CN104479444B - Boiling-resistant mirror resin and preparation method thereof - Google Patents
Boiling-resistant mirror resin and preparation method thereof Download PDFInfo
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- CN104479444B CN104479444B CN201410730609.4A CN201410730609A CN104479444B CN 104479444 B CN104479444 B CN 104479444B CN 201410730609 A CN201410730609 A CN 201410730609A CN 104479444 B CN104479444 B CN 104479444B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/14—Printing inks based on carbohydrates
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses boiling-resistant mirror resin and a preparation method thereof. The boiling-resistant mirror resin is prepared from the following raw materials in parts by mass: 30-50 parts of common mirror resin, 10-25 parts of a curing agent, 1-2 parts of a catalyst and 20-35 parts of a diluent. The preparation method of the boiling-resistant mirror resin comprises the following steps: adding the diluents into a mixing cylinder, adding the common mirror resin, the curing agent and the catalyst and uniformly mixing at room temperature. Boiling-resistant mirror ink is prepared by mixing the boiling-resistant mirror resin and mirror silver slurry at a mass ratio of 1:(1.5-2). The mirror ink obtained by the mirror resin has good mirror effect and relatively strong boiling resistance, after the ink is boiled for 1 hour, the adhesion of the ink to a glass substrate or a metal substrate can still reach Level 0.
Description
Technical field
The present invention relates to a kind of water boiling resistance minute surface resin and preparation method thereof.
Background technology
Ink with mirror effect is a kind of ink with special decorative effect, and bulk composition is aluminum paste and resin, is constructed flat
On whole, transparent base material.After film forming, paint film has the light reflexive of height, and from terms of front, ink has the effect of similar mirror
Really.Under some special environments, in the presence of such as boiling water, coating structure can be destroyed common ink with mirror effect, thus cause ink
Loss of gloss and loss of adhesion.
Therefore, study a kind of water boiling resistance minute surface resin necessary with ink with mirror effect.
The content of the invention
It is an object of the invention to provide a kind of water boiling resistance minute surface resin and preparation method thereof.
The technical solution used in the present invention is：
A kind of water boiling resistance minute surface resin, which is made up of the raw material of following mass parts：The common minute surface resin of 30-50 parts,
The firming agent of 10-25 parts, the catalyst of 1-2 parts, the diluent of 20-35 parts.
Described common minute surface resin is nitrocellulose resin solution or acetylbutyrylcellulose solution, and solid content exists
Between 5%-15%.
Described firming agent is organosilicon firming agent or amino resin curing agents.
The formula of described organosilicon firming agent is YSiX3, Y is selected from alkyl, thiazolinyl or end with Cl, NH2, SH, ring
Oxygen, N3、（Methyl）The alkyl of acryloxy, NCO；X is selected from Cl, OMe, OEt, OC2H4OCH3、OSiMe3、OAc。
Described organosilicon firming agent is MTES, ethyl triethoxysilane, vinyl triacetyl oxygen
Silane, methyl tributanoximo silane, tetraethoxysilane, γ-glycidyl ether oxygen propyl trimethoxy silicane, 3- shrink sweet
At least one in oily ether epoxide propyl-triethoxysilicane, β-(3,4- epoxycyclohexyls) ethyl trimethoxy silane.
Described amino resin curing agents are melamine class amino resins, benzene for amino resins, methyl-etherified tripolycyanamide
Class amino resins, butyl ether melamine class amino resins, methyl-etherified benzene are in amino resins, the etherification benzene substituted amino resins of fourth
It is at least one.
When described firming agent is organosilicon, at least one of the catalyst in carboxylic acid, sulfonic acid, sulfinic acid, thionothiolic acid；
When described firming agent is amino resins, catalyst is carboxylic acid.
Described diluent is selected from ethyl acetate, butyl acetate, glycol methyl ether acetate, propylene glycol monomethyl ether, ethylene glycol
One kind in butyl ether, dimethylbenzene, Ketohexamethylene, isophorone.
A kind of preparation method of water boiling resistance minute surface resin, step are as follows：Diluent is added in mixed cylinder, is subsequently adding general
Logical minute surface resin, firming agent, catalyst, mix homogeneously under room temperature.
A kind of water boiling resistance ink with mirror effect, it is 1 according to mass ratio by described water boiling resistance minute surface resin and minute surface silver paste which is：
（1.5-2）It is mixed.
The invention has the beneficial effects as follows：The ink with mirror effect mirror effect that the present invention is obtained is good；Water boiling resistance ability is stronger, water
0 grade can still be reached to the adhesive force of glass baseplate or metal base after boiling 1h.
Specific embodiment
A kind of water boiling resistance minute surface resin, which is made up of the raw material of following mass parts：The common minute surface resin of 30-50 parts,
The firming agent of 10-25 parts, the catalyst of 1-2 parts, the diluent of 20-35 parts.
Described common minute surface resin is nitrocellulose resin solution or acetylbutyrylcellulose solution, and solid content exists
Between 5%-15%；
Preferably, described common minute surface resin is acetylbutyrylcellulose（Model is CAB381-20）Solution；Or,
For acetylbutyrylcellulose solution, wherein, in 10.7%-11.2%, viscosity is in falling ball viscosity for the nitrogen content of acetylbutyrylcellulose
More than second；
It is further preferred that be acetylbutyrylcellulose solution, wherein, the nitrogen content of acetylbutyrylcellulose is in 10.7%-
11.2%, viscosity is in falling ball viscosity more than the second.
Described firming agent is organosilicon firming agent or amino resin curing agents.
The formula of described organosilicon firming agent is YSiX3, Y is selected from alkyl, thiazolinyl or end with Cl, NH2, SH, ring
Oxygen, N3、（Methyl）The alkyl of acryloxy, NCO；X is selected from Cl, OMe, OEt, OC2H4OCH3、OSiMe3、OAc。
Preferably, described organosilicon firming agent is MTES, ethyl triethoxysilane, vinyl three
Acetoxysilanes, methyl tributanoximo silane, tetraethoxysilane, γ-glycidyl ether oxygen propyl trimethoxy silicane, 3-
In glycydoxy triethoxysilane, β-(3,4- epoxycyclohexyls) ethyl trimethoxy silane at least one
Kind.
Described amino resin curing agents are melamine class amino resins, benzene for amino resins, methyl-etherified tripolycyanamide
Class amino resins, butyl ether melamine class amino resins, methyl-etherified benzene are in amino resins, the etherification benzene substituted amino resins of fourth
It is at least one.
When described firming agent is organosilicon, at least one of the catalyst in carboxylic acid, sulfonic acid, sulfinic acid, thionothiolic acid；
When described firming agent is amino resins, catalyst is carboxylic acid.
Preferably, when described firming agent is organosilicon, catalyst is selected from acetic acid, butanoic acid, succinic acid, ethanedioic acid, benzene first
One kind in acid, p-methyl benzenesulfonic acid；Described firming agent be amino resins when, catalyst selected from acetic acid, butanoic acid, succinic acid,
One kind in ethanedioic acid, benzoic acid.
Described diluent is selected from ethyl acetate, butyl acetate, glycol methyl ether acetate, propylene glycol monomethyl ether, ethylene glycol
One kind in butyl ether, dimethylbenzene, Ketohexamethylene, isophorone.
A kind of preparation method of water boiling resistance minute surface resin, step are as follows：Diluent is added in mixed cylinder, is subsequently adding general
Logical minute surface resin, firming agent, catalyst, mix homogeneously under room temperature.
A kind of water boiling resistance ink with mirror effect, it is 1 according to mass ratio by described water boiling resistance minute surface resin and minute surface silver paste which is：
（1.5-2）It is mixed.
With reference to specific embodiment, the present invention is described further：
Embodiment 1：
A kind of water boiling resistance minute surface resin, its formula composition such as following table：
Table 1：The formula composition of water boiling resistance minute surface resin
The composition of ink with mirror effect and preparation in present case：Minute surface resin in the present embodiment takes 40 parts, 60 parts of minute surface silver pastes
Mix homogeneously obtains final product ink with mirror effect, and on a glass, paint film toasts 10min at 180 DEG C to ink silk screen printing.
Testing inspection：
Embodiment 2：
A kind of water boiling resistance minute surface resin, its formula composition such as following table：
Table 2：The formula composition of water boiling resistance minute surface resin
The composition of ink with mirror effect and preparation in present case：Minute surface resin in the present embodiment takes 40 parts, 60 parts of minute surface silver pastes
Mix homogeneously obtains final product ink with mirror effect, and on a glass, paint film toasts 10min at 180 DEG C and can be obtained by water boiling resistance ink silk screen printing
Ink with mirror effect.
Testing inspection：
Embodiment 3：
A kind of water boiling resistance minute surface resin, its formula composition such as following table：
Table 3：The formula composition of water boiling resistance minute surface resin
The composition of ink with mirror effect and preparation in the present embodiment：Minute surface resin in the present embodiment takes 40 parts, 60 parts of mirror-like silvers
Slurry mix homogeneously obtains final product ink with mirror effect, and on stainless steel, paint film can be obtained by resistance to ink silk screen printing in 180 DEG C of baking 10min
The minute surface of decocting in water
Testing inspection:
Claims (4)
1. a kind of water boiling resistance minute surface resin, it is characterised in that：Which is made up of the raw material of following mass parts：40 parts of acetate butyrate
Cellulose solution, 15 parts of ethyl triethoxysilane, 14 parts of 3- glycydoxy triethoxysilanes, 1 part
Butanoic acid, 15 parts of butyl acetate, 10 parts of propylene glycol methyl ether acetate, 5 parts of Ketohexamethylene；Described acetylbutyrylcellulose
Solution contains 15wt%, acetylbutyrylcellulose model CAB381-20 admittedly.
2. a kind of water boiling resistance minute surface resin, it is characterised in that：Which is made up of the raw material of following mass parts：50 parts of nitrocellulose
Plain solution, 15 parts of ethyl triethoxysilane, 5 parts of 3- glycydoxy triethoxysilanes, 5 parts of tetrem
TMOS, 2 parts of p-methyl benzenesulfonic acid, 10 parts of butyl acetate, 5 parts of butyl glycol ether, 5 parts of Ketohexamethylene；Described nitre
Cellulose solution contains 8wt% admittedly.
3. the preparation method of a kind of water boiling resistance minute surface resin described in claim 1 or 2, it is characterised in that：Step is as follows：Mixed
Close, be subsequently adding acetylbutyrylcellulose solution, ethyl three
Ethoxysilane, 3- glycydoxy triethoxysilanes, butanoic acid, mix homogeneously under room temperature；Or mixed
Close cylinder in add butyl acetate, butyl glycol ether, Ketohexamethylene, be subsequently adding nitrocellulose solution, ethyl triethoxysilane,
3- glycydoxy triethoxysilanes, tetraethoxysilane, p-methyl benzenesulfonic acid, mix homogeneously under room temperature.
4. a kind of water boiling resistance ink with mirror effect, it is characterised in that：It is water boiling resistance minute surface resin by described in claim 1 or 2 and
Minute surface silver paste is 1 according to mass ratio：（1.5-2）It is mixed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410730609.4A CN104479444B (en) | 2014-12-05 | 2014-12-05 | Boiling-resistant mirror resin and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410730609.4A CN104479444B (en) | 2014-12-05 | 2014-12-05 | Boiling-resistant mirror resin and preparation method thereof |
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| Publication Number | Publication Date |
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| CN104479444A CN104479444A (en) | 2015-04-01 |
| CN104479444B true CN104479444B (en) | 2017-04-19 |
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| CN201410730609.4A Active CN104479444B (en) | 2014-12-05 | 2014-12-05 | Boiling-resistant mirror resin and preparation method thereof |
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Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105153800B (en) * | 2015-07-08 | 2019-02-26 | 合肥旭阳铝颜料有限公司 | A kind of one-component mirror-like silver ink |
| CN105038397A (en) * | 2015-07-08 | 2015-11-11 | 合肥旭阳铝颜料有限公司 | Ultrasonic cleaning resistant mirror ink for mobile phone lens |
| CN105691074B (en) * | 2016-02-18 | 2018-12-28 | 徐州千百度鞋业有限公司 | The laser carving pattern process of TPU rubber material product surface |
| CN109836754B (en) * | 2019-01-17 | 2021-08-10 | 广州致辉精化股份有限公司 | Solvent-resistant and boiling-resistant PC mirror resin and preparation method thereof |
| CN109763349A (en) * | 2019-01-22 | 2019-05-17 | 华大化学(安徽)有限公司 | A kind of middle hard synthetic leather bloom bright face mirror face resin and its preparation method and application |
| CN111484767A (en) * | 2019-01-26 | 2020-08-04 | 深圳市和泰辉科技有限公司 | Single-component mirror ink and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US20050123764A1 (en) * | 2003-12-05 | 2005-06-09 | Hoffmann Rene C. | Markable powder and interference pigment containing coatings |
| CN102533014A (en) * | 2012-02-16 | 2012-07-04 | 上海天地涂料有限公司 | Mirror silver coating, mirror silver resin forming mirror silver coating, and preparation methods for mirror silver coating and mirror silver resin |
| CN103951789B (en) * | 2014-04-04 | 2017-03-15 | 广州伊德尔化学科技有限公司 | A kind of resistant to elevated temperatures minute surface silver resin and preparation method thereof |
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