CN104388736A - Zirconium oxide dispersion strengthened silver-base alloy and preparation method thereof - Google Patents
Zirconium oxide dispersion strengthened silver-base alloy and preparation method thereof Download PDFInfo
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- CN104388736A CN104388736A CN201410582855.XA CN201410582855A CN104388736A CN 104388736 A CN104388736 A CN 104388736A CN 201410582855 A CN201410582855 A CN 201410582855A CN 104388736 A CN104388736 A CN 104388736A
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Abstract
The invention provides a zirconium oxide dispersion strengthened silver-base alloy and a preparation method thereof. The alloy comprises a silver base material and a dispersion strengthening phase dispersed in the silver base material, wherein the dispersion strengthening phase is composed of zirconium oxide, CuO and Cu2O; elements apart from oxygen in the dispersion strengthening phase account for 0.12-0.6wt% of the total weight. Compared with the prior art, the zirconium oxide dispersion strengthened silver-base alloy has the advantages that zirconium and copper are added as alloy elements, and zirconium oxide, CuO and Cu2O are distributed in the silver base material as the dispersion strengthening phase to improve the electrical loss resistance and the specific conductance of the alloy. Experimental results indicate that the zirconium oxide dispersion strengthened silver-base alloy has excellent electrical conductivity and thermal conductivity, and relatively high specific conductance and excellent electrical loss resistance, and is suitable for electric contact materials in the fields of electric power, automation, communications, precision electronic instruments and the like.
Description
Technical field
The present invention relates to technical field of alloy, particularly relate to a kind of Zirconium oxide dispersion strengthening silver-base alloy and preparation method thereof.
Background technology
Electrical-contact element bears the work of the connection of electrical equipment, disjunction, water conservancy diversion, isolation, and its performance quality directly affects the reliability of electrical equipment, stability, accuracy and work-ing life, and ensures that the key of electrical-contact element excellent property is the preparation of its material.Therefore, the research and apply of contact material has been become to the important topic in the fields such as electric power, automatization, communication, precision electronic device.
In contact material, siluer metal oxide material, owing to having good resistance to electrical wear, resistance fusion welding and electroconductibility, is widely used in the low-voltage apparatus of various commutator for light-heavy load, household electrical appliance, car electrics, aerospace electrical equipment.But as conventional contacts material, there is following shortcoming in Agcdo (AgCdO): 1, the requirement of environment protection, silver cadmium oxide material inevitably produces cadmium poison in manufacture and use procedure, day by day received the concern of people, some western developed countries have been forbidden using this material on household electrical appliance and car electrics at present; 2, the requirement of electrical equipment use properties, although the title in AgCdO material with the omnipotent contact of large, medium load electrical equipment, exposes at aspect of performances such as anti-melting welding, resistance to arc losses that some is not enough.Therefore, in exploration with nontoxic metal oxide, have important practical significance.
The present inventor considers, provides a kind of Zirconium oxide dispersion strengthening silver-base alloy and preparation method thereof, and it has higher specific conductivity and good resistance to electricity damages performance.
Summary of the invention
The technical problem that the present invention solves is to provide a kind of Zirconium oxide dispersion strengthening silver-base alloy and preparation method thereof, has higher specific conductivity and good resistance to electricity damage performance.
In view of this, the invention provides a kind of Zirconium oxide dispersion strengthening silver-base alloy, comprise money base material and be dispersed in the dispersion-strengthened phase in money base material, described dispersion-strengthened is by zirconium white, CuO and Cu
2o forms, and the element in described dispersion-strengthened mutually outside deoxygenation accounts for 0.12 ~ 0.6 % by weight of gross weight.
Preferably, zr element accounts for 0.115 ~ 0.5 % by weight of gross weight.
Preferably, Cu element accounts for 0.005 ~ 0.1 % by weight of gross weight.
Preferably, the element in described dispersion-strengthened mutually outside deoxygenation accounts for 0.15 ~ 0.5 % by weight of gross weight.
Preferably, described dispersion-strengthened has at least 88 % by weight mutually with nano-scale particle state Dispersed precipitate in money base material.
Preferably, described dispersion-strengthened mutually 90 % by weight ~ 95 % by weight with nano-scale particle state Dispersed precipitate in money base material.
Accordingly, the present invention also provides the preparation method of the Zirconium oxide dispersion strengthening silver-base alloy described in a kind of technique scheme, comprises the following steps:
By zirconium, copper and silver mixing, in vacuum induction furnace, carry out vacuum induction melting, obtain money base multicomponent alloy;
Adopt powder metallurgic method that described money base multicomponent alloy is made the multicomponent alloy powder that median size is 20 ~ 40 μm;
Internal oxidition-sintering processes is carried out to described multicomponent alloy powder, obtains Zirconium oxide dispersion strengthening silver-base alloy.
Preferably, also comprise:
Described Zirconium oxide dispersion strengthening silver-base alloy is carried out hot-forming and forge hot process.
Preferably, the pressure of described vacuum induction melting is 5 × 10
-6pa ~ 8 × 10
-5pa, temperature 700 DEG C ~ 800 DEG C.
Preferably, the temperature of described internal oxidition-sintering processes is 500 DEG C ~ 700 DEG C, and the time is 10 ~ 15h.
The invention provides a kind of Zirconium oxide dispersion strengthening silver-base alloy and preparation method thereof, comprise money base material and be dispersed in the dispersion-strengthened phase in money base material, described dispersion-strengthened is by zirconium white, CuO and Cu
2o forms, and the element in described dispersion-strengthened mutually outside deoxygenation accounts for 0.12 ~ 0.6 % by weight of gross weight.Compared with prior art, the alloying element that the present invention is interpolation with zirconium, copper, zirconium white, CuO, Cu
2o in money base material as dispersion-strengthened Entropy density deviation, has and improves the effect that the resistance to electricity of alloy damages performance and specific conductivity.Experimental result shows, this Zirconium oxide dispersion strengthening silver-base alloy has good electroconductibility, thermal conductivity, has higher specific conductivity and good resistance to electricity damage performance, is applicable to the contact material in the fields such as electric power, automatization, communication, precise electronic instrument.
Embodiment
In order to understand the present invention further, below in conjunction with embodiment, the preferred embodiment of the invention is described, but should be appreciated that these describe just for further illustrating the features and advantages of the present invention, instead of limiting to the claimed invention.
The embodiment of the invention discloses a kind of Zirconium oxide dispersion strengthening silver-base alloy, comprise money base material and be dispersed in the dispersion-strengthened phase in money base material, described dispersion-strengthened is by zirconium white, CuO and Cu
2o forms, and the element in described dispersion-strengthened mutually outside deoxygenation accounts for 0.12 ~ 0.6 % by weight of gross weight.
The alloying element that the present invention is interpolation with zirconium, copper, zirconium white, CuO, Cu
2o in money base material as dispersion-strengthened Entropy density deviation, has and improves the effect that the resistance to electricity of alloy damages performance and specific conductivity.Experimental result shows, this Zirconium oxide dispersion strengthening silver-base alloy has good electroconductibility, thermal conductivity, has higher specific conductivity and good resistance to electricity damage performance, is applicable to the contact material in the fields such as electric power, automatization, communication, precise electronic instrument.
Preferably, zr element accounts for 0.115 ~ 0.5 % by weight of gross weight, is more preferably 0.118 ~ 0.4 % by weight; Cu element accounts for 0.005 ~ 0.1 % by weight of gross weight, is more preferably 0.01 ~ 0.2 % by weight.
Element in described dispersion-strengthened mutually outside deoxygenation preferably accounts for 0.15 ~ 0.5 % by weight of gross weight, is more preferably 0.2 ~ 0.4 % by weight.
Described dispersion-strengthened preferably has at least 88 % by weight mutually with nano-scale particle state Dispersed precipitate in money base material, preferred, described dispersion-strengthened mutually 90 % by weight ~ 95 % by weight with nano-scale particle state Dispersed precipitate in money base material.
Accordingly, the present invention also provides a kind of preparation method of above-mentioned Zirconium oxide dispersion strengthening silver-base alloy, comprises the following steps:
By zirconium, copper and silver mixing, in vacuum induction furnace, carry out vacuum induction melting, obtain money base multicomponent alloy;
Adopt powder metallurgic method that described money base multicomponent alloy is made the multicomponent alloy powder that median size is 20 ~ 40 μm;
Internal oxidition-sintering processes is carried out to described multicomponent alloy powder, obtains Zirconium oxide dispersion strengthening silver-base alloy.
The present invention adopts the method for vacuum induction melting, first money base multicomponent alloy is prepared, then adopt powder metallurgy process that described money base multicomponent alloy is made the multicomponent alloy powder that median size is 20 ~ 40 μm, then internal oxidition-sintering processes is carried out to described multicomponent alloy powder, zirconium, copper in-situ oxidation are become nano level oxide compound particle, thus obtain Zirconium oxide dispersion strengthening silver-base alloy.
Wherein, zirconium, copper that the present invention preferably adopts purity to be greater than 99.8% are raw material, obtain money base multicomponent alloy after vacuum induction melting., control the pressure and temperature of vacuum induction melting, the pressure of described vacuum induction melting is preferably 5 × 10 meanwhile
-6pa ~ 8 × 10
-5pa, is more preferably 9 × 10
-6pa ~ 6 × 10
-5pa; Temperature is preferably 700 DEG C ~ 800 DEG C, is more preferably 720 DEG C ~ 760 DEG C.
After vacuum induction melting, the solution-cast preferably melting obtained forms corresponding money base multicomponent alloy ingot casting in water cooled copper mould.The present invention preferably adopts powder metallurgic method that described money base multicomponent alloy is made the multicomponent alloy powder that median size is 25 ~ 35 μm, and the particle diameter of described multicomponent alloy powder is more preferably 28 ~ 32 μm.
Particle diameter due to multicomponent alloy powder is 20 ~ 40 μm, and therefore, the temperature of internal oxidition-sintering processes is preferably 500 DEG C ~ 700 DEG C, is more preferably 550 DEG C ~ 650 DEG C; Time is preferably 10 ~ 15h, is more preferably 11 ~ 13h.Oxidizing atmosphere is air atmosphere.The object of this internal oxidition-sintering processes be make the zirconium in multicomponent alloy powder, copper in position capture by Sauerstoffatom generate nano level oxide compound particle, alloy plays the effect of strengthening, carry heavy alloyed electroconductibility, thermal conductivity, specific conductivity and resistance to electricity damage performance.Make between powder, sintering reaction occur and form agglomerates of sintered pellets simultaneously, be beneficial to follow-up compression moulding procedures.
After obtaining Zirconium oxide dispersion strengthening silver-base alloy, also preferably include: described Zirconium oxide dispersion strengthening silver-base alloy is carried out hot-forming and forge hot process.Described hot-forming time forming pressure remain between 400 ~ 500MPa, temperature is 500 ~ 700 DEG C.Adopt hot pressing compared with coldmoulding: coming off of in knockout course workpiece angle edge metal can be reduced, improve utilization ratio and the workpiece surface quality of noble metal powder; Reduce and reduce workpiece crack, improving the quality of workpiece in subsequent thermal forging process.In forge hot process, the Heating temperature of forging is preferably 600 ~ 1000 DEG C, is more preferably 700 ~ 900 DEG C.
Therefore, Zirconium oxide dispersion strengthening silver-base alloy prepared by the present invention has good electroconductibility, thermal conductivity, there is higher specific conductivity and good resistance to electricity damage performance, also there is long lifetime and excellent pressworkability simultaneously, be applicable to the contact material in the fields such as electric power, automatization, communication, precise electronic instrument.
In order to understand the present invention further, be described in detail to technical scheme provided by the invention below in conjunction with embodiment, protection scope of the present invention is not limited by the following examples.
The raw material that the embodiment of the present invention adopts and chemical reagent are commercial.
Embodiment 1
Take zirconium, copper and silver, carry out vacuum induction melting after mixing in vacuum induction furnace, obtain money base multicomponent alloy, the pressure of described vacuum induction melting is 5 × 10
-5pa, temperature 750 DEG C;
Adopt powder metallurgic method that described money base multicomponent alloy is made the multicomponent alloy powder that median size is 30 μm;
Internal oxidition-sintering processes is carried out to described multicomponent alloy powder, the temperature of described internal oxidition-sintering processes is 600 DEG C, time is 12h, then carry out hot-forming at being 600 DEG C in 450MPa, temperature, then at 800 DEG C, forge hot process is carried out, obtain Zirconium oxide dispersion strengthening silver-base alloy, 0.122 % by weight, the Cu element that zr element accounts for gross weight accounts for 0.02 % by weight of gross weight.
Embodiment 2
Take zirconium, copper and silver, carry out vacuum induction melting after mixing in vacuum induction furnace, obtain money base multicomponent alloy, the pressure of described vacuum induction melting is 3 × 10
-5pa, temperature 760 DEG C;
Adopt powder metallurgic method that described money base multicomponent alloy is made the multicomponent alloy powder that median size is 30 μm;
Internal oxidition-sintering processes is carried out to described multicomponent alloy powder, the temperature of described internal oxidition-sintering processes is 600 DEG C, time is 12h, then carry out hot-forming at being 600 DEG C in 450MPa, temperature, then at 800 DEG C, forge hot process is carried out, obtain Zirconium oxide dispersion strengthening silver-base alloy, 0.2 % by weight, the Cu element that zr element accounts for gross weight accounts for 0.05 % by weight of gross weight.
Embodiment 3
Take zirconium, copper and silver, carry out vacuum induction melting after mixing in vacuum induction furnace, obtain money base multicomponent alloy, the pressure of described vacuum induction melting is 4 × 10
-5pa, temperature 730 DEG C;
Adopt powder metallurgic method that described money base multicomponent alloy is made the multicomponent alloy powder that median size is 30 μm;
Internal oxidition-sintering processes is carried out to described multicomponent alloy powder, the temperature of described internal oxidition-sintering processes is 620 DEG C, time is 12h, then carry out hot-forming at being 600 DEG C in 450MPa, temperature, then at 800 DEG C, forge hot process is carried out, obtain Zirconium oxide dispersion strengthening silver-base alloy, 0.3 % by weight, the Cu element that zr element accounts for gross weight accounts for 0.08 % by weight of gross weight.
Carry out Performance Detection to Zirconium oxide dispersion strengthening silver-base alloy prepared by the present embodiment 1 ~ 3 respectively, result is as table 1.
Table 1 Zirconium oxide dispersion strengthening silver-base alloy performance table
The explanation of above embodiment just understands method of the present invention and core concept thereof for helping.It should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention, can also carry out some improvement and modification to the present invention, these improve and modify and also fall in the protection domain of the claims in the present invention.
To the above-mentioned explanation of the disclosed embodiments, professional and technical personnel in the field are realized or uses the present invention.To be apparent for those skilled in the art to the multiple amendment of these embodiments, General Principle as defined herein can without departing from the spirit or scope of the present invention, realize in other embodiments.Therefore, the present invention can not be restricted to these embodiments shown in this article, but will meet the widest scope consistent with principle disclosed herein and features of novelty.
Claims (10)
1. a Zirconium oxide dispersion strengthening silver-base alloy, is characterized in that, comprise money base material and be dispersed in the dispersion-strengthened phase in money base material, described dispersion-strengthened is by zirconium white, CuO and Cu
2o forms, and the element in described dispersion-strengthened mutually outside deoxygenation accounts for 0.12 ~ 0.6 % by weight of gross weight.
2. Zirconium oxide dispersion strengthening silver-base alloy according to claim 1, is characterized in that, zr element accounts for 0.115 ~ 0.5 % by weight of gross weight.
3. Zirconium oxide dispersion strengthening silver-base alloy according to claim 1, is characterized in that, Cu element accounts for 0.005 ~ 0.1 % by weight of gross weight.
4. Zirconium oxide dispersion strengthening silver-base alloy according to claim 1, is characterized in that, the element in described dispersion-strengthened mutually outside deoxygenation accounts for 0.15 ~ 0.5 % by weight of gross weight.
5. Zirconium oxide dispersion strengthening silver-base alloy according to claim 1, is characterized in that, described dispersion-strengthened has at least 88 % by weight mutually with nano-scale particle state Dispersed precipitate in money base material.
6. Zirconium oxide dispersion strengthening silver-base alloy according to claim 5, is characterized in that, described dispersion-strengthened mutually 90 % by weight ~ 95 % by weight with nano-scale particle state Dispersed precipitate in money base material.
7. a preparation method for Zirconium oxide dispersion strengthening silver-base alloy according to claim 1, is characterized in that, comprise the following steps:
By zirconium, copper and silver mixing, in vacuum induction furnace, carry out vacuum induction melting, obtain money base multicomponent alloy;
Adopt powder metallurgic method that described money base multicomponent alloy is made the multicomponent alloy powder that median size is 20 ~ 40 μm;
Internal oxidition-sintering processes is carried out to described multicomponent alloy powder, obtains Zirconium oxide dispersion strengthening silver-base alloy.
8. preparation method according to claim 7, is characterized in that, also comprises:
Described Zirconium oxide dispersion strengthening silver-base alloy is carried out hot-forming and forge hot process.
9. preparation method according to claim 7, is characterized in that, the pressure of described vacuum induction melting is 5 × 10
-6pa ~ 8 × 10
-5pa, temperature 700 DEG C ~ 800 DEG C.
10. preparation method according to claim 7, is characterized in that, the temperature of described internal oxidition-sintering processes is 500 DEG C ~ 700 DEG C, and the time is 10 ~ 15h.
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|---|---|---|---|---|
| CN108149044A (en) * | 2017-12-27 | 2018-06-12 | 洛阳神佳窑业有限公司 | A kind of preparation method of Zirconium oxide dispersion strengthening copper alloy |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1477219A (en) * | 2002-08-21 | 2004-02-25 | 中国科学院金属研究所 | Preparation method of siluer metal oxide electric contact material |
| CN101649401A (en) * | 2009-07-20 | 2010-02-17 | 温州宏丰电工合金有限公司 | Ag-Ni-oxide electrical contact material and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1477219A (en) * | 2002-08-21 | 2004-02-25 | 中国科学院金属研究所 | Preparation method of siluer metal oxide electric contact material |
| CN101649401A (en) * | 2009-07-20 | 2010-02-17 | 温州宏丰电工合金有限公司 | Ag-Ni-oxide electrical contact material and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108149044A (en) * | 2017-12-27 | 2018-06-12 | 洛阳神佳窑业有限公司 | A kind of preparation method of Zirconium oxide dispersion strengthening copper alloy |
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Application publication date: 20150304 |