CN104312276A - Antibacterial heat-resistant special ink and preparation method thereof - Google Patents
Antibacterial heat-resistant special ink and preparation method thereof Download PDFInfo
- Publication number
- CN104312276A CN104312276A CN201410627595.3A CN201410627595A CN104312276A CN 104312276 A CN104312276 A CN 104312276A CN 201410627595 A CN201410627595 A CN 201410627595A CN 104312276 A CN104312276 A CN 104312276A
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- China
- Prior art keywords
- ink
- parts
- preparation
- silver
- zeolite
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
Abstract
The invention relates to special printing ink, in particular to antibacterial heat-resistant special ink and a preparation method thereof. The ink is prepared from the following raw materials in parts by weight: 3-5 parts of silver-loaded zinc 4A zeolite, 1-2 parts of 8-hydroxyquinoline, 50-60 parts of epoxy resin, 1-1.5 parts of a silane coupling agent KH550, 15-20 parts of DBE (Dibasic Ester) solvent, 2-3 parts of calcium stearate, 12-18 parts of ethyl acetate, 20-30 parts of environment-friendly pigment and 2-4 parts of an assistant. According to the ink, the epoxy resin serves as a connecting material, and an environment-friendly low-toxicity solvent is adopted, so that the environmental protection property of the ink is greatly improved, the combination and compatibility of the silver-loaded zinc 4A zeolite and the resin after pretreatment in the raw materials are promoted, and uniform, stable and long-acting and lasting bacterial ability of the ink can be obtained; moreover, the prepared ink further has good thermal aging resistance, is high in bonding capacity with a metallic material, and is particularly suitable for being used on the surface of the metallic material exposed to a higher temperature environment; the special ink is good in printing effect and new in duration.
Description
Technical field
The present invention relates to a kind of special printing inks, be specifically related to heat-resisting special ink of a kind of antimicrobial form and preparation method thereof.
Background technology
Special printing inks is a class to adapt to different printing materials and in order to reach the ink that different printing effects is developed, special ink kind is more, common comprises luminescent ink, sterilizing ink, anti-forgery ink, magnetic ink, fragrant printing ink, electrically conductive ink etc., adopt toluene in the formula of current special ink more, dimethylbenzene etc. all have the volatile solvent of higher hazardness, the potential safety hazard used is very big, and adopt water not fully up to expectations as the use properties of the water color ink of primary solvent, therefore, be badly in need of researching and developing low toxicity and the special printing inks with good use properties.
Summary of the invention
The object of the invention is to, provide heat-resisting special ink of a kind of antimicrobial form and preparation method thereof, to achieve these goals, the technical solution used in the present invention is as follows:
Heat-resisting special ink of a kind of antimicrobial form and preparation method thereof, it is characterized in that, this ink is made up of the raw material of following weight part: carry silver-colored zinc 4A zeolite 3-5, oxine 1-2, epoxy resin 50-60, Silane coupling agent KH550 1-1.5, DBE solvent 15-20, calcium stearate 2-3, ethyl acetate 12-18, environmental-friendly pigment 20-30, auxiliary agent 2-4;
Described auxiliary agent is made up of the raw material of following weight part: polyvinyl butyral acetal 2-4, silane coupling agent KH560 1-2, phosphoric acid propylene diamine 0.2-0.4, polyamide wax 2-3, silicone antifoam agent 1-3, diethylene glycol ether acetic ester 12-15, nano-starch 4-6, preparation method is: first nano-starch and silane coupling agent KH560 mixed grinding are disperseed 20-30min, obtain surface-modified nano starch for subsequent use, again other leftover materials are mixed subsequently, after stirring 30-40min, mixing solutions is heated to 60-80 DEG C, and drop into surperficial modified nano-starch, dispersed with stirring is evenly incubated and ultrasonic disperse 4-5h afterwards, obtain.
Described heat-resisting special ink of a kind of antimicrobial form and preparation method thereof, is characterized in that, in described year silver-colored zinc 4A zeolite, silver content is 0.2-0.3wt%, and Zn content is 4-5wt%.
Described heat-resisting special ink of a kind of antimicrobial form and preparation method thereof, its preparation method is:
(1) after first carrying silver-colored zinc 4A zeolite and Silane coupling agent KH550 mixing and stirring, thermal treatment 20-30min under 110-120 DEG C of environment, material after process terminates carries out grinding distribution process after being cooled to room temperature, and make particle diameter≤400 order of material, gained material is for subsequent use;
(2) other leftover materials are besides pigments dropped in batch can, be uniformly mixed 1-1.5h, add step (1) gained material subsequently, after mix and blend 30-40min, add environmental-friendly pigment again, continue stirring and make it mix completely, finally gained slurry is sent into grinding distribution in three-roller, to particle diameter≤25 μm of gained slurry, slurry is through packing and get product after the assay was approved.
The advantage of special ink prepared by the present invention is: using epoxy resin as binder, and adopt environmental protection low poison solvent, greatly improve the feature of environmental protection of ink, the combination of after pretreatment year in raw material silver-colored zinc 4A zeolite powder and resin and consistency obtain and promote, and can give ink uniform and stable, long-acting lasting antibacterial ability; In addition, ink prepared by the present invention also has good heat-proof aging ability, and strong with the viscosifying power of metallic substance, and be especially applicable to being applied to the metal material surface use exposed with under comparatively high temps environment, printing effect is excellent, prolonged more new.
Embodiment
Embodiment
The ink of the present embodiment is made up of the raw material of following weight part: carry silver-colored zinc 4A zeolite 4, oxine 2, epoxy resin 60, Silane coupling agent KH550 1.2, DBE solvent 20, calcium stearate 3, ethyl acetate 15, environmental-friendly pigment 26, auxiliary agent 3.
Wherein auxiliary agent is made up of the raw material of following weight part: polyvinyl butyral acetal 4, silane coupling agent KH560 2, phosphoric acid propylene diamine 0.3, polyamide wax 3, silicone antifoam agent 2, diethylene glycol ether acetic ester 15, nano-starch 6, preparation method is: first nano-starch and silane coupling agent KH560 mixed grinding are disperseed 30min, obtain surface-modified nano starch for subsequent use, again other leftover materials are mixed subsequently, after stirring 40min, mixing solutions is heated to 60-80 DEG C, and drop into surperficial modified nano-starch, dispersed with stirring is evenly incubated and ultrasonic disperse 5h afterwards, obtain.
In wherein said year silver-colored zinc 4A zeolite, silver content is 0.3wt%, and Zn content is 4wt%.
The preparation method of this printing-ink is:
(1) after first carrying silver-colored zinc 4A zeolite and Silane coupling agent KH550 mixing and stirring, thermal treatment 30min under 110-120 DEG C of environment, material after process terminates carries out grinding distribution process after being cooled to room temperature, and make particle diameter≤400 order of material, gained material is for subsequent use;
(2) other leftover materials are besides pigments dropped in batch can, be uniformly mixed 1.2h, add step (1) gained material subsequently, after mix and blend 35min, add environmental-friendly pigment again, continue stirring and make it mix completely, finally gained slurry is sent into grinding distribution in three-roller, to particle diameter≤25 μm of gained slurry, slurry is through packing and get product after the assay was approved.
By the ink printing obtained by the present embodiment on base material after complete drying, according to corresponding national examination criteria, the performance test results of this ink coating is:
Claims (3)
1. heat-resisting special ink of antimicrobial form and preparation method thereof, it is characterized in that, this printing-ink is made up of the raw material of following weight part: carry silver-colored zinc 4A zeolite 3-5, oxine 1-2, epoxy resin 50-60, Silane coupling agent KH550 1-1.5, DBE solvent 15-20, calcium stearate 2-3, ethyl acetate 12-18, environmental-friendly pigment 20-30, auxiliary agent 2-4;
Described auxiliary agent is made up of the raw material of following weight part: polyvinyl butyral acetal 2-4, silane coupling agent KH560 1-2, phosphoric acid propylene diamine 0.2-0.4, polyamide wax 2-3, silicone antifoam agent 1-3, diethylene glycol ether acetic ester 12-15, nano-starch 4-6, preparation method is: first nano-starch and silane coupling agent KH560 mixed grinding are disperseed 20-30min, obtain surface-modified nano starch for subsequent use, again other leftover materials are mixed subsequently, after stirring 30-40min, mixing solutions is heated to 60-80 DEG C, and drop into surperficial modified nano-starch, dispersed with stirring is evenly incubated and ultrasonic disperse 4-5h afterwards, obtain.
2. heat-resisting special ink of a kind of antimicrobial form as claimed in claim 1 and preparation method thereof, is characterized in that, in described year silver-colored zinc 4A zeolite, silver content is 0.2-0.3wt%, and Zn content is 4-5wt%.
3. heat-resisting special ink of a kind of antimicrobial form as claimed in claim 1 and preparation method thereof, its preparation method is:
(1) after first carrying silver-colored zinc 4A zeolite and Silane coupling agent KH550 mixing and stirring, thermal treatment 20-30min under 110-120 DEG C of environment, material after process terminates carries out grinding distribution process after being cooled to room temperature, and make particle diameter≤400 order of material, gained material is for subsequent use;
(2) other leftover materials are besides pigments dropped in batch can, be uniformly mixed 1-1.5h, add step (1) gained material subsequently, after mix and blend 30-40min, add environmental-friendly pigment again, continue stirring and make it mix completely, finally gained slurry is sent into grinding distribution in three-roller, to particle diameter≤25 μm of gained slurry, slurry is through packing and get product after the assay was approved.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410627595.3A CN104312276A (en) | 2014-11-10 | 2014-11-10 | Antibacterial heat-resistant special ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410627595.3A CN104312276A (en) | 2014-11-10 | 2014-11-10 | Antibacterial heat-resistant special ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104312276A true CN104312276A (en) | 2015-01-28 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410627595.3A Pending CN104312276A (en) | 2014-11-10 | 2014-11-10 | Antibacterial heat-resistant special ink and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2919081A1 (en) * | 2021-01-21 | 2022-07-21 | Torrecid Sa | Bactericide and antiviral ink (Machine-translation by Google Translate, not legally binding) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040024037A1 (en) * | 2002-07-03 | 2004-02-05 | Samsung Electronics Co., Ltd. | Antibiotic additive and ink composition comprising the same |
| CN1762219A (en) * | 2005-10-28 | 2006-04-26 | 太原理工大学 | Composite antibacterial agent and its preparation method |
| CN102942821A (en) * | 2012-10-30 | 2013-02-27 | 广东壮丽彩印股份有限公司 | Nano-antibacterial gravure aqueous printing ink and preparation method thereof |
| CN103865326A (en) * | 2014-02-27 | 2014-06-18 | 安徽颍美彩印包装有限公司 | Printing ink for surface of light-resistant metal and preparation method thereof |
-
2014
- 2014-11-10 CN CN201410627595.3A patent/CN104312276A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040024037A1 (en) * | 2002-07-03 | 2004-02-05 | Samsung Electronics Co., Ltd. | Antibiotic additive and ink composition comprising the same |
| CN1762219A (en) * | 2005-10-28 | 2006-04-26 | 太原理工大学 | Composite antibacterial agent and its preparation method |
| CN102942821A (en) * | 2012-10-30 | 2013-02-27 | 广东壮丽彩印股份有限公司 | Nano-antibacterial gravure aqueous printing ink and preparation method thereof |
| CN103865326A (en) * | 2014-02-27 | 2014-06-18 | 安徽颍美彩印包装有限公司 | Printing ink for surface of light-resistant metal and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2919081A1 (en) * | 2021-01-21 | 2022-07-21 | Torrecid Sa | Bactericide and antiviral ink (Machine-translation by Google Translate, not legally binding) |
| WO2022157400A1 (en) * | 2021-01-21 | 2022-07-28 | Torrecid, S.A | Bactericidal and antiviral digital ink |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150128 |
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| RJ01 | Rejection of invention patent application after publication |