CN104357838A - Method for refining silicide phase in multi-principal-element alloy coating - Google Patents
Method for refining silicide phase in multi-principal-element alloy coating Download PDFInfo
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Abstract
The invention discloses a method for refining a silicide phase in multi-principal-element alloy coating. The method comprises the following steps: 1) respectively weighing Cr, Ti, Si, V, B and Al powder; 2) mixing powder weighed in the step 1); 3) preparing a 4% polyvinyl alcohol solution; 4) grinding and cleaning the surface of an aluminum alloy plate; 5) mixing the powder mixed in the step 2) with a solution prepared in the step 3) to form paste, and pre-coating the aluminum alloy plate treated in the step 4) with the paste; and 6) irradiating the pre-prepared coating on the aluminum alloy plate. By adopting the method disclosed by the invention, the aluminum alloy surface coating has high hardness, and good wear resistance and oxidization resistance, and is strong in metallurgical bonding force and cracking is prevented.
Description
Technical field
The present invention relates to material surface process and intensifying technology field, particularly relate to the method for silicide phase in a kind of refinement multi-principal elements alloy coating; Formed the alloying layer of high rigidity, high-wearing feature and high corrosion resistance on the surface of aluminium alloy by the method.
Background technology
Many excellent properties such as Al and Alalloy is one of most widely used material in non-ferrous metal, and aluminium alloy has little, the easy processing of density, thermal expansivity is low, thermal conductivity is high, specific rigidity and specific tenacity are high.Widespread use is achieved in daily production and the field such as life and aviation, automobile, high ferro, engine piston, opticinstrument, guided missile pattern structure.But further develop along with industrial, have higher requirement to the surface property of aluminium alloy, wear resistance, erosion resistance and oxidation-resistance seem particularly important.
At present, the method preparing wear-resistant coating in aluminum alloy surface normally sprays one deck bond coating in aluminum alloy surface, spray oxide ceramics working lining again, prepare the compound coatings such as Ni/Al-Al2O3, NiCrAl-Al2O3, Ni-Al2O3, but the anchoring strength of coating that this method prepares is low, and surface easily forms oxide film.As (Authorization Notice No.: CN 100549233C) such as Li Fuquan strengthens aluminum or aluminum alloy surface by electric arc auxiliary laser molten note ceramic particle.Guo Zhi waits in " a kind of method of aluminum alloy surface coating wear-resistant coating " (Authorization Notice No.: CN 100408724C) suddenly by adding excessive aluminium in reaction raw materials, utilize self-propagating reaction liberated heat that the oxide film on the aluminium surface on surface is melted, under the influence of centrifugal force oxide compound is separated.The internal surface that the method is only suitable for tubing component obtains wear-resistant coating, and because of the conductive force of aluminium alloy, is difficult to make intermetallic Fe-Al compound and aluminum substrate good combination.
High-current pulsed electron beam (HCPEB) is the new and effective process for treating surface of one that development in recent years is got up, and is to accelerate the novel high-energy density charged particle line that electronics is energy carrier.High-current pulsed electron beam is easy to draw and control than pulsed ionizing beam, and device is simple and reliable.There is not the energy reflection problem of pulse laser beam in high-current pulsed electron beam, S. E. A. is little by the impact of material composition and configuration of surface when irradiating metallic substance.High-current pulsed electron beam ratio completes in vacuum environment, effectively can suppress the problem such as high temperature oxidation and pollution of material.As " treatment process of ultrahigh-strength aluminum alloy surface alloying " (Authorization Notice No.: CN 102691040A); but the surface reforming layer that E.B surface treatment obtains is too thin, enough protections can not be played for the aluminum alloy part surface being operated in severe friction environment.
Sun Ronglu etc. (Authorization Notice No.: CN 100491593C) have invented a kind of aluminum alloy surface strengthening method of high-energy-density laser remolten surface cladding SiC/Al-Si powder, alloy matrix aluminum obtain surface quality is good, the strengthened coat of high abrasion and high rigidity.But adopt ceramic powder to improve the wear resistance of aluminium alloy, inherently can not solve the problem of bonding interface crackle that high-melting-point ceramic layer brings and cracking.
Summary of the invention
For prior art above shortcomings, the object of the present invention is to provide the method for silicide phase in a kind of refinement multi-principal elements alloy coating, aluminum alloy surface coating is had, and that hardness is high, wear resistance and good in oxidation resistance, metallurgical junction are made a concerted effort is strong, prevent the advantages such as cracking.
In order to solve the problems of the technologies described above, the technical solution used in the present invention is such: a kind of method of silicide phase in refinement multi-principal elements alloy coating, is characterized in that: comprise the steps:
1) take Cr, Ti, Si, V, B and Al powder respectively, wherein, the molar percentage of Cr, Ti, Si, V, B and Al is: Cr:20-30%, Ti:20-30%, Si:20-30%, V:20-30%, B:0-0.2%, and surplus is Al;
2) by 1) in the powder that takes put into ball mill mixing 2-5 hours;
3) configuration concentration is the polyvinyl alcohol solution of 4%, and heating in water bath, its polyvinyl alcohol is dissolved completely;
4) polish off with the oxide film of abrasive paper for metallograph by aluminium alloy plate surface, and clean up with acetone;
5) by 2) powder that mixes is with 3) polyvinyl alcohol solution that configures reconciles into thick, by its precoating through 4) aluminium alloy plate after process forms prefabricated coating, this prefabricated coat-thickness is 0.3-0.6 mm, then dry 2-5 hour;
6) with laser apparatus, irradiation is carried out to the prefabricated coating on aluminium alloy plate, and adopt high-purity argon gas to protect.
Further, in step 6), the defocusing amount of laser focal spot is 3-5mm, and pulse width is 5-10ms, and laser peak power is 6-8kw, frequency 5-13HZ, and sweep velocity is 2-6mm/s.
Further, described laser apparatus adopts is UW-600A type YAG laser.
Further, in step 1), electronic balance FA2004N is adopted to carry out taking of various powder.
Compared with prior art, tool of the present invention has the following advantages:
1. can form on the surface of aluminum alloy base material the Al-Cr-Ti-Si-V-B alloying layer that one deck hardness is high, wear resistance is good, and alloying layer and aluminum alloy base material have good bonding force, resistance of oxidation is stronger.
2. effectively improve aluminum alloy surface intensity, improve aluminum alloy surface wear resistance and solidity to corrosion.
3. adding micro-B can refinement silicide further, can reduce top coat tearing tendency, thus prevent top coat from ftractureing.
Accompanying drawing explanation
Fig. 1 is the schematic diagram of the coating that embodiment 1 obtains.
Fig. 2 is the X ray diffracting spectrum that embodiment 1 obtains coating.
Embodiment
Below in conjunction with drawings and Examples, the invention will be further described.
In refinement multi-principal elements alloy coating, a method for silicide phase, comprises the steps:
1) take Cr, Ti, Si, V, B and Al powder respectively, wherein, the molar percentage of Cr, Ti, Si, V, B and Al is: Cr:20-30%, Ti:20-30%, Si:20-30%, V:20-30%, B:0-0.2%, and surplus is Al; Take in process, adopt electronic balance FA2004N to carry out taking of various powder, tolerance range is high, and it is more accurate to take.
2) by 1) in the powder that takes put into ball mill mixing 2-5 hours.
3) configuration concentration is the polyvinyl alcohol solution of 4%, and heating in water bath, polyvinyl alcohol is dissolved completely.
4) polish off with the oxide film of abrasive paper for metallograph by aluminium alloy plate surface, and clean up with acetone.
5) by 2) powder that mixes is with 3) polyvinyl alcohol solution that configures reconciles into thick, by its precoating through 4) aluminium alloy plate after process forms prefabricated coating, this prefabricated coat-thickness is 0.3-0.6mm, then dry 2-5 hours.
6) with laser apparatus, irradiation is carried out to the prefabricated coating on aluminium alloy plate, and adopt high-purity argon gas to protect; During operation, from side direction blowing argon gas, in case oxidation.Because aluminium alloy is high to YAG laser absorption rate; Therefore, described laser apparatus adopts UW-600A type YAG laser, and concrete technology parameter is: the defocusing amount of laser focal spot is 3-5mm, and pulse width is 5-10ms, and laser peak power is 6-8kw, frequency 5-13HZ, and sweep velocity is 2-6mm/s.
High-entropy alloy is formed by equimolar ratio or nearly equimolar ratio preparation by more than 5 kinds or 5 kinds alloying elements, many pivots high-entropy alloy is by its distinctive high entropy effect, slow diffusional effect, the features such as nanophase strengthening and superelevation lattice distortion, be conducive to keeping the high tenacity of alloy, and the high hardness of material, the multiple excellent properties such as high temperature resistant, wear-resistant, corrosion-resistant can be given.The present invention adopts Cr, Ti, Si, V, B and Al to carry out proportioning, make coated material, when ensureing that it reaches demand, saves material cost better; And heat physical properties difference is less between this coated material and alloy matrix aluminum material, thus can be directly used in laser melting coating and obtain the coating of uniform composition, can be implemented in the painting of low cost metal material surface and be covered with high performance high-entropy alloy coating, adding micro-B can refinement silicide further, top coat tearing tendency can be reduced, thus prevent top coat from ftractureing; This will have a good application prospect.
Specific embodiment is as follows:
Embodiment 1, see Fig. 1, Fig. 2, take Cr, Ti, Si, V, B and Al powder with electronic balance FA2004N, the mol ratio of each powder is: the Cr of 23%, the Ti of 28%, the Si of 21%, the V of 27%, the B of 0.05%, surplus Al, and the powder just weighed up is placed in ball mill and fully mixes, mixing time is 4 hours.Configure the polyvinyl alcohol of 4% again as caking agent, by its heating in water bath about 10 minutes, make it dissolve completely.Aluminium alloy plate abrasive paper for metallograph is polished off the oxide film on surface, and clean up with acetone.Reconcile into thick by the mixed powder caking agent prepared, by its precoating on the aluminium alloy plate cleaned, coating thickness is 0.5mm, dry 3 hours.What adopt is that UW-600A type YAG laser carries out irradiation to the prefabricated coating on aluminium alloy, adopts high-purity argon gas protection.The defocusing amount of laser focal spot is 3mm, and pulse width is 6ms, and laser peak power is 8kw, frequency 8HZ, and sweep velocity is 5mm/s.Coating Linear cut will be obtained cut, do X-ray diffraction, obtain diffracting spectrum as shown in Figure 2.Momentum profiles analysis and the main alloy phase of the known coating of calculation of thermodynamics are M5Si3 type silicide and BCC phase; The average hardness of coating is HV805; Illustrate that the performance on surface improves.
Embodiment 2, takes Cr, Ti, Si, V, B and Al powder with electronic balance FA2004N, and mol ratio is: the Cr of 21%, the Ti of 25%, the Si of 23%, the V of 28%, the B of 0.2%, surplus is Al, and the powder just weighed up is placed in ball mill and fully mixes, and mixing time is 5 hours.Configure the polyvinyl alcohol of 4% again as caking agent, by its heating in water bath about 10 minutes, make it dissolve completely.Aluminium alloy plate abrasive paper for metallograph is polished off the oxide film on surface, and clean up with acetone.Reconcile into thick by the mixed powder caking agent prepared, by its precoating on the aluminium alloy plate cleaned, coating thickness is 0.5mm, dry 3 hours.What adopt is that UW-600A type YAG laser carries out irradiation to the prefabricated coating on aluminium alloy, adopts high-purity argon gas protection.The defocusing amount of laser focal spot is 3mm, and pulse width is 6ms, and laser peak power is 8kw, frequency 8HZ, and sweep velocity is 5mm/s.Momentum profiles analysis and the main alloy phase of the known coating of calculation of thermodynamics are M5Si3 type silicide and BCC phase; The average hardness of coating is HV846; Illustrate that the performance on surface improves.
Finally it should be noted that, above embodiment is only in order to illustrate technical scheme of the present invention but not restriction technologies scheme, those of ordinary skill in the art is to be understood that, those are modified to technical scheme of the present invention or equivalent replacement, and do not depart from aim and the scope of the technical program, all should be encompassed in the middle of right of the present invention.
Claims (4)
1. the method for silicide phase in refinement multi-principal elements alloy coating, is characterized in that: comprise the steps:
1) take Cr, Ti, Si, V, B and Al powder respectively, wherein, the molar percentage of Cr, Ti, Si, V, B and Al is: Cr:20-30%, Ti:20-30%, Si:20-30%, V:20-30%, B:0-0.2%, and surplus is Al;
2) by 1) in the powder that takes put into ball mill mixing 2-5 hours;
3) configuration concentration is the polyvinyl alcohol solution of 4%, and heating in water bath, its polyvinyl alcohol is dissolved completely;
4) polish off with the oxide film of abrasive paper for metallograph by aluminium alloy plate surface, and clean up with acetone;
5) by 2) powder that mixes is with 3) polyvinyl alcohol solution that configures reconciles into thick, by its precoating through 4) aluminium alloy plate after process forms prefabricated coating, this prefabricated coat-thickness is 0.3-0.6 mm, then dry 2-5 hour;
6) with laser apparatus, irradiation is carried out to the prefabricated coating on aluminium alloy plate, and adopt high-purity argon gas to protect.
2. the method for silicide phase in a kind of refinement multi-principal elements alloy coating according to claim 1, it is characterized in that: in step 6), the defocusing amount of laser focal spot is 3-5mm, pulse width is 5-10ms, laser peak power is 6-8kw, frequency 5-13HZ, and sweep velocity is 2-6mm/s.
3. the method for silicide phase in a kind of refinement multi-principal elements alloy coating according to claim 1, is characterized in that: it is UW-600A type YAG laser that described laser apparatus adopts.
4. the method for silicide phase in a kind of refinement multi-principal elements alloy coating according to claim 1, is characterized in that: in step 1), adopts electronic balance FA2004N to carry out taking of various powder.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109913771A (en) * | 2019-04-02 | 2019-06-21 | 中国科学院宁波材料技术与工程研究所 | A kind of VAlTiCrSi high-entropy alloy film and its application under briny environment |
| CN113059158A (en) * | 2021-03-22 | 2021-07-02 | 东北大学 | Process method for preparing high-silicon aluminum silicon alloy coating by electron beam |
| CN113373365A (en) * | 2021-06-09 | 2021-09-10 | 北京理工大学 | Nano silicide reinforced refractory high-entropy alloy and preparation method thereof |
| CN116288191A (en) * | 2023-03-14 | 2023-06-23 | 纳狮新材料有限公司杭州分公司 | High-temperature antioxidant AlTiN-based nano coating and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101532141A (en) * | 2009-04-14 | 2009-09-16 | 山东大学 | Method for in situ producing aluminide reinforced layer on surface of aluminum alloy |
-
2014
- 2014-11-14 CN CN201410644576.1A patent/CN104357838B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101532141A (en) * | 2009-04-14 | 2009-09-16 | 山东大学 | Method for in situ producing aluminide reinforced layer on surface of aluminum alloy |
Non-Patent Citations (5)
| Title |
|---|
| C.LI ET AL.: "Microstructure and properties of AlTiNiMnBx high entropy alloys", 《MATERIALS SCIENCE AND TECHNOLOGY》 * |
| C.P.LEE ET AL.: "Effect of boron on the corrosion properties of Al0.5CoCrCuFeNiBx high entropy alloys in 1N sulfuric acid", 《ECS TRANSACTIONS》 * |
| CHIN-YOU HSU ET AL.: "Wear Resistance and High-Temperature Compression Strength of Fcc CuCoNiCrAl0.5Fe Alloy with Boron Addition", 《METALLURGICAL AND MATERIALS TRANSACTIONS A》 * |
| 旷云峰等: "6061铝合金表面激光合金化Al-Fe-Mn-Zn-Si合金涂层的组织与性能研究", 《激光杂志》 * |
| 黄灿: "钛合金表面激光熔覆TiCrAlSi系多主元合金涂层的研究", 《中国博士学位论文全文数据库 工程科技Ⅰ辑》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109913771A (en) * | 2019-04-02 | 2019-06-21 | 中国科学院宁波材料技术与工程研究所 | A kind of VAlTiCrSi high-entropy alloy film and its application under briny environment |
| CN113059158A (en) * | 2021-03-22 | 2021-07-02 | 东北大学 | Process method for preparing high-silicon aluminum silicon alloy coating by electron beam |
| CN113059158B (en) * | 2021-03-22 | 2022-04-12 | 东北大学 | Process method for preparing high-silicon aluminum silicon alloy coating by electron beam |
| CN113373365A (en) * | 2021-06-09 | 2021-09-10 | 北京理工大学 | Nano silicide reinforced refractory high-entropy alloy and preparation method thereof |
| CN116288191A (en) * | 2023-03-14 | 2023-06-23 | 纳狮新材料有限公司杭州分公司 | High-temperature antioxidant AlTiN-based nano coating and preparation method thereof |
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Effective date of registration: 20221202 Address after: 274000 intersection of Changjiang Road and Fuzhou Road, Heze Development Zone, Shandong Province Patentee after: SHANDONG ZHONGKENENG ARTIFICIAL ENVIRONMENT Co.,Ltd. Address before: No. 69 lijiatuo Chongqing District of Banan City Road 400054 red Patentee before: Chongqing University of Technology |
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