CN104356992B - 一种厌氧胶、制备方法及应用 - Google Patents
一种厌氧胶、制备方法及应用 Download PDFInfo
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- CN104356992B CN104356992B CN201410583096.9A CN201410583096A CN104356992B CN 104356992 B CN104356992 B CN 104356992B CN 201410583096 A CN201410583096 A CN 201410583096A CN 104356992 B CN104356992 B CN 104356992B
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- anaerobic adhesive
- methacrylic acid
- modified
- epoxy resin
- preparation
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- 239000000853 adhesive Substances 0.000 title claims abstract description 56
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 56
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical class CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 40
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000004814 polyurethane Substances 0.000 claims abstract description 26
- 239000003822 epoxy resin Substances 0.000 claims abstract description 25
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 25
- 229920002635 polyurethane Polymers 0.000 claims abstract description 25
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims abstract description 24
- 238000010438 heat treatment Methods 0.000 claims abstract description 17
- 239000003999 initiator Substances 0.000 claims abstract description 17
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- 238000010792 warming Methods 0.000 claims abstract description 8
- 239000007787 solid Substances 0.000 claims description 12
- 239000012467 final product Substances 0.000 claims description 11
- 239000000049 pigment Substances 0.000 claims description 9
- 239000004593 Epoxy Substances 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- 239000002562 thickening agent Substances 0.000 claims description 7
- 239000013008 thixotropic agent Substances 0.000 claims description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical group C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 claims description 6
- 229940081974 saccharin Drugs 0.000 claims description 6
- 235000019204 saccharin Nutrition 0.000 claims description 6
- 239000000901 saccharin and its Na,K and Ca salt Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 4
- YQHLDYVWEZKEOX-UHFFFAOYSA-N cumene hydroperoxide Chemical compound OOC(C)(C)C1=CC=CC=C1 YQHLDYVWEZKEOX-UHFFFAOYSA-N 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- 239000004014 plasticizer Substances 0.000 claims description 4
- 229920000570 polyether Polymers 0.000 claims description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 238000013019 agitation Methods 0.000 claims description 3
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 3
- 229920005862 polyol Polymers 0.000 claims description 3
- 150000003077 polyols Chemical class 0.000 claims description 3
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 claims description 2
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 2
- 239000012948 isocyanate Substances 0.000 claims description 2
- -1 acrylic ester Chemical class 0.000 description 7
- 239000000178 monomer Substances 0.000 description 7
- 229940002712 malachite green oxalate Drugs 0.000 description 4
- GTCAXTIRRLKXRU-UHFFFAOYSA-N methyl carbamate Chemical compound COC(N)=O GTCAXTIRRLKXRU-UHFFFAOYSA-N 0.000 description 4
- 238000007789 sealing Methods 0.000 description 4
- 239000000843 powder Substances 0.000 description 3
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- 229910002012 Aerosil® Inorganic materials 0.000 description 2
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N Methyl ethyl ketone Natural products CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- MRIZMKJLUDDMHF-UHFFFAOYSA-N cumene;hydrogen peroxide Chemical class OO.CC(C)C1=CC=CC=C1 MRIZMKJLUDDMHF-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- QFPFILNVZSVKBW-UHFFFAOYSA-N OCCCC=C(C(=O)O)C.C(C=C)(=O)O Chemical compound OCCCC=C(C(=O)O)C.C(C=C)(=O)O QFPFILNVZSVKBW-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 244000144987 brood Species 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000003642 hunger Nutrition 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000012945 sealing adhesive Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000037351 starvation Effects 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
Description
项目 | 牵出扭矩/N.m | 破坏扭矩/N.m | 初固时间/min | 储存时间/Y |
实施例5 | 15 | 13 | 1 | 0.5 |
实施例6 | 19 | 13 | 5 | 1 |
实施例7 | 18 | 16 | 7 | 1 |
实施例8 | 22 | 15 | 4 | 1 |
Claims (11)
Priority Applications (1)
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CN201410583096.9A CN104356992B (zh) | 2014-10-27 | 2014-10-27 | 一种厌氧胶、制备方法及应用 |
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CN201410583096.9A CN104356992B (zh) | 2014-10-27 | 2014-10-27 | 一种厌氧胶、制备方法及应用 |
Publications (2)
Publication Number | Publication Date |
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CN104356992A CN104356992A (zh) | 2015-02-18 |
CN104356992B true CN104356992B (zh) | 2016-06-22 |
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CN201410583096.9A Active CN104356992B (zh) | 2014-10-27 | 2014-10-27 | 一种厌氧胶、制备方法及应用 |
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Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104934550A (zh) * | 2015-05-07 | 2015-09-23 | 京东方科技集团股份有限公司 | Oled器件的封装结构、封装方法以及电子设备 |
CN107983603A (zh) * | 2018-01-30 | 2018-05-04 | 成都正恒动力股份有限公司 | 发动机缸体微孔密封工艺 |
CN109536110A (zh) * | 2018-12-04 | 2019-03-29 | 合肥江淮铸造有限责任公司 | 一种发动机铸缸体专用修复胶 |
CN112608702A (zh) * | 2020-12-03 | 2021-04-06 | 迪马新材料科技(苏州)有限公司 | 双组份丙烯酸改性环氧胶黏剂及其制备工艺 |
CN112876997A (zh) * | 2021-01-19 | 2021-06-01 | 合肥美凯电子有限公司 | 一种ab胶的生产工艺 |
CN114032037B (zh) * | 2021-11-26 | 2023-08-29 | 迪马新材料科技(苏州)有限公司 | 厌氧密封胶及其制备方法 |
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JPH10237420A (ja) * | 1997-02-20 | 1998-09-08 | Three Bond Co Ltd | 嫌気硬化性シール剤組成物 |
CN103509509A (zh) * | 2013-01-16 | 2014-01-15 | 上海都为电子有限公司 | 硅块切割用室温快速固化单组份厌氧胶 |
CN103725243B (zh) * | 2013-12-27 | 2015-07-08 | 山东禹王实业有限公司 | 一种用于惰性金属表面粘结的厌氧胶 |
CN104046280A (zh) * | 2014-06-04 | 2014-09-17 | 重庆聚瑞化工新材料有限公司 | 用于发动机碗型塞密封的厌氧胶 |
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Address after: Xinghu street Suzhou Industrial Park in Jiangsu province 215000 BioBAY No. 218 building A4 Room 305 Patentee after: SUZHOU JINQIANG NEW MATERIALS Co.,Ltd. Address before: Xinghu Street Industrial Park of Suzhou city in Jiangsu province 215000 BioBAY No. 218 building A4 Room 305 Patentee before: SUZHOU ADHESIVE FACTORY Co.,Ltd. |
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PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Anaerobic adhesive as well as preparation method and application thereof Effective date of registration: 20200427 Granted publication date: 20160622 Pledgee: All bondholders Pledgor: SUZHOU JINQIANG NEW MATERIALS Co.,Ltd. Registration number: Y2020320010024 |
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Granted publication date: 20160622 Pledgee: All bondholders Pledgor: SUZHOU JINQIANG NEW MATERIALS Co.,Ltd. Registration number: Y2020320010024 |
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