CN104355886B - A kind of jujube tree organic-inorganic compound fertilizer special - Google Patents
A kind of jujube tree organic-inorganic compound fertilizer special Download PDFInfo
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- CN104355886B CN104355886B CN201410654236.7A CN201410654236A CN104355886B CN 104355886 B CN104355886 B CN 104355886B CN 201410654236 A CN201410654236 A CN 201410654236A CN 104355886 B CN104355886 B CN 104355886B
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
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Abstract
The present invention provides a kind of jujube tree organic-inorganic compound fertilizer special, is made up of following raw material: sugar slag, Chelates of Amino Acids And Trace Elements, fulvic acid, binding agent, carbamide, MAP, potassium chloride, sulfur ammonium and killing pests and suppressing bacteria agent；Wherein, killing pests and suppressing bacteria agent is made up of raw material of Chinese medicine, plant sterol and auxiliary agent.Jujube tree organic-inorganic compound fertilizer special of the present invention can improve soil, balanced Releasing nutrient, formula is reasonable, strengthen plant resistance, add killing pests and suppressing bacteria agent, the physiological disturbance that prevention jujube tree is easily generated, strengthen the disease-resistant insect pest ability of jujube tree, promote volume increase, be the free of contamination environment-friendly fertilizer of noresidue of a kind of " combination of pesticide and fertilizer ".
Description
Technical field
The invention belongs to agricultural fertilizer technical field, relate to a kind of compound organic and inorganic fertilizer, be specifically related to a kind of jujube tree organic-inorganic compound fertilizer special.
Background technology
Jujube cultivation is with a long history, nutritious, various in style.Jujube tree is perennial bearing-age tree, and annual results fruit will take away substantial amounts of nutrient, if being supplemented not in time, will certainly affect tree vigo(u)r, causing serious biennial bearing phenomenon.Therefore, the rational application of fertilizer is to promote that jujube tree tree body is healthy and strong, strengthens resistance and the prolongation result time limit, it is thus achieved that high yield, stable yields one of important measures.
Current jujube tree is applied fertilizer based on chemical fertilizer such as carbamide, Diammonium phosphate (DAP), quick-acting compound fertilizer, due to the chronic administration chemical fertilizer based on nitrogenous fertilizer, cause the soil organism to lack and trunk infusion is unbalance, cause Fructus Jujubae fruit low yield inferior, for solving this problem, applying of fertilizer should be increased.
Using Chemical Mixed Fertilizer to overcome and use the problem that soil nutrient that chemical fertilizer of simple substance brings is unbalance, but the effective rate of utilization of existing Chemical Mixed Fertilizer is low, runs off fast, wastage is big, it is impossible to thoroughly solve the pollution problem of soil compaction and underground water source atmosphere soil.Meanwhile, its nutritional labeling is few, it is impossible to the nutrient needed for supply crop growth comprehensively.Have the disadvantage in that simultaneously and use same formula for Different Crop, it is impossible to meet the growth demand of specified plant；When existing Chemical Mixed Fertilizer is directly applied to jujube tree, there is effective composition proportion not reasonable, effective rate of utilization is low, runs off fast, and wastage is big, it is impossible to the problems such as the thorough pollution solving soil compaction and underground water source atmosphere soil.Meanwhile, its nutritional labeling is few, it is impossible to the nutrient needed for supply growth and development of jujube trees comprehensively.
Summary of the invention
Present invention aim at providing a kind of jujube tree organic-inorganic compound fertilizer special, soil can be improved, increase the crumb structure in soil, have long-acting, the slow double dominant of the quick-acting of inorganic fertilizer and fertilizer concurrently, nutrients release is balanced, effective disease-prevention and insecticide, strengthens resistance, mean fruit weight substantially increases, and painted good yield is high.
Jujube tree organic-inorganic compound fertilizer special provided by the invention, this fertilizer is with nitrogen (N), phosphorus (P2O5), potassium (K2O) based on, with the addition of several slow dissolubility nutrients such as medium trace element, beneficial element, fulvic acid and killing pests and suppressing bacteria agent science group and join and form, each raw material cooperates, and has potentiation, can improve medium trace element utilization rate.Chemical Mixed Fertilizer of the present invention adds organic sugar slag, the by-product of recoverable sugaring process, preserve the ecological environment, simultaneously containing abundant vitamin and medium trace element in sugar slag, growth and development of jujube trees desired nutritional element can be supplied comprehensively, conversion organic matter is decomposed by adding fulvic acid etc., promote Crop, make nutrition more comprehensive, it is that a kind of nutrition is complete, function is many, comprehensive fertility is high, the Chemical Mixed Fertilizer that yield potential is big, simultaneously, the organic additions such as sugar slag add adsorption structure, anti-caking simultaneously, increase its dispersibility, be conducive to effective release of fertilizer efficiency, crop fully absorbs；Product of the present invention has slow release long-acting effect, by optimizing nitrogen, phosphorus, potassium combination, reasonably combined medium trace element, can improve utilization rate of fertilizer, reduce fertilizer amount and application times, alleviate the pollution to environment.The killing pests and suppressing bacteria agent added, nutrition more comprehensively, add Pesticidal and sterilizing effect, strengthen the disease-resistant insect pest ability of jujube tree, improve jujube tree quality, promote jujube tree volume increase.
A kind of jujube tree organic-inorganic compound fertilizer special of the present invention, is made up of the raw material of following weight parts: sugar slag 180～220, Chelates of Amino Acids And Trace Elements 18～25, fulvic acid 25～35, binding agent 45～60, carbamide 220～250, MAP 170～200, potassium chloride 80～90, sulfur ammonium 180～210 and killing pests and suppressing bacteria agent 20～50；Described killing pests and suppressing bacteria agent is made up of the raw material of following weight parts: Pyrethrum 3～5, mentha leave 8～10, Folium Capsici 4～6, Flos Caryophylli 3～5, Azadirachta Indica A. 3～5 and plant sterol 9～12, dispersant 0.5～0.6, disintegrating agent 0.5～1.0, synergist 0.5～0.6 and penetrating agent 0.6～1.0.
Described sugared slag is one or more the mixture in pears sugar slag, Fructus Mali pumilae sugar slag, cane suger slag, beet sugar slag and primverose slag, it is preferable that pears sugar slag, Fructus Mali pumilae sugar slag；
Described Chelates of Amino Acids And Trace Elements medium trace element is zinc, manganese, ferrum, copper, wherein, and zinc: manganese: ferrum: copper mass is than for 1.5:1.0:1.5:2；
Described described binding agent is attapulgite, bentonite or starch adesive etc.；
Described dispersant is di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, sodium lignin sulfonate, sodium humate or styrene acrylic；
Described disintegrating agent is starch, carboxymethyl starch sodium, carboxymethylcellulose calcium, cross-linking sodium carboxymethyl cellulose, sodium alginate or alginic acid；
Described synergist is Nafusaku, indolebutyric acid, brassinolide, organosilicon, tea saponin or methylenedioxy benzene derivant；
Described penetrating agent is emulsifier BP, azone, triphen phosphorus or polyoxyethylenated alcohol sodium sulfate salt.
Described killing pests and suppressing bacteria agent preparation method is: weigh each raw material by weight, by Pyrethrum, mentha leave, Folium Capsici, Flos Caryophylli, Azadirachta Indica A. dry to moisture 2～5% time, be crushed to 40～50 orders, mix homogeneously, mixes with the ratio of mass ratio 1:8～10 with water, supersonic wave wall breaking, filter, it is concentrated into original volume 10～15%, obtains lixiviating solution, add plant sterol, dispersant, disintegrating agent, synergist and penetrating agent, mix homogeneously, obtains killing pests and suppressing bacteria agent；
Described supersonic wave wall breaking method is: the hydrochloric acid of 0.1～0.3mol/L adjusts pH to 3.0～3.5, temperature 40～50 DEG C, supersonic wave wall breaking 10～15min, ultrasonic power 125～150w, after breaking cellular wall, the NaOH solution of 0.1～0.3mol/L adjusts pH to 5.0～5.5, then with ultrasonic extraction 45～50min, ultrasonic power 150～200w.
In above-mentioned jujube tree organic-inorganic compound fertilizer special, it is preferred that each composition total content, it is by mass percentage: nitrogen (N) 10～15%, phosphorus (P2O5) 6～10%, potassium (K2O) 8～12%, organic 15～20%, medium trace element 0.5～1%, surplus is water and other solid contents；Wherein nitrogen (N): phosphorus (P2O5): the preferred 12:8:10 of potassium (k2O) mass ratio.
One jujube tree organic-inorganic compound fertilizer special of the present invention, it is preferable that the raw material composition of following weight portion: sugar slag 200, Chelates of Amino Acids And Trace Elements 20, fulvic acid 30, binding agent 50, carbamide 240, MAP 180, potassium chloride 85, sulfur ammonium 200 and killing pests and suppressing bacteria agent 25；The raw material composition of the described preferred following weight parts of killing pests and suppressing bacteria agent: Pyrethrum 4, mentha leave 9, Folium Capsici 5, Flos Caryophylli 4, Azadirachta Indica A. 4 and plant sterol 10, dispersant 0.5, disintegrating agent 1, synergist 0.5 and penetrating agent 0.8.
The preparation method of the above-mentioned jujube tree organic-inorganic compound fertilizer special of the present invention, step is:
1) each raw material is weighed in proportion；
2) killing pests and suppressing bacteria agent is prepared；
3) by sugar slag, fulvic acid and step 2) medicinal residues after lixiviate, mix homogeneously, it is placed in fermentation vat, ferments 6～7 days in 30～40 DEG C；
4) by killing pests and suppressing bacteria agent and other raw materials remaining, join in the material after step 3) fermentation, mix homogeneously, proceed to comminutor, suitably spraying adds water, and 55～60 DEG C of hot-air seasonings obtain jujube tree organic-inorganic compound fertilizer special of the present invention.
One jujube tree organic-inorganic compound fertilizer special of the present invention, the scope of application: the main area of application of Chemical Mixed Fertilizer of the present invention is Fructus Jujubae producing region, Xinjiang.
Application process: should spread fertilizer over the fields, row replacement, spread manuer in holes, adds soil covering, and the degree of depth is to be advisable to 40～50cm.
One jujube tree organic-inorganic compound fertilizer special of the present invention, compared with prior art, it has the beneficial effect that
1) soil can be improved, balanced Releasing nutrient, have long-acting, the slow double dominant of the quick-acting of inorganic fertilizer and fertilizer concurrently.
2) formula is reasonable, and compared with using common Chemical Mixed Fertilizer, the resistance of plant strengthens, and yield significantly improves.
3) add killing pests and suppressing bacteria agent, strengthen the disease-resistant insect pest ability of jujube tree, the physiological disturbance that jujube tree can be prevented to be easily generated, improve fruit tree quality, promote jujube tree volume increase, be the free of contamination environment-friendly fertilizer of noresidue of a kind of " combination of pesticide and fertilizer ".
Detailed description of the invention
Technical solution of the present invention and beneficial effect are described below by specific embodiment.
Chelates of Amino Acids And Trace Elements medium trace element used in the embodiment of the present invention is zinc, manganese, ferrum, copper, wherein, and zinc: manganese: ferrum: copper mass ratio is for 1.5:1.0:1.5:2.
Embodiment 1
A kind of jujube tree organic-inorganic compound fertilizer special, is made up of the raw material of following weight portion: pears sugar slag 200, Chelates of Amino Acids And Trace Elements 20, fulvic acid 30, attapulgite 50, carbamide 240, MAP 180, potassium chloride 85, sulfur ammonium 200 and killing pests and suppressing bacteria agent 25；Killing pests and suppressing bacteria agent is made up of the raw material of following weight parts: Pyrethrum 4, mentha leave 9, Folium Capsici 5, Flos Caryophylli 4, Azadirachta Indica A. 4 and plant sterol 10, di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate 0.5, starch 1, Nafusaku 0.5 and emulsifier BP 0.8.
Preparation method is:
1) each raw material is weighed in proportion；
2) killing pests and suppressing bacteria agent is prepared: by Pyrethrum, mentha leave, Folium Capsici, Flos Caryophylli, when Azadirachta Indica A. is dried to moisture 5%, it is crushed to 50 orders, mix homogeneously, mix with the ratio of mass ratio 1:10 with water, the hydrochloric acid of 0.1mol/L adjusts pH to 3.5, temperature 50 C, supersonic wave wall breaking 15min, ultrasonic power 150w, after breaking cellular wall, the NaOH solution of 0.1mol/L adjusts pH to 5.5, use ultrasonic extraction 45min again, ultrasonic power 200w, filter, it is concentrated into original volume 10%, obtain lixiviating solution, add plant sterol, dispersant, disintegrating agent, synergist and penetrating agent, mix homogeneously, obtain killing pests and suppressing bacteria agent；
3) by sugar slag, fulvic acid and step 2) medicinal residues after lixiviate, mix homogeneously, it is placed in fermentation vat, ferments 7 days in 35 DEG C；
4) by killing pests and suppressing bacteria agent and other raw materials remaining, join in the material after step 3) fermentation, mix homogeneously, proceed to comminutor, suitably spraying adds water, and 60 DEG C of hot-air seasonings obtain the embodiment of the present invention 1 jujube tree organic-inorganic compound fertilizer special.
Embodiment 2
A kind of jujube tree organic-inorganic compound fertilizer special, is made up of the raw material of following weight portion: cane suger slag 180, Chelates of Amino Acids And Trace Elements 18, fulvic acid 25, bentonite 45, carbamide 220, MAP 170, potassium chloride 80, sulfur ammonium 180 and killing pests and suppressing bacteria agent 20.Killing pests and suppressing bacteria agent is made up of the raw material of following weight parts: Pyrethrum 4, mentha leave 9, Folium Capsici 5, Flos Caryophylli 4, Azadirachta Indica A. 4 and plant sterol 10, sodium lignin sulfonate 0.5, carboxymethyl starch sodium 1, indolebutyric acid 0.5 and azone 0.8.
Preparation method is with embodiment 1.
Embodiment 2
A kind of jujube tree organic-inorganic compound fertilizer special, is made up of the raw material of following weight portion: beet sugar slag 220, Chelates of Amino Acids And Trace Elements 25, fulvic acid 35, starch adesive 60, carbamide 250, MAP 200, potassium chloride 90, sulfur ammonium 210 and killing pests and suppressing bacteria agent 45；Killing pests and suppressing bacteria agent is made up of the raw material of following weight parts: Pyrethrum 4, mentha leave 9, Folium Capsici 5, Flos Caryophylli 4, Azadirachta Indica A. 4 and plant sterol 10, styrene acrylic 0.5, sodium alginate 1, brassinolide 0.5 and triphen phosphorus 0.8.
Preparation method is with embodiment 1.
In order to better illustrate one jujube tree organic-inorganic compound fertilizer special of the present invention, the beneficial effect in jujube growth, the present invention has carried out field test.
1, test plot basic condition: ground, gentle slope, medium fertility, uniformity, every mu of seedling arranges 45 3 years age of tree jujube trees uniformly at intervals.
2, experiment packet and Term Fertilization mode:
Totally 3 mu of plot of test, is divided into 3 communities, and plot area is 1 mu, respectively corresponding experimental group and matched group 1～2.
Experimental group: use the jujube tree organic-inorganic compound fertilizer special that embodiment 1 prepares.
Matched group: totally 2 groups, the Chemical Mixed Fertilizer that matched group 1 is used is with reference to embodiment 1, and without killing pests and suppressing bacteria agent, other each material content proportioning is with embodiment 1；Matched group 2 uses other compound fertilizer, total active constituent content N+P2O5+k2O=32%, N:P2O5: k2O mass ratio is 12:8:10, organic 15%.
Term Fertilization mode: Wa Yiquan, ditch depth 40cm are enclosed in distance 1 meter of of jujube tree root, every jujube tree is applied fertilizer 20 kilograms.
Test kind: Zanxindazao
4, interpretation of result:
Soil nutrients variability after use fertilizer, result is in Table 1
Table 1 soil nutrient content and test result
Using after Chemical Mixed Fertilizer of the present invention factor impact effects such as jujube tree yield, only use result of use contrast during common fertilizer with matched group and former years, result is in Table 2
Table 2 experimental group and matched group Fertilizer application Contrast on effect
From table 1 and 2, jujube tree organic-inorganic compound fertilizer special of the present invention is compared with Common compound fertilizer, when the use of same amount N P and K, experimental group and matched group 1 soil fertility substantially increase, experimental group single fruit weightening finish 3.9%, increase production 9.3%, fruit-setting rate is high, Cracking fruit, insect pest rate disease rate substantially lower, and soluble solid improves 0.9 degree, and indices is superior to matched group.
Claims (8)
1. a jujube tree organic-inorganic compound fertilizer special, it is characterized in that, be made up of the raw material of following weight parts: sugar slag 180～220, Chelates of Amino Acids And Trace Elements 18～25, fulvic acid 25～35, binding agent 45～60, carbamide 220～250, MAP 170～200, potassium chloride 80～90, sulfur ammonium 180～210 and killing pests and suppressing bacteria agent 20～50；Described killing pests and suppressing bacteria agent is made up of the raw material of following weight parts: Pyrethrum 3～5, mentha leave 8～10, Folium Capsici 4～6, Flos Caryophylli 3～5, Azadirachta Indica A. 3～5 and plant sterol 9～12, dispersant 0.5～0.6, disintegrating agent 0.5～1.0, synergist 0.5～0.6 and penetrating agent 0.6～1.0.
2. jujube tree organic-inorganic compound fertilizer special according to claim 1, it is characterised in that: described sugared slag is one or more the mixture in pears sugar slag, Fructus Mali pumilae sugar slag, cane suger slag, beet sugar slag and primverose slag；Described binding agent is attapulgite, bentonite or starch adesive；Described Chelates of Amino Acids And Trace Elements medium trace element is zinc, manganese, ferrum, copper, wherein, and zinc: manganese: ferrum: copper mass is than for 1.5:1.0:1.5:2.
3. jujube tree organic-inorganic compound fertilizer special according to claim 1, it is characterised in that: described dispersant is di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, sodium lignin sulfonate, sodium humate or styrene acrylic；Described disintegrating agent is starch, carboxymethyl starch sodium, carboxymethylcellulose calcium, cross-linking sodium carboxymethyl cellulose, sodium alginate or alginic acid；Described synergist is Nafusaku, indolebutyric acid, brassinolide, organosilicon, tea saponin or methylenedioxy benzene derivant；Described penetrating agent is emulsifier BP, azone, triphen phosphorus or polyoxyethylenated alcohol sodium sulfate salt.
4. jujube tree organic-inorganic compound fertilizer special according to claim 1, it is characterized in that, described killing pests and suppressing bacteria agent preparation method is: weigh each raw material by weight, by Pyrethrum, mentha leave, Folium Capsici, Flos Caryophylli, Azadirachta Indica A. dry to moisture 2～5% time, be crushed to 40～50 orders, mix homogeneously, mix with the ratio of mass ratio 1:8～10 with water, supersonic wave wall breaking, filter, it is concentrated into original volume 10～15%, obtains lixiviating solution, add plant sterol, dispersant, disintegrating agent, synergist and penetrating agent, mix homogeneously, obtains killing pests and suppressing bacteria agent.
5. jujube tree organic-inorganic compound fertilizer special according to claim 1, it is characterized in that, each composition total content in described Chemical Mixed Fertilizer, it is by mass percentage: nitrogen 10～15%, phosphorus 6～10%, potassium 8～12%, organic 15～20%, medium trace element 0.5～1%, surplus is water and other solid contents.
6. jujube tree organic-inorganic compound fertilizer special according to claim 5, it is characterised in that described nitrogen: phosphorus: potassium mass ratio is 12:8:10.
7. jujube tree organic-inorganic compound fertilizer special according to claim 1, it is characterized in that, be made up of the raw material of following weight parts: sugar slag 200, Chelates of Amino Acids And Trace Elements 20, fulvic acid 30, binding agent 50, carbamide 240, MAP 180, potassium chloride 85, sulfur ammonium 200 and killing pests and suppressing bacteria agent 25；Described killing pests and suppressing bacteria agent is made up of the raw material of following weight parts: Pyrethrum 4, mentha leave 9, Folium Capsici 5, Flos Caryophylli 4, Azadirachta Indica A. 4 and plant sterol 10, dispersant 0.5, disintegrating agent 1, synergist 0.5 and penetrating agent 0.8.
8. the jujube tree organic-inorganic compound fertilizer special according to any one of claim 1-7, it is characterised in that preparation method, step is:
1) each raw material is weighed in proportion；
2) prepare killing pests and suppressing bacteria agent: by Pyrethrum, mentha leave, Folium Capsici, Flos Caryophylli, Azadirachta Indica A. dry to moisture 2～5% time, be crushed to 40～50 orders, mix homogeneously, mix with the ratio of mass ratio 1:8～10 with water, supersonic wave wall breaking, filters, is concentrated into original volume 10～15%, obtain lixiviating solution, add plant sterol, dispersant, disintegrating agent, synergist and penetrating agent, mix homogeneously, obtain killing pests and suppressing bacteria agent；
3) by sugar slag, fulvic acid and step 2) medicinal residues after lixiviate, mix homogeneously, it is placed in fermentation vat, ferments 6～7 days in 30～40 DEG C；
4) by killing pests and suppressing bacteria agent and other raw materials remaining, join in the material after step 3) fermentation, mix homogeneously, proceed to comminutor, suitably spraying adds water, and 55～60 DEG C of hot-air seasonings obtain jujube tree organic-inorganic compound fertilizer special.
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| CN104973974B (en) * | 2015-07-08 | 2017-11-10 | 青岛嘉瑞生物技术有限公司 | A kind of winter jujube tailored version biological organic fertilizer |
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| CN105254425A (en) * | 2015-10-26 | 2016-01-20 | 广西农垦国有立新农场 | Ecological organic fertilizer and preparing method thereof |
| CN105254426A (en) * | 2015-10-26 | 2016-01-20 | 广西农垦国有立新农场 | Organic fertilizer and preparation method thereof |
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| CN105237231A (en) * | 2015-11-06 | 2016-01-13 | 唐睿 | Preparation method of neem cake organic fertilizer |
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| CN106007858A (en) * | 2016-05-27 | 2016-10-12 | 王学海 | Compound fertilizer for vegetables and application method thereof |
| CN105925273A (en) * | 2016-05-31 | 2016-09-07 | 山东胜伟园林科技有限公司 | Method for greening original soil of drought and flood alkaline land with soil conditioner containing lotus leaf extract |
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| CN107141106A (en) * | 2017-06-14 | 2017-09-08 | 合肥助航生态农业科技有限公司 | Water conservation synergy organic fertilizer and preparation method thereof |
| CN107935684A (en) * | 2017-11-23 | 2018-04-20 | 宿州市东方红肥业有限公司 | A kind of a great number of elements slow-release fertilizer and preparation method thereof |
| CN107926993A (en) * | 2017-12-11 | 2018-04-20 | 林厚海 | Insecticidal bactericide and preparation method thereof and application method |
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| CN101709011B (en) * | 2009-12-09 | 2010-12-08 | 山东光大肥业科技有限公司 | Special organic-inorganic compound fertilizer for root-promoting type jujube trees and preparation method thereof |
| CN102515927B (en) * | 2011-09-21 | 2013-09-11 | 周法永 | Drug effect type microbial fertilizer, preparation method thereof and application thereof |
| CN102617211B (en) * | 2012-03-23 | 2014-06-25 | 新疆天海腾惠科技有限公司 | Special organic fertilizer for red dates and preparation method of special organic fertilizer |
| CN102775230B (en) * | 2012-07-28 | 2014-09-03 | 崔瑞珍 | Large-element water-soluble organic fertilizer and method for preparing same |
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