CN104277620A - Environment-friendly wall coating - Google Patents

Environment-friendly wall coating Download PDF

Info

Publication number
CN104277620A
CN104277620A CN201410449251.8A CN201410449251A CN104277620A CN 104277620 A CN104277620 A CN 104277620A CN 201410449251 A CN201410449251 A CN 201410449251A CN 104277620 A CN104277620 A CN 104277620A
Authority
CN
China
Prior art keywords
parts
minute
add
deionized water
obtains
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410449251.8A
Other languages
Chinese (zh)
Inventor
夏明才
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Lulei Chemical (lu'an) Co Ltd
Original Assignee
Shanghai Lulei Chemical (lu'an) Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Lulei Chemical (lu'an) Co Ltd filed Critical Shanghai Lulei Chemical (lu'an) Co Ltd
Priority to CN201410449251.8A priority Critical patent/CN104277620A/en
Publication of CN104277620A publication Critical patent/CN104277620A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C09D131/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C08F218/08—Vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses an environment-friendly wall coating which is prepared from the following raw materials in parts by weight: 2-3 parts of polypropylene oxide glycol, 1-2 parts of propylgallate, 0.8-1 part of seed oil of camellia oleifera abel, 0.7-1 part of n-salicylanilide, 1-2 parts of calcium lactate, 2-3 parts of palm wax, 3-4 parts of polypropylene glycol adipate, 2-3 parts of polytetrafluoroethylene, 0.7-2 parts of polybenzimidazole, 5-7 parts of attapulgite, 10-13 parts of feldspar powder, 100-140 parts of butyl acrylate, 160-200 parts of vinyl acetate, 4-6 parts of polyvinyl alcohol, 0.5-2 parts of potassium persulfate, 500-700 parts of deionized water, 2-4 parts of sodium dodecyl sulfate and 4-6 parts of a bonding auxiliary. The coating disclosed by the invention is good in environment-friendliness and free of volatile toxic substances, can be widely applied to brushing indoor and outdoor exterior walls, further has killing and inhibiting effects on some microorganisms and is strong in weather resistance and good in bonding strength and resistance.

Description

A kind of environmental protection wall surface coating
?
Technical field
The present invention relates generally to paint field, particularly relates to a kind of environmental protection wall surface coating.
Background technology
Be applied to body surface can be formed there is protection, the class I liquid I of solid-state film of decoration or property (as insulation, anticorrosion, mark etc.) or the general name of solid material, comprise oil (property) paint, water-miscible paint, powder coating.Paint is flowable liquid coating, comprises oil (property) paint and water-miscible paint.Paint take organic solvent as medium or high solid, solvent-free oil-base paint.Water-miscible paint is used water dissolving or the coating with water-dispersion.Coating is as one of the main material of house decoration, and the large percentage accounted in decorations, buys the whether qualified environment directly having influence on overall finishing effect and room of coating, sometimes even can produce harm greatly to the health of human body.At present along with the generation of various coating, the quality requirements of coating is also improved constantly, and improve constantly coating quality and can play very large help for building, life.
Summary of the invention
The object of the invention is just to provide a kind of environmental protection wall surface coating.
The present invention is achieved by the following technical solutions:
A kind of environmental protection wall surface coating, is characterized in that what it was made up of the raw material of following weight parts:
Polyoxypropyleneglycol 2-3, Tenox PG 1-2, Chinese vegetable tallow 0.8-1, n-Salicylanlide 0.7-1, calcium lactate 1-2, palm wax 2-3, hexanodioic acid propanediol polyester 3-4, tetrafluoroethylene 2-3, polybenzimidazole 0.7-2, attapulgite 5-7, feldspar in powder 10-13, butyl acrylate 100-140, vinyl acetate 160-200, polyvinyl alcohol 4-6, Potassium Persulphate 0.5-2, deionized water 500-700, sodium laurylsulfonate 2-4, adhesive aid 4-6;
Described adhesive aid is made up of each raw material of following weight parts:
Organosilicon crylic acid latex 30-35, methyl methacrylate 2-4, exsiccated ammonium alum 1-2, emulsifier op-10 0.5-1, ammonium persulphate 0.7-1, Triethylene glycol dimethacrylate 2-3, triolein 1-2, titania powder 2-4, deionized water 10-14;
By titania powder, Triethylene glycol dimethacrylate, triolein mixing, 3-4 minute is uniformly mixed at 70-75 DEG C, add 40-50%, the ammonium persulphate of above-mentioned deionized water weight, 100-150 rev/min of dispersed with stirring 10-13 minute, obtains dispersion liquid;
Emulsifier op-10 and exsiccated ammonium alum are mixed to join in remaining deionized water, at 60-70 DEG C, are uniformly mixed 3-5 minute, add methyl methacrylate, dispersion liquid, be stirred to normal temperature, add each raw material of residue, obtain described adhesive aid.
A preparation method for environmental protection wall surface coating, comprises the following steps:
(1) mixed by the 10-15% of Potassium Persulphate with above-mentioned deionized water weight, stirring and dissolving, obtains initiator solution;
(2) by sodium laurylsulfonate, polyoxypropyleneglycol, Tenox PG, polyvinyl alcohol mixing, add the 70-80% of residue deionized water weight, insulated and stirred 30-40 minute at 80-90 DEG C, is cooled to normal temperature, obtains pre-emulsion;
(3) the 40-50% mixing of the 30-40% of aforesaid propylene acid butyl ester weight, vinyl acetate weight is got, add above-mentioned pre-emulsion, 30-35 minute is uniformly mixed at 60-65 DEG C, raised temperature is 70-75 DEG C, add above-mentioned initiator solution, treat that emulsion is blue phase, insulation 60-70 minute, obtains seed emulsion;
(4) by remaining butyl acrylate, vinyl acetate mixing, add palm wax, hexanodioic acid propanediol polyester, insulated and stirred 20-30 minute at 70-80 DEG C, obtains mix monomer;
(5) in above-mentioned seed emulsion, add dropping mix monomer, time for adding is 90-120 minute, after dropwising, at 80-90 DEG C, is incubated 50-60 minute, cooling, filters discharging with 200-250 eye mesh screen;
(6) material above-mentioned steps (5) obtained mixes with each raw material of residue, and 800-1200 rev/min of dispersed with stirring 20-30 minute, obtains described environmental protection wall surface coating.
Advantage of the present invention is:
The coating feature of environmental protection of the present invention is good, not containing volatile toxic substance, can be widely used in indoor and outdoor body of wall brushing, and for the effect that some microorganisms also have killing and suppress, durability of coating is strong, cohesive strength, better resistance.The titania powder added in adhesive aid of the present invention can improve resistivity against fire and surface resistive, methyl methacrylate, exsiccated ammonium alum, emulsifier op-10, triolein mix with organosilicon crylic acid latex and effectively can improve cohesive strength, ammonium persulphate can promote the consistency between each raw material, improves the surface stability of finished product.
Embodiment
Embodiment 1
A kind of environmental protection wall surface coating, is characterized in that what it was made up of the raw material of following weight parts:
Polyoxypropyleneglycol 3, Tenox PG 2, Chinese vegetable tallow 0.8, n-Salicylanlide 0.7-, calcium lactate 2, palm wax 2, hexanodioic acid propanediol polyester 4, tetrafluoroethylene 3, polybenzimidazole 0.7, attapulgite 7, feldspar in powder 13, butyl acrylate 140, vinyl acetate 200, polyvinyl alcohol 4, Potassium Persulphate 0.5, deionized water 500, sodium laurylsulfonate 2-4, adhesive aid 4;
Described adhesive aid is made up of each raw material of following weight parts:
Organosilicon crylic acid latex 35, methyl methacrylate 2, exsiccated ammonium alum 2, emulsifier op-10 0.5, ammonium persulphate 0.7, Triethylene glycol dimethacrylate 2, triolein 2, titania powder 2, deionized water 14;
By titania powder, Triethylene glycol dimethacrylate, triolein mixing, at 75 DEG C, be uniformly mixed 4 minutes, add 40-50%, the ammonium persulphate of above-mentioned deionized water weight, 150 revs/min of dispersed with stirring 13 minutes, obtain dispersion liquid;
Emulsifier op-10 and exsiccated ammonium alum are mixed to join in remaining deionized water, at 70 DEG C, are uniformly mixed 3 minutes, add methyl methacrylate, dispersion liquid, be stirred to normal temperature, add each raw material of residue, obtain described adhesive aid.
A preparation method for environmental protection wall surface coating, is characterized in that comprising the following steps:
(1) mixed with 15% of above-mentioned deionized water weight by Potassium Persulphate, stirring and dissolving, obtains initiator solution;
(2) by sodium laurylsulfonate, polyoxypropyleneglycol, Tenox PG, polyvinyl alcohol mixing, add 80% of residue deionized water weight, at 90 DEG C, insulated and stirred 40 minutes, is cooled to normal temperature, obtains pre-emulsion;
(3) get 40% of aforesaid propylene acid butyl ester weight, 50% mixing of vinyl acetate weight, add above-mentioned pre-emulsion, at 65 DEG C, be uniformly mixed 35 minutes, raised temperature is 75 DEG C, adds above-mentioned initiator solution, treats that emulsion is blue phase, be incubated 70 minutes, obtain seed emulsion;
(4) by remaining butyl acrylate, vinyl acetate mixing, add palm wax, hexanodioic acid propanediol polyester, at 80 DEG C, insulated and stirred 30 minutes, obtains mix monomer;
(5) in above-mentioned seed emulsion, add dropping mix monomer, time for adding is 120 minutes, after dropwising, at 90 DEG C, be incubated 60 minutes, and cooling filters discharging with 250 eye mesh screens;
(6) material above-mentioned steps (5) obtained mixes with each raw material of residue, and 1200 revs/min of dispersed with stirring 30 minutes, obtain described environmental protection wall surface coating.
Performance test:
Unit elongation: >=300%;
Watertightness: 0.3MPa (one hour waterproof).

Claims (2)

1. an environmental protection wall surface coating, is characterized in that what it was made up of the raw material of following weight parts:
Polyoxypropyleneglycol 2-3, Tenox PG 1-2, Chinese vegetable tallow 0.8-1, n-Salicylanlide 0.7-1, calcium lactate 1-2, palm wax 2-3, hexanodioic acid propanediol polyester 3-4, tetrafluoroethylene 2-3, polybenzimidazole 0.7-2, attapulgite 5-7, feldspar in powder 10-13, butyl acrylate 100-140, vinyl acetate 160-200, polyvinyl alcohol 4-6, Potassium Persulphate 0.5-2, deionized water 500-700, sodium laurylsulfonate 2-4, adhesive aid 4-6;
Described adhesive aid is made up of each raw material of following weight parts:
Organosilicon crylic acid latex 30-35, methyl methacrylate 2-4, exsiccated ammonium alum 1-2, emulsifier op-10 0.5-1, ammonium persulphate 0.7-1, Triethylene glycol dimethacrylate 2-3, triolein 1-2, titania powder 2-4, deionized water 10-14;
By titania powder, Triethylene glycol dimethacrylate, triolein mixing, 3-4 minute is uniformly mixed at 70-75 DEG C, add 40-50%, the ammonium persulphate of above-mentioned deionized water weight, 100-150 rev/min of dispersed with stirring 10-13 minute, obtains dispersion liquid;
Emulsifier op-10 and exsiccated ammonium alum are mixed to join in remaining deionized water, at 60-70 DEG C, are uniformly mixed 3-5 minute, add methyl methacrylate, dispersion liquid, be stirred to normal temperature, add each raw material of residue, obtain described adhesive aid.
2. a preparation method for environmental protection wall surface coating as claimed in claim 1, is characterized in that comprising the following steps:
(1) mixed by the 10-15% of Potassium Persulphate with above-mentioned deionized water weight, stirring and dissolving, obtains initiator solution;
(2) by sodium laurylsulfonate, polyoxypropyleneglycol, Tenox PG, polyvinyl alcohol mixing, add the 70-80% of residue deionized water weight, insulated and stirred 30-40 minute at 80-90 DEG C, is cooled to normal temperature, obtains pre-emulsion;
(3) the 40-50% mixing of the 30-40% of aforesaid propylene acid butyl ester weight, vinyl acetate weight is got, add above-mentioned pre-emulsion, 30-35 minute is uniformly mixed at 60-65 DEG C, raised temperature is 70-75 DEG C, add above-mentioned initiator solution, treat that emulsion is blue phase, insulation 60-70 minute, obtains seed emulsion;
(4) by remaining butyl acrylate, vinyl acetate mixing, add palm wax, hexanodioic acid propanediol polyester, insulated and stirred 20-30 minute at 70-80 DEG C, obtains mix monomer;
(5) in above-mentioned seed emulsion, add dropping mix monomer, time for adding is 90-120 minute, after dropwising, at 80-90 DEG C, is incubated 50-60 minute, cooling, filters discharging with 200-250 eye mesh screen;
(6) material above-mentioned steps (5) obtained mixes with each raw material of residue, and 800-1200 rev/min of dispersed with stirring 20-30 minute, obtains described environmental protection wall surface coating.
CN201410449251.8A 2014-09-04 2014-09-04 Environment-friendly wall coating Pending CN104277620A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410449251.8A CN104277620A (en) 2014-09-04 2014-09-04 Environment-friendly wall coating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410449251.8A CN104277620A (en) 2014-09-04 2014-09-04 Environment-friendly wall coating

Publications (1)

Publication Number Publication Date
CN104277620A true CN104277620A (en) 2015-01-14

Family

ID=52252986

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410449251.8A Pending CN104277620A (en) 2014-09-04 2014-09-04 Environment-friendly wall coating

Country Status (1)

Country Link
CN (1) CN104277620A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106366713A (en) * 2016-08-26 2017-02-01 安徽钰锦生态木材料有限公司 Delicate-fragrant-type environment-friendly wall surface coating
CN110379292A (en) * 2019-07-13 2019-10-25 广州彩邦印刷有限公司 High temperature resistant labels

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1454949A (en) * 2003-05-19 2003-11-12 复旦大学 Self-cleaning external wall organic coating for building and preparing method thereof
CN1696219A (en) * 2004-05-11 2005-11-16 张海波 Environmental protection type Nano Coating
CN103965716A (en) * 2014-02-28 2014-08-06 北京东方雨虹防水技术股份有限公司 Water-based quick-drying acrylic acid protective coating and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1454949A (en) * 2003-05-19 2003-11-12 复旦大学 Self-cleaning external wall organic coating for building and preparing method thereof
CN1696219A (en) * 2004-05-11 2005-11-16 张海波 Environmental protection type Nano Coating
CN103965716A (en) * 2014-02-28 2014-08-06 北京东方雨虹防水技术股份有限公司 Water-based quick-drying acrylic acid protective coating and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106366713A (en) * 2016-08-26 2017-02-01 安徽钰锦生态木材料有限公司 Delicate-fragrant-type environment-friendly wall surface coating
CN110379292A (en) * 2019-07-13 2019-10-25 广州彩邦印刷有限公司 High temperature resistant labels
CN110379292B (en) * 2019-07-13 2021-06-25 广州彩邦印刷有限公司 High temperature resistant label

Similar Documents

Publication Publication Date Title
CN104449121A (en) Antibacterial anticorrosive coating
CN104263122A (en) Stable paint
CN104263125A (en) Polymer exterior wall paint
CN104277620A (en) Environment-friendly wall coating
CN104231695A (en) Green antibacterial coating for interior wall
CN104250504A (en) High-viscosity silicone-acrylic paint
CN104263036A (en) Bactericidal organic silicon coating
CN104277619A (en) Hydrophobic self-cleaning paint
CN104263127A (en) Insulating crack-resistant coating for exterior wall
CN104277621A (en) Waterproof coating for building
CN104263128A (en) Resin-base paint
CN104263031A (en) Smooth bubble-free decorative paint
CN104231771A (en) Lightweight coating
CN104250481A (en) Refreshing environment-friendly paint
CN104231770A (en) Fireproof coating
CN104231766A (en) Sound-absorbing and heat-insulating paint
CN104263138A (en) Soft antibacterial coating
CN104356835A (en) Macromolecular emulsion paint
CN104263112A (en) Fluorine-containing styrene-acrylic coating
CN104356703A (en) Decorative type hard coating
CN104250506A (en) Yellowing-resistant paint
CN104231828A (en) Green and natural antibacterial coating
CN104263139A (en) Fiber-reinforced paint
CN104449115A (en) Flexible fluorinated coating
CN106280950A (en) Waterborne wall surface paint preparation method

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20150114

RJ01 Rejection of invention patent application after publication