CN104532572A - Novel electrostatic removal agent for textile materials and preparation method of novel electrostatic removal agent - Google Patents
Novel electrostatic removal agent for textile materials and preparation method of novel electrostatic removal agent Download PDFInfo
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- CN104532572A CN104532572A CN201410815758.0A CN201410815758A CN104532572A CN 104532572 A CN104532572 A CN 104532572A CN 201410815758 A CN201410815758 A CN 201410815758A CN 104532572 A CN104532572 A CN 104532572A
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Abstract
The invention discloses a novel electrostatic removal agent for textile materials and a preparation method of the novel electrostatic removal agent. The material is prepared from the following components in parts by weight: 10-20 parts of sodium alginate, 5-10 parts of poly(dimethylsiloxane) divalent quaternary ammonium, 3-6 parts of polyvinyl alcohol, 1.5-3 parts of ethoxylated alkyl ammonium sulfate, 0.8-1.4 parts of poly(methylcyclotetrasiloxane), 0.5-2 parts of acetic acid aqueous solution and 100-150 parts of deionized water. The invention also provides a method for preparing the novel electrostatic removal agent. The method comprises the following steps: (1) adding 10-20 parts of sodium alga acid, 5-10 parts of poly(dimethylsiloxane) divalent quaternary ammonium, 3-6 parts of polyvinyl alcohol and 1.5-3 parts of ethoxylated alkyl ammonium sulfate into 100-150 parts of deionized water, and uniformly stirring at the temperature of 55-70 DEG C; and (2) slowly adding 0.5-2 parts of the 0.5-2 parts of acetic acid aqueous solution, adding 0.8-1.4 parts of polymethylcyclotetrasiloxane under heating conditions, and uniformly stirring, thereby obtaining the electrostatic removal agent for textile materials.
Description
Technical field
The invention belongs to destaticizer field, particularly a kind of novel destaticizer for textile material and preparation method thereof.
Background technology
Along with the increase of synthetic fiber and BLENDED FABRIC thereof, fabric after cyclic washing gradually hardening, feel is coarse, even produce electrostatic precipitation, sparkle phenomenon.Therefore the antistatic problem being textile industry always and paying close attention to.
Although there is certain progress in recent years, after arranging there is feel in textiles, hygroscopicity changes, antistatic effect affects greatly by ambient humidity, the not problem such as wash resistant.
" textile technology progress " magazine is the 2nd interim in 2006, disclose one section of name and be called in " processing method of antistatic spinning wool fabric " that disclose fabric adds the antistatic effect that appropriate nonionic surface active agent can reach certain in the soft process of Final finishing, but the hydrone that fabric absorbs when ambient humidity is less is less, the antistatic effect of non-ionic surface active agent declines very fast, and fabric is after repeatedly washing, antistatic additive and fabric are in conjunction with insecure, antistatic property declines significantly, not lastingly.
In existing softener, the representational product of most is cationic surfactant, wherein uses maximum are dioctadecyl dimethyl ammonium chloride or claim two hydrogenated-tallow group alkyl dimethyl ammonium chloride.Although its result of use is better, also there is biological degradability poor, the impact on environment may be caused.Therefore, for the textiles with skin contact and finishing agent must be safe, to people's totally nontoxic, non-stimulated, softener must be also non-sensitization.
Summary of the invention
For above-mentioned demand, the object of this invention is to provide a kind of destaticizer for textile material and preparation method thereof.
Object of the present invention can be achieved through the following technical solutions:
A novel destaticizer for textile material, be made up of the component comprising following weight portion:
The relative molecular weight of described polyvinyl alcohol is 1500-2500.
In described aqueous acetic acid, acetic acid content is 56-68wt%.
A preparation method for the novel destaticizer for textile material, the method comprises the following steps:
(1), in deionized water 100-150 part, add sodium alginate 10-20 part, dimethyl silicone polymer two quaternary amine 5-10 part, polyvinyl alcohol 3-6 part, ethoxylated alkyl ammonium sulfate 1.5-3 part, at 55-70 DEG C, stir;
(2) slowly add aqueous acetic acid 0.5-2 part, in a heated condition, add poly-methyl cyclotetrasiloxane 0.8-1.4 part, stir, obtain the destaticizer for textile material.
Described heating-up temperature in step 2 is at 50-65 DEG C.
Beneficial effect:
(1) main component of the destaticizer for textile material of the present invention has sodium alginate, dimethyl silicone polymer two quaternary amine, poly-methyl cyclotetrasiloxane etc., and these components all belong to degradable, environmental friendliness shaped material.
(2) destaticizer of the present invention is easier to dissolving and is dispersed in water, strong at water stability, and containing more hydrogen bond in structure, fully can contact with fabric surface, plays long-actingly to remove electrostatic interaction enduringly.
(3) destaticizer of the present invention is except having good antistatic property, also has good submissive and maintenance effect to clothing.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
(1), in deionized water 150kg, add sodium alginate 10kg, dimethyl silicone polymer two quaternary amine 5kg, relative molecular weight be 1500 polyvinyl alcohol 3kg, ethoxylated alkyl ammonium sulfate 1.5kg, at 55 DEG C, stir;
(2) slowly add 56wt% aqueous acetic acid 0.5kg, at 50 DEG C, add poly-methyl cyclotetrasiloxane 0.8kg, stir, obtain the destaticizer for textile material.
Embodiment 2
(1), in deionized water 150kg, add sodium alginate 10kg, dimethyl silicone polymer two quaternary amine 5kg, relative molecular weight be 1500 polyvinyl alcohol 3kg, ethoxylated alkyl ammonium sulfate 3kg, at 55 DEG C, stir;
(2) slowly add 68wt% aqueous acetic acid 2kg, at 55 DEG C, add poly-methyl cyclotetrasiloxane 1kg, stir, obtain the destaticizer for textile material.
Embodiment 3
(1), in deionized water 100kg, add sodium alginate 20kg, dimethyl silicone polymer two quaternary amine 10kg, relative molecular weight be 2500 polyvinyl alcohol 6kg, ethoxylated alkyl ammonium sulfate 3kg, at 70 DEG C, stir;
(2) slowly add 68wt% aqueous acetic acid 2kg, at 65 DEG C, add poly-methyl cyclotetrasiloxane 1.4kg, stir, obtain the destaticizer for textile material.
Embodiment 4
(1), in deionized water 100kg, add sodium alginate 20kg, dimethyl silicone polymer two quaternary amine 5kg, relative molecular weight be 2500 polyvinyl alcohol 6kg, ethoxylated alkyl ammonium sulfate 3kg, at 70 DEG C, stir;
(2) slowly add 68wt% aqueous acetic acid 0.5kg, at 50 DEG C, add poly-methyl cyclotetrasiloxane 0.8kg, stir, obtain the destaticizer for textile material.
Embodiment 5
(1), in deionized water 120kg, add sodium alginate 15kg, dimethyl silicone polymer two quaternary amine 8kg, relative molecular weight be 2000 polyvinyl alcohol 4kg, ethoxylated alkyl ammonium sulfate 2kg, at 60 DEG C, stir;
(2) slowly add 60wt% aqueous acetic acid 1kg, at 55 DEG C, add poly-methyl cyclotetrasiloxane 1.4kg, stir, obtain the destaticizer for textile material.
Add wool fibre by the destaticizer of embodiment 1-5, after oven dry, the concrete condition recording wool textile electrostatic half-life asks for an interview table 1.
Table 1
The invention is not restricted to embodiment here, those skilled in the art, according to announcement of the present invention, do not depart from improvement that scope makes and amendment all should within protection scope of the present invention.
Claims (5)
1. a novel destaticizer for textile material, is characterized in that, is made up of the component comprising following weight portion:
2. the novel destaticizer for textile material according to claim 1, is characterized in that, the relative molecular weight of described polyvinyl alcohol is 1500-2500.
3. the novel destaticizer for textile material according to claim 1, is characterized in that, in described aqueous acetic acid, acetic acid content is 56-68wt%.
4. a preparation method for the novel destaticizer for textile material, it is characterized in that, the method comprises the following steps:
(1), in deionized water 100-150 part, add sodium alginate 10-20 part, dimethyl silicone polymer two quaternary amine 5-10 part, polyvinyl alcohol 3-6 part, ethoxylated alkyl ammonium sulfate 1.5-3 part, at 55-70 DEG C, stir;
(2) slowly add aqueous acetic acid 0.5-2 part, in a heated condition, add poly-methyl cyclotetrasiloxane 0.8-1.4 part, stir, obtain the destaticizer for textile material.
5. the preparation method of the novel destaticizer for textile material according to claim 4, is characterized in that, the described heating-up temperature in step 2 is at 50-65 DEG C.
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| CN201410815758.0A CN104532572A (en) | 2014-12-24 | 2014-12-24 | Novel electrostatic removal agent for textile materials and preparation method of novel electrostatic removal agent |
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| CN201410815758.0A CN104532572A (en) | 2014-12-24 | 2014-12-24 | Novel electrostatic removal agent for textile materials and preparation method of novel electrostatic removal agent |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105064021A (en) * | 2015-09-11 | 2015-11-18 | 无锡市长安曙光手套厂 | Destaticizer, preparation method and textile materials containing destaticizer |
| CN105113243A (en) * | 2015-09-18 | 2015-12-02 | 杨洋 | Static-eliminating cleaning agent for textile materials and preparation method thereof |
| CN105200789A (en) * | 2015-09-17 | 2015-12-30 | 无锡市长安曙光手套厂 | Antistatic agent and preparation method and application thereof |
| CN105220490A (en) * | 2015-10-20 | 2016-01-06 | 湖州博润实业有限公司 | A kind of novel textile material antistatic agent and preparation method thereof |
| CN105220497A (en) * | 2015-10-20 | 2016-01-06 | 湖州博润实业有限公司 | A kind of new type natural fiber softener and preparation method thereof |
| CN105220499A (en) * | 2015-11-13 | 2016-01-06 | 付淑珍 | A kind of novel electrostatic prevention, degerming fiber treatment materials and preparation method thereof |
| CN105951238A (en) * | 2016-07-18 | 2016-09-21 | 山东正凯新材料股份有限公司 | Production process of polyester viscose corn-spun yarn |
| CN107190507A (en) * | 2017-06-29 | 2017-09-22 | 顾渊 | It is a kind of for destaticizer of textile material and preparation method thereof |
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| US20030195130A1 (en) * | 2002-04-10 | 2003-10-16 | Lentsch Steven E. | Fabric softener composition and methods for manufacturing and using |
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| CN104088143A (en) * | 2014-07-16 | 2014-10-08 | 上海制皂(集团)如皋有限公司 | Woolen clothes softening agent and preparation method thereof |
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| GB1041271A (en) * | 1962-09-21 | 1966-09-01 | Ici Ltd | Process for modifying the properties of textile materials |
| JPS59130370A (en) * | 1982-09-09 | 1984-07-26 | ウ−ルリサ−チ オ−ガニゼイシヨン オブ ニユ−・ジ−ランド インコ−ポレ−テツド | Anti-static agent and anti-static treatment of fabric |
| US20030195130A1 (en) * | 2002-04-10 | 2003-10-16 | Lentsch Steven E. | Fabric softener composition and methods for manufacturing and using |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105064021A (en) * | 2015-09-11 | 2015-11-18 | 无锡市长安曙光手套厂 | Destaticizer, preparation method and textile materials containing destaticizer |
| CN105200789A (en) * | 2015-09-17 | 2015-12-30 | 无锡市长安曙光手套厂 | Antistatic agent and preparation method and application thereof |
| CN105113243A (en) * | 2015-09-18 | 2015-12-02 | 杨洋 | Static-eliminating cleaning agent for textile materials and preparation method thereof |
| CN105220490A (en) * | 2015-10-20 | 2016-01-06 | 湖州博润实业有限公司 | A kind of novel textile material antistatic agent and preparation method thereof |
| CN105220497A (en) * | 2015-10-20 | 2016-01-06 | 湖州博润实业有限公司 | A kind of new type natural fiber softener and preparation method thereof |
| CN105220499A (en) * | 2015-11-13 | 2016-01-06 | 付淑珍 | A kind of novel electrostatic prevention, degerming fiber treatment materials and preparation method thereof |
| CN105951238A (en) * | 2016-07-18 | 2016-09-21 | 山东正凯新材料股份有限公司 | Production process of polyester viscose corn-spun yarn |
| CN107190507A (en) * | 2017-06-29 | 2017-09-22 | 顾渊 | It is a kind of for destaticizer of textile material and preparation method thereof |
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Application publication date: 20150422 |