CN104475051B - A kind of have mixing desulfurization and dedusting granule of bactericidal action and preparation method thereof - Google Patents

A kind of have mixing desulfurization and dedusting granule of bactericidal action and preparation method thereof Download PDF

Info

Publication number
CN104475051B
CN104475051B CN201410638582.6A CN201410638582A CN104475051B CN 104475051 B CN104475051 B CN 104475051B CN 201410638582 A CN201410638582 A CN 201410638582A CN 104475051 B CN104475051 B CN 104475051B
Authority
CN
China
Prior art keywords
granule
hour
bactericidal action
ammonium chloride
dimethyl ammonium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201410638582.6A
Other languages
Chinese (zh)
Other versions
CN104475051A (en
Inventor
巫界树
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI PHOENIX FILTER Co Ltd
Original Assignee
ANHUI PHOENIX FILTER Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI PHOENIX FILTER Co Ltd filed Critical ANHUI PHOENIX FILTER Co Ltd
Priority to CN201410638582.6A priority Critical patent/CN104475051B/en
Publication of CN104475051A publication Critical patent/CN104475051A/en
Application granted granted Critical
Publication of CN104475051B publication Critical patent/CN104475051B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/12—Quaternary ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0248—Compounds of B, Al, Ga, In, Tl
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
    • B01J20/0281—Sulfates of compounds other than those provided for in B01J20/045
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/043—Carbonates or bicarbonates, e.g. limestone, dolomite, aragonite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/045—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing sulfur, e.g. sulfates, thiosulfates, gypsum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/12—Naturally occurring clays or bleaching earth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/14—Diatomaceous earth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/24—Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/102—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/112—Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/202—Polymeric adsorbents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Plant Pathology (AREA)
  • Wood Science & Technology (AREA)
  • Agronomy & Crop Science (AREA)
  • Health & Medical Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

The invention discloses a kind of mixing desulfurization and dedusting granule with bactericidal action is it is characterised in that be made up of the raw material of following weight portion：Activated carbon 95 110, kieselguhr 30 40, Alumen 23, sodium silicate 23, sodium carbonate 3 4.5, cellulose acetate 35, nano titanium oxide 9 12, adhesive chitin fiber 12, myristyl benzyl dimethyl ammonium chloride 12, hargil 8 12, Linesless charcoal 35, adsorption aid 46, appropriate amount of water；Inventive formulation is reasonable, add sodium carbonate, sodium silicate, nano titanium oxide etc. and increased desulfurized effect, activated carbon and kieselguhr etc. are made granule, specific surface area is big, and pore structure is reasonable, add myristyl benzyl dimethyl ammonium chloride, there is good bactericidal action, the present invention can adsorb various solutes and free gass, can effectively remove acidity or volatile harmful gas, it is suitable for industry dry desulfurization, vehicle exhaust desulfurization etc..

Description

A kind of have mixing desulfurization and dedusting granule of bactericidal action and preparation method thereof
Technical field
The present invention relates to a kind of desulphurized aetivated carbon and preparation method thereof, particularly a kind of have mixing desulfurization and dedusting granule of bactericidal action and preparation method thereof.
Background technology
At present the pollutant of in the air are mainly the gas that industrial fuel burning produces, vehicle exhaust, the toxic and harmful producing in production, such as hydrogen sulfide or sulfur dioxide gas.In numerous methods of desulfurization, have a kind of method be active carbon adsorption although activated carbon can adsorb multiple sour gas, but activated carbon price is higher, desulfuration efficiency is low, increased cost.Activated carbon is combined by the present invention with the kieselguhr with special porous, by adding several functions type material, make particulate material, desulfurizing agent is easily fixed, safety non-toxic, absorption property is strong, strengthens rigidity and the intensity of product, extend the use time of activated carbon, reduce the cost of dry desulfurization.
With the raising of people's living standard, there is new cognition to the pure and fresh degree of air, have higher requirement to air-filtering ability.Also having in people's life many times needs to remove toxin, such as antibacterial, toxin.The most limited sorption capacity of adsorbent now, needs the adsorbents different for different requirement research, plays best effect.
Content of the invention
It is an object of the invention to provide a kind of have mixing desulfurization and dedusting granule of bactericidal action and preparation method thereof.
In order to realize the purpose of the present invention, the present invention is implemented by below scheme：
A kind of mixing desulfurization and dedusting granule with bactericidal action, is made up of the raw material of following weight portion：Activated carbon 95-110, kieselguhr 30-40, Alumen 2-3, sodium silicate 2-3, sodium carbonate 3-4.5, cellulose acetate 3-5, nano titanium oxide 9-12, adhesive chitin fiber 1-2, myristyl benzyl dimethyl ammonium chloride 1-2, hargil 8-12, Linesless charcoal 3-5, adsorption aid 4-6, appropriate amount of water；
Described adsorption aid is made up of the raw material of following weight portion：Zirconium English powder 8-11, deer natural pond soil 2-3, magnesium chloride 2-3, sodium bicarbonate 1.5-2.5, natural coal powdered carbon 2-4, polyacrylamide 2-3.5, ceria 2-3, cork 12-14, bamboo fibre 10-13；Preparation method is that cork, bamboo fibre are dried under the conditions of 100 DEG C -120 DEG C 1-1.5 hour, it is ground into 40-60 mesh powder, it is subsequently adding suitable quantity of water to stir with remaining residual components in addition to the soil of deer natural pond, form purees, it is then placed in carbonization 2-3 hour in 400 DEG C -500 DEG C of retort, it is ground into 80-100 mesh powder after taking out cooling, add deer natural pond soil, soak 1.5-2 hour with the acetum of 50%-60%, filter, take the pure water that filtering residue adds 1.5-2 times amount to grind 40-50 minute and obtain slurry.
A kind of mixing desulfurization and dedusting granule with bactericidal action of the present invention, is made up of step in detail below：
（1）Activated carbon, kieselguhr, Linesless charcoal are put into ball milling 1.5-2.5 hour in ball mill, crosses 150-200 mesh sieve after ball milling, obtain mixed-powder stand-by；
（2）Appropriate water will be added in Alumen, sodium silicate, sodium carbonate, nano titanium oxide, hargil, it is stirred continuously and make slurry, it is subsequently adding remaining residual components in addition to myristyl benzyl dimethyl ammonium chloride, adsorption aid, it is heated to 80 DEG C -90 DEG C, 1-1.5 hour is ground in insulation, be cooled to again room temperature add myristyl benzyl dimethyl ammonium chloride, stir mixed slurry is stand-by；
（3）Mixed-powder, mixed slurry, adsorption aid are mutually stirred, then concentrate drying, send into pelletize in comminutor and obtain final product.
The invention has the beneficial effects as follows：Inventive formulation is reasonable, add sodium carbonate, sodium silicate, nano titanium oxide etc. and increased desulfurized effect, activated carbon and kieselguhr etc. are made granule, specific surface area is big, and pore structure is reasonable, add myristyl benzyl dimethyl ammonium chloride, there is good bactericidal action, the present invention can adsorb various solutes and free gass, can effectively remove acidity or volatile harmful gas, it is suitable for industry dry desulfurization, vehicle exhaust desulfurization etc..
Specific embodiments
Below by instantiation, the present invention is described in detail.
A kind of mixing desulfurization and dedusting granule with bactericidal action, by following weight portion（Kilogram）Raw material make：Activated carbon 95, kieselguhr 30, Alumen 2, sodium silicate 2, sodium carbonate 3, cellulose acetate 3, nano titanium oxide 9, adhesive chitin fiber 1, myristyl benzyl dimethyl ammonium chloride 1, hargil 8, Linesless charcoal 3, adsorption aid 4, appropriate amount of water；
Described adsorption aid is by following weight portion（Kilogram）Raw material make：Zirconium English powder 8, deer natural pond soil 2, magnesium chloride 2, sodium bicarbonate 1.5, natural coal powdered carbon 2, polyacrylamide 2, ceria 2, cork 12, bamboo fibre 10；Preparation method is that cork, bamboo fibre are dried under the conditions of 100 DEG C -120 DEG C 1-1.5 hour, it is ground into 40-60 mesh powder, it is subsequently adding suitable quantity of water to stir with remaining residual components in addition to the soil of deer natural pond, form purees, it is then placed in carbonization 2-3 hour in 400 DEG C -500 DEG C of retort, it is ground into 80-100 mesh powder after taking out cooling, add deer natural pond soil, soak 1.5-2 hour with the acetum of 50%-60%, filter, take the pure water that filtering residue adds 1.5-2 times amount to grind 40-50 minute and obtain slurry.
A kind of mixing desulfurization and dedusting granule with bactericidal action of the present invention, is made up of step in detail below：
（1）Activated carbon, kieselguhr, Linesless charcoal are put into ball milling 1.5-2.5 hour in ball mill, crosses 150-200 mesh sieve after ball milling, obtain mixed-powder stand-by；
（2）Appropriate water will be added in Alumen, sodium silicate, sodium carbonate, nano titanium oxide, hargil, it is stirred continuously and make slurry, it is subsequently adding remaining residual components in addition to myristyl benzyl dimethyl ammonium chloride, adsorption aid, it is heated to 80 DEG C -90 DEG C, 1-1.5 hour is ground in insulation, be cooled to again room temperature add myristyl benzyl dimethyl ammonium chloride, stir mixed slurry is stand-by；
（3）Mixed-powder, mixed slurry, adsorption aid are mutually stirred, then concentrate drying, send into pelletize in comminutor and obtain final product.
Inventive samples important technological parameters are：Sulfur capacity (wt%)：>=21%, desulfurization precision（ppm）：≤0.6；Carry out exhaust-gas treatment using inventive samples, trap micronic dust efficiency >=99%.

Claims (2)

1. a kind of mixing desulfurization and dedusting granule with bactericidal action is it is characterised in that be made up of the raw material of following weight portion：Activated carbon 95-110, kieselguhr 30-40, Alumen 2-3, sodium silicate 2-3, sodium carbonate 3-4.5, cellulose acetate 3-5, nano titanium oxide 9-12, adhesive chitin fiber 1-2, myristyl benzyl dimethyl ammonium chloride 1-2, hargil 8-12, Linesless charcoal 3-5, adsorption aid 4-6, appropriate amount of water；
Described adsorption aid is made up of the raw material of following weight portion：Zirconium English powder 8-11, deer natural pond soil 2-3, magnesium chloride 2-3, sodium bicarbonate 1.5-2.5, natural coal powdered carbon 2-4, polyacrylamide 2-3.5, ceria 2-3, cork 12-14, bamboo fibre 10-13；Preparation method is that cork, bamboo fibre are dried under the conditions of 100 DEG C -120 DEG C 1-1.5 hour, it is ground into 40-60 mesh powder, it is subsequently adding suitable quantity of water to stir with remaining residual components in addition to the soil of deer natural pond, form purees, it is then placed in carbonization 2-3 hour in 400 DEG C -500 DEG C of retort, it is ground into 80-100 mesh powder after taking out cooling, add deer natural pond soil, soak 1.5-2 hour with the acetum of 50%-60%, filter, take the pure water that filtering residue adds 1.5-2 times amount to grind 40-50 minute and obtain slurry.
2. according to claim 1 a kind of mixing desulfurization and dedusting granule with bactericidal action it is characterised in that being made up of step in detail below：
（1）Activated carbon, kieselguhr, Linesless charcoal are put into ball milling 1.5-2.5 hour in ball mill, crosses 150-200 mesh sieve after ball milling, obtain mixed-powder stand-by；
（2）Appropriate water will be added in Alumen, sodium silicate, sodium carbonate, nano titanium oxide, hargil, it is stirred continuously and make slurry, it is subsequently adding remaining residual components in addition to myristyl benzyl dimethyl ammonium chloride, adsorption aid, it is heated to 80 DEG C -90 DEG C, 1-1.5 hour is ground in insulation, be cooled to again room temperature add myristyl benzyl dimethyl ammonium chloride, stir mixed slurry is stand-by；
（3）Mixed-powder, mixed slurry, adsorption aid are mutually stirred, then concentrate drying, send into pelletize in comminutor and obtain final product.
CN201410638582.6A 2014-11-13 2014-11-13 A kind of have mixing desulfurization and dedusting granule of bactericidal action and preparation method thereof Active CN104475051B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410638582.6A CN104475051B (en) 2014-11-13 2014-11-13 A kind of have mixing desulfurization and dedusting granule of bactericidal action and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410638582.6A CN104475051B (en) 2014-11-13 2014-11-13 A kind of have mixing desulfurization and dedusting granule of bactericidal action and preparation method thereof

Publications (2)

Publication Number Publication Date
CN104475051A CN104475051A (en) 2015-04-01
CN104475051B true CN104475051B (en) 2017-03-08

Family

ID=52749734

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410638582.6A Active CN104475051B (en) 2014-11-13 2014-11-13 A kind of have mixing desulfurization and dedusting granule of bactericidal action and preparation method thereof

Country Status (1)

Country Link
CN (1) CN104475051B (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104826391A (en) * 2015-04-21 2015-08-12 安徽凤凰滤清器股份有限公司 Nanometer-ceramic-powder-base adsorption filtering agent and preparation method thereof
CN104841393A (en) * 2015-04-21 2015-08-19 蚌埠德美过滤技术有限公司 Adsorption filtering agent capable of efficiently adsorbing hydrogen sulfide and preparation method thereof
CN104826444A (en) * 2015-04-22 2015-08-12 芜湖市鸿坤汽车零部件有限公司 Fiber modified antibacterial activated carbon diatomite air purifier and preparation method thereof
CN104888733A (en) * 2015-05-21 2015-09-09 安徽凤凰滤清器股份有限公司 Adsorbent able to purify water
CN105921098A (en) * 2016-06-16 2016-09-07 马鞍山市顺达环保设备有限公司 Easily dispersed modified fly ash adsorbent
CN106000071A (en) * 2016-06-27 2016-10-12 含山县科宇环境工程有限公司 Industrial desulfurizing agent and preparation method thereof
CN106582570A (en) * 2016-12-26 2017-04-26 南宁梦幻三体环保科技有限公司 Filtering membrane prepared with 3d printing technology and preparation method of filtering membrane
CN106807348B (en) * 2017-04-07 2019-04-12 武夷学院 Activated carbon fiber-loaded TiO2The preparation method of photochemical catalyst
CN107149810A (en) * 2017-06-08 2017-09-12 安徽天诚环保机械有限公司 A kind of active carbon air filtering material with bactericidal action and preparation method thereof
CN107890747A (en) * 2017-11-15 2018-04-10 江苏齐力涂装机械制造有限公司 One kind spraying filter cotton and preparation method thereof

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3757490A (en) * 1971-06-07 1973-09-11 Ja Ma Chromatographic adsorbents
JPS5644040A (en) * 1979-09-17 1981-04-23 Katsuyoshi Kojima Production of porous adsorbent-desorbent
CN103382127B (en) * 2013-06-25 2014-11-26 蚌埠凤凰滤清器有限责任公司 Composite ceramic filter core and preparation method thereof
CN103381320B (en) * 2013-06-25 2015-08-05 安徽凤凰滤清器股份有限公司 A kind of filtering micropore filter core and preparation method thereof
CN103566922A (en) * 2013-09-26 2014-02-12 蚌埠华纺滤材有限公司 Rare-earth modified active carbon catalytic material and preparation method thereof

Also Published As

Publication number Publication date
CN104475051A (en) 2015-04-01

Similar Documents

Publication Publication Date Title
CN104475051B (en) A kind of have mixing desulfurization and dedusting granule of bactericidal action and preparation method thereof
KR101516095B1 (en) Air purification agent of multi-pore-sized charcoal particles and process for production of same
CN104437432B (en) A kind of finely dispersed activated carbon kieselguhr air purifying particles and preparation method thereof
CN102745879B (en) Sludge-based adsorbent used for desulfurization and demercuration of flue-gas and preparation method thereof
CN104289195B (en) A kind of activated carbon diatomite particle of hole prosperity low cost and preparation method thereof
CN104437371A (en) Composite porous activated carbon flue gas adsorbent and preparation method thereof
CN104475020A (en) Environment-friendly active carbon particle with good absorption degradation effect and method for preparing environment-friendly active carbon particle with good absorption degradation effect
CN104475050A (en) Activated carbon diatomite particles capable of rapid purification of flue gas and preparation method thereof
CN104437366A (en) Uneasily-disintegrated mixed active carbon desulfurizing agent and preparation method thereof
CN106669604A (en) Air purifying material capable of removing ammonia and secondhand smoke and preparation method thereof
CN104275032A (en) Tough active carbon filtration material applied to air conditioner and preparation method of tough active carbon filtration material
CN103566893A (en) Oyster shell modified activated carbon desulfurizing agent, and preparation method thereof
CN104307493A (en) Solid and durable activated carbon diatomite particles for desulfurization and dust removal and preparation method thereof
CN106000073B (en) A kind of environment-protective process for administering boiler smoke
CN103495403A (en) Modified activated carbon adsorption desulfurization agent and its preparation method
CN104353421A (en) Anti-haze adsorbent and preparation method thereof
CN104353422A (en) Antibacterial breathing mask adsorbent and preparation method thereof
CN109967032A (en) A kind of method of flyash and stalk joint preparation industrial wastewater adsorbent
CN104437385A (en) Expanded graphite added activated carbon filter material and preparation method thereof
CN104437420A (en) Polymetallic diatomite activated carbon composite solid desulfurizing agent and preparation method thereof
CN107344062A (en) A kind of desulfurizing agent, its preparation method and application
CN104437399A (en) Low-cost activated carbon kieselguhr particles with developed pores, and preparation method of kieselguhr particles
CN106268633A (en) A kind of mixed active charcoal desulfurizing agent of not easy disintegrating and preparation method thereof
CN104437428A (en) Novel multi-carbon antibacterial desulfurization particles with good mixing performance and preparation method of novel multi-carbon antibacterial desulfurization particles
CN104437357A (en) Antibacterial modified active carbon desulfurizing particles prepared from tobacco stems and tea seed hulls and preparation method of antibacterial modified active carbon desulfurizing particles

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant