CN104419960A - Anodic oxidation production line and production process thereof - Google Patents

Anodic oxidation production line and production process thereof Download PDF

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Publication number
CN104419960A
CN104419960A CN201310385728.6A CN201310385728A CN104419960A CN 104419960 A CN104419960 A CN 104419960A CN 201310385728 A CN201310385728 A CN 201310385728A CN 104419960 A CN104419960 A CN 104419960A
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electrolyzer
carrier
travelling belt
district
anodic oxidation
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CN201310385728.6A
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Chinese (zh)
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谢彪
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Individual
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/04Anodisation of aluminium or alloys based thereon

Abstract

The invention discloses an anodic oxidation production line and a production process thereof. The anodic oxidation production line comprises a conveying belt with a closed loop structure and a carrier which is arranged on the conveying belt and is subjected to cycling operation with the conveying belt, wherein the carrier is conveyed by the conveying belt to sequentially pass through an upper hanging area, an oxidation area and a lower hanging area, and then enters the upper hanging area again to perform cycling operation, and the oxidation area is provided with a plurality of electrolytic tanks which are used for oxidizing to-be-oxidized products. Closed-loop continuous production can be achieved by the anodic oxidation production process through the following steps: providing the production line, arranging the carrier capable of loading the to-be-oxidized products on the closed loop conveying belt, sequentially performing upper hanging, oxidation and lower hanging on the carrier along with the conveying belt, and then circulating to enter a new upper hanging process. In the oxidation step, the technical problem that an oxidation process is jumped from one electrolytic tank to another electrolytic tank can be solved by sequentially setting process steps such as electrolysis, uphill treatment, cleaning, downhill treatment and the like, continuous oxidation can be achieved, and uniform and consistent colors of oxidized products can be ensured.

Description

Anodic oxidation production line and production technique thereof
[technical field]
The present invention relates to a kind of anodic oxidation production line and production technique thereof, particularly relate to a kind of loop production, the anodic oxidation production line of continuous oxidation and production technique thereof.
[background technology]
In order to overcome the defect of the aspects such as aluminum alloy surface hardness, wearability, broadened application scope, increases the service life, and usually can carry out anode oxidation process to materials such as Aluminum-aluminum alloy.So-called anodizing of aluminium is a kind of electrolytic acid cleaning oxydation process, and in this process, the surface of aluminum and its alloy is converted into layer oxide film usually, and this layer of oxide film has protectiveness, ornamental and some other functional performance.
Traditional anodic oxidation production line, is generally, by transfer gantry, the product of band oxidation is put into electrolyzer, after process for some time, then hangs out and enter next process.Such meeting causes being with the part of the advanced electrolyzer of the product of oxidation but can finally go out, electrolysis time is longer, thus the product oxide thickness that processes can be caused uneven, color and luster is inconsistent, and production process need adopt transfer gantry such reset greatly standby lifting, it is inadequate that whole piece produces line handiness, and production efficiency is low, and cost is high.
Prior art also has the production line adopting continuous oxidation, but it is all unidirectional production line, can not realize circulation continuous seepage, and need to adopt lifting appliance that product is lifted to another treating pond from a treating pond, product line structure is complicated, and production efficiency is low, and oxide film color and luster is inconsistent.
[summary of the invention]
Produce for the anodic oxidation production line and production technique thereof that overcome prior art can not realize continuous circulation, the technical problems such as complex structure, the invention provides a kind of loop production, the anodic oxidation production line of continuous oxidation and oxidizing process thereof.
The technical scheme that the present invention solves prior art problem is: provide a kind of anodic oxidation production line, the carrier comprising the travelling belt in closed-loop structure and be placed in travelling belt cycle operation on travelling belt, travelling belt transmits carrier and carries out cycle operation by again entering Shang Gua district behind Shang Gua district, oxidation zone Ji Xiagua district successively, and wherein oxidation zone arranges the multiple electrolyzers treated oxygenated products and carry out being oxidized.
Preferably, arrange wheel bottom carrier, wheel matches with travelling belt, makes carrier with travelling belt parallel running.
Preferably, between every two adjacent electrolyzers, rinse bath is set.
Preferably, each electrolyzer is provided with multiple electrolysis zone, and the plurality of electrolysis zone is by polylith cathode separator interval.
Preferably, travelling belt arranges upward slope district by the electrolyzer section entered between rinse bath, descending district is set between this rinse bath and next electrolyzer, carrier is departed from by upward slope district from the electrolyzer of low level and enters into high-order rinse bath and cleans, and is then entered into the electrolyzer of next low level by descending district.
Preferably, each electrolyzer is provided with one for carrying out the liquid medicine auto-feeding device that liquid medicine supplements to electrolyzer.
Preferably, this liquid medicine auto-feeding device comprises storage tank, transfer tank, electromagnetic pump, the first pipeline and second pipe, storage tank is placed in bottom of electrolytic tank, transfer tank is placed in electrolyzer top, first pipeline is from storage tank UNICOM to transfer tank, second pipe is incorporated into electrolyzer from transfer tank, the first pipeline arranges check valve, second pipe arranges magnetic valve.
Anodic oxidation production line provided by the invention consists of the loop structure closed travelling belt, production can be carried out continuously, and the carrier on travelling belt can recirculation utilize very easily, the utilization ratio that improve carrier and the loading work decreasing carrier.Carrier loads product to be oxidized and moves in parallel continuously inside electrolyzer, makes Realization of Product continuous oxidation to be oxidized, to obtain the oxidated layer thickness of uniformity and consistent color and luster, makes product surface Disposal quality higher.Multiple electrolyzer is set to realize different oxidizing procesies, improves oxide film precision and the quality of product.Travelling belt arranges upward slope district from the position that an electrolyzer enters into rinse bath, by this rinse bath position entered between next electrolyzer, descending district is set, like this, carrier just can realize product and depart from from electrolyzer and enter into rinse bath and then enter into again next electrolyzer while passing forward with travelling belt, and do not need to use heavy transfer gantry, also without any need for other lifting appliances, structure simplifies greatly, and production efficiency improves greatly.Each electrolyzer configures an automatic liquid medicine supplementary device simultaneously, so that automatically supplement the liquid medicine in electrolyzer, improves level of automation further.
The another technical scheme that the present invention solves prior art problem is: provide a kind of anodic oxidation production technique, and provide a set of anodic oxidation production line as claimed in claim 1, it comprises the steps,
(1) upper extension, product to be oxidized is loaded carrier, and carrier is with travelling belt cycle operation;
(2) be oxidized, carrier enters oxidation zone, and product to be oxidized is placed in electrolyzer and carries out oxide treatment; And
(3) hang under, unloaded by well-oxygenated product from carrier, carrier unloaded subsequently enters into next round cycle operation with travelling belt.
Preferably, in oxidation zone, multiple electrolyzer is set, between every two adjacent electrolyzers, a rinse bath is set, the section that travelling belt enters into rinse bath by electrolyzer arranges upward slope district, the section being entered into electrolyzer by rinse bath arranges descending district, this step (2) oxidizing process comprises following processing step further
A. electrolysis, product introduction to be oxidized carries out electrolysis to electrolyzer;
B. go up a slope, carrier enters upward slope district with travelling belt, advances and promotes, and makes product depart from electrolysis zone and enters into cleaning area;
C. clean, in cleaning area, product is cleaned;
D. descending, cleaned product enters descending district with travelling belt, and product advances to decline and enters next treating pond.
Preferably, multiple continuous print oxidation step is set.
Anodic oxidation production technique provided by the invention, by product line is arranged to closed-loop structure, makes carrier cycle operation on a moving belt, can realize circulation continuous seepage, improve the utilization ratio of production efficiency and carrier.In oxidizing process, by arranging rinse bath between two electrolyzers, upward slope district is set between last electrolyzer and rinse bath, arrange descending district between rinse bath and next electrolyzer, like this, carrier just can realize product and depart from from electrolyzer and enter into rinse bath and then enter into again next electrolyzer while passing forward with travelling belt, and do not need to use heavy transfer gantry, also without any need for other lifting appliances, structure simplifies greatly, and production efficiency improves greatly.Arrange multiple oxidizing process step, the surface treatment situation can treating oxygenated products more accurately controls, and makes its color and luster and oxide thickness all keep uniformity.
[accompanying drawing explanation]
Fig. 1 is the structural representation of a kind of anodic oxidation production line that first embodiment of the invention provides, and it comprises multiple oxidation unit.
Fig. 2 is the oxidation unit operation principles structural representation shown in Fig. 1, and it comprises liquid medicine supplementary device.
Fig. 3 is the liquid medicine supplementary device operation principles structural representation shown in Fig. 2.
Fig. 4 is the anodic oxidation production technological process that second embodiment of the invention provides.
[embodiment]
In order to make object of the present invention, technical scheme and advantage are clearly understood, below in conjunction with drawings and Examples, are further elaborated to the present invention.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
Refer to Fig. 1, for first embodiment of the invention provides a kind of anodic oxidation production line 10, it comprises travelling belt 11, Shang Gua district 12, oxidation zone 16 Ji Xiagua district 17, this travelling belt 11 by entering into again the cycle operation of carrying out going round and beginning again in initial Shang Gua district 11 behind Shang Gua district 12, oxidation zone 16 Ji Xiagua district 17, makes this anodic oxidation production line 10 form quantity-produced closed-loop structure successively.Product to be oxidized is at Shang Gua district 12 material loading, and after then carrying out oxide treatment via oxidation zone 16, well-oxygenated product is carried out discharging by Zai Congxiagua district 17.This oxidation zone 16 comprises the oxidation unit 161 of multiple series winding.
Refer to Fig. 2, the electrolyzer 13 be connected before and after this oxidation unit 161 comprises and rinse bath 14, and the supplementary liquid medicine auto-feeding device 18 of liquid medicine is carried out to electrolyzer 13.Multiple oxidation unit 161 is concatenated into oxidation zone 16, makes to be provided with a rinse bath 14 between every two electrolyzers 13.Travelling belt 11 arranges upward slope district 111 between preceding electrolyzer 13 and posterior rinse bath 14, between this rinse bath 14 and next electrolyzer 13, arrange descending district 112.Travelling belt 11 is arranged multiple climbing trolley 15 to operate with travelling belt, dangle bottom climbing trolley 15 product to be oxidized.The climbing trolley 15 that product to be oxidized is housed is departed from by upward slope district 111 from the electrolyzer 13 of low level and enters into high-order rinse bath 14 and cleans, and is then entered into the electrolyzer 13 of next low level by descending district 112.
Arrange wheel (non-label) bottom climbing trolley 15, arrange wheel (non-label) bottom climbing trolley 15, wheel (non-label) matches with travelling belt 11, makes climbing trolley 15 with travelling belt 11 parallel running.
Each rinse bath 14 arranges multiple cleaning area (non-label), the plurality of cleaning area (non-label) is separated by dividing plate 141, each dividing plate 141 is all arranged multiple nozzle (non-label), nozzle alignment product carries out cleaning showers.
Refer to Fig. 3, each electrolyzer 13 is provided with one for carrying out the liquid medicine auto-feeding device 18 that liquid medicine supplements to electrolyzer 13.This liquid medicine auto-feeding device 18 comprises storage tank 181, transfer tank 184, electromagnetic pump 1821, electric control box 183, first pipeline (non-label) and second pipe (non-label), storage tank 181 is placed in bottom electrolyzer 13, transfer tank 184 is placed in electrolyzer 13 top, first pipeline is communicated to transfer tank from storage tank 181, second pipe is incorporated into electrolyzer 13 from transfer tank 184, first pipeline is arranged check valve 1822, second pipe is arranged magnetic valve 1823.Check valve 1822 controls liquid medicine can only flow to transfer tank 184 by storage tank 181, magnetic valve 1823 control transfer tank 184 pairs of electrolyzers 13 carry out liquid medicine supplement, climbing trolley 15 often cross once, supplementary liquid medicine is once.
Arrange for detecting the high-order check point 1842 of top water-level and the low level check point 1841 for detecting lowest water level point in this transfer tank 184, and the regulation of level pipe 1843 for regulating top water-level check point and lowest water level check point.This high-order check point 1842, low level monitoring point 1841, electromagnetic pump 1821 and magnetic valve 1823 are all electrically connected with electric control box 183, by electric control box 183 centralized Control.
Each electrolyzer 13 is provided with multiple electrolysis zone (non-label), and the plurality of electrolysis zone by polylith negative plate 131 separately.
Anodic oxidation production line 10 provided by the invention can also have various deformation structure, climbing trolley 15 can be that other is for hanging the carrier (not shown) of product (not shown) to be oxidized, it coordinates with travelling belt 11, with travelling belt 11 cycle operation.The two-wire pleated sheet structure taken the shape of the letter U that this anodic oxidation production line 10 entirety can be closed also can be closed bilinear shape or other forms of two-wire loop structure.
When anodic oxidation production line 10 provided by the invention operates, travelling belt 11 is laid in closed-loop structure, cycle operation, successively by again entering Shang Gua district 12 behind Shang Gua district 12, oxidation zone 16 Ji Xiagua district 17.Oxidation zone 12 is provided with multiple electrolyzer 13 and multiple rinse bath 14.Product to be oxidized loads climbing trolley 15 in Shang Gua district 12, then enters into oxidation zone 16 with travelling belt 11, carries out oxide treatment successively through each oxidation unit 161.At each oxidation unit 161, climbing trolley 15 carries out slope climbing movement via upward slope district 111, and climbing trolley 15 advances and rises, thus realizes departing from from last electrolyzer 13 and entering rinse bath 14.Advance via descending district 112 while decline again, thus realize entering into next electrolyzer 13 from rinse bath 14, whole process is carried out continuously, climbing trolley 15 moves in parallel, without the need to other lifting appliances, and without the need to re-using heavy transfer gantry, product to be oxidized is hung in another electrolyzer 13 from an electrolyzer 13.Product to be oxidized moves in parallel in electrolyzer 13, realizes continuous oxidation, ensures that zone of oxidation is consistent with uniform color.Multiple electrolyzer 13 is set so that control the surface treatment quality of product to be oxidized more accurately.Product enters into Xia Gua district 17 with travelling belt 11 after the repeatedly oxidizing process of oxidation zone 16, unloads product in Xia Gua district 17, and unloaded climbing trolley 15 remains in operation with travelling belt 11, again enters Shang Gua district 12.
Anodic oxidation production line 10 provided by the invention forms enclosed construction cycle operation by travelling belt 11, production can be carried out by continuous circulation, carrier (climbing trolley 15) on travelling belt 11 can recirculation utilize very easily, improves the utilization ratio of carrier (climbing trolley 15) and decreases the loading work of carrier (climbing trolley 15).Carrier (climbing trolley 15) loads product to be oxidized and moves in parallel continuously inside electrolyzer 13, makes Realization of Product continuous oxidation to be oxidized, to obtain the oxidated layer thickness of uniformity and consistent color and luster, makes product surface Disposal quality higher.Multiple electrolyzer 13 is set to realize different oxidizing procesies, improves oxide film precision and the quality of product.Travelling belt 11 arranges upward slope district 111 from the position that an electrolyzer 13 enters into rinse bath 14, the position entered between next electrolyzer 13 by this rinse bath 14 arranges descending district 112, like this, carrier (climbing trolley 15) just can realize product and depart from from electrolyzer 13 and enter into rinse bath 14 and then enter into again next electrolyzer 13 while passing forward with travelling belt 11, and do not need to use heavy transfer gantry, also without any need for other lifting appliances, structure simplifies greatly, and production efficiency improves greatly.Each electrolyzer 13 configures an automatic liquid medicine supplementary device 18 simultaneously, so that automatically supplement the liquid medicine in electrolyzer 13, improves level of automation further.
Refer to Fig. 4, second embodiment of the invention provides a kind of anodic oxidation production technique, and structure number involved below please refer to the first embodiment accompanying drawing 1-3, and it comprises the steps:
Step 201: a set of closed loop anodic oxidation production line is provided, this anodic oxidation production line is identical with the anodic oxidation line that first embodiment of the invention provides, it comprises in closed-loop structure, the travelling belt of cycle operation, and be placed on travelling belt with the carrier that travelling belt operates, be climbing trolley in the present embodiment, product to be oxidized can be loaded above climbing trolley, this climbing trolley is arranged on this travelling belt and operates with travelling belt, the climbing trolley of running is successively by Shang Gua district, oxidation zone Ji Xiagua district and then enter Shang Gua district and carry out cyclic motion, the multiple electrolyzers treated oxygenated products and carry out being oxidized are set in oxidation zone,
Step 202: upper extension, loads climbing trolley by product to be oxidized;
Step 203: oxidation, is placed in product to be oxidized in electrolyzer and carries out oxide treatment;
Step 205: lower extension, unloads well-oxygenated product from climbing trolley, and climbing trolley unloaded subsequently enters into next round cycle operation with travelling belt.
Wherein, the oxidizing process of step 203 can repeat to arrange multiple, and the concrete oxidizing condition of each oxidizing process step can adjust according to the actual requirements.
Wherein, arrange a rinse bath between every two adjacent electrolyzers, the section that travelling belt enters into rinse bath by electrolyzer arranges upward slope district, and the section being entered into electrolyzer by rinse bath arranges descending district, this step 203 oxidizing process comprises following processing step further
Step 2031: electrolysis, product introduction to be oxidized carries out electrolysis to electrolyzer;
Step 2032: go up a slope, the product of electrolysis enters upward slope district with travelling belt, and product advances and promotes, and departs from electrolysis zone and enter into cleaning area;
Step 2033: cleaning, cleans product in cleaning area;
Step 2034: descending, cleaned product enters descending district with travelling belt, and product advances to decline and enters next treating pond.
Anodic oxidation production technique provided by the invention, by product line is arranged to closed-loop structure, makes climbing trolley cycle operation on a moving belt, can realize circulation continuous seepage, improve the utilization ratio of production efficiency and climbing trolley.In oxidizing process, by arranging rinse bath between two electrolyzers, upward slope district is set between last electrolyzer and rinse bath, arrange descending district between rinse bath and next electrolyzer, like this, climbing trolley just can realize product and depart from from electrolyzer and enter into rinse bath and then enter into again next electrolyzer while passing forward with travelling belt, and do not need to use heavy transfer gantry, also without any need for other lifting appliances, structure simplifies greatly, and production efficiency improves greatly.Arrange multiple oxidizing process step, the surface treatment situation can treating oxygenated products more accurately controls, and makes its color and luster and oxide thickness all keep uniformity.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, all any amendments done within principle of the present invention, equivalent replacement and improvement etc. all should be included within protection scope of the present invention.

Claims (10)

1. an anodic oxidation production line, it is characterized in that: the carrier comprising the travelling belt in closed-loop structure and be placed in travelling belt cycle operation on travelling belt, travelling belt transmits carrier and carries out cycle operation by again entering Shang Gua district behind Shang Gua district, oxidation zone Ji Xiagua district successively, and wherein oxidation zone arranges the multiple electrolyzers treated oxygenated products and carry out being oxidized.
2. anodic oxidation production line as claimed in claim 1, it is characterized in that: arrange wheel bottom carrier, wheel matches with travelling belt, makes carrier with travelling belt parallel running.
3. anodic oxidation production line as claimed in claim 1, is characterized in that: arrange rinse bath between every two adjacent electrolyzers.
4. anodic oxidation production line as claimed in claim 3, is characterized in that: each electrolyzer is provided with multiple electrolysis zone, and the plurality of electrolysis zone is by polylith cathode separator interval.
5. the anodic oxidation production line as described in claim 3 or 4, it is characterized in that: travelling belt arranges upward slope district by the electrolyzer section entered between rinse bath, descending district is set between this rinse bath and next electrolyzer, carrier is departed from by upward slope district from the electrolyzer of low level and enters into high-order rinse bath and cleans, and is then entered into the electrolyzer of next low level by descending district.
6. anodic oxidation production line as claimed in claim 5, is characterized in that: each electrolyzer is provided with one for carrying out the liquid medicine auto-feeding device that liquid medicine supplements to electrolyzer.
7. anodic oxidation production line as claimed in claim 1, it is characterized in that: this liquid medicine auto-feeding device comprises storage tank, transfer tank, electromagnetic pump, the first pipeline and second pipe, storage tank is placed in bottom of electrolytic tank, transfer tank is placed in electrolyzer top, first pipeline is from storage tank UNICOM to transfer tank, second pipe is incorporated into electrolyzer from transfer tank, the first pipeline arranges check valve, second pipe arranges magnetic valve.
8. an anodic oxidation production technique, provides a set of anodic oxidation production line as claimed in claim 1, it is characterized in that: comprise the steps,
(1) upper extension, product to be oxidized is loaded carrier, and carrier is with travelling belt cycle operation;
(2) be oxidized, carrier enters oxidation zone, and product to be oxidized is placed in electrolyzer and carries out oxide treatment; And
(3) hang under, unloaded by well-oxygenated product from carrier, carrier unloaded subsequently enters into next round cycle operation with travelling belt.
9. anodic oxidation production technique as claimed in claim 8, it is characterized in that: in oxidation zone, multiple electrolyzer is set, between every two adjacent electrolyzers, a rinse bath is set, the section that travelling belt enters into rinse bath by electrolyzer arranges upward slope district, the section being entered into electrolyzer by rinse bath arranges descending district, this step (3) oxidizing process comprises following processing step further
A. electrolysis, product introduction to be oxidized carries out electrolysis to electrolyzer;
B. go up a slope, carrier enters upward slope district with travelling belt, advances and promotes, and makes product depart from electrolysis zone and enters into cleaning area;
C. clean, in cleaning area, product is cleaned;
D. descending, cleaned product enters descending district with travelling belt, and product advances to decline and enters next treating pond.
10. anodic oxidation production technique as claimed in claim 9, is characterized in that: arrange multiple continuous print oxidation step.
CN201310385728.6A 2013-08-20 2013-08-20 Anodic oxidation production line and production process thereof Pending CN104419960A (en)

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CN105063731A (en) * 2015-08-08 2015-11-18 谢彪 Continuous rack plating production line and production process thereof
CN105112986A (en) * 2015-07-27 2015-12-02 谢彪 Rack plating production line and rack plating production process
CN105386110A (en) * 2015-12-16 2016-03-09 四川迅吉科技有限责任公司 Anodic oxidation treatment device for aluminum alloy surface
CN106319613A (en) * 2015-06-23 2017-01-11 谢彪 Horizontal continuous electroplating production line and production technology thereof
CN108149294A (en) * 2018-01-12 2018-06-12 山东省科学院新材料研究所 Continuous oxidation processing system and method
BE1024745B1 (en) * 2017-03-27 2018-06-18 Malve Nv METHOD AND DEVICE FOR ANODIZING ALUMINUM OBJECTS AND ANODIZED ALUMINUM OBJECT
CN108560033A (en) * 2018-04-11 2018-09-21 安徽玄同工业设计有限公司 A kind of workpiece anodized technique
CN108796575A (en) * 2018-09-04 2018-11-13 俊杰机械(深圳)有限公司 A kind of control system and method for anodic oxidation line
CN111218705A (en) * 2020-01-16 2020-06-02 西安庄信新材料科技有限公司 Titanium product anodic oxidation processing apparatus

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CN106319613A (en) * 2015-06-23 2017-01-11 谢彪 Horizontal continuous electroplating production line and production technology thereof
CN106319613B (en) * 2015-06-23 2019-01-18 惠州市安泰普表面处理科技有限公司 Horizontal continuity electroplating assembly line and its production technology
CN105112986A (en) * 2015-07-27 2015-12-02 谢彪 Rack plating production line and rack plating production process
CN105063731A (en) * 2015-08-08 2015-11-18 谢彪 Continuous rack plating production line and production process thereof
CN105386110A (en) * 2015-12-16 2016-03-09 四川迅吉科技有限责任公司 Anodic oxidation treatment device for aluminum alloy surface
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CN108149294A (en) * 2018-01-12 2018-06-12 山东省科学院新材料研究所 Continuous oxidation processing system and method
CN108560033A (en) * 2018-04-11 2018-09-21 安徽玄同工业设计有限公司 A kind of workpiece anodized technique
CN108796575A (en) * 2018-09-04 2018-11-13 俊杰机械(深圳)有限公司 A kind of control system and method for anodic oxidation line
CN111218705A (en) * 2020-01-16 2020-06-02 西安庄信新材料科技有限公司 Titanium product anodic oxidation processing apparatus
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