CN102977666B - Zirconia loaded metal antirust paint and its preparation method - Google Patents
Zirconia loaded metal antirust paint and its preparation method Download PDFInfo
- Publication number
- CN102977666B CN102977666B CN201210432591.0A CN201210432591A CN102977666B CN 102977666 B CN102977666 B CN 102977666B CN 201210432591 A CN201210432591 A CN 201210432591A CN 102977666 B CN102977666 B CN 102977666B
- Authority
- CN
- China
- Prior art keywords
- parts
- clay
- preparation
- antirust paint
- modified nano
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a zirconia loaded metal antirust paint and its preparation method. The metal antirust paint comprises the following raw materials, by weight, 35-40 parts of an epoxy resin, 15-20 parts of a polytetrafluoroethylene resin, 23-28 parts of modified nanometer argil, 9-11 parts of zirconia, 8-10 parts of a butadiene-styrene latex, 1.3-1.8 parts of a tallow amine, 15-20 parts of polycaprolactone, 0.7-0.9 parts of glycerol monostearate, 0.4-0.6 parts of polybutylene terephthalate, 0.7-0.9 parts of poly-4-methyl-1-pentene, 0.4-0.6 parts of salicylic acid, 0.5-1.0 part of an oxidant 168, 3-5 parts of a modified styrene-acrylate emulsion, 0.8-1.2 parts of polyacrylic acid, 0.6-1.2 parts of vinyl-tri(beta-methoxyethoxy)silane, and 1.0-1.2 parts of fatty alcohol polyoxyethylene ether. The film of the metal antirust paint has the advantages of good adhesion, fast drying, good heat resistance, environmental protection and no pollution, the modified nanometer argil and the modified styrene-acrylate emulsion which are added into the raw materials improve the excellent performances of high-polymer materials in the raw materials, and simultaneously increase the corrosion and heat resistances of the metal antirust paint, and the preparation method has the advantages of simplicity, low cost and suitableness for large-scale production.
Description
Technical field
The present invention relates to metallic anti-rust paint of a kind of loaded zirconia and preparation method thereof, belong to rush-resisting material technical field.
Background technology
What adopted in recent years that industrial antirust paint protects metal take epoxy zinc-rich paint as at most, because the density ratio of metal zinc is larger, in order not make zinc powder settling or the settling velocity of the zinc powder that slows down, need in paint, add a certain amount of anti-sedimentation agent; The viscosity that adds paint of anti-settling agent also increases thereupon, will select as much as possible the resin (E44) of small molecules amount when selecting polyamide resin; During construction, in order to meet brushing property, in paint, add a large amount of solvents, during construction, solvent serious harm workman's healthy, paint solvent evaporates in drying process makes to have improved construction cost to contaminate environment, solvent in air; After small molecules amount resin solidification, the fragility of paint film is large, metal heat-expansion shrinkage system greatly when temperature variation paint film easily chap or come off.
Summary of the invention
In order to alleviate shortcomings and deficiencies of the prior art, metallic anti-rust paint providing a kind of loaded zirconia and preparation method thereof is provided the object of the invention.
The present invention adopts following technical scheme to achieve these goals:
The metallic anti-rust paint of loaded zirconia, the weight part of its constitutive material is: epoxy resin 35-40, teflon resin 15-20, modified Nano potter's clay 23-28, zirconium white 9-11, butadiene-styrene latex 8-10, tallow amine 1.3-1.8, vinegar 15-20 in poly-caproic acid, stearic acid direactive glyceride 0.7-0.9, polybutylene terephthalate 0.4-0.6, poly--4-methyl-1-pentene 0.7-0.9, Whitfield's ointment 0.4-0.6, oxygenant 168 0.5-1.0, modifying cinepazid emulsion 3-5, polyacrylic acid 0.8-1.2, vinyl three ('beta '-methoxy oxyethyl group) silane 0.6-1.2 and fatty alcohol-polyoxyethylene ether 1.0-1.2.
The metallic anti-rust paint of loaded zirconia, the weight part of its constitutive material is: vinegar 18, stearic acid direactive glyceride 0.8, polybutylene terephthalate 0.5, poly--4-methyl-1-pentene 0.8, Whitfield's ointment 0.5, oxygenant 168 0.8, modifying cinepazid emulsion 4, polyacrylic acid 1, vinyl three ('beta '-methoxy oxyethyl group) silane 0.9 and fatty alcohol-polyoxyethylene ether 1.1 in epoxy resin 38, teflon resin 18, modified Nano potter's clay 25, zirconium white 10, butadiene-styrene latex 9, tallow amine 1.5, poly-caproic acid.
The preparation method of the metallic anti-rust paint of loaded zirconia, comprises the following steps:
(1) weight part of pressing constitutive material is by epoxy resin, teflon resin, butadiene-styrene latex, zirconium white, modifying cinepazid emulsion, fatty alcohol-polyoxyethylene ether, modified Nano potter's clay and polyacrylic acid mixing and stirring, and high speed dispersion is also ground to below 35um fineness;
(2) in above-mentioned reaction system, add by weight vinegar, stearic acid direactive glyceride, polybutylene terephthalate, poly--4-methyl-1-pentene, Whitfield's ointment, oxygenant 168 and vinyl three ('beta '-methoxy oxyethyl group) silane in tallow amine, poly-caproic acid, at 700-800
turn/
minuteunder rotating speed, high speed dispersion 10-15 minute, obtains finished product.
Described modified Nano potter's clay preparation method is that potter's clay mixes with the anilinomethyl triethoxysilane of 3-5%, be heated to 50-60 ℃ and stir 20-30 minute, then add the nano silicon of 1-3%, high speed dispersion, ovendry power is broken into 300-350 order powder, obtains modified Nano potter's clay.
Described modifying cinepazid emulsion preparation method adds 4-5% magnetic, 3-5% aluminum oxide for adopting in benzene emulsion, is mixed and heated to 70-80 ℃, cooling obtaining after 30-40 minute.
Beneficial effect of the present invention:
The metallic anti-rust paint paint film adhesion of loaded zirconia prepared by the present invention is good, fast drying, good heat resistance, environment friendly and pollution-free, modified Nano potter's clay and modifying cinepazid emulsion in raw material, have been added, by the modification to nanometer potter's clay and benzene emulsion, improved the premium properties of the macromolecular material in starting material, increased erosion resistance and the thermotolerance of product, and preparation method of the present invention has been simple simultaneously, cost is low, is applicable to scale operation.
Embodiment
embodiment:the metallic anti-rust paint of loaded zirconia, the weight part of its constitutive material is: vinegar 18, stearic acid direactive glyceride 0.8, polybutylene terephthalate 0.5, poly--4-methyl-1-pentene 0.8, Whitfield's ointment 0.5, oxygenant 168 0.8, modifying cinepazid emulsion 4, polyacrylic acid 1, vinyl three ('beta '-methoxy oxyethyl group) silane 0.9 and fatty alcohol-polyoxyethylene ether 1.1 in epoxy resin 38, teflon resin 18, modified Nano potter's clay 25, zirconium white 10, butadiene-styrene latex 9, tallow amine 1.5, poly-caproic acid.
The preparation method of the metallic anti-rust paint of loaded zirconia, comprises the following steps:
(1) weight part of pressing constitutive material is by epoxy resin, teflon resin, butadiene-styrene latex, zirconium white, modifying cinepazid emulsion, fatty alcohol-polyoxyethylene ether, modified Nano potter's clay and polyacrylic acid mixing and stirring, and high speed dispersion is also ground to below 35um fineness;
(2) in above-mentioned reaction system, add by weight vinegar, stearic acid direactive glyceride, polybutylene terephthalate, poly--4-methyl-1-pentene, Whitfield's ointment, oxygenant 168 and vinyl three ('beta '-methoxy oxyethyl group) silane in tallow amine, poly-caproic acid, at 700-800
turn/
minuteunder rotating speed, high speed dispersion 10-15 minute, obtains finished product.
Described modified Nano potter's clay preparation method is that potter's clay mixes with the anilinomethyl triethoxysilane of 3-5%, be heated to 50-60 ℃ and stir 20-30 minute, then add the nano silicon of 1-3%, high speed dispersion, ovendry power is broken into 300-350 order powder, obtains modified Nano potter's clay.
Described modifying cinepazid emulsion preparation method adds 4-5% magnetic, 3-5% aluminum oxide for adopting in benzene emulsion, is mixed and heated to 70-80 ℃, cooling obtaining after 30-40 minute.
Adopt the metallic anti-rust paint of embodiment 1 to carry out technology for detection, result is as follows:
1, sticking power/level≤1 grade; 2, snappiness/level: 1 grade; 3, thermotolerance: 335 ℃ excellent; 4, alkali resistance: 20% sodium hydroxide 36 days is excellent; 5, acid resistance 20% sulfuric acid stands intact for 35 days; 6, non-volatile content: >=84.7%.
Claims (2)
1. the metallic anti-rust paint of a loaded zirconia, the weight part that it is characterized in that its constitutive material is: epoxy resin 35-40, teflon resin 15-20, modified Nano potter's clay 23-28, zirconium white 9-11, butadiene-styrene latex 8-10, tallow amine 1.3-1.8, polycaprolactone 15-20, stearic acid direactive glyceride 0.7-0.9, polybutylene terephthalate 0.4-0.6, poly--4-methyl-1-pentene 0.7-0.9, Whitfield's ointment 0.4-0.6, antioxidant 168 0.5-1.0, modifying cinepazid emulsion 3-5, polyacrylic acid 0.8-1.2, vinyl three ('beta '-methoxy oxyethyl group) silane 0.6-1.2 and fatty alcohol-polyoxyethylene ether 1.0-1.2,
Described modified Nano potter's clay preparation method is that potter's clay mixes with the anilinomethyl triethoxysilane of 3-5%, be heated to 50-60 ℃ and stir 20-30 minute, then add the nano silicon of 1-3%, high speed dispersion, ovendry power is broken into 300-350 order powder, obtains modified Nano potter's clay;
Described modifying cinepazid emulsion preparation method adds 4-5% magnetic, 3-5% aluminum oxide for adopting in benzene emulsion, is mixed and heated to 70-80 ℃, cooling obtaining after 30-40 minute;
The preparation method of the metallic anti-rust paint of described loaded zirconia, comprises the following steps:
(1) weight part of pressing constitutive material is by epoxy resin, teflon resin, butadiene-styrene latex, zirconium white, modifying cinepazid emulsion, fatty alcohol-polyoxyethylene ether, modified Nano potter's clay and polyacrylic acid mixing and stirring, and high speed dispersion is also ground to below 35 μ m fineness;
(2) in above-mentioned reaction system, add by weight tallow amine, polycaprolactone, stearic acid direactive glyceride, polybutylene terephthalate, poly--4-methyl-1-pentene, Whitfield's ointment, antioxidant 168 and vinyl three ('beta '-methoxy oxyethyl group) silane, high speed dispersion 10-15 minute under 700-800 rev/min of rotating speed, obtains finished product.
2. the metallic anti-rust paint of loaded zirconia according to claim 1, is characterized in that the weight part of its constitutive material is: epoxy resin 38, teflon resin 18, modified Nano potter's clay 25, zirconium white 10, butadiene-styrene latex 9, tallow amine 1.5, polycaprolactone 18, stearic acid direactive glyceride 0.8, polybutylene terephthalate 0.5, poly--4-methyl-1-pentene 0.8, Whitfield's ointment 0.5, antioxidant 168 0.8, modifying cinepazid emulsion 4, polyacrylic acid 1, vinyl three ('beta '-methoxy oxyethyl group) silane 0.9 and fatty alcohol-polyoxyethylene ether 1.1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210432591.0A CN102977666B (en) | 2012-11-02 | 2012-11-02 | Zirconia loaded metal antirust paint and its preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210432591.0A CN102977666B (en) | 2012-11-02 | 2012-11-02 | Zirconia loaded metal antirust paint and its preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102977666A CN102977666A (en) | 2013-03-20 |
| CN102977666B true CN102977666B (en) | 2014-08-13 |
Family
ID=47852019
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210432591.0A Expired - Fee Related CN102977666B (en) | 2012-11-02 | 2012-11-02 | Zirconia loaded metal antirust paint and its preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102977666B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103642366A (en) * | 2013-11-21 | 2014-03-19 | 江苏博思源防火材料科技有限公司 | Ageing and heat resistant wall coating and preparation method thereof |
| CN104513578A (en) * | 2014-11-28 | 2015-04-15 | 蚌埠南自仪表有限公司 | Lasting antifouling antirusting paint and preparation method thereof |
| CN106479287A (en) * | 2016-09-30 | 2017-03-08 | 合肥华运机械制造有限公司 | A kind of magnetic force pump case coating |
| CN115948082B (en) * | 2022-05-10 | 2024-02-02 | 首牵科技(广州)有限公司 | Water-based antirust paint for metal parts and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101292003A (en) * | 2005-10-20 | 2008-10-22 | 中国涂料株式会社 | Polyfunctional epoxy resin coating composition containing rust-preventive pigment, coating film obtained therefrom, base coated with the coating film, and method of rust prevention |
| CN102260450A (en) * | 2011-02-17 | 2011-11-30 | 湖南晟通科技集团有限公司 | Anticorrosive paint |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5476220B2 (en) * | 2010-06-18 | 2014-04-23 | 関西ペイント株式会社 | Metal rust inhibitor |
-
2012
- 2012-11-02 CN CN201210432591.0A patent/CN102977666B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101292003A (en) * | 2005-10-20 | 2008-10-22 | 中国涂料株式会社 | Polyfunctional epoxy resin coating composition containing rust-preventive pigment, coating film obtained therefrom, base coated with the coating film, and method of rust prevention |
| CN102260450A (en) * | 2011-02-17 | 2011-11-30 | 湖南晟通科技集团有限公司 | Anticorrosive paint |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102977666A (en) | 2013-03-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102977667B (en) | Metal antirust paint containing modified water-soluble nanometer silica sol, and its preparation method | |
| CN102977730B (en) | Metal antirust paint treating modified attapulgite as filler, and its preparation method | |
| CN102977767B (en) | A kind of metallic anti-rust paint containing modified Nano grade titanium dioxide and preparation method thereof | |
| CN102977666B (en) | Zirconia loaded metal antirust paint and its preparation method | |
| CN102352170B (en) | Epoxy polyester metal corrosion resistant paint and preparation method thereof | |
| CN102977665B (en) | Metal antirust paint containing modified pure acrylic emulsion, and its preparation method | |
| CN102977768B (en) | Metal antirust paint prepared from modified phenolic resin, and its preparation method | |
| CN103382366A (en) | High-temperature resistance organic silicon impregnating varnish and preparation method thereof | |
| CN102977724B (en) | Multi-component composite metal antirust paint and its preparation method | |
| CN103131304B (en) | A kind of powder coating containing modified carbide slag | |
| CN104311750A (en) | Styrene modified alkyd resin, preparation method thereof and alkyd resin paint | |
| CN103224745A (en) | Heat-resistant anticorrosive paint and preparation method thereof | |
| CN103409062A (en) | High-temperature-resistant organic silicon impregnating varnish and preparation method thereof | |
| CN104650697A (en) | High temperature resistant nano coating | |
| CN102977664B (en) | Metal antirust paint treating modified diatomite as filler, and its preparation method | |
| CN102942885B (en) | A kind of alcohol type glue economic benefits and social benefits auxiliary agent and its preparation method and application | |
| CN107286588A (en) | A kind of special encapsulating material of LED and its preparation technology | |
| CN102286239B (en) | High molecular epoxy resin metal anticorrosion paint and preparation method thereof | |
| CN104327667B (en) | A kind of preparation method for dry and wet transformator solvent-free Self-leveling iron core coating varnish | |
| CN102352169B (en) | Multi-component metal antirust painting and preparation method thereof | |
| CN102286237B (en) | High molecular metal anticorrosion paint and preparation method thereof | |
| CN102977693B (en) | Metal antirust paint containing modified monoethaneamine benzoate, and its preparation method | |
| CN102977654B (en) | A kind of metallic anti-rust paint containing modified acrylic acid emulsion and preparation method thereof | |
| CN102286247B (en) | Metal anticorrosive paint for automobile parts and preparation method thereof | |
| CN102286238B (en) | Metal anticorrosion paint and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140813 Termination date: 20151102 |
|
| EXPY | Termination of patent right or utility model |