CN104294404B - The manufacture method of three-dimensional crimp bi-component composite hollow aromatic polyester staple fibre - Google Patents
The manufacture method of three-dimensional crimp bi-component composite hollow aromatic polyester staple fibre Download PDFInfo
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- CN104294404B CN104294404B CN201410474128.1A CN201410474128A CN104294404B CN 104294404 B CN104294404 B CN 104294404B CN 201410474128 A CN201410474128 A CN 201410474128A CN 104294404 B CN104294404 B CN 104294404B
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Abstract
The invention provides a kind of manufacture method of three-dimensional crimp bi-component composite hollow aromatic polyester staple fibre, its step comprises: (1), EVA absorption has volatile oiliness essence and swelling; (2), cortex adopts PET, and sandwich layer adopts the blended polymer of EVA of PE and absorption essence, and by core-sheath spinning assembly, adopt spinnerets ejection to have the silk of skin-core structure, unsymmetrical excavation is shaping; (3) the silk super drawing, by previous step spun, heated-air drying after cutting off.The aromatic polyester staple fibre physical and mechanical properties that the present invention makes is equal to generally generally by force stretches cotton polyester staple fiber, can be used for spinning and makes the dulcet textiles of tool, for household textiles, toy, packing material, decorative fabric etc.Sandwich layer hollow can make fragrance continue slow releasing from the two ends of aromatic polyester staple fibre, and the addition of spices can be reduced to 1/3 ~ 1/10 of original technology.The overall cost of fragrant fiber significantly reduces.
Description
Technical field
The present invention relates to a kind of manufacture method of three-dimensional crimp bi-component composite hollow aromatic polyester staple fibre, belong to synthetic fiber technical field.
Background technology
Last century the mid-80, polyester fiber industrialization obtains fast development, meanwhile, also obtains extensive investigation and application to the chemistry of fiber and physical modification technology.Wherein, functional textile and fiber obtain effect in the added value of raising weaving final products with improving in the extension of human body einnehmen function and sensory comfort (nice and cool, warming, the color of vision, the fragrance etc. of sense of smell of body sense).Fragrant fiber belongs to a class of functional fiber, and last century, the mid-80 formed achievement in research and mass production in companies such as Japan.
Different fragrance is known from experience people and is produced different feeling and have physiotherapy, expelling parasite, the feature such as antibacterial concurrently, such as, natural cupressin (Cupressin) is to auxiliary sleep quality and expel acarid effective, eucalyptol (Cineole) infects human respiratory tract and has mitigation, also have sterilization and antibacterial effect concurrently, Jasmine essential oil (Jasmineessential) has function etc. that is excited and warm mood to human body.
Fragrant fiber should have two important features concurrently, one be there is volatile oiliness essence can be more stable and be carried in securely on fiber, after fiber process process (such as combing, heating, washing), still can maintain the fragrance that can experience; Two is the physical and mechanical properties and the serviceability that not exclusively affect fiber itself.Melt spinning is the shaping relatively simple method of chemical fibre, and therefore, fragrant fiber has carried out effective trial and defined many patents on the fundamental technology of melt spinning.
Patent CN101294315 discloses a kind of far infrared flat fibre with fragranced, adds far-infrared powder spinning together with the nanometer odor type microcapsules of 2 ~ 6% of 3.5 ~ 12% particle diameter less than 1 micron, obtain the fiber having far infrared and fragrance concurrently in polyester fondant.Patent CN1594684 discloses blending method and produces fragrant fiber method, adopts polypropylene fragrant masterbatch and polyester to carry out co-blended spinning and obtains fragrant fiber.Patent CN1032874 discloses perfume synthetic fibre and manufacture method thereof, adopts microcapsules technology to be loaded in fiber by fragrance.
Adopt the relative technics comparing of said method simple, low cost of manufacture, but fiber keeps the effect of fragrance undesirable, fiber is through washing and textile process, and loss of aroma is obvious, higher to fiber instructions for use, such as, can not use chemical washing liquid etc.; Patent CN102586943A discloses a kind of sheath-core type aromatic filament of long-acting slow-release, by core-sheath mode, aromatic substance is constrained in sandwich layer to reach the object of slowly-releasing, fiber is made to keep fragrance for a long time, but the fiber of this structure needs fiber high temperature curling in Final finishing step, the physical and mechanical properties of infringement fiber, causes the spinnability of fiber to be obviously deteriorated.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, there is provided a kind of and avoid the curling infringement to fibrous physics mechanical performance of fragrant fiber high-temperature machinery, essence addition is low, lasting fragrance, the manufacture method of wash fast three-dimensional crimp bi-component composite hollow aromatic polyester staple fibre.
The technical solution used in the present invention is: a kind of manufacture method of three-dimensional crimp bi-component composite hollow aromatic polyester staple fibre, and its step comprises:
(1), EVA room temperature or lower than the closed container of 150 DEG C in absorption there is volatile oiliness essence and swelling;
(2), using PET as cortex, spinning temperature 285 ~ 290 DEG C, the method that the EVA of imbibition essence adds as master batch is entered composite spinning casing by twin-screw is blended together with PE, become the sandwich layer of aromatic polyester staple fibre, spinning temperature 190 ~ 220 DEG C, employing spinnerets micropore is the hollow spinneret plate of C type structure, and the winding speed of spinning is 960 ~ 1100m/min, cooling air temperature is 16 ~ 18 DEG C, and wind speed is 4.5 ~ 6m/s;
(3) silk, by previous step spun stretches 4.5 times, and water-bath draft temperature is 60 ~ 70 DEG C, cuts off after oiling, and after cutting off, fiber enters drying equipment, and hot blast temperature is 100 ~ 110 DEG C, makes its sandwich layer hollow and hollow space communicates with ambient atmosphere.
As the preferred technical scheme of the present invention, the raw material weight ratio of sandwich layer and cortex is 10:90 ~ 25:75.
As the preferred technical scheme of the present invention, in described sandwich layer, the part by weight of EVA and PE is 1:1 ~ 1:5.
As the preferred technical scheme of the present invention, described essence addition is 0.01 ~ 0.3% of total weight of fiber.
Manufacture method of the present invention is without the need to machine crimp, self-assembling formation profile can have spiral helicine aromatic polyester staple fibre, and possess the good elasticity of compression and spinning performance, the aromatic polyester staple fibre physical and mechanical properties made is equal to generally generally by force stretches cotton polyester staple fiber, can be used for spinning and make the dulcet textiles of tool, 130 DEG C of disperse dyeing processing can be stood, also Nonwoven Processing Methods can be adopted to make stuffing, for household textiles, toy, packing material, decorative fabric etc.Sandwich layer hollow can make fragrance continue slow releasing from the two ends of aromatic polyester staple fibre, aromatic polyester staple fibre is when repeated multiple times washing, placing half a year more than under natural conditions still can the existence of perception fragrance, compared with technology in the past, the addition of spices can be reduced to 1/3 ~ 1/10 of original technology.The overall cost of fragrant fiber significantly reduces.The raw material weight ratio of sandwich layer and cortex is 10:90 ~ 25:75, can ensure that fiber possesses spinning or non-weaving cloth processing request.
Detailed description of the invention
embodiment 1
Cortex raw material is the regeneration of PET bottle sheet, and intrinsic viscosity is 0.75dl/g, and spinning temperature is 288 ~ 290 DEG C, and consumption is the 80%wt of aromatic polyester staple fibre.
The melt index MFI of sandwich layer high density PE is 24g/10min, and consumption is the 16%wt of aromatic polyester staple fibre.
Sandwich layer EVA consumption is the 3.95%wt of aromatic polyester staple fibre total amount.
(1), EVA powder is placed in airtight rustless steel container, add and account for the Lavender of aromatic polyester staple fibre total amount 0.03%wt and the cupressin of 0.02%wt, hot water jacket heats 50 ~ 60 DEG C, 8 turns per minute of slow stirring, after 8 hours, the essence of observation of liquid state is all absorbed rear taking-up by EVA.
(2), using PET as cortex, spinning temperature 285 ~ 290 DEG C, the method that the EVA of imbibition essence adds as master batch is entered composite spinning casing by twin-screw is blended together with PE, become the sandwich layer of aromatic polyester staple fibre, spinning temperature 200 DEG C, employing spinnerets micropore is the hollow spinneret plate of C type structure, and the winding speed of spinning is 1000m/min, cooling air temperature is 17 DEG C, and wind speed is 5m/s.
(3), post processing: stretching ratio is 4.5 times, and water-bath draft temperature is 65 DEG C, and cut off after oiling, shearing length is 38mm, and after cutting off, fiber enters drying equipment, and hot blast temperature is 105 DEG C, obtains the aromatic polyester staple fibre of hollow.
The fine density of actual measurement of fiber is 2.55dtex, and degree of hollowness is 28.5%, and fracture strength is 4.12cN/dtex, and extension at break is 32.8%.
Adopt this fiber to carry out spinning and obtain 20s stocking yarn, and make knit textile, through the textile dyeing of 130 DEG C of disperse blue conventional polyesters and arrangement, obtain final fragrant textile product.
Evaluation group sense of smell via spices expert composition judges, this aromatic fabric through washing 50 times, place under field conditions (factors) 365 days still savory, and fragrance is pure.
embodiment 2
Cortex raw material is the regeneration of PET bottle sheet, and intrinsic viscosity is 0.72dl/g, and spinning temperature is 288 ~ 290 DEG C, and consumption is the 90%wt of aromatic polyester staple fibre.
The melt index MFI of sandwich layer high density PE is 25g/10min, and consumption is the 5%wt of aromatic polyester staple fibre.
Sandwich layer EVA consumption is the 5%wt of aromatic polyester staple fibre total amount.
(1), EVA(powder) be placed in airtight rustless steel container, add the Rosa Damascana accounting for aromatic polyester staple fibre total amount 0.01%wt, hot water jacket heats 75 ~ 98 DEG C, slowly stirs 5 turns per minute, after 8 hours, the essence of observation of liquid state is all absorbed rear taking-up by EVA.
(2), using PET as cortex, spinning temperature 285 ~ 290 DEG C, the method that the EVA of imbibition essence adds as master batch is entered composite spinning casing by twin-screw is blended together with PE, become the sandwich layer of aromatic polyester staple fibre, spinning temperature 190 DEG C, employing spinnerets micropore is the hollow spinneret plate of C type structure, and the winding speed of spinning is 960m/min, cooling air temperature is 16 DEG C, and wind speed is 4.5m/s.
(3) post processing stretching ratio is 4.5 times, and water-bath draft temperature is 60 DEG C, and cut off after oiling, shearing length is 38mm, and after cutting off, fiber enters drying equipment, and hot blast temperature is 100 DEG C, obtains the aromatic polyester staple fibre of hollow.
The fine density of actual measurement of fiber is 2.48dtex, and degree of hollowness is 27.3%, and fracture strength is 3.95cN/dtex, and extension at break is 32.0%.
Adopt this fiber to carry out spinning and obtain 20s stocking yarn, and make knit textile, through the textile dyeing of 130 DEG C of disperse blue conventional polyesters and arrangement, obtain final fragrant textile product.
Evaluation group sense of smell via spices expert composition judges, this aromatic fabric through washing 50 times, place under field conditions (factors) 200 days still savory, and fragrance is pure.
embodiment 3
Cortex raw material is the regeneration of PET bottle sheet, and intrinsic viscosity is 0.77dl/g, and spinning temperature is 288 ~ 290 DEG C, and consumption is the 75%wt of aromatic polyester staple fibre.
The melt index MFI of sandwich layer high density PE is 24g/10min, and consumption is the 20.8%wt of aromatic polyester staple fibre.
Sandwich layer EVA consumption is the 4.2%wt of aromatic polyester staple fibre total amount.
(1), EVA(powder) be placed in airtight rustless steel container, add the cupressin (Cupressin) of Lavender (Lavender) and the 0.14%wt accounting for aromatic polyester staple fibre total amount 0.16%wt, hot water jacket heats 60 ~ 75 DEG C, 10 turns per minute of slow stirring, after 8 hours, the essence of observation of liquid state is all absorbed rear taking-up by EVA.
(2), using PET as cortex, spinning temperature 290 DEG C, the method that the EVA of imbibition essence adds as master batch is entered composite spinning casing by twin-screw is blended together with PE, become the sandwich layer of aromatic polyester staple fibre, spinning temperature 220 DEG C, employing spinnerets micropore is the hollow spinneret plate of C type structure, and the winding speed of spinning is 1100m/min, cooling air temperature is 18 DEG C, and wind speed is 6m/s.
(3) post processing stretching ratio is 4.5 times, and water-bath draft temperature is 70 DEG C, and cut off after oiling, shearing length is 38mm, and after cutting off, fiber enters drying equipment, and hot blast temperature is 110 DEG C, obtains the aromatic polyester staple fibre of hollow.
The fine density of actual measurement of fiber is 2.52dtex, and degree of hollowness is 28.1%, and fracture strength is 4.04cN/dtex, and extension at break is 30.6%.
Adopt this fiber to carry out spinning and obtain 20s stocking yarn, and make knit textile, through the textile dyeing of 130 DEG C of disperse blue conventional polyesters and arrangement, obtain final fragrant textile product.
Evaluation group sense of smell via spices expert composition judges, this aromatic fabric through washing 80 times, place under field conditions (factors) 400 days still savory, and fragrance is pure.
Claims (2)
1. a manufacture method for three-dimensional crimp bi-component composite hollow aromatic polyester staple fibre, the steps include:
(1), EVA absorption in lower than the closed container of 150 DEG C has volatile oiliness essence and swelling;
(2), using PET as cortex, spinning temperature 285 ~ 290 DEG C, the method that the EVA of imbibition essence adds as master batch is entered composite spinning casing by twin-screw is blended together with PE, become the sandwich layer of aromatic polyester staple fibre, spinning temperature 190 ~ 220 DEG C, employing spinnerets micropore is the hollow spinneret plate of C type structure, and the winding speed of spinning is 960 ~ 1100m/min, cooling air temperature is 16 ~ 18 DEG C, and wind speed is 4.5 ~ 6m/s;
(3), the silk that previous step is spun is stretched 4.5 times, water-bath draft temperature is 60 ~ 70 DEG C, cut off after oiling, after cutting off, fiber enters drying equipment, hot blast temperature is 100 ~ 110 DEG C, make its sandwich layer hollow and hollow space communicates with ambient atmosphere, obtain three-dimensional crimp bi-component composite hollow aromatic polyester staple fibre;
The raw material weight ratio of its center core layer and cortex is 10:90 ~ 25:75, and in described sandwich layer, the part by weight of EVA and PE is 1:1 ~ 1:5.
2. the manufacture method of three-dimensional crimp bi-component composite hollow aromatic polyester staple fibre according to claim 1, is characterized in that: described essence addition is 0.01 ~ 0.3% of total weight of fiber.
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| CN105541149B (en) * | 2015-12-08 | 2018-01-09 | 余姚市交通规划设计研究院 | A kind of modification for bituminous pavement top is the same as the compound fine fibre of core and application |
| US20190289847A1 (en) * | 2016-08-25 | 2019-09-26 | Invista Textiles (U.K.) Limited | Sustained release fibers |
| CN110359129B (en) * | 2019-06-14 | 2022-06-28 | 福建康百赛新材料有限公司 | Preparation method of microporous skin-core structure bi-component composite fiber |
| CN110318117A (en) * | 2019-06-14 | 2019-10-11 | 福建康百赛新材料有限公司 | A kind of health high fluffy PE-PET composite fibre and preparation method thereof |
| CN111118636B (en) * | 2019-12-29 | 2022-03-18 | 江苏恒力化纤股份有限公司 | Preparation method of toy filler |
| TWI761281B (en) * | 2021-08-18 | 2022-04-11 | 康那香企業股份有限公司 | Multi-component side-by-side cooling-feeling composite fiber and cooling-feeling sanitary products |
| CN115233500B (en) * | 2022-08-20 | 2024-01-30 | 肖晓声 | Sustained-release aromatic wallpaper and preparation method thereof |
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| CN1007362B (en) * | 1985-02-27 | 1990-03-28 | 三菱丽阳株式会社 | Fragrant fiber |
| CN1488788A (en) * | 2002-10-10 | 2004-04-14 | 上海香料研究所 | Method for preparing rose-fragrant master batch for perfuming composite fiber |
| DE102005052857A1 (en) * | 2005-11-07 | 2007-05-10 | Saurer Gmbh & Co. Kg | A process for producing core-sheath staple fibers having a three-dimensional crimp, and such a core-sheath staple fiber |
| CN101067222A (en) * | 2007-04-28 | 2007-11-07 | 江苏盛虹化纤有限公司 | Capsule type permanent perfumed filament |
| CN102618960A (en) * | 2012-01-21 | 2012-08-01 | 福建省金纶高纤股份有限公司 | Three-dimensional crimp hollow bamboo charcoal-polyester blended fragrant antimicrobial fiber, and preparation method thereof |
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