane acrylate 30%, Foral 20%, two contracting three propyl alcohol diacrylates 20%, butyl acrylate 10%, TPO 4%, ITX 3%, levelling agent 0.5%, photosensitivity promotor 2%, defoamer 0.5%.
Marble grain melamine impregnated paper used is produced by Foshan Tianyuan Hui Bang ornament materials Co., Ltd.
Embodiment 2. imitates wood grain PU paper decorative panel
Decorative panel base material is glass magnesium plate, first base material 1 is removed surface dirt, again at decorative panel substrate surface roller coat one deck ultraviolet light polymerization adhesion primer 2, thickness is 35 μm, enter and 2 10kw ultraviolet lights (high-pressure sodium lamp) are housed, irradiation speed is the photo solidification machine of 12 ms/min, after solidification, be the ultraviolet light polymerization pressure-sensitive hot melt adhesive 3 of 50 μm again in ultraviolet light polymerization adhesion primer surface roller coating a layer thickness, levelling 1 minute under the infrared levelling line that temperature is 100 DEG C, enter and 2 20kw ultraviolet lights (high-pressure sodium lamp) and 2 20kw metal halid lamps (Iodine gallium light) are housed, irradiation speed is the photo solidification machine of 10 ms/min, after solidification, on ultraviolet light polymerization pressure-sensitive hot melt adhesive, post one deck again print grained PU paper 4, then it is 220 DEG C in temperature, pressure is extrude 40s under the moulding press of 80MPa, take out, room temperature cools, after cooling, criterion of acceptability is reached through test rating, packaging, obtain imitative wood grain PU paper decorative panel finished product.
The percentage by weight of ultraviolet light polymerization adhesion primer consists of: polyester acrylate 25%, amino acrylates 20%, hydroxy-ethyl acrylate 30%, two contracting three propyl alcohol diacrylates 10%, French chalk 5%, Ciba 184 5%, levelling agent 1%, adhesion promoter 2.5%, defoamer 1%, wetting dispersing agent 0.5%.
The percentage by weight of ultra-violet curing pressure-sensitive hot melt adhesive consists of: polyester acrylate 20%, urethane acrylate 10%, Petropols 25%, third oxidation neopentylglycol diacrylate 22%, two contracting three propyl alcohol diacrylates 15%, TPO 5%, levelling agent 0.5%, adhesion promoter agent 2%, defoamer 0.5%.
Wood grain PU paper used is produced by Dongguan Glan Paper Co., Ltd.
Embodiment 3. imitates metal laser effect transfer film decorative panel
Decorative panel base material is calcium silicate board, first base material 1 is removed surface dirt, one deck ultraviolet light polymerization adhesion primer 2 is sprayed again at decorative panel substrate surface, thickness is 30 μm, enter and 2 7.5kw ultraviolet lights (high-pressure sodium lamp) are housed, irradiation speed is the photo solidification machine of 7 ms/min, after solidification, be the ultraviolet light polymerization pressure-sensitive hot melt adhesive 3 of 50 μm again in ultraviolet light polymerization adhesion primer surface showering a layer thickness, levelling 1 minute under the infrared levelling line that temperature is 80 DEG C, enter and 1 16.8kw ultraviolet light (high-pressure sodium lamp) and 1 16.8kw metal halid lamp (Iodine gallium light) are housed, irradiation speed is the photo solidification machine of 5 ms/min, after solidification, the transfer film 4 that one deck is printed on metal laser effect is posted again on ultraviolet light polymerization pressure-sensitive hot melt adhesive, then it is 150 DEG C in temperature, pressure is extrude 50s under the moulding press of 30MPa, take out, room temperature cools, after cooling, criterion of acceptability is reached through test rating, packaging, obtain imitative metal laser effect transfer film decorative panel finished product.
The percentage by weight of ultraviolet light polymerization adhesion primer consists of: amino acrylates 25%, epoxy acrylate 20%, pentaerythritol triacrylate 30%, methylisobomyl acrylate 10%, blanc fixe 5%, Ciba 1,173 5%, levelling agent 1%, adhesion promoter 2.5%, defoamer 1%, dispersing agent 0.5%.
The percentage by weight of ultra-violet curing pressure-sensitive hot melt adhesive consists of: epoxy acrylate 25%, urethane acrylate 15%, rosin ester 20%, hydroxy-ethyl acrylate 20%, third oxidation neopentylglycol diacrylate 10%, Ciba 184 6%, levelling agent 0.5%, photosensitivity promotor 3%, defoamer 0.5%.
Metal laser effect transfer film used is produced by German KURZ (KURZ) company.
Embodiment 4. imitates wood grain PU paper decorative panel
Decorative panel base material is glass magnesium plate, first base material 1 is removed surface dirt, again at decorative panel substrate surface roller coat one deck ultraviolet light polymerization adhesion primer 2, thickness is 100 μm, enter and 6 4kw ultraviolet lights (high-pressure sodium lamp) are housed, irradiation speed is the photo solidification machine of 3 ms/min, after solidification, be the ultraviolet light polymerization pressure-sensitive hot melt adhesive 3 of 10 μm again in ultraviolet light polymerization adhesion primer surface roller coating a layer thickness, levelling 10 minutes under the infrared levelling line that temperature is 20 DEG C, enter and 3 3kw ultraviolet lights (high-pressure sodium lamp) and 3 3kw metal halid lamps (Iodine gallium light) are housed, irradiation speed is the photo solidification machine of 2 ms/min, after solidification, on ultraviolet light polymerization pressure-sensitive hot melt adhesive, post one deck again print grained PU paper 4, then it is 100 DEG C in temperature, pressure is extrude 60s under the moulding press of 10MPa, take out, room temperature cools, after cooling, criterion of acceptability is reached through test rating, packaging, obtain imitative wood grain PU paper decorative panel finished product.
The percentage by weight of ultraviolet light polymerization adhesion primer consists of: polyester acrylate 10%, hydroxy-ethyl acrylate 30%, two contracting three propyl alcohol diacrylates 10%, hydroxypropyl acrylate 10%, French chalk 50%, Ciba 1,173 1%, levelling agent 1%, adhesion promoter 2.5%, defoamer 1%, wetting dispersing agent 0.5%.
The percentage by weight of ultra-violet curing pressure-sensitive hot melt adhesive consists of: polyester acrylate 20%, urethane acrylate 10%, acrylate copolymer 50%, rosin ester 35%, third oxidation neopentylglycol diacrylate 5%, TPO 7%, levelling agent 0.5%, adhesion promoter agent 2%, defoamer 0.5%.
Wood grain PU paper used is produced by Dongguan Glan Paper Co., Ltd.
Embodiment 5. marbling melamine impregnated paper decorative panel
Decorative panel base material is fiber reinforced cement board, first base material 1 is removed surface dirt, again at decorative panel substrate surface roller coat one deck ultraviolet light polymerization adhesion primer 2, thickness is 10 μm, enter and 1 20kw ultraviolet light (high-pressure sodium lamp) is housed, irradiation speed is the photo solidification machine of 20 ms/min, after solidification, be the ultraviolet light polymerization pressure-sensitive hot melt adhesive 3 of 100 μm again in ultraviolet light polymerization adhesion primer surface roller coating a layer thickness, levelling 10 minutes under the infrared levelling line that temperature is 150 DEG C, enter and 5 20kw ultraviolet lights (high-pressure sodium lamp) and 3 20kw metal halid lamps (Iodine gallium light) are housed, irradiation speed is the photo solidification machine of 3 ms/min, after solidification, on ultraviolet light polymerization pressure-sensitive hot melt adhesive, post one deck be again printed on marbled melamine impregnated paper 4, then it is 300 DEG C in temperature, pressure is extrude 40s under the moulding press of 10MPa, take out, room temperature cools, after cooling, criterion of acceptability is reached through test rating, packaging, obtain marbling melamine paper decorative panel finished product.
The percentage by weight of ultraviolet light polymerization adhesion primer consists of: urethane acrylate 25%, epoxy acrylate 20%, amino acrylates 35%, hydroxyethyl methacrylate 5%, flatting silica 20%, Ciba 1,173 3%, levelling agent 1%, adhesion promoter 2.5%, defoamer 1%, wetting dispersing agent 0.5%.
The percentage by weight of ultra-violet curing pressure-sensitive hot melt adhesive consists of: epoxy acrylate 10%, Foral 5%, two contracting three propyl alcohol diacrylates 20%, butyl acrylate 30%, TPO 1%, levelling agent 0.5%, photosensitivity promotor 2%, defoamer 0.5%.
Marble grain melamine impregnated paper used is produced by Foshan Tianyuan Hui Bang ornament materials Co., Ltd.
Claims (10)
1. a decorative panel, it is characterized in that, decorative panel comprises base material, ultraviolet light polymerization adhesion primer layer, ultraviolet light polymerization hot-melt pressure sensitive glue-line, decorative cover, after ultraviolet light polymerization adhesion primer preparing by base material, prime coat is prepared ultraviolet light polymerization hot-melt pressure sensitive glue-line, and decorative cover presses down in the effect of temperature, pressure and is affixed on ultraviolet light polymerization hot-melt pressure sensitive glue-line surface.
2. decorative panel according to claim 1, it is characterized in that, described ultraviolet light polymerization pressure-sensitive hot melt adhesive by weight percentage, comprise following composition, acrylic ester prepolymer 10 ~ 80%, tackifier 5 ~ 35%, acrylate monomer 5 ~ 50%, light trigger 1 ~ 7%, auxiliary agent 0 ~ 5% and filler 0 ~ 50%.
3. decorative panel according to claim 1, is characterized in that, described ultraviolet light polymerization PUR thickness is 10 ~ 100 μm.
4. decorative panel according to claim 1, it is characterized in that, described ultraviolet light polymerization adhesion primer by weight percentage, comprises following composition, the mixture of acrylic ester prepolymer 10 ~ 80%, acrylate monomer 5 ~ 50%, light trigger 1 ~ 5%, auxiliary agent 0 ~ 7% and filler 5 ~ 50%.
5. decorative panel according to claim 1, is characterized in that, the thickness of described ultraviolet light polymerization adhesion primer layer is 10 ~ 100 μm.
6. decorative panel according to claim 1, is characterized in that, described base material is the one in fiber reinforcement magnesium oxide plate, fiber reinforced cement board, fiber reinforced calcium silicate board, lightweight chloro-magnesium cement plate, magnesite board, glass magnesium plate or gypsum plank.
7. decorative panel according to claim 1, is characterized in that, described decorative cover is the one in melamine impregnated paper, Poly paper, PU paper, wallpaper, PVC film or transfer film.
8. the preparation method of decorative panel according to claim 1, is characterized in that, described method comprises following preparation process:
1) decorative panel substrate surface treatment;
2) application ultraviolet light polymerization adhesion primer posterior photocuring on decorative panel substrate surface;
3) after ultraviolet light polymerization adhesion primer coating surface application ultraviolet light polymerization pressure-sensitive hot melt adhesive, second time photocuring is carried out;
4) under pressure, temperature action, decorative cover is overlayed in ultraviolet light polymerization pressure-sensitive hot melt adhesive surface.
9. the preparation method of decorative panel according to claim 8, is characterized in that, preparation process 4) described in temperature be 100 ~ 300 DEG C, pressure is 0.5 ~ 100MPa.
10. the preparation method of decorative panel according to claim 8, it is characterized in that, preparation process 2) or 3) described in ultraviolet curing process be, adopt the ultraviolet tube of 1 ~ 63 ~ 20kw to irradiate separately or be combined into row with the metal halogen fluorescent tube of 0 ~ 33 ~ 20kw and irradiate, irradiate speed 1 ~ 20 m/min.
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| CN201410724885.XA CN104533043A (en) | 2014-12-03 | 2014-12-03 | Decoration board and preparation method thereof |
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| CN201410724885.XA CN104533043A (en) | 2014-12-03 | 2014-12-03 | Decoration board and preparation method thereof |
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Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104859018A (en) * | 2015-06-02 | 2015-08-26 | 骆志延 | Wooden door machining method |
| CN105064641A (en) * | 2015-09-08 | 2015-11-18 | 苏州金螳螂建筑装饰股份有限公司 | Membranization calcium silicate veneer and preparation method thereof |
| CN106179907A (en) * | 2016-06-30 | 2016-12-07 | 卓达新材料科技集团威海股份有限公司 | A kind of photocuring overlay film glass magnesium trim panel preparation method |
| WO2018177288A1 (en) * | 2017-03-30 | 2018-10-04 | 苏州凡赛特材料科技有限公司 | Pressure-sensitive adhesive and manufacturing method thereof |
| CN108908532A (en) * | 2018-07-13 | 2018-11-30 | 中山易必固新材料科技有限公司 | A kind of electronic beam curing facing coating medium density fiberboard and its manufacture craft |
| CN109467387A (en) * | 2018-01-15 | 2019-03-15 | 杭州创屹机电科技有限公司 | A kind of low porosity 3D printing ceramic and preparation method thereof |
| CN109677051A (en) * | 2018-12-29 | 2019-04-26 | 中材华晟科技无锡有限公司 | A kind of decorative panel and its processing technology |
| CN109705444A (en) * | 2018-12-19 | 2019-05-03 | 上海同晋环保科技有限公司 | A kind of polyfluoro compounding ETFE film and decorative panel |
| CN111002654A (en) * | 2019-12-26 | 2020-04-14 | 江苏新丽源南亚新材料有限公司 | Processing technology of wood grain decorative wallboard |
| CN111154430A (en) * | 2020-01-21 | 2020-05-15 | 安徽富印新材料有限公司 | Ultraviolet curing OCA pressure-sensitive adhesive film and preparation method thereof |
| CN111379392A (en) * | 2018-12-29 | 2020-07-07 | 塔吉特Gdl公司 | Method for mounting decorative wall or floor coverings |
| CN112094617A (en) * | 2020-11-19 | 2020-12-18 | 佛山市南海区瑞森新型材料研究所 | Polyurethane adhesive, composite material prepared from polyurethane adhesive and application of composite material |
| CN113509034A (en) * | 2021-06-25 | 2021-10-19 | 华鸿画家居股份有限公司 | Texture paper frame strip |
| CN113717616A (en) * | 2021-10-19 | 2021-11-30 | 成都君子兰涂料有限公司 | Polishing-free UV (ultraviolet) adhesion primer for pasting melamine paper on medium density fiberboard and preparation method thereof |
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|---|---|---|---|---|
| CN104859018A (en) * | 2015-06-02 | 2015-08-26 | 骆志延 | Wooden door machining method |
| CN104859018B (en) * | 2015-06-02 | 2017-11-21 | 骆志延 | Timber processing method |
| CN105064641A (en) * | 2015-09-08 | 2015-11-18 | 苏州金螳螂建筑装饰股份有限公司 | Membranization calcium silicate veneer and preparation method thereof |
| CN106179907A (en) * | 2016-06-30 | 2016-12-07 | 卓达新材料科技集团威海股份有限公司 | A kind of photocuring overlay film glass magnesium trim panel preparation method |
| WO2018177288A1 (en) * | 2017-03-30 | 2018-10-04 | 苏州凡赛特材料科技有限公司 | Pressure-sensitive adhesive and manufacturing method thereof |
| US11590739B2 (en) * | 2017-11-29 | 2023-02-28 | Sika Technology Ag | Sealing tape with a functional layer |
| CN109467387A (en) * | 2018-01-15 | 2019-03-15 | 杭州创屹机电科技有限公司 | A kind of low porosity 3D printing ceramic and preparation method thereof |
| CN108908532A (en) * | 2018-07-13 | 2018-11-30 | 中山易必固新材料科技有限公司 | A kind of electronic beam curing facing coating medium density fiberboard and its manufacture craft |
| CN109705444A (en) * | 2018-12-19 | 2019-05-03 | 上海同晋环保科技有限公司 | A kind of polyfluoro compounding ETFE film and decorative panel |
| CN111379392A (en) * | 2018-12-29 | 2020-07-07 | 塔吉特Gdl公司 | Method for mounting decorative wall or floor coverings |
| CN109677051A (en) * | 2018-12-29 | 2019-04-26 | 中材华晟科技无锡有限公司 | A kind of decorative panel and its processing technology |
| CN111002654A (en) * | 2019-12-26 | 2020-04-14 | 江苏新丽源南亚新材料有限公司 | Processing technology of wood grain decorative wallboard |
| CN111154430A (en) * | 2020-01-21 | 2020-05-15 | 安徽富印新材料有限公司 | Ultraviolet curing OCA pressure-sensitive adhesive film and preparation method thereof |
| CN112094617A (en) * | 2020-11-19 | 2020-12-18 | 佛山市南海区瑞森新型材料研究所 | Polyurethane adhesive, composite material prepared from polyurethane adhesive and application of composite material |
| CN113509034A (en) * | 2021-06-25 | 2021-10-19 | 华鸿画家居股份有限公司 | Texture paper frame strip |
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Application publication date: 20150422 |