CN104292802A - Synthetic plastic - Google Patents
Synthetic plastic Download PDFInfo
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- CN104292802A CN104292802A CN201410543487.8A CN201410543487A CN104292802A CN 104292802 A CN104292802 A CN 104292802A CN 201410543487 A CN201410543487 A CN 201410543487A CN 104292802 A CN104292802 A CN 104292802A
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- synthetic plastics
- ppo
- uhmwpe
- carbon black
- compatilizer
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Abstract
The invention relates to a synthetic plastic. The synthetic plastic is prepared from the following components in percentage by weight: 25-35% of polyphenyl ether, 25-35% of nylon 66, 3-5% of UHMWPE, 15-25% of carbon fibers, 8-12% of carbon black, 5-10% of compatilizer, 5-10% of flexibilizer and 0.5-1.5% of auxiliaries.
Description
Technical field
The invention belongs to polymeric material field, refer to a kind of synthetic plastics especially.
Background technology
PPO (polyphenylene oxide) resin and PA66 (nylon66 fiber) resin are one of widely used engineering plastics.PPO has high heat-resisting, and dimensional stabilizing, electric insulating quality is good, but its processing fluidity is poor, not organic solvent-resistant.PA66 belongs to crystalline material, good fluidity, organic solvent-resistant, but it easily absorbs water, poor dimensional stability.UHMWPE (ultrahigh molecular weight polyethylene(UHMWPE)) is a kind of thermoplastic engineering plastic with Good All-around Property of linear structure.
PPO/PA66 synthetic plastics combines the performance of PPO and PA66, and with the thermotolerance of its excellence, good processibility, can sprayability etc. be used widely.At present, most enhancement type PPO/PA66 synthetic plastics adopts glass fibre to strengthen, and obtained density of material is comparatively large, and strength enhancing is inadequate, does not possess antistatic effect.
Summary of the invention
The object of this invention is to provide a kind of synthetic plastics, solve existing PPO/PA66 synthetic plastics intensity and the not strong problem of antistatic property.
The present invention is achieved through the following technical solutions:
A kind of synthetic plastics, percentage composition comprises following component by weight: the polyphenylene oxide of 25-35%, the nylon66 fiber of 25-35%, the carbon fiber of the UHMWPE of 3-5%, 15-25%, the carbon black of 8-12%, the compatilizer of 5-10%, the toughner of 5-10%, the auxiliary agent of 0.5-1.5%.
Described auxiliary agent includes oxidation inhibitor, lubricant and thermo-stabilizer; Described oxidation inhibitor: lubricant: the weight percent of thermo-stabilizer is 1: 2: 2.
The invention has the beneficial effects as follows:
By doping carbon fiber and carbon black, the intensity of synthetic plastics is improved, synthetic materials antistatic property significantly promotes simultaneously.
Embodiment
The content of the technical program is described in detail below by way of specific embodiment.
In the present invention, described polyphenylene oxide chemical name is poly-2,6-dimethyl-Isosorbide-5-Nitrae-phenylate, is called for short PPO; The chemical name of described nylon66 fiber is poly-adipoyl diamines, is called for short PA66.
Compatilizer is selected from the PPO-g-MAH that percentage of grafting is 0.8-1.5%, polyphenylene oxide grafted maleic anhydride, by adding compatilizer, enhance the interface compatibility of PPO and PA66, interface between carbon fiber, carbon black, PPO and PA66 is mixed more, realizes the Homogeneous phase mixing of each component in PPO/PA66 synthetic plastics.
Toughner is selected from the SEBS-g-MAH that percentage of grafting is 0.8-1.5%, SEBS grafted maleic anhydride, improves toughness and over-all properties by doping plasticizing agent in synthetic plastics.
The length of carbon fiber does not limit, and be preferably short carbon fiber, length is 5-10mm, by doping PPO/PA66 and the synthetic plastics adding UHMWPE, the mechanical property of synthetic plastics is significantly improved, has higher physical strength, antistatic effect promotes simultaneously.Carbon black selects existing carbon black can meet the requirement of technical scheme.
Oxidation inhibitor is selected from triglycol two-3-(the 3-tertiary butyl-4 hydroxy-5-methyl base phenyl), and propylene is fine, four [methyl-β-(3,5-di-t-butyl-4 hydroxy phenyl) propionic ester] pentaerythritol ester, one or more combinations in three (2,4-di-tert-butylphenol) phosphorous acid ester.
Lubricant is selected from one or both combinations in tetramethylolmethane stearate or the two stearic amide of ethyl.
Thermo-stabilizer is selected from one or both combinations in zinc oxide or zinc sulphide.
In all compositions of the application, be not particularly illustrated, the equal weight percentage of consumption is calculated.
Embodiment 1
By the PPO of 25%, the PA66 of 35%, the UHMWPE of 3%, the compatilizer of 6%, the toughner mixing of 5%, stirs; Add the carbon black of 8% again, the auxiliary agent of 1% stirs, and obtains mixture, and this mixture being joined length-to-diameter ratio is in the twin screw extruder of 25-40, joins in forcing machine by the carbon fiber of 17%, and through melt blending, extruding pelletization, forms synthetic plastics.
Embodiment 2
By the PPO of 35%, the PA66 of 25%, the UHMWPE of 5%, the compatilizer of 6%, the toughner mixing of 5%, stirs; Add the carbon black of 8% again, the auxiliary agent of 1% stirs, and obtains mixture, and this mixture being joined length-to-diameter ratio is in the twin screw extruder of 25-40, joins in forcing machine by the carbon fiber of 15%, and through melt blending, extruding pelletization, forms synthetic plastics.
Embodiment 3
By the PPO of 30%, the PA66 of 30%, the UHMWPE of 4%, the compatilizer of 6%, 5% toughner mixing, stirs; Add the carbon black of 9% again, the auxiliary agent of 1% stirs, and obtains mixture, and this mixture being joined length-to-diameter ratio is in the twin screw extruder of 25-40, joins in forcing machine by the carbon fiber of 15%, and through melt blending, extruding pelletization, forms synthetic plastics.
Claims (2)
1. a synthetic plastics, is characterized in that: percentage composition comprises following component by weight: the polyphenylene oxide of 25-35%, the nylon66 fiber of 25-35%, the carbon fiber of the UHMWPE of 3-5%, 15-25%, the carbon black of 8-12%, the compatilizer of 5-10%, the toughner of 5-10%, the auxiliary agent of 0.5-1.5%.
2. synthetic plastics according to claim 1, is characterized in that: described auxiliary agent includes oxidation inhibitor, lubricant and thermo-stabilizer; Described oxidation inhibitor: lubricant: the weight percent of thermo-stabilizer is 1: 2: 2.
Priority Applications (1)
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CN201410543487.8A CN104292802A (en) | 2014-10-14 | 2014-10-14 | Synthetic plastic |
Applications Claiming Priority (1)
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CN201410543487.8A CN104292802A (en) | 2014-10-14 | 2014-10-14 | Synthetic plastic |
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CN104292802A true CN104292802A (en) | 2015-01-21 |
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CN201410543487.8A Pending CN104292802A (en) | 2014-10-14 | 2014-10-14 | Synthetic plastic |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104277447A (en) * | 2014-10-14 | 2015-01-14 | 杨雯雯 | Synthetic plastic and preparation method thereof |
CN105295350A (en) * | 2015-11-03 | 2016-02-03 | 虞惠财 | Anti-static electric synthesized plastic |
CN105295349A (en) * | 2015-11-03 | 2016-02-03 | 虞惠财 | Antistatic plastic and preparation method thereof |
CN106488956A (en) * | 2015-03-10 | 2017-03-08 | 株式会社Lg化学 | Modified poly- (arylene ether) resin combination and the mechanograph prepared by poly- (arylene ether) resin combination of the modification |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102311633A (en) * | 2011-04-29 | 2012-01-11 | 深圳市科聚新材料有限公司 | PPO/PA66 (poly phenylene oxide/polyamide 66) alloy material as well as preparation method and application thereof |
CN102863775A (en) * | 2012-09-05 | 2013-01-09 | 忻峰 | PPO (Poly-P-Phenylene Oxide)/PA66 (Polyamide 66) plastic |
CN102863776A (en) * | 2012-09-05 | 2013-01-09 | 忻峰 | Polyphenylene oxide/polyamide 66 (PPO/PA66) synthetic plastic |
CN102863773A (en) * | 2012-09-05 | 2013-01-09 | 徐琼 | Preparation method of polyphenylene oxide/polyamide 66 (PPO/PA66) synthetic plastic |
CN102863774A (en) * | 2012-09-05 | 2013-01-09 | 徐琼 | PPO (Poly-P-Phenylene Oxide) and PA66 (Polyamide 66) plastic |
CN102964806A (en) * | 2012-12-04 | 2013-03-13 | 上海日之升新技术发展有限公司 | Reinforced high heat resistance and conductivity polyphenyl ether nylon alloy and preparation method thereof |
CN103073874A (en) * | 2012-09-05 | 2013-05-01 | 陈敏 | PPO/PA66 synthetic plastic and preparation method thereof |
CN103087500A (en) * | 2012-10-22 | 2013-05-08 | 虞海香 | PA66 (polyamide 66) plastic |
CN104072974A (en) * | 2014-06-25 | 2014-10-01 | 周开雄 | Preparation method of PPO-PA66 synthetic plastic |
-
2014
- 2014-10-14 CN CN201410543487.8A patent/CN104292802A/en active Pending
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102311633A (en) * | 2011-04-29 | 2012-01-11 | 深圳市科聚新材料有限公司 | PPO/PA66 (poly phenylene oxide/polyamide 66) alloy material as well as preparation method and application thereof |
CN102863775A (en) * | 2012-09-05 | 2013-01-09 | 忻峰 | PPO (Poly-P-Phenylene Oxide)/PA66 (Polyamide 66) plastic |
CN102863776A (en) * | 2012-09-05 | 2013-01-09 | 忻峰 | Polyphenylene oxide/polyamide 66 (PPO/PA66) synthetic plastic |
CN102863773A (en) * | 2012-09-05 | 2013-01-09 | 徐琼 | Preparation method of polyphenylene oxide/polyamide 66 (PPO/PA66) synthetic plastic |
CN102863774A (en) * | 2012-09-05 | 2013-01-09 | 徐琼 | PPO (Poly-P-Phenylene Oxide) and PA66 (Polyamide 66) plastic |
CN103073874A (en) * | 2012-09-05 | 2013-05-01 | 陈敏 | PPO/PA66 synthetic plastic and preparation method thereof |
CN103087500A (en) * | 2012-10-22 | 2013-05-08 | 虞海香 | PA66 (polyamide 66) plastic |
CN102964806A (en) * | 2012-12-04 | 2013-03-13 | 上海日之升新技术发展有限公司 | Reinforced high heat resistance and conductivity polyphenyl ether nylon alloy and preparation method thereof |
CN104072974A (en) * | 2014-06-25 | 2014-10-01 | 周开雄 | Preparation method of PPO-PA66 synthetic plastic |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104277447A (en) * | 2014-10-14 | 2015-01-14 | 杨雯雯 | Synthetic plastic and preparation method thereof |
CN106488956A (en) * | 2015-03-10 | 2017-03-08 | 株式会社Lg化学 | Modified poly- (arylene ether) resin combination and the mechanograph prepared by poly- (arylene ether) resin combination of the modification |
US10329423B2 (en) | 2015-03-10 | 2019-06-25 | Lg Chem, Ltd. | Modified poly(arylene ether) resin composition and molded article produced thereof |
CN106488956B (en) * | 2015-03-10 | 2019-11-12 | 株式会社Lg化学 | Modified poly- (arylene ether) resin combination and the mechanograph prepared by poly- (arylene ether) resin combination of the modification |
CN105295350A (en) * | 2015-11-03 | 2016-02-03 | 虞惠财 | Anti-static electric synthesized plastic |
CN105295349A (en) * | 2015-11-03 | 2016-02-03 | 虞惠财 | Antistatic plastic and preparation method thereof |
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Application publication date: 20150121 |