CN104356810A - Reflective thermal insulation real stone paint - Google Patents

Reflective thermal insulation real stone paint Download PDF

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Publication number
CN104356810A
CN104356810A CN201410669810.6A CN201410669810A CN104356810A CN 104356810 A CN104356810 A CN 104356810A CN 201410669810 A CN201410669810 A CN 201410669810A CN 104356810 A CN104356810 A CN 104356810A
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Prior art keywords
mineral varnish
true mineral
insulating type
reflection heat
type according
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CN201410669810.6A
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Chinese (zh)
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CN104356810B (en
Inventor
卢相志
单秀军
张裕强
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SUZHOU MAHAYANA ENVIRONMENTAL PROTECTION NEW MATERIAL Co.,Ltd.
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Suzhou Manayana Environmental Protection Building Material Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a reflective thermal insulation real stone paint. A technical scheme is characterized in that the paint is composed of the following materials in percentage by weight (wt%): 8-20% of water, 0.3-0.8% of a dispersant, 0.1-0.3% of a defoaming agent, 0.2-0.5% of a thickener, 0.1-0.6% of hydroxyethyl cellulose, 0.8-3% of a coalescing agent, 1-3% of anti-freezing agent, 1-10% of hollow glass beads, 15-25% of a water-based polymer emulsion, 0.5-2% of a bactericide and 40-60% of reflective thermal insulation burning sand. The reflective thermal insulation real stone paint disclosed by the invention has a thermal insulation property and simultaneously bright in color; and real stone paint can be blended into any color, and is good in color stability.

Description

The true mineral varnish of a kind of reflection heat-insulating type
Technical field
The present invention relates to true mineral varnish technology and organic polymer compounding technology field, in particular, it relates to the true mineral varnish of a kind of reflection heat-insulating type.
Background technology
For application present situation and the Problems existing of China's external wall decorative material, governments at all levels have promulgated relevant regulations successively, take measures progressively to limit that Energy in use is large, the external wall decorative material of poor stability and contaminate environment, preferentially use high performance outer wall paint.Advocate and apply building coating in the fitting-out works such as house, Industrial buildings, public building and structures, the building coating of decoration of exterior wall suitable more than the 5 years useful life period of multi-storey building and general industry building and public building, the building coating of Highrise buildings suitable more than 10 years useful life period.Natural real stone paint is low in resources consumption, be easy to construction upgrades, without potential safety hazard, color and wide in variety, so more and more exterior wall will adopt coatings decoration.Natural real stone paint, as a bright spot of external wall latex coating, is that building coating research is in recent years the most active, a development direction the most rapidly.In recent years, along with the development of technology and the growth increasingly of energy consumption, energy-saving and emission-reduction become the theory of housing design.Current reflective insulation technology is only applied on flat coating layer, and the demand of people to coating is diversified, and the design of true mineral varnish still accounts for market greatly, becomes inexorable trend for true mineral varnish application reflective insulation technology.
Summary of the invention
The object of the present invention is to provide the true mineral varnish of a kind of reflection heat-insulating type, meet the requirement of true mineral varnish External Wall decoration and meet true mineral varnish proper property, increase the effect of its reflective insulation, reach the object of energy-saving and emission-reduction, and color stable being good.
For achieving the above object, the invention provides following technical scheme: the true mineral varnish of a kind of reflection heat-insulating type, this coating is made up of (wt%) the material of following weight percent: 8 ~ 20% water, 0.3 ~ 0.8% dispersion agent, 0.1 ~ 0.3% defoamer, 0.2 ~ 0.5% thickening material, 0.1 ~ 0.6% Natvosol, 0.8 ~ 3% film coalescence aid, 1 ~ 3% frostproofer, 1 ~ 10% hollow glass micropearl, 15 ~ 25% aqueous polymer emulsions, 0.5 ~ 2% sterilant, 40 ~ 60% reflective insulation sand burnings.
As preferably, described dispersion agent is environmental protection polycarboxylate sodium water treatment dispersion agent, and described film coalescence aid is alcohol ester 12 film coalescence aid, and described sterilant is LXE fungicidal preservative, and described thickening material is XG-60 thickening material.
As preferably, described aqueous polymer emulsion is mixed formed by ACRYLIC EMULSION 60%-80%, interpolymer latex of polystyrene and acrylic ester 5%-20%, organosilicon crylic acid latex 10%-30%.
As preferably, described reflective insulation sand burning by after one or more the mixing color matchings of basic toner and nano antimony tin oxide, nano-indium stannum oxide, nano zircite sinter and form.
As preferably, described basic toner comprise black masterbatch, white female, yellow female, red female, green female, silver color is female.
As preferably, described hollow glass micropearl is that borosilicate Raw material processing forms.
The present invention in contrast to prior art, there is following effect: reflective insulation burning colorful sand used in the present invention be by after one or more the mixing color matchings of basic toner and nano antimony tin oxide, nano-indium stannum oxide, nano zircite sinter to form and make the material of main part of true mineral varnish possess reflective insulation function, assisted tool is for the hollow glass micropearl of heat insulating function, true mineral varnish is made to possess better reflective insulation effect, and when using artificial sintering reflective insulation coloured silk sand, color can be allocated arbitrarily, not affect boldness and the tint retention of color; Wherein dispersion agent is for improving its toning property, makes the viscosity quite stable of this true mineral varnish; Wherein the stability to hydrolysis of film coalescence aid is very good, can cause better fusion when adding in this true mineral varnish; Wherein sterilant product performance while having the effect of sterilization and anticorrosion are stablized, safety and environmental protection; Wherein thickening material is for increasing the viscosity of this true mineral varnish, has higher yield value and gel structure, better can embody the simulated effect of true mineral varnish; Wherein aqueous polymer emulsion is mixed by ACRYLIC EMULSION, interpolymer latex of polystyrene and acrylic ester, organosilicon crylic acid latex, the color of reflective insulation sand burning can be caught again while can making self can to form transparent film like this, basic physicals and the mechanical property of this true mineral varnish coating are provided; And reflective insulation sand burning is wherein for providing the color of this true mineral varnish and this reflective insulation sand burning various colors is colorful, color stable, does not fade for a long time, and other component dissolubility of holding concurrently is good; Just can reach the true mineral varnish of this reflective insulation above meet the requirement of true mineral varnish External Wall decoration and meet true mineral varnish proper property, increase the effect of its reflective insulation, reach the object of energy-saving and emission-reduction, and color stability be good.
Embodiment
The invention will be further described below.
Embodiment one: the true mineral varnish of this reflection heat-insulating type, according to weight percent meter, composed of the following components: 10% water, 0.8% dispersion agent, 0.2% defoamer, 0.5% thickening material, 0.5% Natvosol, 2% film coalescence aid, 3% frostproofer, 8% hollow glass micropearl, 14% ACRYLIC EMULSION, 2% interpolymer latex of polystyrene and acrylic ester, 4% organosilicon crylic acid latex, 2% sterilant, 53% reflective insulation sand burning.
Embodiment two: the true mineral varnish of this reflection heat-insulating type, according to weight percent meter, composed of the following components: 15% water, 0.5% dispersion agent, 0.3% defoamer, 0.2% thickening material, 0.4% Natvosol, 1.6% film coalescence aid, 2% frostproofer, 5% hollow glass micropearl, 13% ACRYLIC EMULSION, 3% interpolymer latex of polystyrene and acrylic ester, 2% organosilicon crylic acid latex, 1% sterilant, 54% reflective insulation sand burning.
Embodiment three: the true mineral varnish of this reflection heat-insulating type, according to weight percent meter, composed of the following components: 20% water, 0.6% dispersion agent, 0.3% defoamer, 0.3% thickening material, 0.6% Natvosol, 2.2% film coalescence aid, 1% frostproofer, 8% hollow glass micropearl, 13% ACRYLIC EMULSION, 3% interpolymer latex of polystyrene and acrylic ester, 2% organosilicon crylic acid latex, 2% sterilant, 49% reflective insulation sand burning.
Embodiment four: the true mineral varnish of this reflection heat-insulating type, according to weight percent meter, composed of the following components: 18% water, 0.5% dispersion agent, 0.3% defoamer, 0.2% thickening material, 0.3% Natvosol, 0.1% film coalescence aid, 2% frostproofer, 5.6% hollow glass micropearl, 13.2% ACRYLIC EMULSION, 3.3% interpolymer latex of polystyrene and acrylic ester, 5.5% organosilicon crylic acid latex, 1% sterilant, 50% reflective insulation sand burning.
Embodiment five: the true mineral varnish of this reflection heat-insulating type, according to weight percent meter, composed of the following components: 8% water, 0.6% dispersion agent, 0.3% defoamer, 0.5% thickening material, 0.6% Natvosol, 0.8% film coalescence aid, 3% frostproofer, 9.2% hollow glass micropearl, 15% ACRYLIC EMULSION, 3.75% interpolymer latex of polystyrene and acrylic ester, 6.25% organosilicon crylic acid latex, 2% sterilant, 50% reflective insulation sand burning.
Embodiment six: the true mineral varnish of this reflection heat-insulating type, according to weight percent meter, composed of the following components: 12% water, 0.8% dispersion agent, 0.1% defoamer, 0.2% thickening material, 0.1% Natvosol, 2.8% film coalescence aid, 2% frostproofer, 6.5% hollow glass micropearl, 16.8% ACRYLIC EMULSION, 2.1% interpolymer latex of polystyrene and acrylic ester, 2.1% organosilicon crylic acid latex, 0.5% sterilant, 54% reflective insulation sand burning.
Embodiment seven: the true mineral varnish of this reflection heat-insulating type, according to weight percent meter, composed of the following components: 18% water, 0.4% dispersion agent, 0.3% defoamer, 0.5% thickening material, 0.6% Natvosol, 3% film coalescence aid, 2% frostproofer, 7.2% hollow glass micropearl, 12.6% ACRYLIC EMULSION, 1% interpolymer latex of polystyrene and acrylic ester, 4.4% organosilicon crylic acid latex, 2% sterilant, 48% reflective insulation sand burning.
Embodiment eight: the true mineral varnish of this reflection heat-insulating type, according to weight percent meter, composed of the following components: 14% water, 0.7% dispersion agent, 0.2% defoamer, 0.4% thickening material, 0.5% Natvosol, 0.8% film coalescence aid, 1.9% frostproofer, 10% hollow glass micropearl, 12.35% ACRYLIC EMULSION, 2.85% interpolymer latex of polystyrene and acrylic ester, 3.8% organosilicon crylic acid latex, 0.5% sterilant, 52% reflective insulation sand burning.
Product reflective insulation of the present invention true mineral varnish the performance test results is as follows:
The material adopted in above embodiment one to eight is:
Dispersion agent adopts the environmental protection polycarboxylate sodium water treatment dispersion agent produced by Han Tai Chemical Co., Ltd. of Nantong city;
Film coalescence aid adopts alcohol ester 12 film coalescence aid produced by Guangzhou Ang Di Chemical Co., Ltd.;
Sterilant adopts the LXE fungicidal preservative produced by Changzhou Xin Nuoke Chemical Co., Ltd.;
Sterilant adopts the LXE fungicidal preservative produced by Changzhou Xin Nuoke Chemical Co., Ltd..
The material that in the true mineral varnish of this reflective insulation, all the other do not specify the material of concrete model to be well known to the skilled person, does not repeat herein.
National standard is met according to the true mineral varnish of this reflective insulation that the present invention makes, its bonding strength is high, water-tolerant, and alkali resistance is also relatively good, heat-proof quality is excellent, meets the requirement of true mineral varnish External Wall decoration and meets true mineral varnish proper property, adding the effect of reflective insulation, reach the object of energy-saving and emission-reduction, and color has allocated and color stability is good.
The above is only the preferred embodiment of the present invention, protection scope of the present invention be not only confined to above-described embodiment, and all technical schemes belonged under thinking of the present invention all belong to protection scope of the present invention.It should be pointed out that for those skilled in the art, some improvements and modifications without departing from the principles of the present invention, these improvements and modifications also should be considered as protection scope of the present invention.

Claims (6)

1. the true mineral varnish of reflection heat-insulating type, is characterized in that: be made up of (wt%) the material of following weight percent: 8 ~ 20% water, 0.3 ~ 0.8% dispersion agent, 0.1 ~ 0.3% defoamer, 0.2 ~ 0.5% thickening material, 0.1 ~ 0.6% Natvosol, 0.8 ~ 3% film coalescence aid, 1 ~ 3% frostproofer, 1 ~ 10% hollow glass micropearl, 15 ~ 25% aqueous polymer emulsions, 0.5 ~ 2% sterilant, 40 ~ 60% reflective insulation sand burnings.
2. the true mineral varnish of a kind of reflection heat-insulating type according to claim 1, it is characterized in that: described dispersion agent is environmental protection polycarboxylate sodium water treatment dispersion agent, described film coalescence aid is alcohol ester 12 film coalescence aid, and described sterilant is LXE fungicidal preservative, and described thickening material is XG-60 thickening material.
3. the true mineral varnish of a kind of reflection heat-insulating type according to claim 1, is characterized in that: described aqueous polymer emulsion is mixed formed by ACRYLIC EMULSION 60%-80%, interpolymer latex of polystyrene and acrylic ester 5%-20%, organosilicon crylic acid latex 10%-30%.
4. the true mineral varnish of a kind of reflection heat-insulating type according to claim 1, is characterized in that: described reflective insulation sand burning is matched colors afterwards by one or more mixing of basic toner and nano antimony tin oxide, nano-indium stannum oxide, nano zircite sinter and form.
5. the true mineral varnish of a kind of reflection heat-insulating type according to claim 4, is characterized in that: described basic toner comprises black masterbatch, white mother, yellow mother, redness is female, green is female, silver color is female.
6. the true mineral varnish of a kind of reflection heat-insulating type according to claim 1, is characterized in that: described hollow glass micropearl is that borosilicate Raw material processing forms.
CN201410669810.6A 2014-11-21 2014-11-21 A kind of true mineral varnish of reflection heat-insulating type Active CN104356810B (en)

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Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104497881A (en) * 2014-12-03 2015-04-08 江苏丽高博能建筑节能有限公司 Water-based reflective insulation stone paint and manufacturing method thereof
CN104927541A (en) * 2015-06-23 2015-09-23 陈良伢 Reflecting heat-insulation type real stone paint and preparation technology thereof
CN104944837A (en) * 2015-05-30 2015-09-30 广东华兹卜化学工业有限公司 Fireproof real stone paint with reflection and heat insulation effects
CN105111797A (en) * 2015-09-11 2015-12-02 山东地平线建筑节能科技有限公司 Ceramic colored stone coating and preparation method thereof
CN105400342A (en) * 2015-11-27 2016-03-16 宁波双人新材料有限公司 Functional really stone paint and preparation method thereof
CN105820681A (en) * 2016-05-17 2016-08-03 杭州美多乐环保新材料有限公司 Reflective thermal-insulation real stone paint and preparation method thereof
CN106349855A (en) * 2016-08-31 2017-01-25 铃鹿复合建材(上海)有限公司 Reflective thermal insulating really stone paint
CN106380979A (en) * 2016-09-23 2017-02-08 鳄鱼制漆(上海)有限公司 Silicone-acrylic weather-resistant reflective heat-insulation natural stone paint and preparation method thereof
CN106590239A (en) * 2016-11-11 2017-04-26 安徽本雅明涂料有限公司 True stone paint additive and preparation method thereof
CN107162486A (en) * 2017-06-06 2017-09-15 厦门富思特新材料科技有限公司 A kind of true mineral varnish of reflective insulation trowelling and preparation method thereof
CN107540267A (en) * 2017-06-14 2018-01-05 牛智勇 A kind of preparation technology of uvioresistant, heat insulation type vitrified mineral varnish
CN107540266A (en) * 2017-06-14 2018-01-05 牛智勇 A kind of uvioresistant, heat insulation type vitrified mineral varnish
CN107892827A (en) * 2017-12-13 2018-04-10 宁波康曼丝涂料有限公司 A kind of reflective insulation sand textured coating and preparation method thereof
CN107955347A (en) * 2017-11-13 2018-04-24 青岛卓森纳生物工程有限公司 A kind of its manufacture method of the environmentally-friendly plastic high molecular nanometer Masterbatch of zero VOC content
CN108299979A (en) * 2016-09-12 2018-07-20 广东华润涂料有限公司 The true stone coating system of heat reflectivity
CN108715706A (en) * 2018-06-01 2018-10-30 湘江涂料科技有限公司 Elastic reflective insulation sliver and preparation method thereof and lacquer and preparation method thereof
CN109337482A (en) * 2018-10-24 2019-02-15 宿松汉邦新型建材有限公司 A kind of snowflake white sand lacquer and preparation method thereof
CN110016268A (en) * 2019-04-28 2019-07-16 河北晨阳工贸集团有限公司 A kind of reflective insulation lacquer and preparation method thereof
CN110016269A (en) * 2019-04-28 2019-07-16 河北晨阳工贸集团有限公司 A kind of reflection heat-insulating type texture paint and preparation method thereof
CN111393979A (en) * 2020-05-24 2020-07-10 济南捷盛建材新技术有限公司 Antibacterial super-wear-resistant polyurethane surface coating material and preparation method thereof
CN111534210A (en) * 2020-05-24 2020-08-14 济南捷盛建材新技术有限公司 Polyurethane super-wear-resistant conductive topcoat material and preparation method thereof
CN114031994A (en) * 2021-12-17 2022-02-11 上海中南建筑材料有限公司 Special top coating composition for transparent aerogel and preparation method and application thereof

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EP1008564A1 (en) * 1998-12-10 2000-06-14 Sumitomo Metal Mining Company Limited Coating solution for forming a film for cutting off solar radiation and the film formed therefrom
CN1357580A (en) * 2001-12-27 2002-07-10 四川科大洛克新材料有限公司 Production process of colar glaze guartz paint
CN103333572A (en) * 2013-07-02 2013-10-02 宁波清风纳米涂料有限公司 Real stone paint
CN104031508A (en) * 2014-06-25 2014-09-10 中山蓝海洋水性涂料有限公司 Three-resistance type real stone paint and preparation method thereof
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104497881A (en) * 2014-12-03 2015-04-08 江苏丽高博能建筑节能有限公司 Water-based reflective insulation stone paint and manufacturing method thereof
CN104944837A (en) * 2015-05-30 2015-09-30 广东华兹卜化学工业有限公司 Fireproof real stone paint with reflection and heat insulation effects
CN104927541A (en) * 2015-06-23 2015-09-23 陈良伢 Reflecting heat-insulation type real stone paint and preparation technology thereof
CN105111797A (en) * 2015-09-11 2015-12-02 山东地平线建筑节能科技有限公司 Ceramic colored stone coating and preparation method thereof
CN105400342A (en) * 2015-11-27 2016-03-16 宁波双人新材料有限公司 Functional really stone paint and preparation method thereof
CN105820681A (en) * 2016-05-17 2016-08-03 杭州美多乐环保新材料有限公司 Reflective thermal-insulation real stone paint and preparation method thereof
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