CN104292600B - 一种腐植酸/eva树脂共混改性可降解固态地膜 - Google Patents
一种腐植酸/eva树脂共混改性可降解固态地膜 Download PDFInfo
- Publication number
- CN104292600B CN104292600B CN201410487320.4A CN201410487320A CN104292600B CN 104292600 B CN104292600 B CN 104292600B CN 201410487320 A CN201410487320 A CN 201410487320A CN 104292600 B CN104292600 B CN 104292600B
- Authority
- CN
- China
- Prior art keywords
- humic acids
- eva resin
- mulch film
- modifying
- blending
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000004021 humic acid Substances 0.000 title claims abstract description 48
- 229920005989 resin Polymers 0.000 title claims abstract description 34
- 239000011347 resin Substances 0.000 title claims abstract description 34
- 238000002156 mixing Methods 0.000 title claims abstract description 31
- 239000002362 mulch Substances 0.000 title claims abstract description 25
- 239000004014 plasticizer Substances 0.000 claims abstract description 13
- 239000008188 pellet Substances 0.000 claims abstract description 12
- 239000000314 lubricant Substances 0.000 claims abstract description 10
- 239000002904 solvent Substances 0.000 claims abstract description 10
- 238000002360 preparation method Methods 0.000 claims abstract description 5
- 238000010438 heat treatment Methods 0.000 claims abstract description 3
- 239000011259 mixed solution Substances 0.000 claims abstract description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 claims description 6
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 5
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 5
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 5
- 239000008116 calcium stearate Substances 0.000 claims description 5
- 235000013539 calcium stearate Nutrition 0.000 claims description 5
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 5
- PESZCXUNMKAYME-UHFFFAOYSA-N Citroflex A-4 Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)C(C(C)=O)C(=O)OCCCC PESZCXUNMKAYME-UHFFFAOYSA-N 0.000 claims description 4
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 4
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 4
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 4
- VLTOSDJJTWPWLS-UHFFFAOYSA-N pent-2-ynal Chemical compound CCC#CC=O VLTOSDJJTWPWLS-UHFFFAOYSA-N 0.000 claims description 4
- 125000005456 glyceride group Chemical group 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 235000019359 magnesium stearate Nutrition 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 6
- 239000005038 ethylene vinyl acetate Substances 0.000 description 20
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 20
- 238000005516 engineering process Methods 0.000 description 5
- 239000002689 soil Substances 0.000 description 4
- 238000012271 agricultural production Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 125000004151 quinonyl group Chemical group 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- GPLIMIJPIZGPIF-UHFFFAOYSA-N 2-hydroxy-1,4-benzoquinone Chemical compound OC1=CC(=O)C=CC1=O GPLIMIJPIZGPIF-UHFFFAOYSA-N 0.000 description 1
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000012675 alcoholic extract Substances 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 150000002085 enols Chemical class 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000003864 humus Substances 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G13/00—Protecting plants
- A01G13/02—Protective coverings for plants; Coverings for the ground; Devices for laying-out or removing coverings
- A01G13/0256—Ground coverings
- A01G13/0268—Mats or sheets, e.g. nets or fabrics
- A01G13/0275—Films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L99/00—Compositions of natural macromolecular compounds or of derivatives thereof not provided for in groups C08L89/00 - C08L97/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Biological Depolymerization Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410487320.4A CN104292600B (zh) | 2014-09-22 | 2014-09-22 | 一种腐植酸/eva树脂共混改性可降解固态地膜 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410487320.4A CN104292600B (zh) | 2014-09-22 | 2014-09-22 | 一种腐植酸/eva树脂共混改性可降解固态地膜 |
Publications (2)
Publication Number | Publication Date |
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CN104292600A CN104292600A (zh) | 2015-01-21 |
CN104292600B true CN104292600B (zh) | 2016-08-17 |
Family
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Family Applications (1)
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CN201410487320.4A Active CN104292600B (zh) | 2014-09-22 | 2014-09-22 | 一种腐植酸/eva树脂共混改性可降解固态地膜 |
Country Status (1)
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CN (1) | CN104292600B (zh) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104672700B (zh) * | 2015-02-04 | 2017-02-08 | 南京悠谷知识产权服务有限公司 | 一种聚氯乙烯材料及其制备方法 |
KR101899665B1 (ko) * | 2015-11-27 | 2018-09-17 | 주식회사 엘지화학 | 가소제 조성물, 수지 조성물 및 이들의 제조 방법 |
CN108264681A (zh) * | 2017-12-19 | 2018-07-10 | 潍坊友容实业有限公司 | 盐碱土壤栽培用可降解地膜 |
CN108265565B (zh) * | 2018-01-08 | 2021-03-23 | 云南云景林纸股份有限公司 | 一种废纸基地膜及其制备方法 |
CN108373563A (zh) * | 2018-03-28 | 2018-08-07 | 方建波 | 一种可生物降解农膜的制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101481508A (zh) * | 2008-01-11 | 2009-07-15 | 山东科技大学 | 一种腐植酸多功能可降解黑色地膜 |
CN101589681A (zh) * | 2009-07-10 | 2009-12-02 | 李保华 | 完全降解地膜及其生产方法 |
CN103059394A (zh) * | 2012-12-14 | 2013-04-24 | 青岛鑫万通塑业发展有限公司 | 一种聚氯乙烯蔬菜地膜 |
CN103373879A (zh) * | 2013-07-10 | 2013-10-30 | 湖南中烟工业有限责任公司 | 一种烟草专用可降解固体地膜及其制备方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS51114229A (en) * | 1975-03-31 | 1976-10-07 | Tokyo Printing Ink Mfg Co Ltd | Greenncolored malching film for farming |
JPS5421430A (en) * | 1977-07-20 | 1979-02-17 | Three Bond Co Ltd | Rusttpreventive coating composition |
-
2014
- 2014-09-22 CN CN201410487320.4A patent/CN104292600B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101481508A (zh) * | 2008-01-11 | 2009-07-15 | 山东科技大学 | 一种腐植酸多功能可降解黑色地膜 |
CN101589681A (zh) * | 2009-07-10 | 2009-12-02 | 李保华 | 完全降解地膜及其生产方法 |
CN103059394A (zh) * | 2012-12-14 | 2013-04-24 | 青岛鑫万通塑业发展有限公司 | 一种聚氯乙烯蔬菜地膜 |
CN103373879A (zh) * | 2013-07-10 | 2013-10-30 | 湖南中烟工业有限责任公司 | 一种烟草专用可降解固体地膜及其制备方法 |
Non-Patent Citations (1)
Title |
---|
腐植酸多功能可降解黑色液态地膜的应用研究;乔英云等;《腐植酸》;20060225(第1期);第17-19页 * |
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Publication number | Publication date |
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CN104292600A (zh) | 2015-01-21 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C41 | Transfer of patent application or patent right or utility model | ||
CB03 | Change of inventor or designer information |
Inventor after: Zhang Xiru Inventor after: Peng Hongying Inventor after: Luo Zhigang Inventor after: Sui Yan Inventor after: Hu Ronghua Inventor after: Wen Jiwu Inventor before: Luo Zhigang Inventor before: Sui Yan Inventor before: Hu Ronghua Inventor before: Wen Jiwu |
|
COR | Change of bibliographic data | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20150916 Address after: The North Industrial Park of Ji'an city of Jiangxi province Xingan County 331300 Applicant after: JIANGXI SHUANGJIA TECHNOLOGY DEVELOPMENT CO., LTD. Address before: 343009 Ji'an City, Jiangxi province Qingyuan District School Road No. 28 Applicant before: Jinggangshan University |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CP01 | Change in the name or title of a patent holder | ||
CP01 | Change in the name or title of a patent holder |
Address after: The North Industrial Park of Ji'an city of Jiangxi province Xingan County 331300 Patentee after: Jiangxi Shuangjia Technology Co.,Ltd. Address before: The North Industrial Park of Ji'an city of Jiangxi province Xingan County 331300 Patentee before: JIANGXI SHUANGJIA TECHNOLOGY DEVELOPMENT Co.,Ltd. |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A kind of degradable solid mulch film modified by humic acid / EVA resin blending Effective date of registration: 20201218 Granted publication date: 20160817 Pledgee: Jiangxi Xingan Rural Commercial Bank Co.,Ltd. Pledgor: Jiangxi Shuangjia Technology Co.,Ltd. Registration number: Y2020980009525 |