CN104403449A - Insulation anti-fouling self-cleaning paint and preparation method thereof - Google Patents
Insulation anti-fouling self-cleaning paint and preparation method thereof Download PDFInfo
- Publication number
- CN104403449A CN104403449A CN201410590256.2A CN201410590256A CN104403449A CN 104403449 A CN104403449 A CN 104403449A CN 201410590256 A CN201410590256 A CN 201410590256A CN 104403449 A CN104403449 A CN 104403449A
- Authority
- CN
- China
- Prior art keywords
- parts
- paint
- emulsion
- self
- cleaning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1618—Non-macromolecular compounds inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an insulation anti-fouling self-cleaning paint which is prepared from the following raw materials, by weight: 30-36 parts of acrylic resin emulsion, 10-15 parts of elastic emulsion, 20-26 parts of polytetrafluoroethylene emulsion, 1-2 parts of lignocellulose, 1-2 parts of hydroxyethyl cellulose sodium, 0.2-0.4 parts of dimethicone, 2-3 parts of silicon carbide, 0.5-0.8 parts of polyvinyl isobutyl ether, 2-3 parts of triethylene glycol monobutyl ether, 0.3-0.5 parts of a leveling agent BYK-56, 0.3-0.5 parts of polyoxyethylene monooleate, 0.2-0.4 parts of azobisisobutyronitrile heptanenitrile, 2-3 parts of nano-scale antimony-doped tin dioxide, 2-3 parts of silicon phosphate, 1-2 parts of micrometer-scale matting powder, 6-9 parts of self-cleaning slurry, and 14-20 parts of deionized water. The paint provided by the invention has the characteristics of good insulation property, good anti-static property, good self-cleaning property, and the like. The paint is safe and environment-friendly, and does not contain heavy metal and toxic organic solvent. The VOC value of the paint is extremely low. The paint is simple to apply, and does not harm human health. The paint satisfies the requirements of a green and environment-friendly paint.
Description
Technical field
The present invention relates to a kind of coating and preparation method thereof, particularly antifouling self-cleaning coating of a kind of insulation and preparation method thereof.
Background technology
In daily life, along with the enhancing day by day of health of people consciousness, the living environment situation of people more and more attracts much attention, and the healthy of people in the serious harm of a series of derivative such as formaldehyde, benzene.Along with the fast development of China's building industry, the cleaning way of the material of construction such as ceramic tile, glass is but without any change.Manual cleaning and inconvenience are also dangerous, and in addition, life-time service clean-out system not only wastes resource, also will bring pollution to environment, do not meet environmental protection that current country advocates, save policy.Self-cleaning coating is applied in glass, pottery, fluorine carbon plate and other purposes, the photocatalysis of the titanium dioxide semiconductor particle self in self-cleaning coating can be utilized on the one hand, the organic pollutant being adsorbed on substrate surface can be decomposed, make substrate surface keep clean; Good antibacterial, the germicidal action of the titanium dioxide in self-cleaning coating can also being utilized on the other hand, the propagation suppressing germ can be played when self-cleaning coating being applied to these substrate surfaces.Under UV-irradiation, titanium dioxide has the ability of good wetting ability Sum decomposition organic substance, therefore when the organism such as the dust in air, mushroom are attached to substrate surface, the automatic classifying mechanism of the titanium dioxide on substrate surface will start, thus reaches the object keeping substrate surface to clean for a long time.The present invention is directed to this situation, by by there is the self-cleaning material of photo-catalysis function and there is the macromolecular compound doping of conduction property, then through forming slurry with other substance reactions, adding in coating serving good automatically cleaning effect to as auxiliary agent.
Summary of the invention
The object of this invention is to provide antifouling self-cleaning coating of a kind of insulation and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
The antifouling self-cleaning coating of a kind of insulation, be made up of the raw material of following weight part: Emulsion acrylic resin 30-36, elastic emulsion 10-15, ptfe emulsion 20-26, lignocellulose 1-2, sodium hydroxyethyl cellulose 1-2, dimethyl silicone oil 0.2-0.4, silicon carbide 2-3, polyvinyl isobutyl ether 0.5-0.8, Tri(propylene glycol)butyl ether,mixture of isomers 2-3, flow agent BYK-560.3-0.5, Aceonon 300 MO 0.3-0.5, 2,2'-Azobis(2,4-dimethylvaleronitrile) 0.2-0.4, nanometer antimony-doped stannic oxide 2-3, silicon phosphate 2-3, micron flatting silica 1-2, automatically cleaning slurry 6-9, deionized water 14-20,
Described automatically cleaning slurry is made up of the raw material of following weight part: polyisobutene 2-3, tetrabutyl titanate 0.5-1.0, zinc oxide 6-10, dispersion agent 50403-4, titanium dioxide 20-30, zirconium white 10-15, ethanol 30-50, Diisopropyl azodicarboxylate 1-2, sodium laurylsulfonate 1-2, antimony-doped stannic oxide 5-7, sodium acetate 1-2, Vltra tears 2-4, polyaniline 1-2, bipyridyl ruthenium 1-2, preparation method is by zinc oxide, titanium dioxide, zirconium white, antimony-doped stannic oxide ball milling becomes nano-powder, be added to polyaniline, in the ethanolic soln of bipyridyl ruthenium, mix and blend 2-3 hour under baking oven 60-80 ° C dry 1-2 hour for subsequent use, again by Vltra tears, sodium laurylsulfonate, sodium acetate, dispersion agent 5040 and remaining ethanol are mixed and heated to 40-60 ° of C, add the nano-powder ultrasonic disperse 0.5-1 hour of above-mentioned preparation, meanwhile add all the other surplus materials mixing and stirring, the weight that drying is concentrated into titanium dioxide accounts for the 10-30% of slurry weight.
A kind of high weatherability self-cleaning waterproof paint of the present invention, be made up of following concrete steps:
(1) deionized water, Aceonon 300 MO, lignocellulose are mixed and heated to 60-90 ° of C and form emulsion, add sodium hydroxyethyl cellulose again, silicon carbide, nanometer antimony-doped stannic oxide, silicon phosphate, micron flatting silica, automatically cleaning slurry ultrasonic disperse reduce temperature at 50-60 ° of C after 20-30 minute, add 2,2'-Azobis(2,4-dimethylvaleronitrile) and continue to stir 5-10 minute;
(2) Emulsion acrylic resin, elastic emulsion, ptfe emulsion, polyvinyl isobutyl ether, Tri(propylene glycol)butyl ether,mixture of isomers are added in Scattered Kettle and mix, be heated to 40-60 ° of C, under the rotating speed of 200-400 rev/min, stir 30-50 minute;
(3) mixed by all the other surplus materialss, the material added in step (1) and step (2) stirs with the rotating speed of 200-300 rev/min, filters and packages.
Advantage of the present invention is: the micron flatting silica that coating of the present invention adds has the brightness of reduction paint film, paint film brightness is made not stimulate people's eyeball, the nanometer antimony-doped stannic oxide added has anlistatig effect, the automatically cleaning slurry added has good automatically cleaning effect, coating of the present invention has good insulativity, the features such as didirtresistance, static resistance, self-cleaning property, safety and environmental protection, heavy metal free and poisonous organic solvent, VOC value is low, easy construction, is harmful to human health, and meets green environmental friendly coatings.
specific embodiments
Below by specific examples, the present invention is described in detail.
The antifouling self-cleaning coating of a kind of insulation, is made up of the raw material of following weight part (kilogram): Emulsion acrylic resin 36, elastic emulsion 14, ptfe emulsion 24, lignocellulose 2, sodium hydroxyethyl cellulose 1, dimethyl silicone oil 0.3, silicon carbide 2, polyvinyl isobutyl ether 0.7, Tri(propylene glycol)butyl ether,mixture of isomers 3, flow agent BYK-560.4, Aceonon 300 MO 0.4,2,2'-Azobis(2,4-dimethylvaleronitrile) 0.3, nanometer antimony-doped stannic oxide 3, silicon phosphate 2, micron flatting silica 2, automatically cleaning slurry 8, deionized water 17;
Described automatically cleaning slurry is made up of the raw material of following weight part (kilogram): polyisobutene 3, tetrabutyl titanate 0.8, zinc oxide 7, dispersion agent 50403, titanium dioxide 26, zirconium white 14, ethanol 40, Diisopropyl azodicarboxylate 1, sodium laurylsulfonate 1.2, antimony-doped stannic oxide 6, sodium acetate 2, Vltra tears 2, polyaniline 2, bipyridyl ruthenium 1, preparation method is by zinc oxide, titanium dioxide, zirconium white, antimony-doped stannic oxide ball milling becomes nano-powder, be added to polyaniline, in the ethanolic soln of bipyridyl ruthenium, mix and blend 2-3 hour under baking oven 60-80 ° C dry 1-2 hour for subsequent use, again by Vltra tears, sodium laurylsulfonate, sodium acetate, dispersion agent 5040 and remaining ethanol are mixed and heated to 40-60 ° of C, add the nano-powder ultrasonic disperse 0.5-1 hour of above-mentioned preparation, meanwhile add all the other surplus materials mixing and stirring, the weight that drying is concentrated into titanium dioxide accounts for the 10-30% of slurry weight.
A kind of high weatherability self-cleaning waterproof paint of the present invention, be made up of following concrete steps:
(1) deionized water, Aceonon 300 MO, lignocellulose are mixed and heated to 60-90 ° of C and form emulsion, add sodium hydroxyethyl cellulose again, silicon carbide, nanometer antimony-doped stannic oxide, silicon phosphate, micron flatting silica, automatically cleaning slurry ultrasonic disperse reduce temperature at 50-60 ° of C after 20-30 minute, add 2,2'-Azobis(2,4-dimethylvaleronitrile) and continue to stir 5-10 minute;
(2) Emulsion acrylic resin, elastic emulsion, ptfe emulsion, polyvinyl isobutyl ether, Tri(propylene glycol)butyl ether,mixture of isomers are added in Scattered Kettle and mix, be heated to 40-60 ° of C, under the rotating speed of 200-400 rev/min, stir 30-50 minute;
(3) mixed by all the other surplus materialss, the material added in step (1) and step (2) stirs with the rotating speed of 200-300 rev/min, filters and packages.
Coating ageing resistance experiment of the present invention: 3000 hours unchanged, not efflorescence, non-foaming, do not come off, salt fog resistance is tested: 1000 hours unchanged, resistance to boiling water experiment (200H): unchanged, alkaline-resisting experiment (sodium hydroxide of 10%, 130H): unchanged, contamination resistance experiment (5 circulations) :≤30%, coating temperature-change resistance is tested: 5 circulations are without exception, hardness: 3H, and film is to contact angle >=135 of water ° C.
Claims (2)
1. the antifouling self-cleaning coating of insulation, it is characterized in that, be made up of the raw material of following weight part: Emulsion acrylic resin 30-36, elastic emulsion 10-15, ptfe emulsion 20-26, lignocellulose 1-2, sodium hydroxyethyl cellulose 1-2, dimethyl silicone oil 0.2-0.4, silicon carbide 2-3, polyvinyl isobutyl ether 0.5-0.8, Tri(propylene glycol)butyl ether,mixture of isomers 2-3, flow agent BYK-560.3-0.5, Aceonon 300 MO 0.3-0.5, 2,2'-Azobis(2,4-dimethylvaleronitrile) 0.2-0.4, nanometer antimony-doped stannic oxide 2-3, silicon phosphate 2-3, micron flatting silica 1-2, automatically cleaning slurry 6-9, deionized water 14-20,
Described automatically cleaning slurry is made up of the raw material of following weight part: polyisobutene 2-3, tetrabutyl titanate 0.5-1.0, zinc oxide 6-10, dispersion agent 50403-4, titanium dioxide 20-30, zirconium white 10-15, ethanol 30-50, Diisopropyl azodicarboxylate 1-2, sodium laurylsulfonate 1-2, antimony-doped stannic oxide 5-7, sodium acetate 1-2, Vltra tears 2-4, polyaniline 1-2, bipyridyl ruthenium 1-2, preparation method is by zinc oxide, titanium dioxide, zirconium white, antimony-doped stannic oxide ball milling becomes nano-powder, be added to polyaniline, in the ethanolic soln of bipyridyl ruthenium, mix and blend 2-3 hour under baking oven 60-80 ° C dry 1-2 hour for subsequent use, again by Vltra tears, sodium laurylsulfonate, sodium acetate, dispersion agent 5040 and remaining ethanol are mixed and heated to 40-60 ° of C, add the nano-powder ultrasonic disperse 0.5-1 hour of above-mentioned preparation, meanwhile add all the other surplus materials mixing and stirring, the weight that drying is concentrated into titanium dioxide accounts for the 10-30% of slurry weight.
2. a kind of high weatherability self-cleaning waterproof paint according to claim 1, is characterized in that, be made up of following concrete steps:
(1) deionized water, Aceonon 300 MO, lignocellulose are mixed and heated to 60-90 ° of C and form emulsion, add sodium hydroxyethyl cellulose again, silicon carbide, nanometer antimony-doped stannic oxide, silicon phosphate, micron flatting silica, automatically cleaning slurry ultrasonic disperse reduce temperature at 50-60 ° of C after 20-30 minute, add 2,2'-Azobis(2,4-dimethylvaleronitrile) and continue to stir 5-10 minute;
(2) Emulsion acrylic resin, elastic emulsion, ptfe emulsion, polyvinyl isobutyl ether, Tri(propylene glycol)butyl ether,mixture of isomers are added in Scattered Kettle and mix, be heated to 40-60 ° of C, under the rotating speed of 200-400 rev/min, stir 30-50 minute;
(3) mixed by all the other surplus materialss, the material added in step (1) and step (2) stirs with the rotating speed of 200-300 rev/min, filters and packages.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410590256.2A CN104403449A (en) | 2014-10-29 | 2014-10-29 | Insulation anti-fouling self-cleaning paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410590256.2A CN104403449A (en) | 2014-10-29 | 2014-10-29 | Insulation anti-fouling self-cleaning paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104403449A true CN104403449A (en) | 2015-03-11 |
Family
ID=52641123
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410590256.2A Pending CN104403449A (en) | 2014-10-29 | 2014-10-29 | Insulation anti-fouling self-cleaning paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104403449A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107285665A (en) * | 2015-09-27 | 2017-10-24 | 朱海燕 | A kind of preparation method and applications of self-cleaning ceramic coating |
| CN107880317A (en) * | 2017-11-13 | 2018-04-06 | 郑州诚合信息技术有限公司 | A kind of anti-fog thin film and preparation method thereof |
| CN108840720A (en) * | 2018-08-01 | 2018-11-20 | 广东金意陶陶瓷集团有限公司 | Self-cleaning ceramic brick and preparation method thereof |
| CN109054517A (en) * | 2018-08-01 | 2018-12-21 | 广东金意陶陶瓷集团有限公司 | Automatic cleaning coating slurry, automatic cleaning coating and self-cleaning ceramic brick and preparation method thereof for ceramic surface |
| CN113429842A (en) * | 2021-07-14 | 2021-09-24 | 东莞市景润装饰有限公司 | Interior wall coating for interior decoration and preparation method thereof |
-
2014
- 2014-10-29 CN CN201410590256.2A patent/CN104403449A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107285665A (en) * | 2015-09-27 | 2017-10-24 | 朱海燕 | A kind of preparation method and applications of self-cleaning ceramic coating |
| CN107880317A (en) * | 2017-11-13 | 2018-04-06 | 郑州诚合信息技术有限公司 | A kind of anti-fog thin film and preparation method thereof |
| CN108840720A (en) * | 2018-08-01 | 2018-11-20 | 广东金意陶陶瓷集团有限公司 | Self-cleaning ceramic brick and preparation method thereof |
| CN109054517A (en) * | 2018-08-01 | 2018-12-21 | 广东金意陶陶瓷集团有限公司 | Automatic cleaning coating slurry, automatic cleaning coating and self-cleaning ceramic brick and preparation method thereof for ceramic surface |
| CN113429842A (en) * | 2021-07-14 | 2021-09-24 | 东莞市景润装饰有限公司 | Interior wall coating for interior decoration and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104403449A (en) | Insulation anti-fouling self-cleaning paint and preparation method thereof | |
| AU2016204613C1 (en) | An inorganic coating composition which can be cured at low temperature and a preparation method thereof | |
| CN104530851B (en) | A kind of multifunction surface inorganic agent and its application method | |
| CN101955697B (en) | Ceramic non-stick coating with bacteriostasis action and coating method thereof | |
| CN101440243B (en) | Titania fluorocarbon nano-coating and preparation thereof | |
| CN103146289B (en) | A kind of automatically cleaning anti-corrosion and super-weatherability powder coating and its preparation method and application | |
| JP5784481B2 (en) | Coating composition and use thereof | |
| CN104497765A (en) | Inner wall latex paint capable of removing formaldehyde and preparation method of inner wall latex paint | |
| CN107118648A (en) | A kind of new type environment friendly coating and preparation method thereof | |
| CN104761935A (en) | Antimicrobial non-viscous aqueous inorganic nano coating priming paint and preparation method thereof | |
| CN104449205A (en) | Antibacterial and scrubbing-resistant waterborne coating for glass door and preparation method of waterborne coating | |
| CN104277638A (en) | Anti-oil-pollution anti-bacterial self-cleaning type water-based paint and preparation method thereof | |
| CN104277624A (en) | Mildew-proof bactericidal self-cleaning waterproof coating and preparation method thereof | |
| CN102229771A (en) | Diatomaceous earth active paint and preparation method thereof | |
| CN104449206A (en) | Thermal insulating sterilization type coating for glass doors and preparation method of thermal insulating sterilization type coating | |
| CN103740278A (en) | Photocatalysis self-cleaning acrylic acid exterior wall coating | |
| CN103666246A (en) | Photocatalytic super-hydrophilic transparent self-cleaning paint | |
| CN104277696A (en) | High-weather-resistance self-cleaning waterproof coating and preparation method thereof | |
| CN104277637A (en) | Self-cleaning flame-retardant exterior wall coating and preparation method thereof | |
| CN104277670A (en) | Heat-insulating self-cleaning architectural coating and preparation method thereof | |
| CN103865336A (en) | Photocatalyst paint doped with zinc oxide and titanium dioxide | |
| CN104277610A (en) | Self-cleaning waterproof paint with high weather resistance and preparation method of self-cleaning waterproof paint | |
| CN109233504A (en) | A kind of surface super hydrophilic type exterior wall anti-pollution paint and preparation method thereof | |
| CN105754425A (en) | Formaldehyde-adsorbing waterborne environment-friendly coating | |
| CN110452606A (en) | A kind of mould proof, resistant, antibacterial powder paint and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150311 |
|
| RJ01 | Rejection of invention patent application after publication |